Polyazo Component Patents (Class 8/669)
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Patent number: 9023118Abstract: The present invention relates to new azo dyes, a process for their preparation, and their use for dyeing or printing fibrous materials, to produce materials with brownish shades.Type: GrantFiled: November 29, 2011Date of Patent: May 5, 2015Assignee: Kemira OYJInventors: Helmut-Martin Meier, Christof Heide, Klaus-Günter Strumpf, Thomas Hübbe
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Patent number: 8979947Abstract: The present invention relates to dyes of the formula (I) in which R1 to R10, D1 and D2 are defined as given in claim 1, a process for preparing them, and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.Type: GrantFiled: November 24, 2011Date of Patent: March 17, 2015Assignee: DyStar Colours Distribution GmbHInventors: Roxana Barbieru, Vajiravelu Sivamurugan
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Patent number: 8382857Abstract: The present invention relates to a process for dyeing leather with at least one dye F which has at least one alkaline-activable group of the formula A; where - - - - denotes the bond to the rest of the dye molecule; X is halogen, C1-C4-alkyl or C1-C4-alkoxy, k is 0, 1, 2 or 3, n is 0 or 1 and B is a CH?CH2 group or a CH2—CH2-Q group, where Q is an alkaline-detachable group, which comprises treating the leather with an aqueous float comprising at least one dye F at a pH of not less than 8, generally in the region of 8 to 11.Type: GrantFiled: June 7, 2005Date of Patent: February 26, 2013Assignee: BASF SEInventors: Laszlo Somogyi, Andrea Zamponi, Harald Kiesow
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Patent number: 8372161Abstract: The present invention relates to a process for dyeing leather with at least one dye F which has at least one alkaline-activable group of the formula A; where - - - - denotes the bond to the rest of the dye molecule; X is an electron-attracting radical, k is 1, 2 or 3, n is 0 or 1 and B is a CH?CH2 group or a CH2—CH2-Q group, where Q is an alkaline-detachable group, which comprises treating the leather with an aqueous float comprising at least one dye F at a pH of not less than 7.5. The present invention also relates to novel dyes which are particularly useful for reactive dyeing of leather.Type: GrantFiled: October 28, 2004Date of Patent: February 12, 2013Assignee: BASF SEInventors: Laszlo Somogyi, Andrea Zamponi, Rolf Streicher, Harald Kiesow, Rainer Erhardt
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Patent number: 8349029Abstract: The present invention relates to azo dyes of the formula (1) in which R, M, and Y are defined as stated in claim 1, to dye mixtures comprising them, to processes for preparing them, and to their use.Type: GrantFiled: January 30, 2012Date of Patent: January 8, 2013Assignee: DyStar Colours Deutschland GmbHInventors: Jörg Wörner, Andreas Schrell
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Patent number: 8137416Abstract: Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates are described.Type: GrantFiled: April 2, 2007Date of Patent: March 20, 2012Assignee: Clariant Finance (BVI) LimitedInventor: Rainer Nusser
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Patent number: 8097047Abstract: Rejuvenation compositions including a reactive dye are disclosed for the one-shot rejuvenation of the color for dark-colored textile fabrics and garments formed therefrom. The rejuvenation compositions return faded black or dark colored garments to a like-new look. Methods of rejuvenating the faded color of garments by using the dye compositions are also disclosed.Type: GrantFiled: February 6, 2009Date of Patent: January 17, 2012Assignee: The Procter & Gamble CompanyInventors: Mark Robert Sivik, Allison Lynn Gerdes, Gayle Marie Frankenbach, Gregory T. Waning, Ramanan Venkata Ganapathysundaram, Michael Timothy Creedon
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Patent number: 8083811Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein the substituents are defined in the specification.Type: GrantFiled: October 30, 2007Date of Patent: December 27, 2011Assignee: Huntsman International LLCInventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean Luc Christnacher
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Patent number: 7927384Abstract: Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates are described.Type: GrantFiled: June 21, 2007Date of Patent: April 19, 2011Assignee: Clariant Finance (BVI) LimitedInventor: Rainer Nusser
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Patent number: 7857864Abstract: Disclosed herein is a composition for the dyeing of keratin fibers, for example, human keratin fibers such as the hair, comprising at least one 3-amino pyrazolo-[1,5-a]-pyridine derivative or one of its addition salts and a method employing this derivative. The composition of the present disclosure makes it possible to obtain coloration in various shades that is powerful, chromatic, and aesthetic, with low selectivity and with good resistance to various aggressive factors to which the hair may be subjected, such as shampoos, the light, sweat and permanent shaping.Type: GrantFiled: October 9, 2009Date of Patent: December 28, 2010Assignee: L'Oreal S.A.Inventors: Aziz Fadli, Laurent Vidal, Stéphane Sabelle
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Patent number: 7713311Abstract: The present invention relates to aqueous liquid formulations comprising 5-30% by weight of a dye composition comprising 25-85% by weight of Direct Brown 44 15-75% by weight of Direct Yellow 11 and/or of a dye obtainable by reduction or thermal treatment of Direct Yellow 11 0-15% by weight of one or more blue direct dyes and 0-10% by weight of one or more red direct dyes all based on the dye composition 0.5-15% by weight of one or more alkylamines whose one, two or three alkyl radicals may each be substituted by one or two hydroxyl groups and/or amino groups and/or interrupted by one or two oxygen atoms in ether function, based on the total weight of the aqueous liquid formulation, the sodium content of the liquid formulation not exceeding 0.3% by weight, and also their use for dyeing cellulose material especially paper.Type: GrantFiled: November 13, 2006Date of Patent: May 11, 2010Assignee: BASF AktiengesellschaftInventors: Ingo Klopp, Karl-Heinz Etzbach, Helmut Reichelt
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Patent number: 7708786Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2—Z or —Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: June 27, 2008Date of Patent: May 4, 2010Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
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Patent number: 7704287Abstract: The present invention provides a reactive red dye composition comprising (A) 3% to 97% by weight of a reactive azo dye of the following formula (I), wherein W, D1 and D2 are defined the same as the specification; and (B) 97% to 3% by weight of a reactive azo dye of the following formula (II), wherein R, X, Z, D3 and D4 are defined the same as the specification. The reactive red dye composition of the present invention can be utilized to dye cellulose fibers. The cellulose fibers dyed by the reactive red dye composition obtain not only good build-up and level dyeing properties but also an excellent property of white discharging.Type: GrantFiled: May 22, 2007Date of Patent: April 27, 2010Assignee: Everlight USA, Inc.Inventors: Bao-Kun Lai, Huei-Chin Huang, Cheng-Hsiang Hsu, Ya-Chi Tseng
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Patent number: 7637964Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (I) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: May 27, 2008Date of Patent: December 29, 2009Assignee: DyStar Textilfarben GmbH & Co.Inventors: Stefan Meier, Werner Russ, Joachim Eichhorn
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Patent number: 7635394Abstract: Disclosed herein is a composition for the dyeing of keratin fibers, for example, human keratin fibers such as the hair, comprising at least one 3-amino pyrazolo-[1,5-a]-pyridine derivative or one of its addition salts and a method employing this derivative. The composition of the present disclosure makes it possible to obtain coloration in various shades that is powerful, chromatic, and aesthetic, with low selectivity and with good resistance to various aggressive factors to which the hair may be subjected, such as shampoos, the light, sweat and permanent shaping.Type: GrantFiled: November 9, 2006Date of Patent: December 22, 2009Assignee: L'Oreal S.A.Inventors: Aziz Fadli, Laurent Vidal, Stéphane Sabelle
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Patent number: 7578855Abstract: The present disclosure relates to a composition for the dyeing of keratin fibers, such as the hair, comprising at least oneoxidation base chosen from cationic 3-amino pyrazolo-[1,5-a]-pyridine derivatives and addition salts thereof, and a method employing this composition. The present disclosure also relates to cationic 3-amino pyrazolo-[1,5-a]-pyridine derivatives and the addition salts thereof.Type: GrantFiled: November 9, 2006Date of Patent: August 25, 2009Assignee: L'Oréal S.A.Inventor: Aziz Fadli
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Patent number: 7578856Abstract: Disclosed herein are compositions for dyeing keratinous fibers comprising, in an appropriate dyeing medium, at least one aminopyrazolopyridine oxidation base chosen from those of formula (I), wherein it is understood that at least one of the groups R?1, and R?2 is chosen from cationic radicals; at least one coupler and at least one C4-C30 polyol. Dyeing methods and multi-compartment devices for use thereof.Type: GrantFiled: May 9, 2008Date of Patent: August 25, 2009Assignee: L'Oreal S.A.Inventor: Jean-Baptiste Saunier
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Patent number: 7572301Abstract: Reactive dyes of formula wherein Q1 and Q2 are each independently of the other hydrogen or unsubstituted or substituted C1-C4alkyl, D1 is the radical of a diazo component, which is itself a mono- or dis-azo dye or contains such a dye, D2 has the same definition as D1 or is a radical of formula wherein (Q3)0-3 denotes from 0 to 3 identical or different substituents selected from the group halogen, C1-C4alkyl, C1-C4alkoxy, carboxy and sulfo and Z1 is a radical of formula —SO2—Y ??(3a), —NH—CO—(CH2)m—SO2—Y??(3b), —CONH—(CH2)n—SO2—Y??(3c), —NH—CO—CH(Hal)-CH2-Hal??(3d) or —NH—CO—C(Hal)=CH2??(3e), Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, m and n are each independently of the other the number 2, 3 or 4, and Hal is halogen, are suitable for dyeing cellulosic or amide-group-containing fibre materials.Type: GrantFiled: March 9, 2005Date of Patent: August 11, 2009Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Hubert Jean Luc Christnacher
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Patent number: 7553340Abstract: Reactive dyes of formula (1) wherein R1 is hydrogen or unsubstituted or substituted C1-C4alkyl, R2 is hydrogen; C1-C4alkyl; C1-C4alkoxy unsubstituted or substituted by sulfato, hydroxy or by C1-C4alkoxy; halogen; carboxy or sulfo, R3 is hydrogen; C1-C4alkyl; C1-C4alkoxy unsubstituted or substituted by sulfato, hydroxy or by C1-C4alkoxy; halogen; nitro; C2-C4alkanoylamino; ureido; carboxy or sulfo, (R4)k denotes k identical or different substituents selected from the group halogen, C1-C4-alkyl, C1-C4alkoxy, carboxy and sulfo, X is halogen and V is a radical of formula (2a), 2(b) wherein R5 is unsubstituted or substituted C1-C4alkyl, (R6)I denotes I identical or different substituents from the group C1-C4alkyl, C1-C4alkoxy and sulfo, and I is the number 0, 1 or 2, Y is vinyl or a —CH2—CH2—U radical and U is a group that is removable under alkaline conditions, Q is a —CH(HaI)-CH2-HaI or —C(HaI)=CH2 group, Hal is halogen and k is the number 0, 1 , 2 or 3, are suitable especially for dyeing cotton and yield dyeingType: GrantFiled: November 2, 2005Date of Patent: June 30, 2009Assignee: Huntsman International, LLCInventors: Athanassios Tzikas, Georg Roentgen, Herbert Klier
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Patent number: 7540883Abstract: The present invention discloses a reactive yellow dye composition comprising component (A) and component (B). The component (A) is a reactive azo dye represented by the following formula (I) or formula (II), The component (B) is a reactive azo dye represented by the following formula (III), wherein the substituents of the formulas (I), (II) and (III) are defined the same as in the specification. Moreover, the reactive yellow dye composition of the present invention has excellent build-up, wash-off and light fastness and can be applied with dyestuffs in other colors.Type: GrantFiled: August 2, 2007Date of Patent: June 2, 2009Assignee: Everlight USA, Inc.Inventors: Bao-Kun Lai, Cheng-Hsiang Hsu, Ya-Chi Tseng, Huei-Chin Huang
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Patent number: 7531009Abstract: The present invention provides 6-azo-5,5?-dihydroxy-7,7?-disulfo-2,2?-dinaphthylamine derivatives, their use as dyes, dyed paper and formulations comprising them.Type: GrantFiled: January 11, 2006Date of Patent: May 12, 2009Assignee: Ciba Specialty Chemicals CorporationInventor: Holger Lautenbach
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Patent number: 7455699Abstract: Reactive dye mixtures comprising one or more dyes of the general formula (I), one or more dyes of the general formula (II) and optionally one or more dyes of the general formula (III) where D1, D2, D3, D4, D5, R0, R*, R**, T, b, f, v, and M are as defined in claim 1, the dyes of the general formulae (I)-(III) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, are prepared and used for dyeing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: March 18, 2003Date of Patent: November 25, 2008Assignee: DyStar Texilfarben GmbH & Co. Deutschland KGInventors: Joachim Eichhorn, Werner Russ, Stefan Meier, Uwe Mrotzeck
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Patent number: 7429279Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (i) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.Type: GrantFiled: July 26, 2004Date of Patent: September 30, 2008Assignee: DyStar Textilfarben GmbH + Co. Deutschland KGInventors: Stefan Meier, Werner Russ, Joachim Eichhorn
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Patent number: 7387647Abstract: A dye composition, comprising (A) at least one disazo dye selected from the formula (I) or (II), wherein R, R1, R2, D1 and D2 are defined as in the specification; and (B) a diazo dye of the formula (III), wherein (R9)0˜2, (R10)0˜2, Q1 and Q2 are defined as in the specification. These dye compositions have high fixation and good build-up. They are distinguished also by high washing off and low nylon staining and they are suitable for dyeing and printing of materials containing either cellulose fibers, such as cotton, artificial cotton, linen, and artificial linen, or polyamide fibers, such as wool, silk, and nylon etc. Dyed materials with excellent properties can be obtained, showing especially outstanding performance in washing off, levelness, build-up, wet fastness and light fastness.Type: GrantFiled: May 25, 2005Date of Patent: June 17, 2008Assignee: Everlight USA, Inc.Inventors: Huei-Chin Huang, Sheena Lee, Sheue-Rong Lee, Bao-Kun Lai, Cheng-Hsiang Hsu, Ya-Chi Tseng
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Patent number: 7381228Abstract: The present invention relates to processes for mono-, di- or trichromatic dyeing or printing of natural or synthetic polyamide fiber materials, these processes utilizing a) blue-dyeing dye mixture, b) a red-dyeing dye mixture and/or c) a yellow-dyeing dye mixture, and also blue-dyeing, red-dyeing and yellow-dyeing dye mixtures and processes for their preparation.Type: GrantFiled: April 30, 2007Date of Patent: June 3, 2008Assignee: DyStar Textilfarben GmbH & Co. Deutschland KGInventors: Stefan Ehrenberg, Andreas Giehl, Jörg Wörner
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Patent number: 7341607Abstract: The present invention relates to novel yellow anionic dyes, a process for their preparation, certain novel intermediates for their preparation and the use of these dyes for dyeing natural or synthetic materials, in particular, paper.Type: GrantFiled: May 27, 2003Date of Patent: March 11, 2008Assignee: Ciba Specialty Chemicals Corp.Inventors: Michael Lennartz, Adolf Käser, Sandra Weiss
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Publication number: 20040250358Abstract: The present invention relates to a process for the trichromatic dyeing or printing of hydroxy-group-containing or nitrogen-containing organic substrates with dye mixtures and also to such dye mixtures and hydroxy-group-containing or nitrogen-containing organic substrates dyed or printed therewith.Type: ApplicationFiled: April 16, 2004Publication date: December 16, 2004Inventors: Markus Gisler, Roland Wald
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Patent number: 6793687Abstract: The object of the invention is an agent for oxidatively dyeing keratin fibers, wherein it contains (a) at least one 4,5-diaminopyrazole derivative of Formula (I), (II) or (III) or its salt with organic or inorganic acids, as well as (b) at least one pyrazol-5-one derivative of the general formula (IV), (V) or (VI), or its salt with organic or inorganic acids,Type: GrantFiled: October 8, 2002Date of Patent: September 21, 2004Assignee: Wella AktiengesellschaftInventors: Manuela Javet, Christel Dousse, Dominique Le Cruer
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Patent number: 5389110Abstract: Azo dyes useful for dyeing natural or synthetic substrates have the formula ##STR1## where n is from 1 to 4,q is 1 or 2,L.sup.1 is hydrogen or C.sub.1 -C.sub.3 -alkyl,L.sup.2 is acetyl, carbamoyl or hydroxysulfonyl, andD is the radical of a diazo component.Type: GrantFiled: August 18, 1993Date of Patent: February 14, 1995Assignee: BASF AktiengesellschaftInventors: Johannes P. Dix, Bernd Hupfeld, Gunther Lamm, Helmut Reichelt
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Patent number: 4696675Abstract: Using the method of azoic dyeing, fast blue dyeings are obtained when the bis-diazotable diazo component used is a compound of the general formula (1) ##STR1## in which R is a straight-chain or branched alkyl group of 3 to 5 carbon atoms or a (C.sub.1 -C.sub.3)-alkoxy-(C.sub.2 -C.sub.4)-alkyl group having straight-chain and/or branched alkyl groups of in total 3 to 5 carbon atoms, and the coupling component used is a compound conforming to the general formula (2) ##STR2## in which Z stands for a hydrogen atom or a halogen atom or an alkoxy group of 1 to 4 carbon atoms and Aryl denotes a phenyl radical or a 1-naphthyl radical which can be substituted by 1, 2 or 3 substituents from the group consisting of halogen, nitro, alkyl of 1 to 4 carbon atoms and alkoxy of 1 to 4 carbon atoms, and the coupling reaction and dye formation on the fiber are carried out at a pH value between 4 and 10.Type: GrantFiled: March 27, 1986Date of Patent: September 29, 1987Assignee: Hoechst AktiengesellschaftInventors: Hasso Hertel, Klaus Hunger, Heinrich Frolich
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Patent number: 4224025Abstract: A process is described for the dyeing and printing of paper materials by the use of developing dyestuffs, in which process diazo components and heterocyclic coupling components containing a 6-membered heterocyclic radical having one ring nitrogen atom are applied in any sequence, either successively or simultaneously onto or into the paper material to be dyed or printed, and coupled together in alkaline, neutral or acid medium, whereby it is possible using only a single coupling component to obtain on the material, merely by variation of the diazo component, a shade of color ranging from yellow to black.Type: GrantFiled: September 11, 1978Date of Patent: September 23, 1980Assignee: Ciba-Geigy CorporationInventors: Arthur Buhler, Franz H. Nedwed