Halogen Acids Patents (Class 8/634)
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Patent number: 6689175Abstract: In a preferred embodiment, the present process involves subjecting a fabric comprised of conjugate yarns to an acidic treatment, which degrades a portion of one component of the conjugate yarns and to dyeing. The acid treatment, given certain reaction kinetics, removes a portion of the polyamide element of the conjugate filament. The at least partial removal of the polyamide component results in a fabric has enhanced dyed appearance, especially when dyed a dark shade. In an alternate embodiment, the fabric may also be treated with a basic solution to improve its moisture transport properties.Type: GrantFiled: February 12, 2002Date of Patent: February 10, 2004Assignee: Milliken & CompanyInventors: Heather J. Hayes, Crystal A. Garner, Kirkland W. Vogt, Kaushal Gandhi
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Patent number: 6533826Abstract: Process for preparing aqueous solutions of cationic di- and triarylmethane dyes by the aqueous dye solution, which contains organic solvents, being concentrated by nanofiltration and optionally diluted with water.Type: GrantFiled: February 8, 2001Date of Patent: March 18, 2003Assignee: BASF AktiengesellschaftInventors: Thomas Gessner, Gunter-Rudolf Schröder, Robert Reinhardt
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Patent number: 6221113Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25° C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.Type: GrantFiled: January 13, 1998Date of Patent: April 24, 2001Assignee: Clariant Finance (BVI) LimitedInventor: Jürgen Geiwiz
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Patent number: 5944856Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.Type: GrantFiled: January 13, 1998Date of Patent: August 31, 1999Assignee: Clariant Finanace (BVI) LimitedInventor: Jurgen Geiwiz
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Patent number: 5616151Abstract: A method for the adjustment of pH in textile processing solutions that includes the use of urea sulfate or other strong acid in the presence of a weak base.Type: GrantFiled: April 11, 1995Date of Patent: April 1, 1997Assignee: Peach State Labs, Inc.Inventors: R. Richard Sargent, Jeffrey R. Alender
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Patent number: 5525123Abstract: This invention comprises a hair dyeing composition based on oxidation dyestuff precursors which dyes and brightens the hair containing, besides at least one developing and at least one coupling agent, at least one metal salt and at least one ammonium compound selected from the group ammonium chloride, ammonium sulfate, ammonium carbonate, ammonium bicarbonate, and ammonium carbamate, having a pH-value between 8 and 11, preferably from 9 to 10, after admixture with an oxidizing agent in the ready-to-use preparation.Type: GrantFiled: September 8, 1994Date of Patent: June 11, 1996Assignee: Goldwell ACInventors: Heribert Lorenz, Daisuke Misu
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Patent number: 5199954Abstract: An easily employed, effective and predictable hair dye composition is obtained by combining aryl amines with aryl aldehydes along with an inorganic metal salt having a valence between +1 and +3. By employing this formulation, a permanent, long-lasting, non-fading hair coloring is achieved. In the preferred embodiment, the inorganic metal salt is selected from the group consisting of aluminum chloride, ferric chloride, lithium bromide, manganese chloride, copper chloride, and manganese nitrate. In carrying out the teaching of the present invention, the aryl amine and aryl aldehyde may be applied to the hair separately or in combination, along with the inorganic metal salt. In addition, this inorganic metal salt can be applied after the application and removal of the aryl amine and aryl aldehyde.Type: GrantFiled: February 25, 1992Date of Patent: April 6, 1993Assignee: Shiseido Co., Ltd.Inventors: Thomas M. Schultz, Catherine Grillo, Sanae Kubo
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Patent number: 5196031Abstract: A process for dyeing a mixed fibrous substrate comprising applying to the substrate,a) at least one disperse dye,b) at least one copper - containing direct or reactive dye, preferably in a sufficient amount to produce a dyeing greater than a 1/1 standard depth;c) a complexing agent having a stability constant (K-value) with the metal of the direct or reactive dye of from 6 to 17 inclusive;d) a lignin sulphonate dispersing agent; ande) an oxidizing agent capable of converting copper (I) to copper (II) at a temperature of 100.degree.-130.degree. C. at a pH of 5-7 in the process for dyeing the mixed substrate.Type: GrantFiled: August 27, 1991Date of Patent: March 23, 1993Assignee: Sandoz Ltd.Inventor: John A. Hook
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Patent number: 5180397Abstract: A process for dyeing keratinous fibers involves applying to the fibers a dye composition (A) containing an oxidation dye which is a mixture of a coupler and a "rapid" oxidation dye or a "rapid" oxidation dye, in combination with iodide ions. Also applied to the fibers, preceding or following the application of composition (A) is a composition (B) containing hydrogen peroxide having a pH ranging from 2 to 12.Type: GrantFiled: October 17, 1990Date of Patent: January 19, 1993Assignee: L'OrealInventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
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Patent number: 5180396Abstract: Process for dyeing keratinous fibres, characterized in that at least one composition (A) containing, in a medium suitable for dyeing, at least one indole derivative and at least one oxidation dye chosen from rapid oxidation dyes and couplers in combination, either (a) with iodide ions, or (b) with hydrogen peroxide, is applied on these fibres at a pH of between 2 and 7, and preferably between 2 and 5, the application of the composition (A) being preceded or followed by the application of a composition (B) which contains, in a medium suitable for dyeing:either (a) hydrogen peroxide at a pH of between 2 and 12 and preferably between 2 and 7 when (A) contains iodide ions;or (b) iodide ions at a pH of between 3 and 11 when the composition (A) contains hydrogen peroxide.Type: GrantFiled: November 20, 1991Date of Patent: January 19, 1993Assignee: L'OrealInventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
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Patent number: 5180399Abstract: A process for dyeing keratinous fibers employs a dye composition containing an oxidation base selected from a paraphenylenediamine, an N,N'-diphenylalkylene diamine, a para-aminophenol, an ortho-aminophenol, an ortho-phenylenediamine or a heterocyclic oxidation base, in combination with iodide ions. The application of this dyeing composition to the keratinous fibers is preceded or followed by the application to the fibers of a composition containing hydrogen peroxide.Type: GrantFiled: June 18, 1991Date of Patent: January 19, 1993Assignee: L'OrealInventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
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Patent number: 5135544Abstract: The invention relates to a process for dyeing keratinous fibres, comprising the application on these fibres,in a first stage, of a composition (A) containing, in a medium suitable for dyeing:(i) at least one monohydroxyindole corresponding to the formula (I): ##STR1## in which: R.sub.1 denotes hydrogen or alkyl; andR.sub.2 and R.sub.3 denote hydrogen, NH.sub.2, OH, COOH, CH.sub.2 COOH, CONH.sub.2, alkyl optionally substituted with OH or NH.sub.2, alkoxy, CONHR.sub.4, CON(R.sub.5)(R.sub.6) or CO.sub.2 R.sub.4, in which R.sub.4, R.sub.5 and R.sub.6 denote alkyl; halogen, and(ii) at least one 5,6-disubstituted hydroxyindole of formula (II): ##STR2## in which: R.sub.6 denotes hydrogen or acetyl;R.sub.4 denotes hydrogen, methyl, carboxy or ethoxycarbonyl; andR.sub.5 denotes hydrogen or methyl,with the proviso that, when R.sub.6 denotes acetyl, R.sub.4 and R.sub.Type: GrantFiled: June 29, 1990Date of Patent: August 4, 1992Assignee: L'OrealInventors: Jean F. Grollier, Jean Cotteret
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Patent number: 5064442Abstract: The invention relates to a process for dyeing keratinous fibres, consisting in applying a composition (A) containing:(a) at least one indole derivative,(b) a quinone dye chosen from:(i) 1,4-hydroxynaphthoquinones,(ii) benzoquinone derivatives, and(iii) hydroxyanthraquinones.The color being developed by an oxidizing system consisting of:(i) iodide ions and hydrogen peroxide,(ii) nitrites,(iii) oxidizing agents chosen from periodic acid and periodates, sodium hypochlorite, potassium ferricyanide, silver oxide, Fenton's reagent, lead (IV) oxide, caesium (V) sulphate, ammonium persulphate and ferric chloride, and(iv) a permanganate or a dichromate.Type: GrantFiled: January 3, 1991Date of Patent: November 12, 1991Assignee: L'OrealInventor: Jean F. Grollier
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Patent number: 5011500Abstract: Process for dyeing keratinous fibers, which comprises applying to these fibers at least one composition (A) containing, in a suitable medium for dyeing, at least one indole derivative and at least one substituted 2-nitro-para-phenylenediamine selected from the group consisting of 1-N-(.beta.-hydroxyethyl)amino-2-nitro-4-N', N'-(bis-.beta.-hydroxyethyl)aminobenzene and 1-N-(.beta.Type: GrantFiled: December 29, 1988Date of Patent: April 30, 1991Assignee: L'OrealInventors: Jean F. Grollier, Chantal Fourcadier
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Agent for the oxidative dyeing of hair, method for the preparation of the agent and use of the agent
Patent number: 5006127Abstract: In a method for the oxidative dyeing of human or animal hair a hair dyeing agenet is prepared from at least one oxidation dye in creme or gel form, which is adjusted to a pH of 5.9 to 6.9.The preparation is performed with the addition of at least one alkali metal salt or alkaline earth metal salt as catalyst, which is added simultaneously with or immediately after the mixing of the oxidation dye with the oxidizing agent, the amount added being such that it is contained in the treatment-ready hair dyeing agent in proportions between 0.0001 and 1.00 wt.-%, preferably between 0.0004 and 0.001 wt.-%.Type: GrantFiled: April 14, 1988Date of Patent: April 9, 1991Assignee: Goldwell GmbHInventors: Jurgen Tennigkeit, Herbert Lorenz -
Patent number: 4985955Abstract: The invention relates to process, composition, and kit for the oxidative dyeing of keratinous fibers with couplers and/or rapid oxidation dyes combined with iodide ions.Type: GrantFiled: May 25, 1988Date of Patent: January 22, 1991Assignee: L'OrealInventors: Jean F. Grollier, Jean Cotteret, Didier Garoche
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Patent number: 4888027Abstract: Process for dyeing keratinous fibres, characterized in that there is applied to these fibres at least one composition (A) containing, in an appropriate medium for dyeing, 5,6-dihydroxyindole in combination with iodide ions, the application of this composition (A) being preceded or followed by the application of a composition (B) which contains, in an appropriate medium for dyeing, hydrogen peroxide at an alkaline pH of less than 12.Type: GrantFiled: April 4, 1988Date of Patent: December 19, 1989Assignee: L'OrealInventors: Jean F. Grollier, Didier Garoche
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Patent number: 4885006Abstract: Process for dyeing human keratinous fibres, consisting in applying on these fibres at least least one composition (A) containing, in a cosmetically acceptable medium, one or more indole derivatives corresponding to the formula (I) ##STR1## in which: R.sub.1 denotes a hydrogen atom, a lower C.sub.1 -C.sub.6 lower akly group or a group --SiR.sub.9 R.sub.10 R.sub.11 ;R.sub.2 and R.sub.3, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.6 lower alkyl group, a carboxyl group, a lower alkoxycarbonyl group wherein the alkoxy moiety contains 1 to 6 carbon atoms, or a group --COOSiR.sub.9 R.sub.10 R.sub.11 ;R.sub.4 and R.sub.5, which may be identical or different, denote a hydrogen atom, a C.sub.1 -C.sub.20 linear or branched alkyl group, a formyl group, a linear or branched C.sub.2 -C.sub.20 acyl group, a linear or branched C.sub.3 -C.sub.20 alkenoyl group, a group --SiR.sub.9 R.sub.10 R.sub.11, a group --P(O) (OR.sub.6).sub.2 or a group R.sub.6 OSO.sub.2 --, or alternatively R.sub.Type: GrantFiled: November 17, 1987Date of Patent: December 5, 1989Assignee: L'OrealInventors: Jean F. Grollier, Didier Garoche
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Patent number: 4818248Abstract: The present invention relates to a process for dyeing natural or synthetic polyamide fibre material from an aqueous liquor with dyes, in the presence of an alkali metal salt or an ammonium salt and in the presence of an assistant, which process comprises dyeing said fibre material with at least one sulfonated 1:1 metal complex dye or with a mixture containing at least one sulfonated 1:1 metal complex dye and at least one sulfonated metal-free dye, in the presence of 10 to 45 percent by weight of an alkali fluorosilicate or ammonium fluorosilicate or a mixture thereof, based on the amount of the 1:1 metal complex dye employed, and in the presence of an assistant at a pH value of 3 to 5.The process of the invention is suitable for dyeing natural or synthetic polyamide materials to give non-skittery and level dyeings of good fastness properties.Type: GrantFiled: September 30, 1987Date of Patent: April 4, 1989Assignee: Ciba-Geigy CorporationInventors: Gerhard Back, Walter Mosimann
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Patent number: 4808190Abstract: The invention relates to a process for dyeing keratinous fibers characterized in that at least one composition comprising, in a medium suitable for dyeing, 5,6-dihydroxyindole in combination with hydrogen peroxide at a pH of between 2 and 7 is applied to these fibers, the application of said composition being preceded or followed by the application of a composition comprising iodide ions in a medium suitable for dyeing.Type: GrantFiled: January 20, 1987Date of Patent: February 28, 1989Assignee: L'OrealInventors: Jean F. Grollier, Didier Garoche
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Patent number: 4804385Abstract: The invention relates to a plural stage process for dyeing keratinous fibers wherein a composition (A) comprising, in a medium suitable for dyeing, 5,6-dihydroxyindole and iodide ions, is applied to the hair, the application of said composition (A) being preceded or followed by the application of a composition (B) comprising hydrogen peroxide.Type: GrantFiled: January 20, 1987Date of Patent: February 14, 1989Assignee: L'OrealInventors: Jean F. Grollier, Didier Garoche
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Patent number: 4765797Abstract: Liquid formulations of mixtures of cationic dyes frequently have a very short storage life. As a consequence, these formulations give rise to customer complaints concerning incorrect dyeing strengths and hues and concerning isoluble constituents. It has now been found according to the invention that powder formulations and in particular liquid formulations of cationic dyes or of mixtures of these dyes can be stabilized by adding selected oxidizing agents.Type: GrantFiled: June 8, 1987Date of Patent: August 23, 1988Assignee: Hoechst AktiengesellschaftInventors: Manfred Hahnke, Sierling Ong, Kurt Hohmann
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Patent number: 4681596Abstract: The invention relates to a process for dyeing natural or synthetic polyamide fibre material levelly from an aqueous liquor, with 1:1 metal complex dyes and at least one metal free dye, all of which contain sulfo groups, in the presence of an alkali metal salt or an ammonium salt and optionally in the presence of an assistant, which comprises carrying out dyeing in the presence of an alkali metal fluoride or ammonium fluoride, or an alkali metal fluorosilicate or ammonium fluorosilicate, or of an alkali metal fluoroborate or ammonium fluoroborate, at a pH in the range from 3 to 7.The process of this invention is suitable for dyeing natural or synthetic polyamide material in level shades of good fastness properties.Type: GrantFiled: May 9, 1986Date of Patent: July 21, 1987Assignee: Ciba-Geigy CorporationInventors: Gerhard Back, Walter Mosimann
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Patent number: 4364738Abstract: There are described novel crystalline bromine and iodine salts of triazole dyes of the formula ##STR1## wherein R is the CH.sub.3 or C.sub.2 H.sub.5 group,R.sub.1 is a C.sub.1 -C.sub.4 -alkyl group,R.sub.2 is an unsubstituted or substituted C.sub.1 -C.sub.4 -alkyl group, andX is the bromine or iodine ion,and also processes for producing them, and their use for dyeing and printing in particular polyacrylonitrile materials.Type: GrantFiled: July 23, 1981Date of Patent: December 21, 1982Assignee: Ciba-Geigy CorporationInventors: Rudolf Zink, Peter Loew
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Patent number: 4321054Abstract: An acidic, aqueous oxidant including ionized bromate, iodate and a soluble molybdenum-containing material.Type: GrantFiled: March 16, 1981Date of Patent: March 23, 1982Assignee: The Dow Chemical CompanyInventors: Ralph A. Davis, Randy C. Stauffer
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Patent number: 4211527Abstract: Described is a process for dyeing polyester materials, or mixtures thereof with other fibres, by the exhaust method from an aqueous liquor, in which process the liquor contains at least 0.2 percent by weight, relative to the material, of at least one alkaline-earth metal salt, aluminium salt or organic ammonium salt of a mono- or polyvalent aliphatic organic acid or of a mono- or polyvalent inorganic acid. Preferably calcium chloride or magnesium chloride are used.Type: GrantFiled: December 9, 1977Date of Patent: July 8, 1980Assignee: Ciba-Geigy CorporationInventor: Jean P. Luttringer