Nitroaromatic Component Patents (Class 8/667)
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Patent number: 9023118Abstract: The present invention relates to new azo dyes, a process for their preparation, and their use for dyeing or printing fibrous materials, to produce materials with brownish shades.Type: GrantFiled: November 29, 2011Date of Patent: May 5, 2015Assignee: Kemira OYJInventors: Helmut-Martin Meier, Christof Heide, Klaus-Günter Strumpf, Thomas Hübbe
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Patent number: 8979947Abstract: The present invention relates to dyes of the formula (I) in which R1 to R10, D1 and D2 are defined as given in claim 1, a process for preparing them, and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.Type: GrantFiled: November 24, 2011Date of Patent: March 17, 2015Assignee: DyStar Colours Distribution GmbHInventors: Roxana Barbieru, Vajiravelu Sivamurugan
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Mixtures of fibre-reactive dyes and their use in a method for di- or trichromatic dyeing or printing
Patent number: 8911509Abstract: Reactive dye mixtures comprising at least one red dyeing dye and at least one blue, yellow, orange or brown dyeing dye and their use in methods for the dichromatic or trichromatic dyeing or printing of cellulosic fiber materials are described. The reactive dye mixtures yield dyeings or prints having good reproducibility and good all-round fastness properties.Type: GrantFiled: January 13, 2011Date of Patent: December 16, 2014Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Marco Casartelli, Remo Codemo, Jean-Francois Landre -
Patent number: 8349029Abstract: The present invention relates to azo dyes of the formula (1) in which R, M, and Y are defined as stated in claim 1, to dye mixtures comprising them, to processes for preparing them, and to their use.Type: GrantFiled: January 30, 2012Date of Patent: January 8, 2013Assignee: DyStar Colours Deutschland GmbHInventors: Jörg Wörner, Andreas Schrell
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Patent number: 8349028Abstract: The present invention relates to a reactive printing dye composition, which includes: (a) at least one reactive dye; (b) an organic buffer; and (c) a mirabilite or a dispersant. The reactive printing dye composition of the present invention is capable for being used in the fabric-dyeing, for example, dyeing of cotton, hemp, silk, rayon, wool, blending, etc. The reactive printing dye composition of the present invention is advantageous in high pH value stability, high storage stability, and reduced degradation in dyeing strength. In addition, the present invention further provides an aqueous reactive printing dye composition.Type: GrantFiled: November 13, 2009Date of Patent: January 8, 2013Assignee: Everlight USA, Inc.Inventors: Wen-Chin Lin, Chien-Wen Lee
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Patent number: 8118885Abstract: An azo pigment represented by the following general formula (1), a tautomer of the azo pigment, and a salt or a hydrate thereof: wherein each of R1, R2, P1, P2, Q1, and Q2 independently represents a hydrogen atom or a substituent, G represents the non-metallic atoms necessary to complete a 5- to 6-membered heterocyclic group, W represents a substituent capable of binding to the heterocyclic group constituted by G, t represents an integer of from 0 to 4, each of Het-1 and Het-2 independently represents a group selected from specific aromatic heterocyclic groups.Type: GrantFiled: June 27, 2008Date of Patent: February 21, 2012Assignee: Fujifilm CorporationInventors: Keiichi Tateishi, Yoshiaki Nagata, Tomoaki Nakamura
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Patent number: 8083811Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein the substituents are defined in the specification.Type: GrantFiled: October 30, 2007Date of Patent: December 27, 2011Assignee: Huntsman International LLCInventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean Luc Christnacher
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Patent number: 7666232Abstract: A reactive trichromatic set comprising (a) at least one of the following reactive red dye of formula (I), wherein R1, R2, R3, X, D, Z, and n are defined the same as in the specification; (b) at least one reactive yellow dye selected from the following Color Index; C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176; and (c) at least one reactive blue dye selected from the following Color Index; C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222.Type: GrantFiled: June 22, 2006Date of Patent: February 23, 2010Assignee: Everlight USA, Inc.Inventors: Wen-Jang Chen, Bao-Kun Lai, Te-Chin Sung, Cheng-Hsiang Hsu
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Patent number: 7648535Abstract: The agent for coloring keratin fibers is free of chemical oxidants, is in the form of an aqueous or aqueous-alcoholic dye-containing preparation, and contains a combination of oxidation dyes and at least three direct dyes. The agent is characterized by a quantitative ratio of oxidation dyes to direct dyes equal to 5:1 to 0.5:1. A method of dyeing hair is described in which the agent is applied to hair and allowed to act on the hair for an acting time of 5 to 60 minutes without addition of chemical oxidants, so that air oxidation provides a uniform and stable coloration of the hair.Type: GrantFiled: July 6, 2004Date of Patent: January 19, 2010Assignee: Wella AGInventors: Juergen Schmenger, Petra Braun, Jolanthe Kujawa, Martina Glattefelder, Anne Entzminger, Anette Sallwey, Herbert Deutz
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Patent number: 7572301Abstract: Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y ??(3a), —NH—CO—(CH2)m—SO2—Y??(3b), —CONH—(CH2)n—SO2—Y??(3c), —NH—CO—CH(Hal)-CH2-Hal??(3d) or —NH—CO—C(Hal)=CH2??(3e), Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.Type: GrantFiled: March 9, 2005Date of Patent: August 11, 2009Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Luc Christnacher
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Patent number: 7468081Abstract: The present invention relates to processes for mono-, di- or trichromatic dyeing or printing of natural or synthetic polyamide fiber materials, these processes utilizing a) blue-dyeing dye mixture, b) a red-dyeing dye mixture and/or c) a yellow-dyeing dye mixture, and also blue-dyeing, red-dyeing and yellow-dyeing dye mixtures and processes for their preparation.Type: GrantFiled: September 22, 2004Date of Patent: December 23, 2008Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Stefan Ehrenberg, Andreas Giehl, Jörg Wörner
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Patent number: 7452386Abstract: The present disclosure relates to a composition for bleaching and simultaneously dyeing keratin fibers, comprising at least one dye chosen from meta-substituted ortho-nitroanilines and addition salts thereof, at least one peroxygenated salt and at least one alkaline agent. The present disclosure further relates to the process for bleaching and dyeing keratin fibers using this composition, and also to the use of this composition for bleaching and simultaneously dyeing keratin fibers.Type: GrantFiled: December 5, 2005Date of Patent: November 18, 2008Assignee: L'Oreal S.A.Inventors: Sylvain Kravtchenko, Valérie Bonnardel
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Patent number: 7282070Abstract: A reactive dye composition having satisfactory reproducibility, leveling, washing off and toughness under balanced affinity and reactivity, and improving Right First Time success ratio, for dyeing a cellulose fiber or fiber materials containing the cellulose fiber. The reactive dye composition comprising: (a) at least one reactive red dyestuff selected from the group consisting of the following formulas, the component (a) is present in an amount ranging from 1% to 99% by weight, and (b) at least one yellow reactive dyestuff selected from the group consisting of the following Color Index: C.I. Reactive Yellow 145 and C.I. Reactive Yellow 176, and at least one blue reactive dyestuff selected from the group consisting of the following Color Index: C.I. Reactive Blue 194, C.I. Reactive Blue 221 and C.I. Reactive Blue 222, the component (b) is present in an amount ranging from 99% to 1% by weight.Type: GrantFiled: October 19, 2005Date of Patent: October 16, 2007Assignee: Everlight USA, Inc.Inventors: Wen-Jang Chen, Chien-Yu Chen, Bao-Kun Lai, Ya-Chi Tseng
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Patent number: 7238213Abstract: Disclosed are novel compositions and methods employing cyclic nucleotide-gated channels and fluorescence dyes and other indicators in detecting changes of intracellular cAMP levels, for instance in response to the stimulation of G-protein-coupled receptors. CNG mutants comprising one or more pore mutations that enhance sensitivity to cAMP and decrease divalent cation-mediated blockage are used in a variety of assays, including detection of the G-protein-coupled receptor activity. Also disclosed are novel dye quencher formulations that are particularly suited for cell-based assays of protein interactions.Type: GrantFiled: November 1, 2004Date of Patent: July 3, 2007Assignee: Atto BioscienceInventors: Yong Yao, Liang Cao, Jianming Lu, Isabel Llorente
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Patent number: 4874392Abstract: A Monoazo compounds of the formula ##STR1## wherein D is a diazo component radical of the 4-nitrophenyl series, thienyl-2 series, thiazolyl-2 series or 5-nitrobenzoisothiazolyl-3 series,R.sub.1 is hydrogen; C.sub.1-2 alkyl; C.sub.1-2 alkoxy; formylamino; (C.sub.1-4 alkyl)carbonylamino; (C.sub.1-4 alkyl)carbonylamino the alkyl group of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-3 alkoxy, cyano, phenyl, phenoxy and benzyloxy; (C.sub.2-4 alkenyl)carbonylamino; halo(C.sub.2-4 alkenyl)carbonylamino; benzoylamino; benzoylamino the phenyl group of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; (C.sub.1-4 alkoxy)carbonylamino; (C.sub.1-4 alkoxy)carbonylamino the alkyl moiety of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-3 alkoxy, cyano, phenyl, phenoxy and benzyloxy; (C.sub.8-14 alkyl)carbonylamino or (C.sub.8-14 alkoxy)carbonylamino,R.sub.2 is C.sub.Type: GrantFiled: July 29, 1987Date of Patent: October 17, 1989Assignee: Sandoz Ltd.Inventor: Beat Henzi
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Patent number: 4773915Abstract: Azo dyestuffs of the formula ##STR1## wherein R.sub.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkoxyethoxy andX denotes acyl,are distinguished by good levelling properties and good allround fastness properties. They dye polyester fibres in a bright blue shade.Type: GrantFiled: January 7, 1987Date of Patent: September 27, 1988Assignee: Bayer AktiengesellschaftInventors: Winfried Kruckenberg, Klaus Leverenz, Hans-Gunter Otten
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Patent number: 4368054Abstract: Liquid compositions of nitro group-containing aniline compounds containing no sulfonic acid and/or carboxylic acid groups and having a melting point of below 140.degree. C., especially those suitable for use as diazo component in ice color dyeing, which contain 20 to 70% of this nitro-aniline, 5 to 80 weight % of a castor oil oxethylated with 25 to 60 mols of ethylene oxide, and 5 to 65 weight % of N-methyl-pyrrolidone as solvent. By simply mixing these components clear solutions are obtained which can be diazotized within a few seconds by means of an aqueous sodium nitrite solution and thus give diazonium salt solutions free from residue. These diazonium salt solutions can be used in simple manner and very advantageously as developing baths or liquors for producing water-insoluble azo dyestuffs on the fiber according to the ice color technique.Type: GrantFiled: January 29, 1982Date of Patent: January 11, 1983Assignee: Hoechst AktiengesellschaftInventor: Hasso Hertel
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Patent number: 4276045Abstract: A process for dyeing and printing cellulosic textile material, wherein the dye used is a compound of the general formula I ##STR1## where K is a radical of the formula ##STR2## one of the radicals X and Y is a C.sub.2 -C.sub.19 -carboxylic acid ester group, a C.sub.3 -C.sub.19 -carboxamide group, a C.sub.4 -C.sub.18 -sulfonamide group, a C.sub.4 -C.sub.8 -alkylsulfone group, a C.sub.6 -C.sub.8 -arylsulfone group or a sulfonic acid aryl ester group andthe remaining substituents X, Y and Z are hydrogen, bromine or methyl andY may also be nitro,A is cyano or carbamyl,B.sup.1, B.sup.2 and B.sup.3 independently of one another are aliphatic, cycloaliphatic, araliphatic or aromatic radicals, ##STR3## is a saturated heterocyclic radical, R is hydrogen or C.sub.1 -C.sub.3 -alkyl,one of the radicals T is a radical of the formula ##STR4## and the other radical T is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl.Type: GrantFiled: June 30, 1980Date of Patent: June 30, 1981Assignee: BASF AktiengesellschaftInventors: Werner Juenemann, Gunther Lamm, Hermann Loeffler
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Patent number: 4224025Abstract: A process is described for the dyeing and printing of paper materials by the use of developing dyestuffs, in which process diazo components and heterocyclic coupling components containing a 6-membered heterocyclic radical having one ring nitrogen atom are applied in any sequence, either successively or simultaneously onto or into the paper material to be dyed or printed, and coupled together in alkaline, neutral or acid medium, whereby it is possible using only a single coupling component to obtain on the material, merely by variation of the diazo component, a shade of color ranging from yellow to black.Type: GrantFiled: September 11, 1978Date of Patent: September 23, 1980Assignee: Ciba-Geigy CorporationInventors: Arthur Buhler, Franz H. Nedwed
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Patent number: 4212646Abstract: Process for printing textile mixed fabrics of polyester and cellulose fibers with printing pastes containing coupling components dissolved in an alkaline medium, sodium nitrite, diazotizable primary aromatic amines and optionally disperse dyestuffs, in which process the amines are used as a solution or in the form of an aqueous fine dispersion with a particle size of less than 0.03 mm and are selected in a manner that they are practically non-volatile at the drying temperatures and exhibit minimum basicity with the pK.sub.a being 2.Type: GrantFiled: September 7, 1978Date of Patent: July 15, 1980Assignee: Hoechst AktiengesellschaftInventors: Horst Curtius, Erich Feess, Willy Gronen