Halogen Acids Patents (Class 8/634)
  • Patent number: 6689175
    Abstract: In a preferred embodiment, the present process involves subjecting a fabric comprised of conjugate yarns to an acidic treatment, which degrades a portion of one component of the conjugate yarns and to dyeing. The acid treatment, given certain reaction kinetics, removes a portion of the polyamide element of the conjugate filament. The at least partial removal of the polyamide component results in a fabric has enhanced dyed appearance, especially when dyed a dark shade. In an alternate embodiment, the fabric may also be treated with a basic solution to improve its moisture transport properties.
    Type: Grant
    Filed: February 12, 2002
    Date of Patent: February 10, 2004
    Assignee: Milliken & Company
    Inventors: Heather J. Hayes, Crystal A. Garner, Kirkland W. Vogt, Kaushal Gandhi
  • Patent number: 6533826
    Abstract: Process for preparing aqueous solutions of cationic di- and triarylmethane dyes by the aqueous dye solution, which contains organic solvents, being concentrated by nanofiltration and optionally diluted with water.
    Type: Grant
    Filed: February 8, 2001
    Date of Patent: March 18, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Thomas Gessner, Gunter-Rudolf Schröder, Robert Reinhardt
  • Patent number: 6221113
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25° C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: April 24, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Jürgen Geiwiz
  • Patent number: 5944856
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: August 31, 1999
    Assignee: Clariant Finanace (BVI) Limited
    Inventor: Jurgen Geiwiz
  • Patent number: 5616151
    Abstract: A method for the adjustment of pH in textile processing solutions that includes the use of urea sulfate or other strong acid in the presence of a weak base.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: April 1, 1997
    Assignee: Peach State Labs, Inc.
    Inventors: R. Richard Sargent, Jeffrey R. Alender
  • Patent number: 5525123
    Abstract: This invention comprises a hair dyeing composition based on oxidation dyestuff precursors which dyes and brightens the hair containing, besides at least one developing and at least one coupling agent, at least one metal salt and at least one ammonium compound selected from the group ammonium chloride, ammonium sulfate, ammonium carbonate, ammonium bicarbonate, and ammonium carbamate, having a pH-value between 8 and 11, preferably from 9 to 10, after admixture with an oxidizing agent in the ready-to-use preparation.
    Type: Grant
    Filed: September 8, 1994
    Date of Patent: June 11, 1996
    Assignee: Goldwell AC
    Inventors: Heribert Lorenz, Daisuke Misu
  • Patent number: 5199954
    Abstract: An easily employed, effective and predictable hair dye composition is obtained by combining aryl amines with aryl aldehydes along with an inorganic metal salt having a valence between +1 and +3. By employing this formulation, a permanent, long-lasting, non-fading hair coloring is achieved. In the preferred embodiment, the inorganic metal salt is selected from the group consisting of aluminum chloride, ferric chloride, lithium bromide, manganese chloride, copper chloride, and manganese nitrate. In carrying out the teaching of the present invention, the aryl amine and aryl aldehyde may be applied to the hair separately or in combination, along with the inorganic metal salt. In addition, this inorganic metal salt can be applied after the application and removal of the aryl amine and aryl aldehyde.
    Type: Grant
    Filed: February 25, 1992
    Date of Patent: April 6, 1993
    Assignee: Shiseido Co., Ltd.
    Inventors: Thomas M. Schultz, Catherine Grillo, Sanae Kubo
  • Patent number: 5196031
    Abstract: A process for dyeing a mixed fibrous substrate comprising applying to the substrate,a) at least one disperse dye,b) at least one copper - containing direct or reactive dye, preferably in a sufficient amount to produce a dyeing greater than a 1/1 standard depth;c) a complexing agent having a stability constant (K-value) with the metal of the direct or reactive dye of from 6 to 17 inclusive;d) a lignin sulphonate dispersing agent; ande) an oxidizing agent capable of converting copper (I) to copper (II) at a temperature of 100.degree.-130.degree. C. at a pH of 5-7 in the process for dyeing the mixed substrate.
    Type: Grant
    Filed: August 27, 1991
    Date of Patent: March 23, 1993
    Assignee: Sandoz Ltd.
    Inventor: John A. Hook
  • Patent number: 5180396
    Abstract: Process for dyeing keratinous fibres, characterized in that at least one composition (A) containing, in a medium suitable for dyeing, at least one indole derivative and at least one oxidation dye chosen from rapid oxidation dyes and couplers in combination, either (a) with iodide ions, or (b) with hydrogen peroxide, is applied on these fibres at a pH of between 2 and 7, and preferably between 2 and 5, the application of the composition (A) being preceded or followed by the application of a composition (B) which contains, in a medium suitable for dyeing:either (a) hydrogen peroxide at a pH of between 2 and 12 and preferably between 2 and 7 when (A) contains iodide ions;or (b) iodide ions at a pH of between 3 and 11 when the composition (A) contains hydrogen peroxide.
    Type: Grant
    Filed: November 20, 1991
    Date of Patent: January 19, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
  • Patent number: 5180397
    Abstract: A process for dyeing keratinous fibers involves applying to the fibers a dye composition (A) containing an oxidation dye which is a mixture of a coupler and a "rapid" oxidation dye or a "rapid" oxidation dye, in combination with iodide ions. Also applied to the fibers, preceding or following the application of composition (A) is a composition (B) containing hydrogen peroxide having a pH ranging from 2 to 12.
    Type: Grant
    Filed: October 17, 1990
    Date of Patent: January 19, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
  • Patent number: 5180399
    Abstract: A process for dyeing keratinous fibers employs a dye composition containing an oxidation base selected from a paraphenylenediamine, an N,N'-diphenylalkylene diamine, a para-aminophenol, an ortho-aminophenol, an ortho-phenylenediamine or a heterocyclic oxidation base, in combination with iodide ions. The application of this dyeing composition to the keratinous fibers is preceded or followed by the application to the fibers of a composition containing hydrogen peroxide.
    Type: Grant
    Filed: June 18, 1991
    Date of Patent: January 19, 1993
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
  • Patent number: 5135544
    Abstract: The invention relates to a process for dyeing keratinous fibres, comprising the application on these fibres,in a first stage, of a composition (A) containing, in a medium suitable for dyeing:(i) at least one monohydroxyindole corresponding to the formula (I): ##STR1## in which: R.sub.1 denotes hydrogen or alkyl; andR.sub.2 and R.sub.3 denote hydrogen, NH.sub.2, OH, COOH, CH.sub.2 COOH, CONH.sub.2, alkyl optionally substituted with OH or NH.sub.2, alkoxy, CONHR.sub.4, CON(R.sub.5)(R.sub.6) or CO.sub.2 R.sub.4, in which R.sub.4, R.sub.5 and R.sub.6 denote alkyl; halogen, and(ii) at least one 5,6-disubstituted hydroxyindole of formula (II): ##STR2## in which: R.sub.6 denotes hydrogen or acetyl;R.sub.4 denotes hydrogen, methyl, carboxy or ethoxycarbonyl; andR.sub.5 denotes hydrogen or methyl,with the proviso that, when R.sub.6 denotes acetyl, R.sub.4 and R.sub.
    Type: Grant
    Filed: June 29, 1990
    Date of Patent: August 4, 1992
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret
  • Patent number: 5064442
    Abstract: The invention relates to a process for dyeing keratinous fibres, consisting in applying a composition (A) containing:(a) at least one indole derivative,(b) a quinone dye chosen from:(i) 1,4-hydroxynaphthoquinones,(ii) benzoquinone derivatives, and(iii) hydroxyanthraquinones.The color being developed by an oxidizing system consisting of:(i) iodide ions and hydrogen peroxide,(ii) nitrites,(iii) oxidizing agents chosen from periodic acid and periodates, sodium hypochlorite, potassium ferricyanide, silver oxide, Fenton's reagent, lead (IV) oxide, caesium (V) sulphate, ammonium persulphate and ferric chloride, and(iv) a permanganate or a dichromate.
    Type: Grant
    Filed: January 3, 1991
    Date of Patent: November 12, 1991
    Assignee: L'Oreal
    Inventor: Jean F. Grollier
  • Patent number: 5011500
    Abstract: Process for dyeing keratinous fibers, which comprises applying to these fibers at least one composition (A) containing, in a suitable medium for dyeing, at least one indole derivative and at least one substituted 2-nitro-para-phenylenediamine selected from the group consisting of 1-N-(.beta.-hydroxyethyl)amino-2-nitro-4-N', N'-(bis-.beta.-hydroxyethyl)aminobenzene and 1-N-(.beta.
    Type: Grant
    Filed: December 29, 1988
    Date of Patent: April 30, 1991
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Chantal Fourcadier
  • Patent number: 5006127
    Abstract: In a method for the oxidative dyeing of human or animal hair a hair dyeing agenet is prepared from at least one oxidation dye in creme or gel form, which is adjusted to a pH of 5.9 to 6.9.The preparation is performed with the addition of at least one alkali metal salt or alkaline earth metal salt as catalyst, which is added simultaneously with or immediately after the mixing of the oxidation dye with the oxidizing agent, the amount added being such that it is contained in the treatment-ready hair dyeing agent in proportions between 0.0001 and 1.00 wt.-%, preferably between 0.0004 and 0.001 wt.-%.
    Type: Grant
    Filed: April 14, 1988
    Date of Patent: April 9, 1991
    Assignee: Goldwell GmbH
    Inventors: Jurgen Tennigkeit, Herbert Lorenz
  • Patent number: 4985955
    Abstract: The invention relates to process, composition, and kit for the oxidative dyeing of keratinous fibers with couplers and/or rapid oxidation dyes combined with iodide ions.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: January 22, 1991
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
  • Patent number: 4888027
    Abstract: Process for dyeing keratinous fibres, characterized in that there is applied to these fibres at least one composition (A) containing, in an appropriate medium for dyeing, 5,6-dihydroxyindole in combination with iodide ions, the application of this composition (A) being preceded or followed by the application of a composition (B) which contains, in an appropriate medium for dyeing, hydrogen peroxide at an alkaline pH of less than 12.
    Type: Grant
    Filed: April 4, 1988
    Date of Patent: December 19, 1989
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Didier Garoche
  • Patent number: 4885006
    Abstract: Process for dyeing human keratinous fibres, consisting in applying on these fibres at least least one composition (A) containing, in a cosmetically acceptable medium, one or more indole derivatives corresponding to the formula (I) ##STR1## in which: R.sub.1 denotes a hydrogen atom, a lower C.sub.1 -C.sub.6 lower akly group or a group --SiR.sub.9 R.sub.10 R.sub.11 ;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.6 lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group wherein the alkoxy moiety contains 1 to 6 carbon atoms, or a group --COOSiR.sub.9 R.sub.10 R.sub.11 ;R.sub.4 and R.sub.5, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.20 linear or branched alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O) (OR.sub.6).sub.2 or a group R.sub.6 OSO.sub.2 --, or alternatively R.sub.
    Type: Grant
    Filed: November 17, 1987
    Date of Patent: December 5, 1989
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Didier Garoche
  • Patent number: 4818248
    Abstract: The present invention relates to a process for dyeing natural or synthetic polyamide fibre material from an aqueous liquor with dyes, in the presence of an alkali metal salt or an ammonium salt and in the presence of an assistant, which process comprises dyeing said fibre material with at least one sulfonated 1:1 metal complex dye or with a mixture containing at least one sulfonated 1:1 metal complex dye and at least one sulfonated metal-free dye, in the presence of 10 to 45 percent by weight of an alkali fluorosilicate or ammonium fluorosilicate or a mixture thereof, based on the amount of the 1:1 metal complex dye employed, and in the presence of an assistant at a pH value of 3 to 5.The process of the invention is suitable for dyeing natural or synthetic polyamide materials to give non-skittery and level dyeings of good fastness properties.
    Type: Grant
    Filed: September 30, 1987
    Date of Patent: April 4, 1989
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Back, Walter Mosimann
  • Patent number: 4808190
    Abstract: The invention relates to a process for dyeing keratinous fibers characterized in that at least one composition comprising, in a medium suitable for dyeing, 5,6-dihydroxyindole in combination with hydrogen peroxide at a pH of between 2 and 7 is applied to these fibers, the application of said composition being preceded or followed by the application of a composition comprising iodide ions in a medium suitable for dyeing.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: February 28, 1989
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Didier Garoche
  • Patent number: 4804385
    Abstract: The invention relates to a plural stage process for dyeing keratinous fibers wherein a composition (A) comprising, in a medium suitable for dyeing, 5,6-dihydroxyindole and iodide ions, is applied to the hair, the application of said composition (A) being preceded or followed by the application of a composition (B) comprising hydrogen peroxide.
    Type: Grant
    Filed: January 20, 1987
    Date of Patent: February 14, 1989
    Assignee: L'Oreal
    Inventors: Jean F. Grollier, Didier Garoche
  • Patent number: 4765797
    Abstract: Liquid formulations of mixtures of cationic dyes frequently have a very short storage life. As a consequence, these formulations give rise to customer complaints concerning incorrect dyeing strengths and hues and concerning isoluble constituents. It has now been found according to the invention that powder formulations and in particular liquid formulations of cationic dyes or of mixtures of these dyes can be stabilized by adding selected oxidizing agents.
    Type: Grant
    Filed: June 8, 1987
    Date of Patent: August 23, 1988
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Sierling Ong, Kurt Hohmann
  • Patent number: 4681596
    Abstract: The invention relates to a process for dyeing natural or synthetic polyamide fibre material levelly from an aqueous liquor, with 1:1 metal complex dyes and at least one metal free dye, all of which contain sulfo groups, in the presence of an alkali metal salt or an ammonium salt and optionally in the presence of an assistant, which comprises carrying out dyeing in the presence of an alkali metal fluoride or ammonium fluoride, or an alkali metal fluorosilicate or ammonium fluorosilicate, or of an alkali metal fluoroborate or ammonium fluoroborate, at a pH in the range from 3 to 7.The process of this invention is suitable for dyeing natural or synthetic polyamide material in level shades of good fastness properties.
    Type: Grant
    Filed: May 9, 1986
    Date of Patent: July 21, 1987
    Assignee: Ciba-Geigy Corporation
    Inventors: Gerhard Back, Walter Mosimann
  • Patent number: 4364738
    Abstract: There are described novel crystalline bromine and iodine salts of triazole dyes of the formula ##STR1## wherein R is the CH.sub.3 or C.sub.2 H.sub.5 group,R.sub.1 is a C.sub.1 -C.sub.4 -alkyl group,R.sub.2 is an unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl group, andX is the bromine or iodine ion,and also processes for producing them, and their use for dyeing and printing in particular polyacrylonitrile materials.
    Type: Grant
    Filed: July 23, 1981
    Date of Patent: December 21, 1982
    Assignee: Ciba-Geigy Corporation
    Inventors: Rudolf Zink, Peter Loew
  • Patent number: 4321054
    Abstract: An acidic, aqueous oxidant including ionized bromate, iodate and a soluble molybdenum-containing material.
    Type: Grant
    Filed: March 16, 1981
    Date of Patent: March 23, 1982
    Assignee: The Dow Chemical Company
    Inventors: Ralph A. Davis, Randy C. Stauffer
  • Patent number: 4211527
    Abstract: Described is a process for dyeing polyester materials, or mixtures thereof with other fibres, by the exhaust method from an aqueous liquor, in which process the liquor contains at least 0.2 percent by weight, relative to the material, of at least one alkaline-earth metal salt, aluminium salt or organic ammonium salt of a mono- or polyvalent aliphatic organic acid or of a mono- or polyvalent inorganic acid. Preferably calcium chloride or magnesium chloride are used.
    Type: Grant
    Filed: December 9, 1977
    Date of Patent: July 8, 1980
    Assignee: Ciba-Geigy Corporation
    Inventor: Jean P. Luttringer