Phenoxy, Phenol, Mercapto, Alkoxy, Or Thioalkyl Group Patents (Class 8/678)
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Publication number: 20120272462Abstract: The present invention relates to a compound of formula (I), where X, Y, T and Z are each as defined in claim 1, to its preparation and to its use.Type: ApplicationFiled: January 17, 2012Publication date: November 1, 2012Applicant: DyStar Colours Deutschland GmbHInventors: Roxana Barbieru, Carsten Harfmann, Werner Russ
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Patent number: 7419510Abstract: The invention provides an oxidation hair color system consists essentially of a dye phase and a developer phase, wherein the dye phase includes: a) a water soluble nonionic surfactant; b) a water soluble anionic polymer; c) water; d) oxidation dye intermediate; e) dye antioxidants and stabilizers and wherein the developer phase includes: a) secondary ethoxylated fatty alcohols; b) an oxidizer and c) water.Type: GrantFiled: August 8, 2005Date of Patent: September 2, 2008Assignee: Combe IncorporatedInventor: Jack Massoni
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Patent number: 6964689Abstract: The present invention relates to anthraquinone dyes of the formula (I) where R1 is hydrogen, R2 is hydrogen or CO—C2C6alkyl moiety may be substituted by carboxyl, or is (II) wherein R6 is hydrogen, C1-C4alkyl, hydroxyl, carboxyl or halogen, R7 is hygrogen, C1-C4alkyl or halogen and R8 is hydrogen or C2-C3alkyl or when R4 is halogen R8 ? may be methyl or halogen R3 is hydrogen or halogen, R4 is hydrogen or halogen and n is (0), (1) or (2), with the proviso that R3, R4, R6, R7 and R8 are not all hydrogen at one and the same time, processes for their preparation and their use for dyeing or printing hydrophobic fiber materials or for preparing colored plastics or polymeric color particles.Type: GrantFiled: December 13, 2001Date of Patent: November 15, 2005Assignee: Ciba Specialty Chemicals CorporationInventors: Peter Sutter, Peter Aeschlimann
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Patent number: 6962610Abstract: Provided is a hair dye composition containing a dissociative direct dye represented by the following formula (1): wherein, R1 to R4 each represents H or substituent, X represents OH or —NHSO2R5, R5 represents an alkyl, aryl or heterocyclic group, and A represents a divalent group capable of forming a methine dye as a whole compound, together with the portion other than A. The hair dye composition of the present invention is capable of strongly dyeing the hair with a vivid color tone without causing decomposition of the dye during the dyeing process, exhibits an excellent resistance against sunlight, hair washing, perspiration, friction and heat, has a high stability against an alkali agent and an oxidizing agent, has a high dyeing property, and has less color fade after the passage of time.Type: GrantFiled: September 12, 2003Date of Patent: November 8, 2005Assignees: Kao Corporation, Fuji Photo Film Co., Ltd.Inventors: Dominic Pratt, Toshio Kawagishi
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Patent number: 6893472Abstract: The present invention relates to a process for dyeing or printing manufactured natural polymer or synthetic hydrophobic fiber materials, characterized in that it comprises using dyes of the formula (I), where R1 is hydrogen, hydroxyl or a radical —NHCO—R6, where R6 is C1-C6alkyl or unsubstituted or C1-C4alkyl- or halogen-substituted phenyl, R2 is hydrogen, hydroxyl or a radical W—R7, where W is —NHCO— or —S— and R7 is C1C6alkyl or unsubstituted or C1-C4alkyl- or halogen-substituted phenyl, R3 is hydrogen, R4 is hydrogen or hydroxyl, R5 is hydrogen, halogen, methoxy, phenoxy or phenylthio, or R3 and R4 combine to form the radical of the formula (II), where the rings A and B may independently bear further substituents, to the use of these dyes for trichromatic dyeing of manufactured natural polymer or synthetic hydrophobic fiber materials and mass dyeing of plastics materials and to producing solid on-tone combinations of plastics material and manufactured natural polymer or synthetic fiber material.Type: GrantFiled: December 13, 2001Date of Patent: May 17, 2005Assignee: Ciba Specialty Chemicals CorporationInventors: Rainer Hildebrand, Peter Sutter
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Patent number: 6783558Abstract: The present invention is directed to a hair coloring method by using a composition comprising a specified ring-fused heterocycle direct dyestuff having the general formula (1) or a salt thereof wherein the formulas are as defined in the patent claims. Furthermore, the present invention is also directed to the composition. This composition has a surprisingly good hair coloring performance and compatibility with peroxides. The use of this composition leads to long lasting brilliant colors wherein the color is stable against washing of the hair and environmental influences.Type: GrantFiled: March 14, 2002Date of Patent: August 31, 2004Assignees: Kao Corporation, Fuji Photo Film Co., Ltd.Inventors: Dominic Pratt, Toshio Kawagishi
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Patent number: 6746492Abstract: A semipermanent hair dye composition comprising (A) a direct dye, (B) a hydrocarbon oil and (C) polyoxyalkylene-modified dimethyl polysiloxane. The semipermanent hair dye composition can uniformly dye hair without coloring the scalp and skin and gives the hair an excellent feel after hair coloring.Type: GrantFiled: December 20, 2001Date of Patent: June 8, 2004Assignee: Kao CorporationInventors: Tetsuya Kawai, Takashi Itou
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Patent number: 6218552Abstract: A compound, 3-phenyl-7-[4-(tetrahydrofurfuryloxy)phenyl]-1,5-dioxa-s-indacene-2,6-dione, which has a structure of crystals exhibiting the strongest peak at an angle of diffraction, 2&thgr;, of 4.7°, among peaks appearing within the range of not smaller than 3° of 2&thgr;, in an X-ray diffraction using a Cu-K&agr;-ray. The compound gives dyed or printed products having deep and brilliant tint of colors with excellent fastnesses, when applied to hydrophobic fiber materials, particularly, polyester fiber materials.Type: GrantFiled: April 19, 1994Date of Patent: April 17, 2001Assignee: Sumitomo Chemical Co., Ltd.Inventors: Junichi Sekihachi, Jun Yamamoto, Yasuyoshi Ueda
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Patent number: 6203578Abstract: The use of linear or cyclic silicon compounds containing at least one chromophoric group of quinone or azo type as direct dyes in dye compositions intended for dyeing human keratin fibres and in particular the hair. The invention also relates to novel silicon compounds and dye compositions containing them, as well as to the corresponding direct dyeing process.Type: GrantFiled: September 29, 1999Date of Patent: March 20, 2001Assignee: L'OrealInventors: Madeleine Leduc, Hervé Richard, Alain Lagrange
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Patent number: 5882358Abstract: Automatic transmission fluid containing a red dye stable even in long-lived transmission fluids.Type: GrantFiled: June 12, 1996Date of Patent: March 16, 1999Assignee: United Color Manufacturing, Inc.Inventors: Michael J. Smith, Bharat Desai
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Patent number: 5607481Abstract: Fiber-reactive anthraquinone dyes Anthraquinone dyes of the formula (1) ##STR1## in which the variables are defined in the disclosure, exhibit excellent fastness properties, in particular chlorine fastness, light fastness and wash fastness, and give good fixation yields.Type: GrantFiled: February 13, 1996Date of Patent: March 4, 1997Assignee: Hoechst AktiengesellschaftInventors: Werner H. Russ, Christian Schumacher
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Patent number: 5578419Abstract: Dyes suitable for use in the fabrication of color filters are described which contain one or more photopolymerizable substituents preferably represented by the following formula:D-(A-Yn.sup.1)n.sup.2 (1)where D represents a chromphoric nucleus, A denotes a connecting group, Y means the photopolymerizable group, n.sup.1 is 1-10,000, and n.sup.2 stands for an integer of 1-10. Also described are photosensitive resist resin compositions containing the dyes as well as color filters fabricated by curing the photosensitive resist resin compositions.Type: GrantFiled: April 6, 1994Date of Patent: November 26, 1996Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Hisato Itoh, Akio Karasawa, Kenichi Sugimoto
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Patent number: 5547478Abstract: The invention is to provide a composition made by blending a benzodifuranone compound of the formula (I): ##STR1## wherein R.sub.1 represents a methylene or straight or branched C.sub.2 -C.sub.6 alkylene group optionally substituted with a hydroxy, C.sub.1 -C.sub.4 alkoxy or C.sub.1 -C.sub.4 alkylcarbonyloxy group; and Q represents 5- or 6-membered saturated or unsaturated heterocyclic ring residue, with an anthraquinone compound of the formula (II): ##STR2## wherein R.sub.2 represents an optionally substituted C.sub.1 -C.sub.6 alkyl, optionally substituted phenyl or C.sub.1 -C.sub.4 alkoxyphenylsulfonyl group, and a method for dyeing hydrophobic materials using the composition to obtain red dyed products with excellent pH dependency and fastnesses to light and washing.Type: GrantFiled: December 16, 1993Date of Patent: August 20, 1996Assignee: Sumitomo Chemical Company, LimitedInventors: Toshinori Fukui, Nobuyuki Katsuda, Shinichi Yabushita, Shuhei Hashizume
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Patent number: 5187207Abstract: A hydrophilic contact lens is disclsoed incorporating melanin that protects the eye from harmful radiation and superoxide.Type: GrantFiled: December 19, 1989Date of Patent: February 16, 1993Assignee: Photoprotective Technologies, Inc.Inventor: James M. Gallas
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Patent number: 5131919Abstract: The invention relates to a dye mixture containing a dye of the formula ##STR1## and a dye of the formula ##STR2## where R is cyclohexyl or phenyl, which may each be substituted by C.sub.1 -C.sub.4 alkyl, acetylamino, N-C.sub.1 -C.sub.4 alkylacetylamino, benzoylamino, ureido or by phenylsulfonylamino or phenylsulfonyloxy which may be substituted in the phenyl ring by C.sub.1 -C.sub.4 alkyl.Said dye mixture is suitable for dyeing and printing natural or synthetic polyamide materials, in particular in combination with other dyes and in particular from short liquors. The mixture is notable for generally good properties, in particular good dyeing properties and good solubility.Type: GrantFiled: April 18, 1991Date of Patent: July 21, 1992Assignee: Ciba-Geigy CorporationInventor: Dieter Mausezahl
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Patent number: 5116884Abstract: A hydrophilic contact lens is disclosed incorporating melanin that protects the eye from harmful radiation and superoxide.Type: GrantFiled: February 16, 1990Date of Patent: May 26, 1992Assignee: Photoprotective Technology IncorporatedInventor: James M. Gallas
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Patent number: 5112883Abstract: The present invention is directed to a medium incorporating melanin for radiation protection.Type: GrantFiled: November 9, 1990Date of Patent: May 12, 1992Assignee: Photoprotective Technologies IncorporatedInventor: James M. Gallas
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Patent number: 5071442Abstract: A process for dyeing or printing cellulosic textile fibre materials by the trichromatic technique, which process comprises dyeing or printing said materials from an aqueous liquor with at least one red or reddish brown dyeing dye of formula ##STR1## and at least one yellow or orange dyeing dye of formula ##STR2## and at least one blue dyeing dye of formula ##STR3## wherein A.sub.1, A.sub.2, (B.sub.2).sub.1-3, R.sub.1, R.sub.2, R.sub.3, (R.sub.4).sub.1-2, (X).sub.1-2, (T.sub.1).sub.1-2, (T.sub.2).sub.1-2, (Y).sub.1-3 and Z in formulae (1) to (7) are as defined in claim 1.The process of this invention is suitable for dyeing or printing cellulosic fibre materials.Type: GrantFiled: January 4, 1991Date of Patent: December 10, 1991Assignee: Ciba-Geigy CorporationInventors: Jean P. Luttringer, Athanassios Tzikas, Pierre Galafassi
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Patent number: 4880432Abstract: Disclosed is a process for preparing particles colored with a dye which comprises: (a) forming, by a free radical dispersion polymerization process in a nonaqueous solution, polymeric particles having attached thereto stabilizing copolymers with at least one functional group capable of undergoing a chemical reaction with a dye, the particles having an average diameter of from about 0.1 to about 20 microns; (b) adding a dye to the polymeric particles having attached thereto stabilizing copolymers; and (c) effecting a chemical reaction between the dye and the stabilizing copolymers that results in the dye becoming covalently bound to the polymeric particles. Also disclosed is a liquid electrophotographic developer composition comprising a liquid medium, a charge control agent, and colored polymeric toner particles prepared as stated above and having an average diameter of from about 0.5 to about 5 microns.Type: GrantFiled: January 11, 1988Date of Patent: November 14, 1989Assignee: Xerox CorporationInventors: Luke S. Egan, Mitchell A. Winnik, Francoise M. Winnik
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Patent number: 4846846Abstract: A process for coloring polyurethane resins made by a polyaddition reaction of a polyol and an isocyanate is provided, which comprises adding to the reaction mixture before or during the polyaddition reaction a reactive coloring agent suitable for incorporation in the resin with the formation of covalent bonds, said coloring agent having the formula: ##STR1## in which R.sub.1 and R.sub.2 are independently selected from an alkyl group having from 1 to about 12 carbon atoms, X is --CH.sub.2 --, a and a' are integers from 1 to about 6, and Y and Y' are independently selected from polymeric units of hydroxy alkylenes or alkylene oxide monomers selected from ethylene oxide, propylene oxide, butylene oxide, cyclohexene oxide, or glycidol, b and b' are independently either 0 or 1, and Z and Z' are reactive groups independently selected from --OH, --NH.sub.2, or --SH.Type: GrantFiled: June 20, 1988Date of Patent: July 11, 1989Assignee: Milliken Research CorporationInventors: John W. Rekers, John W. Miley
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Patent number: 4725284Abstract: The invention relates to:(A) A thermal transfer printing sheet comprising a substrate having a coating comprising either,(i) a dye of the formula: ##STR1## wherein R.sup.1 is C.sub.5-12 -alkyl;R.sup.2 is H or C.sub.1-12 -alkyl; and Rings A & B are optionally substituted in the free positions by non-ionic groups; or(ii) a mixture of at least two dyes of the formula: ##STR2## wherein R.sup.3 is H or C.sub.1-12 -alkyl;R.sup.4 is H or C.sub.1-4 -alkyl; and Rings A & B are optionally substituted in the free positions by non-ionic groups;provided that in at least one component R.sup.3 is C.sub.5-12 -alkyl and in at least one other component R.sup.3 is H or C.sub.1-4 -alkyl;(B) A thermal transfer printing process using the transfer sheets; and(C) The mixture of dyes defined in (A)(ii).Type: GrantFiled: July 18, 1986Date of Patent: February 16, 1988Assignee: Imperial Chemical Industries PLCInventors: William Black, Roy Bradbury, Peter Gregory, Roy Porter, Geoffrey R. Rothwell
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Patent number: 4614804Abstract: Dyes of the formula ##STR1## where A and B are H and/or ##STR2## Y is unsubstituted or substituted phenyl, ##STR3## or unsubstituted or substituted benzothiazolyl or benzoxazolyl and R is unsubstituted or substituted alkyl, unsubstituted or substituted phenyl, or alkoxy, alkoxyalkoxy, phenalkyl or alkoxycarboalkyl, are suitable for dyeing and printing cellulose swollen with water-miscible swelling agents and cellulose-containing fiber material.Type: GrantFiled: September 14, 1983Date of Patent: September 30, 1986Assignee: BASF AktiengesellschaftInventors: Gerhard Epple, Reinhold Krallmann, Wolf-Dieter Kermer, Hans Weber
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Patent number: 4596666Abstract: Anthraquinone dyestuffs of the formula ##STR1## in which R.sub.1 represents alkyl, aralkyl, --CO--X-alkyl, --CO-- X-aralkyl, --CO--X-aryl, --O-alkyl, --O-aralkyl, --O-- aryl, --CN, --NO.sub.2, --CF.sub.3, halogen or a heterocyclic radical andR.sub.2 represents H or R.sub.1,X representing O, S, NH or a direct bond andY.sub.1, Y.sub.2, Y.sub.3 and Y.sub.4 denoting hydrogen, --NH.sub.2, --OH, halogen, --NO.sub.2 or an arylmercapto group and at least one of the substituents Y.sub.1 -Y.sub.4 representing an arylmercapto group,it being also possible for the alkyl, aryl, aralkyl and heterocyclic radicals mentioned for R.sub.1 and Y.sub.1 -Y.sub.4 to be substituted, the preparation and use thereof, and dichroic material containing these anthraquinone dyestuffs.Type: GrantFiled: December 2, 1983Date of Patent: June 24, 1986Assignee: Bayer AktiengesellschaftInventors: Martin Blunck, Uwe Claussen, Friedrich W. Krock, Rutger Neeff
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Patent number: 4510088Abstract: Dye mixtures containing at least two dyes of the formula (1) ##STR1## wherein R is hydrogen, methyl or ethyl, and n is an integer from 2 to 4, exhibit on synthetic textile material a build-up which is considerably better than that of the individual dyes.Type: GrantFiled: August 18, 1982Date of Patent: April 9, 1985Assignee: Ciba Geigy CorporationInventor: Peter Mockli
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Patent number: 4388078Abstract: The present invention is concerned with modifying the crystal form of the anthraquinone of the formula ##STR1## so as to render it more suitable for disperse dyeing and to improve its performance in thermosol dyeing. The modification is effected by heating the dyestuff at elevated temperatures, preferably between 90.degree. and 185.degree. C. until the Debye-Scherrer strong intensity spacings appear at 6.5A.degree., 18.1A.degree. and 20.6A.degree.. It is also concerned with disperse and thermosol dyeing processes utilizing this crystal modification and with aqueous dispersions of this crystal modification.Type: GrantFiled: March 24, 1982Date of Patent: June 14, 1983Assignee: Mobay Chemical CorporationInventors: Thomas J. Thomas, Robert G. Hoquet
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Patent number: 4385900Abstract: The invention relates to transfer printing supports printed with a design which vaporizes in the temperature range from 180.degree. to 210.degree. C., and also to a process for printing synthetic planar textiles using such supports. The transfer printing supports contain, as red component, a 1-amino-4-hydroxyanthraquinone or -4-aminoanthraquinone compound which does not contain sulfo and carboxyl groups and which carries in the 2-position of the anthraquinone nucleus an alkoxy group which contains at least one fluorine atom and preferably at least three fluorine atoms.Type: GrantFiled: October 14, 1981Date of Patent: May 31, 1983Assignee: Ciba-Geigy AGInventor: Peter Mockli
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Patent number: 4294581Abstract: Uniformly dyed water-swellable cellulosic fibers which have been produced by contacting water-swellable cellulosic fibers successively or simultaneously with water, with ethylene glycol, propylene glycol or derivatives of these and with an essentially water-insoluble dye of the formula ##STR1## where Y is unsubstituted or substituted phenyl or naphthyl or an unsubstituted or substituted saturated or unsaturated 5-membered or 6-membered heterocyclic radical, two of the three radicals X are hydroxyl and the remaining radical X is ##STR2## where A is chlorine, bromine, cyano, nitro, an aliphatic, cycloaliphatic, araliphatic or aromatic radical and n is 0, 1, 2 or 3 and where, if n>1, the radicals are identical or different. Deep reddish blue to green dyeings or prints are obtained. The dyeings have very good fastness characteristics.Type: GrantFiled: November 16, 1979Date of Patent: October 13, 1981Assignee: BASF AktiengesellschaftInventors: Siegfried Mensch, Gerhard Epple, Wolfgang Elser
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Patent number: 4290768Abstract: In order to dye and print cellulose fibres, which have been swollen with water-miscible swelling agents, or fibre mixtures containing such cellulose fibres, the fibres are treated with a dyestuff of the general formula ##STR1## wherein A denotes an optionally substituted anthraquinone radical, which can contain a further fused ring,X denotes oxygen or sulphur,Z denotes a mononuclear or binuclear aryl radical andn denotes 1 or 2,and the dyestuff is fixed by means of a heat treatment.Type: GrantFiled: January 7, 1980Date of Patent: September 22, 1981Assignee: Bayer AktiengesellschaftInventors: Rutger Neeff, Robert Kuth, Werner Kuhnel, Wilhelm Gohrbandt
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Patent number: 4278434Abstract: Dyestuffs of the formula ##STR1## wherein R represents C.sub.1 -C.sub.5 -alkyl which is optionally substituted by fluorine, chlorine, hydroxyl or methoxy,are outstandingly suitable for printing polymeric materials in accordance with the transfer printing principle in that they produce intensely colored prints on these materials, especially on polyester and polyamide fibre materials.Type: GrantFiled: February 11, 1980Date of Patent: July 14, 1981Assignee: Bayer AktiengesellschaftInventors: Friedrich W. Krock, Rutger Neeff, Robert Kuth
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Patent number: 4249902Abstract: Formulations for dyeing polyesters and polyamides, the dyestuff component of which does not tend to crystallize in the dyebath and the effluents of which can be readily degraded biologically, are obtained in an inexpensive manner when those organophilic dyestuffs which have melting points below 140.degree. C., preferably below 100.degree. C., are used and these dyestuffs are homogeneously mixed with emulsifying polar/non-polar compounds, such as, for example, fatty sulphates and sulphonates, without expensive fine comminution processes.Type: GrantFiled: May 30, 1978Date of Patent: February 10, 1981Assignee: Bayer AktiengesellschaftInventors: Winfried Kruckenberg, Karl H. Schundehutte