Diazines (including Hydrogenated) Patents (Class 8/689)
  • Patent number: 8206465
    Abstract: An azo pigment showing excellent coloring characteristics such as tinctorial strength and hue and excellent fastness such as light fastness, and a pigment dispersion containing the azo pigment are provided. An azo pigment represented by the following general formula (1) and a pigment dispersion containing the pigment: Wherein Y, G, X1, X2, R1, R2 and R3 are defined in the claims and in the specification.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: June 26, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Nobuo Seto, Keiichi Tateishi
  • Patent number: 7686851
    Abstract: The present invention concerns concentrated storage-stable aqueous dye solutions comprising a) 5% to 30% by weight of a dye of the formula ?where K is a coupling component of the acetoacetanilide, pyridone, pyrazolone or pyrimidine series, and b) 0.1 to 0.9 mol of aminoalkoxy alcohols or monoalkanolamines per mole of dye of the formula (1) and c) 0 to 3 mol of trialkanolamine per mole of dye of the formula (1).
    Type: Grant
    Filed: March 4, 2005
    Date of Patent: March 30, 2010
    Assignee: Clariant Finance (BVI) Limited
    Inventor: Heidrun Schene
  • Patent number: 7413578
    Abstract: The present invention relates to agents comprising cationic azacyanine dyes of the formula (I) for coloring keratin fibers, such as, for example, wool, silk or furs and in particular human hair (where X1 is N—R1, O or S and X2 is N—R2, O or S), and to a method of coloring hair with varying degrees of damage.
    Type: Grant
    Filed: January 25, 2006
    Date of Patent: August 19, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Manuela Javet, Catherine Müller, Anita Roulin, Cécile Pasquíer
  • Patent number: 7410507
    Abstract: The present invention relates to the use of cationic azacyanine dyes of the formula (Ia) or (Ib) for coloring keratin fibers, and to a method of coloring hair with various degrees of damage.
    Type: Grant
    Filed: January 25, 2006
    Date of Patent: August 12, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Manuela Javet, Catherine Müller, Anita Roulin, Cécile Pasquier
  • Patent number: 7407517
    Abstract: The present disclosure relates to the use of cationic azo compounds with julolidine units as direct dyes, for the dyeing of keratin fibers, including human keratin fibers, such as the hair. The present disclosure also relates to a dyeing composition for the dyeing of keratin fibers, including human keratin fibers such as the hair, containing at least one cationic direct azo dye with julolidine units, in a suitable dyeing medium. The present disclosure also relates to a method of dyeing of keratin fibers, including human keratin fibers such as the hair, employing the dyeing composition according to the disclosure. The present disclosure also relates to cationic azo compounds with julolidine units.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: August 5, 2008
    Assignee: L'Oreal S.A.
    Inventors: Nicolas Daubresse, Andrew Greaves
  • Patent number: 7374583
    Abstract: The present invention relates to agents containing cationic azacyanine dyes having formula (I) for dyeing fibers, such as, for example, keratin fibers, wool, silk or fleeces, and in particular human hair, as well as to new asymmetrical azacyanine dyes.
    Type: Grant
    Filed: April 3, 2007
    Date of Patent: May 20, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Manuela Javet, Catherine Müller
  • Patent number: 7341607
    Abstract: The present invention relates to novel yellow anionic dyes, a process for their preparation, certain novel intermediates for their preparation and the use of these dyes for dyeing natural or synthetic materials, in particular, paper.
    Type: Grant
    Filed: May 27, 2003
    Date of Patent: March 11, 2008
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Michael Lennartz, Adolf Käser, Sandra Weiss
  • Patent number: 7326257
    Abstract: Disclosed herein is a composition for dyeing keratinous fibers, comprising at least one direct dye corresponding to the following formula (I): in which R1 and R2 may be chosen from hydrogen atoms; R3 may be a phenyl group, n may chosen from 0 and 1; R4 and R5 may be alkyl groups having 1 to 6 carbon atoms; R6 may be chosen from phenol groups and aniline groups; X and Y may represent nitrogen atoms, wherein the group —NR4R5 may occupy a position chosen from the 1-, 6-, 8-, and 9-position when n is equal to 1; and A is an anionic counterion. Further disclosed herein are methods for dyeing keratinous fibers using these direct dyes.
    Type: Grant
    Filed: July 30, 2004
    Date of Patent: February 5, 2008
    Assignee: L'Oreal
    Inventors: Alain Lagrange, Frédéric Guerin, Sylvain Kravtchenko
  • Patent number: 7270684
    Abstract: The present invention relates to a composition for dyeing keratinous fibers, containing at least one azodiazine direct dye corresponding to the following formula (I): The present invention also relates to a method for dyeing keratinous fibers using these direct dyes.
    Type: Grant
    Filed: July 30, 2004
    Date of Patent: September 18, 2007
    Assignee: L'Oreal
    Inventors: Alain LaGrange, Sylvain Kravtchenko
  • Patent number: 7182792
    Abstract: The present invention relates to a composition for dyeing keratinous fibers, containing at least one azodiazine direct dye corresponding to the following formula (I): The present invention also relates to a method for dyeing keratinous fibers using these direct dyes.
    Type: Grant
    Filed: July 30, 2004
    Date of Patent: February 27, 2007
    Assignee: L'Oreal S.A.
    Inventors: Alain Lagrange, Frédéric Guerin, Sylvain Kravtchenko
  • Patent number: 7175672
    Abstract: The present disclosure relates to a composition for dyeing keratinous fibers, comprising at least one azodiazine direct dye aminated at the 7-position. The present disclosure also relates to a process for dyeing keratinous fibers using the direct dyes described herein.
    Type: Grant
    Filed: July 30, 2004
    Date of Patent: February 13, 2007
    Assignee: L'Oreal
    Inventors: Alain Lagrange, Frédéric Guerin, Sylvain Kravtchenko
  • Patent number: 7029501
    Abstract: Provided is a hair dye composition containing a dissociative direct dye represented by the following formula (1): wherein, R1 to R4 each represents H or substituent, X represents OH or —NHSO2R5 (R5 representing an alkyl, aryl or heterocyclic group) and A represents a group of any one of formulas (Cp-1) through (Cp-12). The hair dye composition of the present invention is capable of strongly dyeing the hair with a vivid color tone without causing decomposition of the dye during the dyeing process, exhibits excellent resistance against sunlight, hair washing, perspiration, friction and heat, has a high stability against an alkali agent and an oxidizing agent, has a high dyeing property, and shows less color fade over time.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: April 18, 2006
    Assignees: Kao Corporation, Fuji Photo Film, Co., Ltd.
    Inventors: Dominic Pratt, Toshio Kawagishi
  • Patent number: 6833455
    Abstract: Disclosed herein are bridged perinones/quinophthalones of the general formula (I) or tautomeric forms thereof where X1, X2, Ar1 Ar2 and B are as described herein and are particularly characterized in that the bridging B is a radical of the formula —T1—W—T2—, where T1 and T2 are independently O or S and W is alkylene, especially C1-C6-alkylene, C6-C10-arylene, especially phenylene or cycloalkylene, which are each optionally substituted or is the radical of the formula (a) where the phenyl rings are optionally substituted and A is a radical of the formula O, S, SO, SO2 or CO, optionally substituted alkylene, or optionally substituted cycloalkylene, said alkylene or cycloalkylene being attached to the adjacent phenyl rings itself or else via its substitutents, or W is a radical of the formulae where s and t are independently from 1 to 6, the ends of the radical B each being attached to an aromatic carbon atom of the two radicals Ar1
    Type: Grant
    Filed: November 22, 2002
    Date of Patent: December 21, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christoph Thiebes, Josef-Walter Stawitz, Ulrich Feldhues
  • Publication number: 20030187108
    Abstract: Metal complexes of metals of the scandium group with an azo compound which conforms to the formula (I) or to one of its tautomeric structures 1
    Type: Application
    Filed: March 25, 2003
    Publication date: October 2, 2003
    Inventors: Ulrich Feldhues, Frank Linke, Ronald Gobel, Udo Herrmann, Sabine Endert
  • Publication number: 20010037532
    Abstract: The present invention relates to methods of dyeing a material which involve contacting the material with a dyeing system which comprises: (a) a mixture of (i) an aromatic diamine and (ii) one or more of a naphthol and an aminonaphthalene and (b) an oxidation system comprising (i) a hydrogen peroxide source and an enzyme exhibiting peroxidase activity or (ii) an enzyme exibiting oxidase activity on one or more of the compounds of mixture (a). The material may be a fabric, yarn, fiber, garment or film made of fur, hide, leather, silk or wool, or made of cationic polysaccharide, cotton, diacetate, flax, linen, lyocel, polyacrylic, synthetic polyamide, polyester, ramie, rayon, triacetate, or viscose.
    Type: Application
    Filed: March 8, 2001
    Publication date: November 8, 2001
    Applicant: Novozymes A/S
    Inventors: Martin Barfoed, Ole Kirk, Sonja Salmon
  • Patent number: 5525124
    Type: Grant
    Filed: September 2, 1994
    Date of Patent: June 11, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Jean-Francois Landre, Athanassios Tzikas, Jean P. Luttringer
  • Patent number: 5423888
    Abstract: A reactive dyestuff mixture contains at least one vinylsulphonylphthalocyanine dyestuff, at least one Ni fluoro-chloropyrimidenyl phthalocyanine dyestuff and/or one Ni chlorotriazinyl-phthalocyanine dyestuff.
    Type: Grant
    Filed: February 24, 1994
    Date of Patent: June 13, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dietrich Hildebrand, Joachim Wolff, Rolf Schulz
  • Patent number: 5393306
    Abstract: Dye mixtures which comprise a reactive dye of the formula ##STR1## together with at least one reactive dye of the formulae ##STR2## in which D, D', R.sub.1, R.sub.2, R.sub.3, R.sub.3 ' and B are as defined in claim 1, are particularly suitable for dyeing or printing cellulosic fibre materials or naturally occurring or synthetic polyamide fibre materials with a high tinctoffal yield, and produce dyeings and prints having good fastness properties.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: February 28, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Athanassios Tzikas, Claudia Carisch
  • Patent number: 5352246
    Abstract: The invention relates to dye compositions for obtaining level dyeings on carboxamido-containing and hydroxyl-containing fiber materials, which dyeings have comparably good light and wetlightfastness properties, the dye compositions containing dioxazine dyes (I) and disazo dyes (II) (one or more than one from IIa to IIf) in a weight ratio of 90:10 to 10:90, preferably 60:40 to 10:90, in particular 40:60 to 15:85.
    Type: Grant
    Filed: September 10, 1992
    Date of Patent: October 4, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Manfred Hahnke, Marcos Segal, Werner H. Russ, Uwe Mrotzeck, Jutta Reiter, Christine Feuchtner
  • Patent number: 5210188
    Abstract: 1. Dyestuffs for cyclic or straight polyfluoropolyoxyalkylenes, of general formula:Q[B--(A).sub.s ].sub.t (III)or[(Q).sub.s --B].sub.2 A (IV)where:Q=an organic group containing a chromophore group, free from free or salified sulphonic and/or carboxylic groups, and/or sulphon-amidic groups;A=a perfluorooxyalkylene chain, which is monovalent in formula (II) and divalent in formula (III);B=an organic at least divalent group;s, t=1 or 2, respectively.2. Compositions comprising cyclic or straight polyfluoropolyoxyalkylenes and at least a dyestuff of formula (III) or (IV) dissolved therein.
    Type: Grant
    Filed: February 11, 1992
    Date of Patent: May 11, 1993
    Assignee: Ausimont S.p.A.
    Inventors: Ezio Strepparola, Piero Gavezotti, Giovanni Gavazzi
  • Patent number: 5188641
    Abstract: A colored polymer containing repeat units derived from at least one azo dye which is free from water-solubilizing groups and contains at least one polymerizable olefinically unsaturated group and has the formula:A--N.dbd.N--Ewherein A represents the residue of a carbocyclic or heterocyclic diazotisable amine containing at least one electron-withdrawing substituent and E represents the residue of a carbocyclic or heterocyclic coupling component with the proviso that when both A and E are carbocyclic, the residue of the diazotisable amine does not contain a nitro or chloro substituent except when another different electron-withdrawing substituent is also present, the or each polymerizable group being attached to a carbon atom forming part of residue A or E.
    Type: Grant
    Filed: January 9, 1992
    Date of Patent: February 23, 1993
    Assignee: Imperial Chemical Industries PLC
    Inventor: Brian Parton
  • Patent number: 5173086
    Abstract: Aqueous solutions containing, each percentage being based on the weight of the aqueous solution,a) from 5 to 20% by weight of the dye of the formula ##STR1## (calculated as free acid) where cat.sup..sym. is a mixture of cations comprising from 5 to 50 mol % of lithium ions, from 5 to 40 mol % of diethanolammonium ions and from 20 to 90 mol % of triethanolammonium ions, andb) from 0 to 15% of urea, are useful for dyeing paper stock.
    Type: Grant
    Filed: September 12, 1991
    Date of Patent: December 22, 1992
    Assignee: BASF Aktiengesellschaft
    Inventor: Rudolf Bermes
  • Patent number: 5163971
    Abstract: Dyestuff mixtures containing one or more dyestuffs of the formula ##STR1## and one or more dyestuffs of the formula ##STR2## in which the substituents have the meanings given in the description are highly suitable for producing green cotton dyeings.
    Type: Grant
    Filed: May 16, 1991
    Date of Patent: November 17, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Josef-Walter Stawitz, Frank-Michael Stohr, Manfred Groll, Karl-Josef Herd, Karl-Heinz Schundehutte, deceased
  • Patent number: 5143519
    Abstract: Concentrated dye solutions of dyes of the formula (1) shown in claim are described.The dye solutions are distinguished by a good storage stability and are suitable, in particular, for dyeing paper.
    Type: Grant
    Filed: March 29, 1991
    Date of Patent: September 1, 1992
    Assignee: Ciba-Geigy Corporation
    Inventor: Willy Stingelin
  • Patent number: 5049189
    Abstract: A liquid dyestuff, useful as a major component of a ballpoint ink is prepared. A dye base, having both a sulfonic acid group and an azo group bonded to the same aromatic ring system, is provided in the aqueous phase of a two-phase system in which the organic phase is about 30 percent or more benzyl alcohol. In this two-phase system, the dye base is complexed with a diaryl quanidine, and the resulting dye concentrates in the organic solvent phase.
    Type: Grant
    Filed: February 2, 1990
    Date of Patent: September 17, 1991
    Assignee: Morton International, Inc.
    Inventors: Michael R. Friswell, Michael P. Hinton, Alejandro Zimin
  • Patent number: 4995885
    Abstract: Concentrated dye solutions of the formula (1) shown in claim 1 are described.The dye solutions are notable for a long shelf life and are suitable in particular for dyeing paper.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: February 26, 1991
    Assignee: Ciba-Geigy Corp.
    Inventor: Hans Morawietz
  • Patent number: 4980459
    Abstract: The invention describes a process for the preparation of formulations of water-insoluble to sparingly soluble azo dyes by simultaneous diazotization and coupling in a single step reaction, filtering the dye dispersion and, if desired, drying the dyestuff, which process comprises carrying out said simultaneous diazotization and coupling by intimately mixing the aqueous solution or suspension of the reactants, in the presence of one or more surface-active agents, concentrating the dilute dye dispersion by membrane separating methods, and at the same time at least partially removing salt and/or acid from the dispersion and converting it into a storage stable liquid formulation or, by drying, into a solid dye formulation.
    Type: Grant
    Filed: August 14, 1989
    Date of Patent: December 25, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Alberto Rabassa, Beat Bruttel
  • Patent number: 4917705
    Abstract: The invention relates to a process for dyeing or printing natural or synthetic polyamide fiber materials which comprises dyeing or printing these fiber materials with reactive dyes of the formula ##STR1## where each M is a cation, R.sub.1 and R.sub.2 are independently of each other hydrogen or C.sub.1 -alkyl, and X.sub.1 and X.sub.2 are independently of each other .alpha.,.beta.-dibromopropionyl, .alpha.-bromoacryloyl, chloroacetyl or a mono-, di- or trihalopyrimidinyl radical.
    Type: Grant
    Filed: September 21, 1988
    Date of Patent: April 17, 1990
    Assignee: Ciba-Geigy Corp.
    Inventors: Dieter Mausezahl, Peter Loew
  • Patent number: 4840642
    Abstract: Compounds of the formula ##STR1## and salts thereof, useful for dyeing and printing hydroxy group - or nitrogen-containing organic substrates, for example, leather and fibrous materials containing or consisting of natural or synthetic polyamides or natural or regenerated cellulose; preferably textile material containing or consisting of cotton which is preferably dyed using the exhaust dyeing method.
    Type: Grant
    Filed: September 4, 1987
    Date of Patent: June 20, 1989
    Assignee: Sandoz Ltd.
    Inventors: Gunther Auerbach, Helmut A. Moser
  • Patent number: 4647286
    Abstract: Reactive dyes of the formula ##STR1## in which M is twice-coupled 1-amino-8-hydroxynaphthalene-3,6-disulfonic acid, 1-amino-8-hydroxynaphthalene-4,6-disulfonic acid, 1-amino-8-hydroxynaphthalene-4-sulfonic acid or 2-amino-5-hydroxynaphthalene-7-sulfonic acid, A and B, independently of each other, are each sulfophenylene or sulfonaphthylene which can be further substituted, and X.sub.1 and X.sub.2 are each a 2,4-difluoro-5-chloropyrimid-6-yl radical, subject to the condition that A and B together contain at least 3 sulfo groups, are particularly suitable for dyeing and printing cellulose-containing fibre materials and produce, in high dyeing yield, dyeings and prints having good fastness properties.
    Type: Grant
    Filed: August 20, 1985
    Date of Patent: March 3, 1987
    Assignee: Ciba-Geigy Corporation
    Inventor: Karl Seitz
  • Patent number: 4631065
    Abstract: The invention relates to reactive dyes of the formula ##STR1## wherein D is the radical of a dye of the monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide series, each of R.sub.1 and R.sub.2 independently is hydrogen or an unsubstituted or substituted C.sub.1 -C.sub.4 alkyl radical, X.sub.1 is an unsubstituted or substituted aminofluoro-s-triazine radical, and X.sub.2 is a heterocyclic reactive radical which is attached direct to the radical D through the --N(R.sub.2) bridge member, excepting an unsubstituted or substituted aminofluoro-s-triazine.These dyes are particularly suitable for dyeing and printing cellulosic fibre material by the cold pad-batch method and give dyeings and prints of good fastness properties and high tinctorial strength.
    Type: Grant
    Filed: August 20, 1985
    Date of Patent: December 23, 1986
    Assignee: Ciba-Geigy Corporation
    Inventors: Karl Seitz, Peter Scheibli, Herbert Seiler
  • Patent number: 4421601
    Abstract: A dyestuff of the formula ##STR1## wherein X.sub.1 denotes amino, cyanamino, acetylamino, guanidino, ureido or hydroxyl;Y.sub.1 and Z.sub.1 denote hydroxyl or amino, with the proviso that at most 2 of the 3 radicals X.sub.1, Y.sub.1 and Z.sub.1 denote hydroxyl;R.sub.1 represents hydrogen, nitro, chlorine, bromine, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, nitrile, C.sub.1 -C.sub.4 -alkylsulphonyl, trifluoromethyl, phenylsulphonyl, benzylsulphonyl, phenoxy, carbo-C.sub.1 -C.sub.4 -alkoxy, carbophenoxy, carbonamido, C.sub.1 -C.sub.4 -alkylcarbonylamino, benzoylamino, sulphonamido, or carbonamido or sulfonamide mono-substituted or disubstituted by C.sub.1 -C.sub.4 -alkyl, phenyl, or benzyl; andR.sub.2 and R.sub.3 represent hydrogen; chlorine C.sub.1 -C.sub.4 -alkyl, carbo-C.sub.1 -C.sub.4 -alkoxy, carbonamido; carbonamido mono-substituted or disubstituted by C.sub.1 -C.sub.4 -alkyl, phenyl, or benzyl, or C.sub.1 -C.sub.4 -alkoxyand a process for coloring substrates using such dyestuff.
    Type: Grant
    Filed: January 3, 1978
    Date of Patent: December 20, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gunter Stephan, Karl H. Schundehutte
  • Patent number: 4389215
    Abstract: Anthraquinone-azomethine compounds of the formula ##STR1## or of the tautomeric formula ##STR2## or of the tautomeric formula ##STR3## in which A denotes an anthraquinone radical which is free from sulphonic acid groups and optionally further substituted and which preferably consists of at most 5 fused rings,R.sub.1 denotes hydrogen, C.sub.1 -C.sub.4 -alkyl, hydroxy-C.sub.1 -C.sub.4 -alkyl, optionally substituted phenyl, carboxyl, carboxylic acid, C.sub.1 -C.sub.4 -alkyl ester or hydroxyl,R.sub.2 denotes hydrogen, halogen, nitro, cyano, optionally substituted carbamoyl or optionally substituted sulphamoyl, sulphonic acid C.sub.1 -C.sub.4 -alkyl ester, sulphonic acid aryl ester, C.sub.1 -C.sub.4 -alkylcarbonyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, optionally substituted benzoyl, alkyl or optionally substituted phenyl sulphone, or a hetero-aromatic radical, for example a radical of the formula ##STR4## or of the formula ##STR5## or of the formula ##STR6## R.sub.
    Type: Grant
    Filed: September 24, 1981
    Date of Patent: June 21, 1983
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rutger Neeff, Meinhard Rolf, Walter Muller
  • Patent number: 4314818
    Abstract: Compounds of the formula ##STR1## in which R.sub.1 is hydrogen or methyl,either R.sub.2 is hydrogen; C.sub.1-6 alkyl; C.sub.1-4 alkyl monosubstituted by halo or phenyl; C.sub.2-4 alkyl monosubstituted in the 2-, 3- or 4-position by hydroxy or C.sub.1-2 alkoxy; C.sub.5-7 cycloalkyl; C.sub.5-7 cycloalkyl substituted by one to three C.sub.1-4 alkyl groups; phenyl; phenyl substituted by one or two substituents selected from the group consisting of halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; or --CH.sub.2 CH.sub.2 SO.sub.3 H, andR.sub.3 is hydrogen or C.sub.1-6 alkyl,or R.sub.2 and R.sub.3, together with the nitrogen atom to which they are bound, form a 5- or 6-membered saturated heterocyclic ring,and mixtures thereof, which compounds are in free acid or salt form, useful for dyeing and printing hydroxy group-containing and amido group-containing organic substrates such as natural and synthetic polyamides (e.g., wool, silk and nylon) and natural and regenerated cellulose (e.g., cotton, viscose and spun rayon).
    Type: Grant
    Filed: August 11, 1980
    Date of Patent: February 9, 1982
    Assignee: Sandoz Ltd.
    Inventor: Alfred Courtin
  • Patent number: 4276045
    Abstract: A process for dyeing and printing cellulosic textile material, wherein the dye used is a compound of the general formula I ##STR1## where K is a radical of the formula ##STR2## one of the radicals X and Y is a C.sub.2 -C.sub.19 -carboxylic acid ester group, a C.sub.3 -C.sub.19 -carboxamide group, a C.sub.4 -C.sub.18 -sulfonamide group, a C.sub.4 -C.sub.8 -alkylsulfone group, a C.sub.6 -C.sub.8 -arylsulfone group or a sulfonic acid aryl ester group andthe remaining substituents X, Y and Z are hydrogen, bromine or methyl andY may also be nitro,A is cyano or carbamyl,B.sup.1, B.sup.2 and B.sup.3 independently of one another are aliphatic, cycloaliphatic, araliphatic or aromatic radicals, ##STR3## is a saturated heterocyclic radical, R is hydrogen or C.sub.1 -C.sub.3 -alkyl,one of the radicals T is a radical of the formula ##STR4## and the other radical T is hydrogen, C.sub.1 -C.sub.4 -alkyl or phenyl.
    Type: Grant
    Filed: June 30, 1980
    Date of Patent: June 30, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Werner Juenemann, Gunther Lamm, Hermann Loeffler