Nitroaromatic Component Patents (Class 8/667)
  • Patent number: 9023118
    Abstract: The present invention relates to new azo dyes, a process for their preparation, and their use for dyeing or printing fibrous materials, to produce materials with brownish shades.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: May 5, 2015
    Assignee: Kemira OYJ
    Inventors: Helmut-Martin Meier, Christof Heide, Klaus-Günter Strumpf, Thomas Hübbe
  • Patent number: 8979947
    Abstract: The present invention relates to dyes of the formula (I) in which R1 to R10, D1 and D2 are defined as given in claim 1, a process for preparing them, and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.
    Type: Grant
    Filed: November 24, 2011
    Date of Patent: March 17, 2015
    Assignee: DyStar Colours Distribution GmbH
    Inventors: Roxana Barbieru, Vajiravelu Sivamurugan
  • Patent number: 8911509
    Abstract: Reactive dye mixtures comprising at least one red dyeing dye and at least one blue, yellow, orange or brown dyeing dye and their use in methods for the dichromatic or trichromatic dyeing or printing of cellulosic fiber materials are described. The reactive dye mixtures yield dyeings or prints having good reproducibility and good all-round fastness properties.
    Type: Grant
    Filed: January 13, 2011
    Date of Patent: December 16, 2014
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen, Marco Casartelli, Remo Codemo, Jean-Francois Landre
  • Patent number: 8349029
    Abstract: The present invention relates to azo dyes of the formula (1) in which R, M, and Y are defined as stated in claim 1, to dye mixtures comprising them, to processes for preparing them, and to their use.
    Type: Grant
    Filed: January 30, 2012
    Date of Patent: January 8, 2013
    Assignee: DyStar Colours Deutschland GmbH
    Inventors: Jörg Wörner, Andreas Schrell
  • Patent number: 8349028
    Abstract: The present invention relates to a reactive printing dye composition, which includes: (a) at least one reactive dye; (b) an organic buffer; and (c) a mirabilite or a dispersant. The reactive printing dye composition of the present invention is capable for being used in the fabric-dyeing, for example, dyeing of cotton, hemp, silk, rayon, wool, blending, etc. The reactive printing dye composition of the present invention is advantageous in high pH value stability, high storage stability, and reduced degradation in dyeing strength. In addition, the present invention further provides an aqueous reactive printing dye composition.
    Type: Grant
    Filed: November 13, 2009
    Date of Patent: January 8, 2013
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Chin Lin, Chien-Wen Lee
  • Patent number: 8118885
    Abstract: An azo pigment represented by the following general formula (1), a tautomer of the azo pigment, and a salt or a hydrate thereof: wherein each of R1, R2, P1, P2, Q1, and Q2 independently represents a hydrogen atom or a substituent, G represents the non-metallic atoms necessary to complete a 5- to 6-membered heterocyclic group, W represents a substituent capable of binding to the heterocyclic group constituted by G, t represents an integer of from 0 to 4, each of Het-1 and Het-2 independently represents a group selected from specific aromatic heterocyclic groups.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: February 21, 2012
    Assignee: Fujifilm Corporation
    Inventors: Keiichi Tateishi, Yoshiaki Nagata, Tomoaki Nakamura
  • Patent number: 8083811
    Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein the substituents are defined in the specification.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: December 27, 2011
    Assignee: Huntsman International LLC
    Inventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean Luc Christnacher
  • Patent number: 7666232
    Abstract: A reactive trichromatic set comprising (a) at least one of the following reactive red dye of formula (I), wherein R1, R2, R3, X, D, Z, and n are defined the same as in the specification; (b) at least one reactive yellow dye selected from the following Color Index; C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176; and (c) at least one reactive blue dye selected from the following Color Index; C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222.
    Type: Grant
    Filed: June 22, 2006
    Date of Patent: February 23, 2010
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Bao-Kun Lai, Te-Chin Sung, Cheng-Hsiang Hsu
  • Patent number: 7648535
    Abstract: The agent for coloring keratin fibers is free of chemical oxidants, is in the form of an aqueous or aqueous-alcoholic dye-containing preparation, and contains a combination of oxidation dyes and at least three direct dyes. The agent is characterized by a quantitative ratio of oxidation dyes to direct dyes equal to 5:1 to 0.5:1. A method of dyeing hair is described in which the agent is applied to hair and allowed to act on the hair for an acting time of 5 to 60 minutes without addition of chemical oxidants, so that air oxidation provides a uniform and stable coloration of the hair.
    Type: Grant
    Filed: July 6, 2004
    Date of Patent: January 19, 2010
    Assignee: Wella AG
    Inventors: Juergen Schmenger, Petra Braun, Jolanthe Kujawa, Martina Glattefelder, Anne Entzminger, Anette Sallwey, Herbert Deutz
  • Patent number: 7572301
    Abstract: Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y ??(3a), —NH—CO—(CH2)m—SO2—Y??(3b), —CONH—(CH2)n—SO2—Y??(3c), —NH—CO—CH(Hal)-CH2-Hal??(3d) or —NH—CO—C(Hal)=CH2??(3e), Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.
    Type: Grant
    Filed: March 9, 2005
    Date of Patent: August 11, 2009
    Assignee: Huntsman International LLC
    Inventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Luc Christnacher
  • Patent number: 7468081
    Abstract: The present invention relates to processes for mono-, di- or trichromatic dyeing or printing of natural or synthetic polyamide fiber materials, these processes utilizing a) blue-dyeing dye mixture, b) a red-dyeing dye mixture and/or c) a yellow-dyeing dye mixture, and also blue-dyeing, red-dyeing and yellow-dyeing dye mixtures and processes for their preparation.
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: December 23, 2008
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Ehrenberg, Andreas Giehl, Jörg Wörner
  • Patent number: 7452386
    Abstract: The present disclosure relates to a composition for bleaching and simultaneously dyeing keratin fibers, comprising at least one dye chosen from meta-substituted ortho-nitroanilines and addition salts thereof, at least one peroxygenated salt and at least one alkaline agent. The present disclosure further relates to the process for bleaching and dyeing keratin fibers using this composition, and also to the use of this composition for bleaching and simultaneously dyeing keratin fibers.
    Type: Grant
    Filed: December 5, 2005
    Date of Patent: November 18, 2008
    Assignee: L'Oreal S.A.
    Inventors: Sylvain Kravtchenko, Valérie Bonnardel
  • Patent number: 7282070
    Abstract: A reactive dye composition having satisfactory reproducibility, leveling, washing off and toughness under balanced affinity and reactivity, and improving Right First Time success ratio, for dyeing a cellulose fiber or fiber materials containing the cellulose fiber. The reactive dye composition comprising: (a) at least one reactive red dyestuff selected from the group consisting of the following formulas, the component (a) is present in an amount ranging from 1% to 99% by weight, and (b) at least one yellow reactive dyestuff selected from the group consisting of the following Color Index: C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176, and at least one blue reactive dyestuff selected from the group consisting of the following Color Index: C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222, the component (b) is present in an amount ranging from 99% to 1% by weight.
    Type: Grant
    Filed: October 19, 2005
    Date of Patent: October 16, 2007
    Assignee: Everlight USA, Inc.
    Inventors: Wen-Jang Chen, Chien-Yu Chen, Bao-Kun Lai, Ya-Chi Tseng
  • Patent number: 7238213
    Abstract: Disclosed are novel compositions and methods employing cyclic nucleotide-gated channels and fluorescence dyes and other indicators in detecting changes of intracellular cAMP levels, for instance in response to the stimulation of G-protein-coupled receptors. CNG mutants comprising one or more pore mutations that enhance sensitivity to cAMP and decrease divalent cation-mediated blockage are used in a variety of assays, including detection of the G-protein-coupled receptor activity. Also disclosed are novel dye quencher formulations that are particularly suited for cell-based assays of protein interactions.
    Type: Grant
    Filed: November 1, 2004
    Date of Patent: July 3, 2007
    Assignee: Atto Bioscience
    Inventors: Yong Yao, Liang Cao, Jianming Lu, Isabel Llorente
  • Patent number: 4874392
    Abstract: A Monoazo compounds of the formula ##STR1## wherein D is a diazo component radical of the 4-nitrophenyl series, thienyl-2 series, thiazolyl-2 series or 5-nitrobenzoisothiazolyl-3 series,R.sub.1 is hydrogen; C.sub.1-2 alkyl; C.sub.1-2 alkoxy; formylamino; (C.sub.1-4 alkyl)carbonylamino; (C.sub.1-4 alkyl)carbonylamino the alkyl group of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-3 alkoxy, cyano, phenyl, phenoxy and benzyloxy; (C.sub.2-4 alkenyl)carbonylamino; halo(C.sub.2-4 alkenyl)carbonylamino; benzoylamino; benzoylamino the phenyl group of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; (C.sub.1-4 alkoxy)carbonylamino; (C.sub.1-4 alkoxy)carbonylamino the alkyl moiety of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-3 alkoxy, cyano, phenyl, phenoxy and benzyloxy; (C.sub.8-14 alkyl)carbonylamino or (C.sub.8-14 alkoxy)carbonylamino,R.sub.2 is C.sub.
    Type: Grant
    Filed: July 29, 1987
    Date of Patent: October 17, 1989
    Assignee: Sandoz Ltd.
    Inventor: Beat Henzi
  • Patent number: 4773915
    Abstract: Azo dyestuffs of the formula ##STR1## wherein R.sub.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxyethoxy andX denotes acyl,are distinguished by good levelling properties and good allround fastness properties. They dye polyester fibres in a bright blue shade.
    Type: Grant
    Filed: January 7, 1987
    Date of Patent: September 27, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Winfried Kruckenberg, Klaus Leverenz, Hans-Gunter Otten
  • Patent number: 4368054
    Abstract: Liquid compositions of nitro group-containing aniline compounds containing no sulfonic acid and/or carboxylic acid groups and having a melting point of below 140.degree. C., especially those suitable for use as diazo component in ice color dyeing, which contain 20 to 70% of this nitro-aniline, 5 to 80 weight % of a castor oil oxethylated with 25 to 60 mols of ethylene oxide, and 5 to 65 weight % of N-methyl-pyrrolidone as solvent. By simply mixing these components clear solutions are obtained which can be diazotized within a few seconds by means of an aqueous sodium nitrite solution and thus give diazonium salt solutions free from residue. These diazonium salt solutions can be used in simple manner and very advantageously as developing baths or liquors for producing water-insoluble azo dyestuffs on the fiber according to the ice color technique.
    Type: Grant
    Filed: January 29, 1982
    Date of Patent: January 11, 1983
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Hasso Hertel
  • Patent number: 4276045
    Abstract: A process for dyeing and printing cellulosic textile material, wherein the dye used is a compound of the general formula I ##STR1## where K is a radical of the formula ##STR2## one of the radicals X and Y is a C.sub.2 -C.sub.19 -carboxylic acid ester group, a C.sub.3 -C.sub.19 -carboxamide group, a C.sub.4 -C.sub.18 -sulfonamide group, a C.sub.4 -C.sub.8 -alkylsulfone group, a C.sub.6 -C.sub.8 -arylsulfone group or a sulfonic acid aryl ester group andthe remaining substituents X, Y and Z are hydrogen, bromine or methyl andY may also be nitro,A is cyano or carbamyl,B.sup.1, B.sup.2 and B.sup.3 independently of one another are aliphatic, cycloaliphatic, araliphatic or aromatic radicals, ##STR3## is a saturated heterocyclic radical, R is hydrogen or C.sub.1 -C.sub.3 -alkyl,one of the radicals T is a radical of the formula ##STR4## and the other radical T is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl.
    Type: Grant
    Filed: June 30, 1980
    Date of Patent: June 30, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Werner Juenemann, Gunther Lamm, Hermann Loeffler
  • Patent number: 4224025
    Abstract: A process is described for the dyeing and printing of paper materials by the use of developing dyestuffs, in which process diazo components and heterocyclic coupling components containing a 6-membered heterocyclic radical having one ring nitrogen atom are applied in any sequence, either successively or simultaneously onto or into the paper material to be dyed or printed, and coupled together in alkaline, neutral or acid medium, whereby it is possible using only a single coupling component to obtain on the material, merely by variation of the diazo component, a shade of color ranging from yellow to black.
    Type: Grant
    Filed: September 11, 1978
    Date of Patent: September 23, 1980
    Assignee: Ciba-Geigy Corporation
    Inventors: Arthur Buhler, Franz H. Nedwed
  • Patent number: 4212646
    Abstract: Process for printing textile mixed fabrics of polyester and cellulose fibers with printing pastes containing coupling components dissolved in an alkaline medium, sodium nitrite, diazotizable primary aromatic amines and optionally disperse dyestuffs, in which process the amines are used as a solution or in the form of an aqueous fine dispersion with a particle size of less than 0.03 mm and are selected in a manner that they are practically non-volatile at the drying temperatures and exhibit minimum basicity with the pK.sub.a being 2.
    Type: Grant
    Filed: September 7, 1978
    Date of Patent: July 15, 1980
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Horst Curtius, Erich Feess, Willy Gronen