Basic Dye Patents (Class 8/644)
  • Patent number: 8425622
    Abstract: A soluble solid hair coloring article having cationic direct dye and one or more soluble porous solids containing nonionic surfactant, cationic surfactant, or a mixture thereof, such that the one or more soluble porous solids have a density of from about 0.03 g/cm3 to about 0.15 g/cm3; and methods of applying the soluble solid hair coloring article to hair.
    Type: Grant
    Filed: May 23, 2012
    Date of Patent: April 23, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Timothy James Felts, Guiru Zhang, Jorge Max Sunkel, Bryan Patrick Murphy
  • Patent number: 8303671
    Abstract: A composition including a basic dye component and an acid dye component providing an internal salt composition wherein at least one of the basic dye component, the acid dye component, or both the basic dye component and the acid dye component comprises a waxy moiety.
    Type: Grant
    Filed: February 6, 2007
    Date of Patent: November 6, 2012
    Assignee: Xerox Corporation
    Inventor: Jeffrey H. Banning
  • Publication number: 20120110750
    Abstract: Disclosed are polymeric dyes of formula (1a), (1b), or (1c); wherein A and B, independently from each other represent a polymer backbone; X1 and X2 independently from each other are a linkage group selected from —S—, —S—S—, —N—, —N?—, —N(R5)—, —S(O)—, —SO2—, —(CH2CH2—O)1-5—, —(CH2CH2CH2—O)1-5—, —C(O)—, —C(O)O—, —OCO—, (formula II) —CON(R1)—, —C(NR1R2)2—, —(R1)NC(O)—, —C(S)R1—; which may be interrupted and/or terminated at one or both ends by one or more than one —C1C30alkylene- or —C2-C12alkenylene-; or an optionally substituted, saturated or unsaturated, fused or non-fused aromatic or nonaromatic (heterocyclic) bivalent radical optionally comprising at least one heteroatom; a saturated or unsaturated, fused or non-fused aromatic or nonaromatic bivalent radical comprising at least one heteroatom, which is optionally substituted by C1-C30alkyl, C1-C30alkoxy, C2-C12alkenyl, C5-C10aryl, C5-C10cycloalkyl, C1-C10alkyl(C5-C10arylene), hydroxy or halogen; R1 and R2 independently from each other are hydrogen; unsubst
    Type: Application
    Filed: July 15, 2010
    Publication date: May 10, 2012
    Applicant: BASF SE
    Inventors: Christian Cremer, Oliver Becherer, Beate Fröhling
  • Patent number: 7744656
    Abstract: The present invention is related to an aqueous colouring composition for keratin fibers especially human hair based on hair direct dyes and optionally oxidative dyes and comprising at least one arylated silicone.
    Type: Grant
    Filed: August 5, 2008
    Date of Patent: June 29, 2010
    Assignee: KPSS-Kao Professional Salon Services GmbH
    Inventors: Michael Molenda, Martin Hoffmann, Mustafa Grit
  • Patent number: 7422608
    Abstract: The present invention concerns a shampoo composition with color enhancing effect and showing optimum hair conditioning properties, especially shine, softness and good manageability. Composition comprises at least one cleansing and lathering surfactant, at least one cationic hair dye and at least one hydroxycarboxylic acid and/or dicarboxylic acid.
    Type: Grant
    Filed: November 7, 2005
    Date of Patent: September 9, 2008
    Assignee: KPSS-KAO Professional Salon Services GmbH
    Inventors: Michael Molenda, Frank Golinski
  • Patent number: 7300473
    Abstract: The invention relates to a composition for dyeing fibers such as the hair, comprising at least one cationic direct dye of given formula, and which also contains at least one thickening polymer chosen from the group comprising: —nonionic amphiphilic polymers comprising at least one hydrophilic unit and at least one unit containing a fatty chain, —anionic amphiphilic polymers comprising at least one hydrophilic unit and at least one unit containing a fatty chain, —cationic amphiphilic polymers comprising at least one hydrophilic unit and at least one unit containing a fatty chain. The invention also relates to the dyeing processes and dyeing kits therefor.
    Type: Grant
    Filed: November 1, 2006
    Date of Patent: November 27, 2007
    Assignee: L'Oreal S.A.
    Inventors: Gérard Lang, Jean Cotteret
  • Patent number: 7198652
    Abstract: The invention relates to a composition for dyeing keratinous fibers, in particular human keratinous fibers such as hair, comprising, in an appropriate dyeing medium, at least one cationic direct dye of a given formula, and which is characterized in that it contains, in addition, at least one quaternary ammonium salt. The invention also relates to the dyeing methods and devices using it.
    Type: Grant
    Filed: March 21, 2006
    Date of Patent: April 3, 2007
    Assignee: L'Oreal S.A.
    Inventor: Christine Rondeau
  • Patent number: 7087096
    Abstract: The invention concerns a dyeing composition for keratinous fibers, in particular human keratinous fibers such as hair, comprising in an appropriate dyeing medium, at least a direct cationic coloring agent of specific formula, and characterized in that it further contains at least a quaternary ammonium salt. The invention also concerns methods and devices using said composition.
    Type: Grant
    Filed: July 1, 2004
    Date of Patent: August 8, 2006
    Assignee: L'Oreal
    Inventor: Christine Rondeau
  • Patent number: 6666897
    Abstract: The present invention relates to black alcohol soluble dye formulations of high color intensity, low viscosity, and high tinctorial strength. The formulations are particularly useful for writing instruments such as felt tip and roller ball pens.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: December 23, 2003
    Inventors: Alejandro Zimin, Sr., Michael R. Friswell
  • Patent number: 6589706
    Abstract: A cyanine dye (I) for using in high density optical disc recording medium, having the following structure: in which R1 represents R2 represents and alkyl with C1-C18 or X− represents an acid anion. This cyanine dye is suitable for use as a &lgr;=500 nm−650 nm visible light-absorbing organic dye useful as a high density optical disc recording medium.
    Type: Grant
    Filed: November 22, 2000
    Date of Patent: July 8, 2003
    Assignees: Industrial Technology Research Institute, National Tsing-Hua University
    Inventors: Wen-Yih Liao, Andrew Teh Hu, Chien-Liang Huang, Huei-Wen Yang, Der-Ray Huang, Ding-Yih Hu, Ming-Chia Lee, Hong-Ji Lee
  • Patent number: 6566522
    Abstract: The present invention provides a rhodamine dye for recording layer of the high density optical recording disc, which has a chemical structure as shown in (I): where X− represents an acid anion and R represents a benzoic acid group, benzene sulfonic acid group or benzoic ester group. The dye of the present invention is applicable to recording layer of the high density optical recording disc after prepared appropriately. The dye of the present invention is cost efficient and simple in synthesis and purification.
    Type: Grant
    Filed: July 29, 2002
    Date of Patent: May 20, 2003
    Assignee: Industrial Technology Research Institute
    Inventors: Song-Yeu Tsai, Tien-Tsan Hung, Shih-Peng Hsu, Hao-Hsien Chiang
  • Publication number: 20020178517
    Abstract: The object of the present invention is to provide organic dye compounds which exert satisfactory optical absorption properties and thermal resistance when used in high density optical recording media. The above object is solved by specific trimethine cyanine dyes, light absorbents and optical recording media which comprise the cyanine dyes, and preparations for the cyanine dyes comprising either reacting a benzoindolium compound having a compatible leaving group with a pyrazinoimidazolium compound having a reactive methyl group; or reacting a benzoindolium compound having a reactive methyl group with a pyrazinoimidazolium compound having a compatible leaving group.
    Type: Application
    Filed: October 23, 2001
    Publication date: December 5, 2002
    Inventors: Chiaki Kasada, Katsumi Orita, Kentaro Yano, Toshio Kawata, Shigeo Yasui
  • Patent number: 6361571
    Abstract: The object of the present invention is a colorant for the semi-permanent tinting of keratin fibers, said colorant being based on a combination of nonoxidative dyes and polymethine dyes of the tautomeric formula (Ia)/(Ib) and a method for tinting keratin fibers.
    Type: Grant
    Filed: January 4, 2000
    Date of Patent: March 26, 2002
    Assignee: Wella Aktiengesellschaft
    Inventors: Otto Goettel, Aline Pirrello
  • Patent number: 6221113
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25° C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: April 24, 2001
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Jürgen Geiwiz
  • Patent number: 5958087
    Abstract: A cyanine dye for using in high density optical disc recording medium, having the following structure: ##STR1## wherein R represents 4-methoxycarbonyl benzyl group, X.sup.- represents an acid anion, and n represents an integer of 1 or 2. This cyanine dye is suitable for use as a .lambda.=450 nm.about.650 nm visible light-absorbing organic dye useful as a high density optical disc recording medium.
    Type: Grant
    Filed: February 8, 1999
    Date of Patent: September 28, 1999
    Assignees: Industrial Technology Research Institute, National Tsing Hua University
    Inventors: Wen-Yih Liao, Chien-Liang Huang, Der-Ray Huang, Don-Yau Chiang, Andrew Teh Hu, Hong-Ji Lee, Shi-Jae Ye, Ying-Jen Kao
  • Patent number: 5944856
    Abstract: A liquid dyestuff composition comprising from 4 to 50 wt % of a basic or cationic water soluble dyestuff, an organic or inorganic acid and 0.1 to 15.0 wt % of a phenolic derivative, the dyestuff having a solubility in water in the presence or absence of a phenolic derivative of at least 1 g/liter at a temperature of 25.degree. C. and the composition being made up to 100 wt % by water and optionally a water-miscible solvent and/or a dissolving auxiliary; a process of dyeing a substrate like paper with such composition; a powder or granulate form of such composition and the use of such a composition or powder or granulate thereof in a dyeing process.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: August 31, 1999
    Assignee: Clariant Finanace (BVI) Limited
    Inventor: Jurgen Geiwiz
  • Patent number: 5514819
    Abstract: The present invention provides a dye-donor element for use according to thermal dye sublimation transfer, said dye-donor element comprising a support provided with a dye layer containing a dye and a polymeric binder, characterized in that said dye corresponds to the following formula: ##STR1## wherein R.sup.1 to R.sup.12 are as set out in the claims and the description.
    Type: Grant
    Filed: September 20, 1994
    Date of Patent: May 7, 1996
    Assignee: Agfa-Gevaert N.V.
    Inventor: Luc Vanmaele
  • Patent number: 5415669
    Abstract: The present invention relates to mixtures of dyes of the general formula I ##STR1## in which R.sup.1 is hydrogen, halogen, (C.sub.1 -C.sub.4) -alkyl or (C.sub.1 -C.sub.4)-alkoxy;R.sup.2 is hydrogen, halogen, cyano, (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy, (C.sub.1 -C.sub.4)-alkoxycarbonyl, (C.sub.1 -C.sub.4)-alkylcarbonyloxy or phenyl, which may be substituted or unsubstituted;R.sup.3 is hydrogen, (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy or phenyl, which may be substituted or unsubstituted; andR.sup.4 is hydrogen, halogen, (C.sub.1 -C.sub.4)-alkoxy, phenylthio or phenoxy, which may be substituted or unsubstituted, to processes for their preparation and to the use of the dyes of the general formula I and their mixtures with one another for the dyeing and printing of textile hydrophobic synthetic fibre materials and blends thereof with natural fibre materials.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: May 16, 1995
    Assignee: Hoechst Mitsubishi Kasei Co.
    Inventors: Ulrich Buhler, Hubert Kruse, Erwin Dietz
  • Patent number: 5328993
    Abstract: The new cationic triazatrimethine dyestuffs of the formula ##STR1## wherein the substituents B, Z, R.sup.2 and An.sup..crclbar. have the meaning given in the description, are suitable for dyeing and printing naturally occurring and synthetic materials.
    Type: Grant
    Filed: April 15, 1993
    Date of Patent: July 12, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hauke Furstenwerth, Karl-Heinrich Lange, Roderich Raue, Alfred Brack
  • Patent number: 5318601
    Abstract: Dye mixtures containing from 50 to 95% by weight, of a 4-chloro-2-nitrophenylazohydroxypyridone dye and from 5 to 50% by weight of a chlorinated quinophthalone dye and/or from 5 to 20% by weight of an unsubstituted quinophthalone dye, dye formulations containing the novel dye mixtures and the use of dye mixtures for dyeing polyesters or printing them by the direct printing method.
    Type: Grant
    Filed: March 29, 1993
    Date of Patent: June 7, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Arno Lange, Gert Motzkus, Helmut Degen, Volker Walther
  • Patent number: 5279622
    Abstract: Solid dyestuff preparations of reactive phthalocyanine dyestuffs of the formula ##STR1## in which the substituents have the meaning given in the description, have improved solubility in water if they contain 5 to 15% by weight of an acid-binding agent.
    Type: Grant
    Filed: April 28, 1992
    Date of Patent: January 18, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Josef-Walter Stawitz, Frank-Michael Stohr, Joachim Wolff
  • Patent number: 5057154
    Abstract: A leuco dye of the formula (I): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, and R.sup.8 each represent a lower alkyl group; A represents ##STR2## in which R.sup.9 and R.sup.10 each represent hydrogen, provided that both R.sup.9 and R.sup.10 may not be hydrogen, --CN or --COR.sup.14 in which R.sup.14 represents a phenyl group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms, or a halogen, a naphthyl group which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, an alkoxyl group having 1 to 4 carbon atoms or a halogen, or a lower alkoxyl group, ##STR3## in which ##STR4## represents a phenyl group or a naphthyl group, R.sup.11 represents hydrogen, a lower alkyl group, a halogen, an amino group, which is unsubstituted or is substituted by an alkyl group having 1 to 4 carbon atoms, or a nitro group, or ##STR5## in which R.sup.
    Type: Grant
    Filed: April 20, 1990
    Date of Patent: October 15, 1991
    Assignee: Ricoh Company, Ltd.
    Inventors: Shigeru Kusakata, Hiroshi Gotoh, Isao Shiojima
  • Patent number: 4944768
    Abstract: There are disclosed solid dye formulations which comprise at least one anionic wool dye and optional additional components as well as a mixture of an anionic dispersant and an amphoteric surfactant. Such formulations are distinguished in particular by improved solubility in water.
    Type: Grant
    Filed: February 13, 1989
    Date of Patent: July 31, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Paolo Balliello, Otto Schilling, Beat Bruttel
  • Patent number: 4840641
    Abstract: Cationic diazacyanine dyestuffs of the formula ##STR1## and their mixtures with the isomeric dyestuffs of the formula ##STR2## wherein R represents methyl or ethyl andX.sup.- represents a colorless anion, are suitable for dyeing polyacrylonitrile and, in particular, polyacrylonitrile-wool mixtures.
    Type: Grant
    Filed: April 4, 1988
    Date of Patent: June 20, 1989
    Assignee: Bayer Aktiengesellschaft
    Inventor: Alfred Brack
  • Patent number: 4705524
    Abstract: The invention relates to dye compositions for preparing level dyeings on carboxamide- or hydroxyl-containing fiber materials of comparatively good light fastness properties, which contain dioxazine dyes I (Ia and/or Ib) and II (one or more of IIa to IId) in a weight ratio of 90:10 to 10:90 ##STR1## where in each case independently of one another Z denotes vinyl or .beta.-sulfatoethyl,Z' denotes vinyl-SO.sub.2 or .beta.-sulfatoethyl-SO.sub.2 --,R denotes sulfo or --SO.sub.2 --NR.sup.8 R.sup.9, wherein R.sup.8 is H or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl and R.sup.9 is H, C.sub.1 -C.sub.4 -alkyl which can be substituted by sulfato, sulfo, carboxyl or phosphato, or is an arylated C.sub.1 -C.sub.4 -alkyl group which can be substituted in the aryl radical by sulfo or carboxyl,R.sup.1 denotes H or substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl,R.sup.2 denotes C.sub.1 -C.sub.
    Type: Grant
    Filed: November 25, 1986
    Date of Patent: November 10, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Marcos Segal
  • Patent number: 4521217
    Abstract: Mixtures of a phthalocyanine dyestuff and a substantive azo dyestuff which preferably has cationic or basic groups are suitable for dyeing paper.
    Type: Grant
    Filed: January 6, 1984
    Date of Patent: June 4, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventors: Ulrich Beck, Frank-Michael Stohr, Horst Nickel
  • Patent number: 4502862
    Abstract: Cationic polyazo dyestuffs which can be obtained by reacting diaminobenzene derivatives of the general formula ##STR1## wherein R represents hydrogen, C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy or halogen,if appropriate in a mixture with up to 30% of aromatic monoamines of the formula ##STR2## wherein R.sup.2 represents hydrogen, C.sub.1 - to C.sub.4 -alkyl, C.sub.1 - to C.sub.4 -alkoxy, halogen or C.sub.1 - to C.sub.4 -acylamino and n represents 1 to 3,with 0.5 to 0.75 mole of a salt or ester of nitrous acid per mole of diamine and then with 1 to 4 moles of an alkylene oxide of the formula ##STR3## wherein R.sup.3 represents hydrogen or an optionally hydroxyl-, alkoxy- or halogen-substituted C.sub.1 - to C.sub.4 -alkyl radical,are used--preferably in the form of their solutions--for dyeing paper, leather and anionically modified synthetic fibres.
    Type: Grant
    Filed: January 16, 1984
    Date of Patent: March 5, 1985
    Assignee: Bayer Aktiengesellschaft
    Inventor: Roderich Rave
  • Patent number: 4462805
    Abstract: A mixture of cationic compounds of the formulae ##STR1## is obtained by reaction of a compound of the formula ##STR2## with an aldehyde of the formula II ##STR3## in an aqueous or organic medium, in the presence of an acid, in which formulae, the symbols have the meanings defined in claim 1. The mixtures obtained are suitable in particular for the dyeing of paper, whereby neutral-yellow dyeings are obtained.
    Type: Grant
    Filed: May 10, 1983
    Date of Patent: July 31, 1984
    Assignee: Ciba-Geigy Corporation
    Inventors: Willy Stingelin, Peter Loew
  • Patent number: 4426205
    Abstract: A red dye composition comprising the dye compound ##STR1## wherein R.sup.1.spsp..sym. and R.sup.2.spsp..sym. are alkali metal cations or ammonium ions of a lower alkylol amine, and R.sub.3 is hydrogen or lower alkyl, and at least one rhodamine dye.
    Type: Grant
    Filed: December 20, 1982
    Date of Patent: January 17, 1984
    Assignee: American Cyanamid Company
    Inventors: Robert F. Bann, John E. Innes
  • Patent number: 4421519
    Abstract: There are described novel dye mixtures of the dyes I and II or Ia and II ##STR1## wherein the symbols have the meanings defined in claim 1. These mixtures can be used in particular for dyeing and printing polyacrylonitrile materials, or mixed fabrics of polyacrylonitrile and wool, the dyeings obtained having a clear, deeply colored blue shade and especially a very good evening shade.
    Type: Grant
    Filed: June 7, 1982
    Date of Patent: December 20, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Peter Loew, Rudolf Zink
  • Patent number: 4410332
    Abstract: A process is described for the level di- and trichromatic dyeing of polyacrylonitrile materials or of blends containing polyacrylonitrile, which process comprises using for the dyeing an aqueous dyeing liquor which contains at least two dye mixtures, each dye mixture consisting of at least (a) one migrating cationic dye, the cation weight of which is less than 310, the parachor of which is less than 750 and the log P of which is less than 3.6, and (b) at least one non-migrating cationic dye, at least one parameter of which is outside the definition given under (a), and the components (a) and (b) being employed in a mixing ratio which is such that during the dyeing process the migrating and non-migrating dyes migrate on the fibre on tone. This produces, on polyacrylonitrile materials, dyeings which are distinguished by high levelness and high lightfastness.
    Type: Grant
    Filed: February 11, 1982
    Date of Patent: October 18, 1983
    Assignee: Ciba-Geigy Corporation
    Inventors: Manfred Herrmann, Rico Jenny, Manfred Motter
  • Patent number: 4400370
    Abstract: In the diagnosis and prognosis of various diseases as well as medical researches in relation thereto studies leading to differentiation, identification, enumeration and following the variations in human blood, leukocytes play a vital role. Heretofore, accurate detailed lengthy and arduous procedures were essential to such ends, if available. In a parent case, of which this is a continuation-in-part, it was found selective use of certain basic quaternary, metachromatic dye staining by supravital techniques made possible instantaneous optical differentiation of the five major individual leukocyte species. Here further research has revealed that with but one of the species of the dye class above one can by the same techniques make the foregoing determinations with regard to specific leukocytes including promyelocytes, myelocytes, metamyelocytes, band cells, T-cells and B-cells as well as the neutrophils, eosinophils, basophils and monocytes of the parent disclosure.
    Type: Grant
    Filed: March 11, 1981
    Date of Patent: August 23, 1983
    Inventor: Lawrence Kass
  • Patent number: 4392864
    Abstract: Disclosed is a Romanowsky stain having improved stability characteristics which comprises a methanol solution of Methylene Blue, an azure dye and the free acid of Eosin Y.
    Type: Grant
    Filed: February 1, 1982
    Date of Patent: July 12, 1983
    Assignee: Miles Laboratories, Inc.
    Inventors: Elaine A. Helfrich, Kin F. Yip
  • Patent number: 4382075
    Abstract: The present invention is a stabilized Romanowsky type stain solution. The stain solution which comprises azures, Methylene Blue and an eosin dye in methanol solution, is stabilized by the addition thereto of a stabilizing amount of a combination of dimethylamine hydrochloride and a second amine of the formula R.sub.2 NH.sub.2.sup.+ Cl.sup.- or R.sub.3 NH.sup.+ Cl.sup.- where R is ethyl, n-propyl or n-butyl.
    Type: Grant
    Filed: April 3, 1981
    Date of Patent: May 3, 1983
    Assignee: Miles Laboratories, Inc.
    Inventors: John C. Liao, John L. Ponzo, Ellen M. Jenning
  • Patent number: 4363632
    Abstract: Disclosed is a cell-staining solution which contains Azure B, Eosin Y, and a stabilizing amount of diethylamine hydrochloride in methanolic solution, which produces a Romanowsky-type staining effect.
    Type: Grant
    Filed: December 28, 1981
    Date of Patent: December 14, 1982
    Assignee: Miles Laboratories, Inc.
    Inventors: Elizabeth Custard, John C. Liao, John L. Ponzo
  • Patent number: 4290769
    Abstract: The present invention is a stabilized Romanowsky type stain solution. The stain solution which comprises azures, Methylene Blue and an eosin dye in methanol is stabilized by the addition thereto of an ammonium halide, a primary, secondary or tertiary alkylamine hydrohalide or a combination thereof.
    Type: Grant
    Filed: October 14, 1980
    Date of Patent: September 22, 1981
    Assignee: Miles Laboratories, Inc.
    Inventors: John C. Liao, Chittaranjan P. Patel, John L. Ponzo
  • Patent number: 4252535
    Abstract: A dyeing process has been found which enables to dye uniformly polyacrylonitrile fiber materials, by using as dyestuffs basic azo dyestuffs being non-quarternized and containing neither cationic quaternary ammonium groups nor cationic N-substituted or N-unsubstituted iminium groups, said azo dyestuffs containing on the other hand at least one unsubstituted or substituted amino group, hydrazino group, amidino group or guanidino group capable of forming salts. The very dyeing process as such is carried out according to usual processing data for dyeing polyacrylonitriles in a slightly acid medium. Especially with the use of several of these dyestuffs for polychromic dyeing, such as trichromic dyeing, special advantages are obtained, insofar that even at cut-rate dyeing periods and for preparing light color shades, there are obtained even dyes with constant color shades, when using these dyestuffs having good migrating properties.
    Type: Grant
    Filed: February 28, 1979
    Date of Patent: February 24, 1981
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Norbert Kollodzeiski, Rudolf Lowenfeld, Eberhard Mundlos, Reinhard Mohr, Kurt Hohmann
  • Patent number: 4233028
    Abstract: Described is a process for the level dyeing of polyacrylonitrile materials of slow, normal and rapid absorptive capacity with an aqueous dye liquor, which process comprises using a liquor containing at least one migrating cationic dye as well as, if required, further additives; and adding to the liquor, before, during or after dyeing, at least one organic cationic migration auxiliary.This process renders possible by the use of organic migration auxiliaries the obtainment of level single-shade and, in particular, combination-shade dyeings at normal dyeing temperatures.Particularly suitable migrating cationic dyestuffs are those having a more or less delocalized positive charge, the cation weight of which dyestuffs is smaller than 310, the parachor smaller than 750 and the log P (relative lipophil property) smaller than 3.6.Particularly suitable organic migration auxiliaries are those of which the cation weight is smaller than 250, the parachor smaller than 700 and the log P smaller than 6.4.
    Type: Grant
    Filed: January 24, 1978
    Date of Patent: November 11, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Josef Koller, Ulrich Horn, Peter Moser, Manfred Motter, Pierre Galafassi