Sulfonated Azo Patents (Class 8/641)
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Patent number: 11009639Abstract: An object of the present invention is to solve the problems which can be peculiarly generated in a coating-type optical film, and provide an optical film which hardly causes deterioration in optical performance with time, a display device equipped with the optical film, and a process for producing the optical film, and there is provided a polarizing plate having a diffusion preventing layer A having the thickness of 0.05 ?m to 3 ?m, a polarizing film comprising a polymer of a polymerizable liquid crystal and a dichroic coloring matter, and a diffusion preventing layer B having the thickness of 0.05 ?m to 3 ?m, in this order.Type: GrantFiled: November 13, 2018Date of Patent: May 18, 2021Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Nobuyuki Hatanaka, Yosuke Ota
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Patent number: 10190255Abstract: The present invention relates to dye mixtures comprising one or more dye(s) of: formula (I) and one or more dye(s) of: formula (II) and/or formula (III) and optionally one or more dye(s) of: formula (IV) to processes for their preparation and to their use for dyeing and printing hydroxyl- and carboxamido-containing materials.Type: GrantFiled: October 24, 2013Date of Patent: January 29, 2019Assignee: DyStar Colours Distribution GmbHInventors: Clemens Grund, Adrian Murgatroyd, Ulrich Hanxleden, Manfred Hoppe, Ulrich Weingarten, Ronald Pedemonte, Antonio Lopez-Torrentera
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Patent number: 10138596Abstract: The present invention relates to dye mixtures comprising one or more dye(s) of: formula (I) and one or more dye(s) of: formula (II) and optionally one or more dye(s) of: formula (IV) to processes for their preparation and to their use for dyeing and printing hydroxyl- and carboxamido-containing materials.Type: GrantFiled: October 24, 2013Date of Patent: November 27, 2018Assignee: DyStar Colours Distribution GmbHInventors: Clemens Grund, Adrian Murgatroyd, Ulrich Hanxleden, Manfred Hoppe, Ulrich Weingarten, Ronald Pedemonte, Antonio Lopez-Torrentera
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Patent number: 9714347Abstract: The present invention relates to dyes of formula (1) a process for preparing them and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.Type: GrantFiled: December 3, 2013Date of Patent: July 25, 2017Assignee: DyStar Colours Distribution GmbHInventors: Roxana Barbieru, Sivamurugan Vajiravelu, Say Wan Yong, Ravi Vedarethinam
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Patent number: 9695339Abstract: Adhesive tape consisting of a textile carrier and of an adhesive layer applied to at least one side of the carrier, the carrier being colored with a mixture of dyes and/or pigments, characterized in that at least one of the dyes and/or one of the pigments is based on anthraquinone.Type: GrantFiled: July 11, 2012Date of Patent: July 4, 2017Assignee: tesa SEInventors: Inga Auktun, Michael Siebert
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Patent number: 8975219Abstract: A fabric cleaning composition comprising from 1% to 20% by weight of the fabric cleaning composition of an oxygen-based bleaching source and a hueing agent, and wherein the neat composition has a pH between 2.5 and 5.5, and a method of using said fabric cleaning composition.Type: GrantFiled: May 16, 2012Date of Patent: March 10, 2015Assignee: The Procter & Gamble CompanyInventors: Margherita Scartozzi, Luca Sarcinelli, Sophie Anne Marguerite Goellner, Enza Ceccobelli, Leo Gagliardi
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Patent number: 8961621Abstract: The present invention relates to dyes of formula (1), wherein each of the residues D1 and D2 represents a radical of formula (2), wherein Ar1 represents the tetravalent radical of a carbocylic or heterocyclic aromatic compound, R1, R2 and R3 are each independently of the other hydrogen, C1-C12alkyl, C1-C12alkoxy, halogen, —OH, —CN, —NO2, —CF3, —SO3H, —NHCOR4, —COOR5, —CONR6R7, —SO2NR8R9, —NR10SO2R11, —SO2R13— or —ZCH2CH2Q, wherein Z is —O—, —SO2—, —NR12—, —CONH— or —NHCO—, Q represents —OH, C1-C12alkyl, —SO2R13—, —NHR14—, —OCH2CH2OH, —SO2CH2CH2OH or —NHCH2CH2OH, R4 is C1-C12alkyl, R5, R6, R7, R8, R9, R10, R12, R13 and R14 are each independently of the others hydrogen or C1-C12alkyl, and R11 is C1-C122alkyl, with the proviso that at least one of the residues D1 and D2 is a radical of formula (2) wherein R3 is —COOR5, —SO2NR8R9, —SO2R13— or —ZCH2CH2Q, dichromatic and trichromatic mixtures containing these dyes and the use of these dyes for dyeing or printing hydroxyl group-containing or nitrogen-containing fibrType: GrantFiled: November 26, 2012Date of Patent: February 24, 2015Assignee: Huntsman International LLCInventors: Alexander Mueller, Rainer Hildebrand, Siro Dalle-Nogare
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Mixtures of fibre-reactive dyes and their use in a method for di- or trichromatic dyeing or printing
Patent number: 8911509Abstract: Reactive dye mixtures comprising at least one red dyeing dye and at least one blue, yellow, orange or brown dyeing dye and their use in methods for the dichromatic or trichromatic dyeing or printing of cellulosic fiber materials are described. The reactive dye mixtures yield dyeings or prints having good reproducibility and good all-round fastness properties.Type: GrantFiled: January 13, 2011Date of Patent: December 16, 2014Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Marco Casartelli, Remo Codemo, Jean-Francois Landre -
Patent number: 8864850Abstract: Dye mixtures comprising at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable for dyeing or printing cellulose-containing fiber materials, while at the same time exhibiting good build-up behavior, and yield dyeings of deep shade having good fastness properties.Type: GrantFiled: January 23, 2013Date of Patent: October 21, 2014Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen
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Publication number: 20140304926Abstract: The present invention relates to dyes of formula (1), wherein each of the residues D1 and D2 represents a radical of formula (2), wherein Ar1 represents the tetravalent radical of a carbocylic or heterocyclic aromatic compound, R1, R2 and R3 are each independently of the other hydrogen, C1-C12alkyl, C1-C12alkoxy, halogen, —OH, —CN, —NO2, —CF3, —SO3H, —NHCOR4, —COOR5, —CONR6R7, —SO2NR8R9, —NR10SO2R11, —SO2R13— or —ZCH2CH2Q, wherein Z is —O—, —SO2—, —NR12—, —CONH— or —NHCO—, Q represents —OH, C1-C12alkyl, —SO2R13—, —NHR14—, —OCH2CH2OH, —SO2CH2CH2OH or —NHCH2CH2OH, R4 is C1-C12alkyl, R5, R6, R7, R8, R9, R10, R12, R13 and R14 are each independently of the others hydrogen or C1-C12alkyl, and R11 is C1-C122alkyl, with the proviso that at least one of the residues D1 and D2 is a radical of formula (2) wherein R3 is —COOR5, —SO2NR8R9, —SO2R13— or —ZCH2CH2Q, dichromatic and trichromatic mixtures containing these dyes and the use of these dyes for dyeing or printing hydroxyl group-containing or nitrogen-containing fibrType: ApplicationFiled: November 26, 2012Publication date: October 16, 2014Inventors: Alexander Mueller, Rainer Hildebrand, Siro Dalle-Nogare
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Patent number: 8834581Abstract: Described are dyes of formula (I) where R1 is hydrogen, alkyl, alkoxy, trifluoromethyl or halogen, M is hydrogen, an alkali metal cation or an optionally substituted ammonium cation, R2 and R3 are each independently hydrogen, alkyl or alkoxy, R4 is alkyl or alkoxy, R5 and R6 are each independently moieties of the formula —(CmH2m)—O—CnH2n+1, m is an integer from 3 to 6, and n is an integer from 0 to 8. These dyes are useful for dyeing and printing materials having polar groups.Type: GrantFiled: December 17, 2011Date of Patent: September 16, 2014Assignee: DyStar Colours Distribution GmbHInventors: Aloysius Engel, Michael Joerss, Clemens Grund, Bernd Hostasch, Gunter Görlitz
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Patent number: 8734534Abstract: The present invention relates to new azo dyes, a process for their preparation, and their use for dyeing or printing fibrous materials, to produce materials with brownish shades.Type: GrantFiled: November 29, 2011Date of Patent: May 27, 2014Assignee: Kemira OyjInventors: Helmut-Martin Meier, Christof Heide, Klaus-Günter Strumpf, Thomas Hübbe
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Patent number: 8734532Abstract: The present invention relates to new azo dyes, a process for their preparation, and their use for dyeing or printing fibrous materials, to produce materials with brownish shades.Type: GrantFiled: November 29, 2011Date of Patent: May 27, 2014Assignee: Kemira OyjInventors: Helmut-Martin Meier, Christof Heide, Klaus-Günter Strumpf, Thomas Hübbe
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Publication number: 20140123407Abstract: The present invention relates to dye mixtures containing at least one dye of formula (I) and at least either a dye of formula (II) and/or at least one dye of formula (III) where R1-R15, n, o, X and D1-D3 are each as defined in claim 1. These dye mixtures are useful for dyeing or printing hydrophobic materials in particular.Type: ApplicationFiled: January 7, 2012Publication date: May 8, 2014Applicant: DyStar Colours Distribution GmbHInventors: Markus Arnold, Andrian Murgatroyd, Clemens Grund, Gunter Görlitz, Timo Liebig
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Patent number: 8506653Abstract: The present invention relates to an aqueous direct dye formulation, comprising (a) 5 to 25% by weight of a dye composition comprising (a1) 50-99% by weight of one or more dyes obtainable by reduction or thermal treatment of Direct Yellow 11, and (a2) 1-50% by weight of a blue, black and/or red direct dye, (all based on the dye composition); (b) up to 0.9% by weight of a saturated, cyclic or acyclic water-soluble amine comprising a primary, secondary or tertiary amino group and at least one further functional group selected from primary, secondary and tertiary amino groups, OH groups and ether groups; and (c) up to 0.9% by weight of urea; and (d) water, wherein the percentages for (a), (b), and (c) relate to the total weight of the aqueous direct dye formulation. The invention moreover relates to a process for their preparation and the use thereof for the dyeing, in particular of paper, as well as paper which has been dyed with this aqueous direct dye formulation.Type: GrantFiled: March 11, 2010Date of Patent: August 13, 2013Assignee: BASF SEInventors: Allan Francis Cunningham, Céline Hossenlopp, Heinz Schneider, Rainer Hans Traber, Horst Herrmann, Michael Jacquier
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Patent number: 8409300Abstract: Novel disperse azo dyes of formula (I), and processes for preparation thereof. These dyes possess superior washing fastness, sublimation fastness and light fastness.Type: GrantFiled: December 23, 2010Date of Patent: April 2, 2013Assignee: Colourtex Industries LimitedInventors: Pankaj Desai, Kiyoshi Himeno, Nikhil Desai
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Patent number: 8349028Abstract: The present invention relates to a reactive printing dye composition, which includes: (a) at least one reactive dye; (b) an organic buffer; and (c) a mirabilite or a dispersant. The reactive printing dye composition of the present invention is capable for being used in the fabric-dyeing, for example, dyeing of cotton, hemp, silk, rayon, wool, blending, etc. The reactive printing dye composition of the present invention is advantageous in high pH value stability, high storage stability, and reduced degradation in dyeing strength. In addition, the present invention further provides an aqueous reactive printing dye composition.Type: GrantFiled: November 13, 2009Date of Patent: January 8, 2013Assignee: Everlight USA, Inc.Inventors: Wen-Chin Lin, Chien-Wen Lee
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Patent number: 8349029Abstract: The present invention relates to azo dyes of the formula (1) in which R, M, and Y are defined as stated in claim 1, to dye mixtures comprising them, to processes for preparing them, and to their use.Type: GrantFiled: January 30, 2012Date of Patent: January 8, 2013Assignee: DyStar Colours Deutschland GmbHInventors: Jörg Wörner, Andreas Schrell
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Patent number: 8323358Abstract: The present invention refers to a red-dyeing acid dye mixture comprising a dye of the formula (I) and at least one dye of the formula (II) a process for its manufacturing and a process for dyeing and printing of natural or synthetic polyamide fiber material in which it used.Type: GrantFiled: February 6, 2006Date of Patent: December 4, 2012Assignee: DyStar Colours Deutschland GmbHInventors: Thomas Ruchser, Andreas Giehl
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Publication number: 20120216356Abstract: The present invention relates to azo dyes of the formula (1) in which R, M, and Y are defined as stated in claim 1, to dye mixtures comprising them, to processes for preparing them, and to their use.Type: ApplicationFiled: January 30, 2012Publication date: August 30, 2012Applicant: DyStar Colours Deutschland GmbHInventors: Jörg Wörner, Andreas Schrell
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Patent number: 8083811Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein the substituents are defined in the specification.Type: GrantFiled: October 30, 2007Date of Patent: December 27, 2011Assignee: Huntsman International LLCInventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean Luc Christnacher
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Patent number: 8034129Abstract: The invention relates to an aqueous dye solution comprising a) 5 to 30% by weight of an anionic or cationic direct dye, b) 0.01 to 5% by weight of the compound of formula (1), in which M represents hydrogen, an alkali metal or alkaline earth metal, ammonium or ammonium, that is mono-, di-, tri- or tetra-substituted by C1-C4alkyl or C2-C4hydroxyalkyl or mixtures thereof, c) 0 to 10% by weight of an inorganic or an organic acid, d) 0 to 20% by weight of further additives and e) water to complete to 100%, with the proviso that direct dyes of the formula (2) in which K is a residue of a coupling component of the acetoacetanilide, pyridone, pyrazolone or pyrimidine series and M is as defined above, are excluded, a process for their preparation and the use thereof for dyeing paper.Type: GrantFiled: May 8, 2006Date of Patent: October 11, 2011Assignee: BASF SEInventors: Holger Lautenbach, Adolf Käser
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Patent number: 7909892Abstract: The present invention relates storage stable aqueous dye solutions comprising a) 5 to 30% by weight of a dye of the formula in which K is a residue of a coupling component of the acetoacetanilide, pyridone, pyrazolone or pyrimidine series and M is hydrogen, an alkali metal or alkaline earth metal, ammonium or alkyl ammonium, b) 0.05 to 5% by weight of one or more compounds of the formula or a residue of the formula in which A, X, Y, R, P and Q are defined herein, c) an organic or an inorganic base or mixtures thereof, d) if desired, further additives and e) water, a process for their preparation and the use thereof for the dyeing, in particular of paper.Type: GrantFiled: January 21, 2003Date of Patent: March 22, 2011Assignee: BASF SEInventors: Holger Lautenbach, Adolf Käser, Michael Heneghan
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Patent number: 7887602Abstract: Reactive dyes of formula wherein the variables are defined herein.Type: GrantFiled: August 2, 2006Date of Patent: February 15, 2011Assignee: Huntsman International, LLCInventors: Hubert Jean Luc Christnacher, Athanassios Tzikas, Georg Roentgen
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Patent number: 7829517Abstract: The present invention relates to a solid laundry detergent composition comprising non-ionic detersive surfactant and reactive dye.Type: GrantFiled: March 30, 2009Date of Patent: November 9, 2010Assignee: The Procter & Gamble CompanyInventor: Alan Thomas Brooker
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Patent number: 7824483Abstract: A composition comprising a compound of Formula (1) or a salt thereof and compound of Formula (2) or a salt thereof: wherein: A is or comprises an aryl or heteroaryl group; Q1 and Q2 each independently is an optionally substituted phenylene group; R1, R2, Ra and Rb each independently is H, optionally substituted alkyl, optionally substituted aryl or optionally substituted arylalkyl; each W1, W2, W3 and W4 independently is a —CO2H, —SO3H, —PO3H2 group or an alkyl substituted with one or more groups selected from —CO2H, —SO3H, —PO3H2; each S1, S2, S3 and S4 independently is a substituent other than those defined for W1, W2, W3 and W4; a and d each independently is from 1 to 5; b and c each independently is from 0 to 4; (a+b) has a value of from 1 to 5; (c+d) has a value of from 1 to 5; e and h each independently is from 1 to 7; f and g each independently is from 0 to 6; (e+f) has a value of from 1 to 7; and (g+h) has a value of from 1 to 7.Type: GrantFiled: June 10, 2008Date of Patent: November 2, 2010Assignee: Fujifilm Imaging Colorants LimitedInventor: Janette Cordwell
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Publication number: 20100257678Abstract: Disclosed is an azo compound represented by the formula (1) below, a salt thereof, or a copper complex salt compound thereof. (In the formula, R1 and R2 independently represent a hydrogen atom, a sulfonic acid group, a lower alkyl group or a lower alkoxyl group; R3-R6 independently represent a hydrogen atom, a lower alkyl group or a lower alkoxyl group; R7 represents a lower alkyl group or a lower alkoxyl group; and n represents 0 or 1.Type: ApplicationFiled: June 21, 2007Publication date: October 14, 2010Inventors: Yuichi Sadamitsu, Takahiro Higeta
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Patent number: 7745385Abstract: The present invention relates to a water-soluble pouch comprising a laundry detergent composition comprising reactive dye.Type: GrantFiled: March 30, 2009Date of Patent: June 29, 2010Assignee: The Procter & Gamble CompanyInventor: Alan Thomas Brooker
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Patent number: 7717965Abstract: Dye mixtures that comprise at least one dye of formula together with at least one dye from the group of formulae wherein the radicals have the definitions given in the claims, are suitable, with good build-up behaviour, for dyeing or printing cellulose-containing fibre materials, and yield dyeings having a deep shade and good fastness properties.Type: GrantFiled: June 28, 2006Date of Patent: May 18, 2010Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Lue Christnacher, Bruno Cortese
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Patent number: 7713311Abstract: The present invention relates to aqueous liquid formulations comprising 5-30% by weight of a dye composition comprising 25-85% by weight of Direct Brown 44 15-75% by weight of Direct Yellow 11 and/or of a dye obtainable by reduction or thermal treatment of Direct Yellow 11 0-15% by weight of one or more blue direct dyes and 0-10% by weight of one or more red direct dyes all based on the dye composition 0.5-15% by weight of one or more alkylamines whose one, two or three alkyl radicals may each be substituted by one or two hydroxyl groups and/or amino groups and/or interrupted by one or two oxygen atoms in ether function, based on the total weight of the aqueous liquid formulation, the sodium content of the liquid formulation not exceeding 0.3% by weight, and also their use for dyeing cellulose material especially paper.Type: GrantFiled: November 13, 2006Date of Patent: May 11, 2010Assignee: BASF AktiengesellschaftInventors: Ingo Klopp, Karl-Heinz Etzbach, Helmut Reichelt
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Patent number: 7708786Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2—Z or —Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: June 27, 2008Date of Patent: May 4, 2010Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
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Patent number: 7704287Abstract: The present invention provides a reactive red dye composition comprising (A) 3% to 97% by weight of a reactive azo dye of the following formula (I), wherein W, D1 and D2 are defined the same as the specification; and (B) 97% to 3% by weight of a reactive azo dye of the following formula (II), wherein R, X, Z, D3 and D4 are defined the same as the specification. The reactive red dye composition of the present invention can be utilized to dye cellulose fibers. The cellulose fibers dyed by the reactive red dye composition obtain not only good build-up and level dyeing properties but also an excellent property of white discharging.Type: GrantFiled: May 22, 2007Date of Patent: April 27, 2010Assignee: Everlight USA, Inc.Inventors: Bao-Kun Lai, Huei-Chin Huang, Cheng-Hsiang Hsu, Ya-Chi Tseng
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Patent number: 7704286Abstract: A dye composition, which comprising: (a) a mono azo dye of the formula (I) wherein R, R1, K, Y and m are defined the same as the specification; and (b)at least one azo dye selected from the group consisting of the following formula (II), (III) and (IV), wherein R, R2, R3, Y, (W)0˜3, (W?)0˜3, D, D1 and D2 are defined the same as the specification. These kinds of dye composition with good stability and build-up. The dye composition are suitable for dyeing and printing of materials containing either cellulose fibers, such as cotton, artificial cotton, linen, and artificial linen, or synthetic polyamide, such as wool, silk, and nylon etc. Dyed materials with excellent properties can be obtained, showing especially outstanding performance in of wash-off, built-up, level-dyeing, photochromism, wet-fastnes, ghosting fastness and light fastness.Type: GrantFiled: December 15, 2005Date of Patent: April 27, 2010Assignee: Everlight USA, Inc.Inventors: Huei-Chin Huang, Ya-Chi Tseng
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Patent number: 7682406Abstract: The invention relates to novel dyes of the formula (1) in which D represents a phenyl or naphthalene residue which is substituted by one or two sulphonic Acid or carboxylic acid groups and, optionally, by one or two groups selected from C1-C4alkyl, hydroxyl and nitro, each R1 and R2, independently, represent hydrogen or, a C1-C4alkyl group, R?1 represents hydrogen, hydroxyl, C1-C4alkyl or C1-C4hydroxyalkyl, R3 represents hydrogen, C1-C4alkyl or phenyl, which is unsubstituted or substituted by one or two groups selected from C1-C4alkyl, C1-C4alkoxy, halogen, hydroxyl, —NH2, nitro, —SO3M and —CO2M and M represents hydrogen, an alkaline or alkaline earth metal, ammonium or ammonium that is mono-, di-, tri- or tetrasubstituted by C1-C4alkyl or C2-C4hydroxyalkyl or a polyglycolammonium cation and also known dyes of formula (5), in which D? represents a phenyl or naphthalene residue which is substituted by one or two sulphonic acid or carboxylic acid groups and, optionally, by one or two groups selected from C1-C4aType: GrantFiled: June 26, 2006Date of Patent: March 23, 2010Assignee: Ciba Specialty Chemicals CorporationInventors: Adolf Käser, Wolfgang Schlenker
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Publication number: 20090320217Abstract: The present invention provides dye mixtures containing one or more dyes of the general formula (I) and one or more dyes of the general formulae (II) where D1, D2, D3 RA, RB, RC, Z1 and M are each as defined in claim 1, processes for their preparation and their use.Type: ApplicationFiled: January 28, 2008Publication date: December 31, 2009Applicant: DyStar Textifarben GmbH & Co. Deutschland KGInventors: Stefan Ehrenberg, Stefan Meier, Christian Schumacher
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Patent number: 7637964Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (I) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: May 27, 2008Date of Patent: December 29, 2009Assignee: DyStar Textilfarben GmbH & Co.Inventors: Stefan Meier, Werner Russ, Joachim Eichhorn
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Patent number: 7604669Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein B1, B2 and B3 are each independently of the others an organic bridging member, Q1 is C1-C4alkyl, halogen or a radical —SO2-Z, Q2 and Q3 are each independently of the other C1-C4alkoxy, Q4 is C1-C4alkoxy, C1-C4alkyl, halogen or sulfo Q5 is C1-C4alkoxy, C1-C4alkyl, C1-C4alkanoylamino, ureido, halogen or sulfo, R1, R2, R3, R4, R5, R6, R7, R8 and R9 are each independently of the others hydrogen or unsubstituted or substituted C1-C4alkyl, k and q are each independently of the other the number 0 or 1, n and p are each independently of the other the number 0, 1 or 2, m is the number 0, 1, 2 or 3, t is the number 1, 2 or 3, X1, X2, X3, X4, X5 and X6 are each independently of the others halogen, and T1, T2 and T3 are each independently of the others a non-fiber-reactive substituent or a fiber-reactive radical of formula wherein (R10)0-2 denotes from 0 to 2 identical or different substituents frType: GrantFiled: November 6, 2006Date of Patent: October 20, 2009Assignee: Huntsman International LLCInventors: Jean-Marie Sire, Athanassios Tzikas, Georg Roentgen
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Patent number: 7572301Abstract: Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y ??(3a), —NH—CO—(CH2)m—SO2—Y??(3b), —CONH—(CH2)n—SO2—Y??(3c), —NH—CO—CH(Hal)-CH2-Hal??(3d) or —NH—CO—C(Hal)=CH2??(3e), Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.Type: GrantFiled: March 9, 2005Date of Patent: August 11, 2009Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Luc Christnacher
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Patent number: 7553340Abstract: Reactive dyes of formula (1) wherein R1 is hydrogen or unsubstituted or substituted C1-C4alkyl, R2 is hydrogen; C1-C4alkyl; C1-C4alkoxy unsubstituted or substituted by sulfato, hydroxy or by C1-C4alkoxy; halogen; carboxy or sulfo, R3 is hydrogen; C1-C4alkyl; C1-C4alkoxy unsubstituted or substituted by sulfato, hydroxy or by C1-C4alkoxy; halogen; nitro; C2-C4alkanoylamino; ureido; carboxy or sulfo, (R4)k denotes k identical or different substituents selected from the group halogen, C1-C4-alkyl, C1-C4alkoxy, carboxy and sulfo, X is halogen and V is a radical of formula (2a), 2(b) wherein R5 is unsubstituted or substituted C1-C4alkyl, (R6)I denotes I identical or different substituents from the group C1-C4alkyl, C1-C4alkoxy and sulfo, and I is the number 0, 1 or 2, Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(HaI)-CH2-HaI or —C(HaI)=CH2 group, Hal is halogen and k is the number 0, 1 , 2 or 3, are suitable especially for dyeing cotton and yield dyeingType: GrantFiled: November 2, 2005Date of Patent: June 30, 2009Assignee: Huntsman International, LLCInventors: Athanassios Tzikas, Georg Roentgen, Herbert Klier
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Patent number: 7540883Abstract: The present invention discloses a reactive yellow dye composition comprising component (A) and component (B). The component (A) is a reactive azo dye represented by the following formula (I) or formula (II), The component (B) is a reactive azo dye represented by the following formula (III), wherein the substituents of the formulas (I), (II) and (III) are defined the same as in the specification. Moreover, the reactive yellow dye composition of the present invention has excellent build-up, wash-off and light fastness and can be applied with dyestuffs in other colors.Type: GrantFiled: August 2, 2007Date of Patent: June 2, 2009Assignee: Everlight USA, Inc.Inventors: Bao-Kun Lai, Cheng-Hsiang Hsu, Ya-Chi Tseng, Huei-Chin Huang
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Patent number: 7531494Abstract: A fabric treatment composition comprising from about 0.0001% to about 0.01% by weight of a fabric substantive dye loaded onto a particle carrier having an average particle size of less than 100 ?m is disclosed. The process for making the fabric treatment composition is described. A fabric substantive dye-loaded particle carrier having an average particle size of less than 100 ?m and comprising from about 0.001% to about 1% by weight of a fabric substantive dye is described.Type: GrantFiled: November 8, 2007Date of Patent: May 12, 2009Assignee: The Procter & Gamble CompanyInventors: Elaine Hunter Gardiner, Xiaotian Zou
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Patent number: 7517369Abstract: The present invention relates to dyes of formula (1) that are soluble in organic solvents, wherein Cat+ is an organic cation, to a process for their preparation and to their use in the production of colored plastics or polymeric color particles, printing colorants, printing pastes and printing inks.Type: GrantFiled: December 19, 2005Date of Patent: April 14, 2009Assignee: Ciba Specialty Chemicals CorporationInventors: Thomas Ruch, Ursula Luterbacher
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Patent number: 7468081Abstract: The present invention relates to processes for mono-, di- or trichromatic dyeing or printing of natural or synthetic polyamide fiber materials, these processes utilizing a) blue-dyeing dye mixture, b) a red-dyeing dye mixture and/or c) a yellow-dyeing dye mixture, and also blue-dyeing, red-dyeing and yellow-dyeing dye mixtures and processes for their preparation.Type: GrantFiled: September 22, 2004Date of Patent: December 23, 2008Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Stefan Ehrenberg, Andreas Giehl, Jörg Wörner
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Patent number: 7455699Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: March 18, 2003Date of Patent: November 25, 2008Assignee: DyStar Texilfarben GmbH & Co. Deutschland KGInventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
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Patent number: 7429279Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (i) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: July 26, 2004Date of Patent: September 30, 2008Assignee: DyStar Textilfarben GmbH + Co. Deutschland KGInventors: Stefan Meier, Werner Russ, Joachim Eichhorn
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Publication number: 20080189883Abstract: Dye mixtures comprising one or more, such as two or three, preferably 1 or 2, dyes of the formula (1) and at least 2 dyes of the formula (2) in which Me, M, n, and V1 to V11 are as defined in claim 1, their preparation, and their use for dyeing and printing hydroxyl- and carboxamido-containing material.Type: ApplicationFiled: March 15, 2006Publication date: August 14, 2008Applicant: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Thomas Ruchser, Oliver Steinau, Andreas Giehl
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Patent number: 7387647Abstract: A dye composition, comprising (A) at least one disazo dye selected from the formula (I) or (II), wherein R, R1, R2, D1 and D2 are defined as in the specification; and (B) a diazo dye of the formula (III), wherein (R9)0˜2, (R10)0˜2, Q1 and Q2 are defined as in the specification. These dye compositions have high fixation and good build-up. They are distinguished also by high washing off and low nylon staining and they are suitable for dyeing and printing of materials containing either cellulose fibers, such as cotton, artificial cotton, linen, and artificial linen, or polyamide fibers, such as wool, silk, and nylon etc. Dyed materials with excellent properties can be obtained, showing especially outstanding performance in washing off, levelness, build-up, wet fastness and light fastness.Type: GrantFiled: May 25, 2005Date of Patent: June 17, 2008Assignee: Everlight USA, Inc.Inventors: Huei-Chin Huang, Sheena Lee, Sheue-Rong Lee, Bao-Kun Lai, Cheng-Hsiang Hsu, Ya-Chi Tseng
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Patent number: 7387667Abstract: The present invention relates to a black dye composition, comprising: (a) a compound of the following formula (I), (b) a compound of the following formula (II), (c) a compound of the following formula (III), wherein R1, R2, R3, and R4 are defined the same as the specification. The present invention also relates to a black ink composition afforded from the aforementioned black dye composition. The black ink composition of the present invention is suitable for paper ink-jet printing, and exhibits the properties of good light-fastness, high color strength, solubility, and fine fluency of ink.Type: GrantFiled: September 13, 2007Date of Patent: June 17, 2008Assignee: Everlight USA, Inc.Inventors: Wen-Chin Lin, Tzu-Kwei Sun, Reng-Fang Lin
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Patent number: 7381256Abstract: The present invention relates to a dye mixture which comprises at least one dye of the general formula (I) and at least one dye of the general formula (II) in which D1, D2, W1, W2, Y1, Y2, R1 to R6, M, m and n are defined as indicated in claim 1, to processes for preparing them, to their use, and to inks comprising them for digital printing.Type: GrantFiled: April 9, 2005Date of Patent: June 3, 2008Assignee: Dystar Textilfarben GmbH & Co. Deutschland KGInventors: Stefan Meier, Uwe Reiher, Werner Hubert Russ, Christian Schumacher
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Patent number: RE47618Abstract: The present invention refers to a red-dyeing acid dye mixture comprising a dye of the formula (I) and at least one dye of the formula (II) a process for its manufacturing and a process for dyeing and printing of natural or synthetic polyamide fiber material in which it used.Type: GrantFiled: July 12, 2017Date of Patent: September 24, 2019Assignee: DyStar Colours Distribution GmbHInventors: Thomas Ruchser, Andreas Giehl