Five-membered Hetero Ring Having Two Or More Ring Hetero Atoms Of Which At Least One Is Nitrogen Patents (Class 8/690)
  • Patent number: 9732201
    Abstract: A method for producing infra-red inert substrates, including molded polymeric articles, films, fibers and coatings and other organic and inorganic materials, by incorporating into the substrate or onto the surface of the substrate an effective amount of a dispersed bis-oxodihydroindolylen-benzodifuranone colorant. The thus obtained, also claimed substrates so produced are reflective and transparent to much of the near infra red radiation not reflected. There are multiple applications for cases of devices comprising electronic components, outdoor construction elements, outdoor furniture, automotive, marine or aerospace parts, laminates, artificial leather or textile materials, as well as in polychrome printing processes and optical fibers. The thus obtained substrates can also be subjected to laser welding. New bis-oxo-dihydroindolylen-benzodifuranone compounds are also claimed.
    Type: Grant
    Filed: January 30, 2015
    Date of Patent: August 15, 2017
    Assignee: BASF SE
    Inventors: Thomas Ruch, Philippe Bugnon, Paul Brown, Véronique Hall-Goulle
  • Patent number: 9023118
    Abstract: The present invention relates to new azo dyes, a process for their preparation, and their use for dyeing or printing fibrous materials, to produce materials with brownish shades.
    Type: Grant
    Filed: November 29, 2011
    Date of Patent: May 5, 2015
    Assignee: Kemira OYJ
    Inventors: Helmut-Martin Meier, Christof Heide, Klaus-Günter Strumpf, Thomas Hübbe
  • Patent number: 8740997
    Abstract: Novel compounds based on diaminostilbene are provided. The compounds conform to the general structures The compounds are useful as optical brighteners. Compositions, such as laundry compositions, containing such compounds are also provided.
    Type: Grant
    Filed: June 3, 2013
    Date of Patent: June 3, 2014
    Assignee: Milliken & Company
    Inventors: Robert L. Mahaffey, Eduardo Torres, Dominick J. Valenti, Patrick D. Moore, Leland G. Close, Jr.
  • Patent number: 8641785
    Abstract: An aqueous pigment dispersion containing A and B, wherein A is an azo pigment, an example of which is shown below, and in a crystal form having at least one characteristic peak at Bragg angles (2?) of 5 to 15° and 20 to 30° in X-ray diffraction with characteristic Cu K? line, a tautomer, a salt or hydrate thereof; and B is a vinyl polymer containing a specific structural unit, a structural unit derived from a salt-forming group-containing monomer (a), and a structural unit derived from a monomer selected from a styrene series macromer (b) and a hydrophobic monomer (c), provided that the water-insoluble vinyl polymer has at least either of 2 or more hydroxyl groups and 1 or more carboxyl groups at the end of the main chain:
    Type: Grant
    Filed: September 2, 2010
    Date of Patent: February 4, 2014
    Assignee: FUJIFILM Corporation
    Inventors: Keiichi Tateishi, Hiroshi Yamamoto
  • Patent number: 8470054
    Abstract: Provided are an azo compound represented by the following formula (1), a tautomer thereof, and a salt or hydrate of the azo compound or the tautomer: wherein in the formula (1), A represents a heterocyclic group; G represents a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; R1 and R2 each independently represent a group represented by the following formula (2) or (3):
    Type: Grant
    Filed: August 9, 2012
    Date of Patent: June 25, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Masahiro Higashi, Yoshihiro Jimbo
  • Patent number: 8465553
    Abstract: The invention provides a pigment dispersion composition including an azo pigment represented by formula (1), in which the azo pigment represented by formula (1) does not have an ionic hydrophilic group, an azo pigment derivative and a dispersant. In formula (1), G represents a hydrogen atom, an aliphatic group, an aryl group or a heterocyclic group; R1 represents an amino group, an aliphatic oxy group, an aliphatic group, an aryl group or a heterocyclic group; R2 represents a substituent; A represents a heterocyclic group; m represents an integer of 0 to 5; and n represents an integer of 1 to 4, wherein: when n=2, the azo pigment is a dimer formed via R1, R2, A or G; when n=3, the azo pigment is a a trimer formed via R1, R2, A or G; and when n=4, the azo pigment is a tetramer formed via R1, R2, A or G.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: June 18, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Toshihito Kuge, Nobuo Seto, Masahiro Higashi, Keiichi Tateishi, Hideki Takakuwa, Kaoru Aoyagi, Hiroshi Taguchi
  • Patent number: 8460397
    Abstract: A composition for the oxidative dyeing of keratin fibers, in particular human keratin fibers, comprising (A) a 1-hexyl/heptyl-4,5-diaminopyrazole compound of the general formula (I), its physiologically compatible water-soluble salt, or mixtures thereof; (B) a pyridine compound of the general formula (II), its physiologically compatible water-soluble salt, or mixtures thereof; and (C) an oxidizing agent. wherein R1, R2, R3, R4, R5, R6, R7 and R8 are as defined herein and a=1 or 2.
    Type: Grant
    Filed: February 16, 2012
    Date of Patent: June 11, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Muill Lim, Bryan Patrick Murphy, Margaret Ann Popp, Richard Matthew Charles Sutton, Guiru Zhang
  • Patent number: 8454710
    Abstract: To provide a process for producing an azo pigment showing excellent coloring characteristics such as tinctorial strength and hue and showing excellent fastness such as light fastness and ozone fastness, an azo pigment dispersion, a coloring composition, and an ink for inkjet recording.
    Type: Grant
    Filed: January 14, 2011
    Date of Patent: June 4, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Masahiro Higashi, Nobuo Seto, Yoshihiro Jimbo, Keiichi Tateishi
  • Patent number: 8454711
    Abstract: Novel compounds based on diaminostilbene are provided. The compounds conform to the general structures The compounds are useful as optical brighteners. Compositions, such as laundry compositions, containing such compounds are also provided.
    Type: Grant
    Filed: September 4, 2012
    Date of Patent: June 4, 2013
    Assignee: Milliken & Company
    Inventors: Robert L. Mahaffey, Eduardo Torres, Dominick J. Valenti, Patrick D. Moore, Leland G. Close
  • Patent number: 8444714
    Abstract: An oxidative dyeing composition comprising (A) a 1-hexyl/heptyl-4,5-diaminopyrazole compound of the general formula (I), its physiologically compatible water-soluble salt, or mixtures thereof; (B) a benzene-1,3-diol compound of the general formula (II), its physiologically compatible water-soluble salt, or mixtures thereof, and (C) an oxidizing agent. wherein R1, R2, R3, R4, R5, R6 and R7 are as defined herein and a=1 or 2.
    Type: Grant
    Filed: February 16, 2012
    Date of Patent: May 21, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Muill Lim, Bryan Patrick Murphy, Margaret Ann Popp, Richard Matthew Charles Sutton, Guiru Zhang
  • Patent number: 8298299
    Abstract: An azo pigment selected from the group consisting of: an azo pigment represented by the following formula (1), which has: a characteristic X-ray diffraction peak at Bragg angles (2?±0.2°) of 6.9°, 21.5°, and 27.3° in CuK? characteristic X-ray diffraction, a peak height at 11.9° of 0.6 or less relative to a peak height at 10.9° or a tautomer thereof, or a salt, hydrate, or solvate of the azo pigment or tautomer thereof; and an azo pigment represented by the following formula (1), which has: a characteristic X-ray diffraction peak at Bragg angles (2?±0.2°) of 6.9°, 25.8°, and 27.1° in CuK? characteristic X-ray diffraction, a peak height at 10.9° of 0.2 or less relative to a peak height at 11.9° or a tautomer thereof, or a salt, hydrate, or solvate of the azo pigment or tautomer thereof.
    Type: Grant
    Filed: May 31, 2011
    Date of Patent: October 30, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Masahiro Higashi, Yoshihiro Jimbo, Keiichi Tateishi
  • Patent number: 8262744
    Abstract: Novel compounds based on diaminostilbene are provided. The compounds conform to the general structures The compounds are useful as optical brighteners. Compositions, such as laundry compositions, containing such compounds are also provided.
    Type: Grant
    Filed: May 18, 2011
    Date of Patent: September 11, 2012
    Assignee: Milliken & Company
    Inventors: Robert L. Mahaffey, Eduardo Torres, Dominick J. Valenti, Patrick D. Moore, Leland G. Close, Jr.
  • Patent number: 8236065
    Abstract: There is provided an azo pigment having excellently good color reproducibility, dispersibility, and storage stability of pigment dispersions and having excellent hue and tinctorial strength. An azo pigment represented by the following formula (1) and having characteristic peaks at Bragg angles (20±0.2°) of 7.2°, 13.4°, 15.0° and 25.
    Type: Grant
    Filed: December 8, 2009
    Date of Patent: August 7, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Keiichi Tateishi, Yoshiaki Nagata, Shinya Hayashi
  • Patent number: 8231691
    Abstract: The present invention relates to disperse azo dyes based on a phthalimido-substituted aniline coupling component and an aromatic-carbocyclic or an aromatic-heterocyclic diazo component, to a process for the preparation of such dyes and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fiber materials, more especially textile materials.
    Type: Grant
    Filed: July 8, 2008
    Date of Patent: July 31, 2012
    Assignee: Huntsman International LLC
    Inventors: Romeo Dreier, Alfons Arquint, Urs Lauk, Patric Nowack
  • Patent number: 8226734
    Abstract: An azo pigment and pigment dispersion show excellent coloring characteristics and light fastness. The azo pigment is represented by general formula (1), its tautomer, a salt or hydrate thereof: wherein G is hydrogen or an aliphatic, aryl, heterocyclic, acyl, aliphatic oxycarbonyl, carbamoyl, or sulfonyl group, R1 is an amino, aliphatic oxy, aliphatic, aryl, or heterocyclic group, R2 is a substituent, A is an aromatic 5- or 6-membered heterocyclic group, m is an integer of 0 to 5, n is an integer of 1 to 4 and, when n=2, 3 or 4, the formula represents a dimer, trimer, or tetramer, respectively, formed through R1, R2, A, or G.
    Type: Grant
    Filed: July 17, 2009
    Date of Patent: July 24, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Nobuo Seto, Masahiro Higashi, Keiichi Tateishi, Hideki Takakuwa
  • Patent number: 8206465
    Abstract: An azo pigment showing excellent coloring characteristics such as tinctorial strength and hue and excellent fastness such as light fastness, and a pigment dispersion containing the azo pigment are provided. An azo pigment represented by the following general formula (1) and a pigment dispersion containing the pigment: Wherein Y, G, X1, X2, R1, R2 and R3 are defined in the claims and in the specification.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: June 26, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Nobuo Seto, Keiichi Tateishi
  • Patent number: 8202327
    Abstract: A pigment composition including (A) an azo pigment represented by formula (1), and at least one of (B) a coloring agent represented by formula (2), or (C) at least one additive represented by formula (3) or an additive represented by formula (4).
    Type: Grant
    Filed: June 29, 2011
    Date of Patent: June 19, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Masahiro Higashi, Yoshihiro Jimbo, Keiichi Tateishi
  • Patent number: 8177861
    Abstract: An azo pigment of formula (1), a tautomer of the azo pigment, or a salt or hydrate thereof, are provided: G0 and G1 each is a non-metal atomic group which can form a 5- or 6-membered heterocyclic ring, The rings may be monocyclic or condensed and are optionally substituted. X is a hetero atom. n is an integer of 1 to 4. When n=2, 3, or 4, the compound is a dimer, trimer, or tetramer, respectively. A is a substituent. The azo pigment has excellent coloring characteristics such as high tinctorial strength and hue. It also has excellent durability including high resistance to light and ozone. A pigment dispersion containing the azo pigment and a coloring composition are also provided.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: May 15, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Keiichi Tateishi, Yoshiaki Nagata, Nobuo Seto
  • Patent number: 8172910
    Abstract: An object of the invention is to provide an azo pigment having extremely good dispersibility and dispersion stability and having excellent hue and tinctorial strength and, preferably, having a long axis observed with a transmission microscope of from 0.01 ?m to 30 ?m. An azo pigment which is represented by the following formula (1) and having characteristic peaks at Bragg angles (2?±0.2°) of (i) 7.6° and 25.6°, (ii) 7.0°, 26.4°, and 27.3°, or (iii) 6.4°, 26.4°, and 27.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: May 8, 2012
    Assignee: FUJIFILM Corporation
    Inventors: Keiichi Tateishi, Shinya Hayashi
  • Patent number: 8142519
    Abstract: A monoazo pigment is represented by the general formula (1), a tautomer of the monoazo pigment, and a salt or a hydrate thereof: in which R1, P1, and Q1 each independently represents a hydrogen or a substituent, G represents the non-metallic atoms necessary to complete a 5- to 6-membered heterocyclic group, W represents a substituent capable of binding to the heterocyclic group constituted by G, t represents an integer of from 0 to 5, Het-1 represents a group selected from the aromatic heterocyclic groups represented by the general formula (2) as recited in the claims and disclosure of the invention.
    Type: Grant
    Filed: September 3, 2008
    Date of Patent: March 27, 2012
    Assignee: Fujifilm Corporation
    Inventors: Keiichi Tateishi, Shinya Hayashi, Yoshiaki Nagata, Tomoaki Nakamura
  • Patent number: 8118885
    Abstract: An azo pigment represented by the following general formula (1), a tautomer of the azo pigment, and a salt or a hydrate thereof: wherein each of R1, R2, P1, P2, Q1, and Q2 independently represents a hydrogen atom or a substituent, G represents the non-metallic atoms necessary to complete a 5- to 6-membered heterocyclic group, W represents a substituent capable of binding to the heterocyclic group constituted by G, t represents an integer of from 0 to 4, each of Het-1 and Het-2 independently represents a group selected from specific aromatic heterocyclic groups.
    Type: Grant
    Filed: June 27, 2008
    Date of Patent: February 21, 2012
    Assignee: Fujifilm Corporation
    Inventors: Keiichi Tateishi, Yoshiaki Nagata, Tomoaki Nakamura
  • Patent number: 8088182
    Abstract: The present invention relates to dyes of formula wherein D, R1, R2, R3, R4 and n are defined as in the claims, to the process for the preparation thereof and to the use thereof in dyeing or printing semi-synthetic and especially synthetic hydrophobic textile materials, more especially textile materials.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: January 3, 2012
    Assignee: Huntsman International LLC
    Inventors: Ralf Petermann, Christian Suppiger, Urs Lauk
  • Patent number: 8083810
    Abstract: To provide an azo pigment excellent in coloristic characteristics such as tinctorial strength and hue and at the same time, excellent in the durability such as light fastness and ozone resistance, a pigment dispersion containing the azo pigment, a coloring composition, and an ink for inkjet recording. An azo pigment represented by the following formula (1), its tautomer, or a salt or hydrate thereof: (wherein R1, R2, R3, Y, Z and G each independently represents a hydrogen atom or a substituent; n represents and integer of 2 to 4; and the formula represents a dimer through R1, R2, R3, Y, Z or G when n is 2, represents a trimer through R1, R2, R3, Y, Z or G when n is 3, and represents a tetramer through R1, R2, R3, Y, Z or G when n is 4).
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: December 27, 2011
    Assignee: Fujifilm Corporation
    Inventors: Shinya Hayashi, Keiichi Tateishi, Naoyuki Hanaki
  • Patent number: 8083811
    Abstract: Dye mixtures, comprising at least one dye of formula and at least one dye from the group of formulae wherein the substituents are defined in the specification.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: December 27, 2011
    Assignee: Huntsman International LLC
    Inventors: Georg Roentgen, Athanassios Tzikas, Hubert Jean Luc Christnacher
  • Patent number: 8080067
    Abstract: To provide an azo pigment composition exhibiting very good hue and light fastness and having excellent tinctorial strength (color density) and preferably further provide an azo pigment composition containing an azo pigment having characteristic X-ray diffraction peaks at different positions or a tautomer thereof. An azo pigment composition comprising at least one kind of an azo pigment represented by formula (1) having characteristic X-ray diffraction peaks at Bragg angles(20±0.2°) of 7.6°, 25.6° and 27.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: December 20, 2011
    Assignee: Fujifilm Corporation
    Inventors: Keiichi Tateishi, Shinya Hayashi
  • Patent number: 8080066
    Abstract: An azo pigment represented by the general formula (1), a tautomer, salt, or hydrate thereof: wherein R1, R2, R3, Y, Z, and G each independently represents a hydrogen atom or a substituent, n represents an integer of from 2 to 4 and, when n=2, the general formula (1) represents a dimer formed through R1, R2, R3, Y, Z, or G and, when n=3, the general formula (1) represents a trimer formed through R1, R2, R3, Y, Z, or G and, when n=4, the general formula (1) represents a tetramer formed through R1, R2, R3, Y, Z, or G.
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: December 20, 2011
    Assignee: Fujifilm Corporation
    Inventors: Shinya Hayashi, Keiichi Tateishi, Naoyuki Hanaki
  • Patent number: 8070832
    Abstract: The invention provides for a dye of the formula (I) where D is the residue of a diazo component; R1 is hydrogen, (C1-C6)-alkyl, (C1-C4)-alkoxy, hydroxyl, halogen, —NHCHO, —NHCO(C1-C6)-alkyl or —NHSO2 (C1-C6)-alkyl; R2 is hydrogen, (C1-C6)-alkyl, (C1-C4)-alkoxy or halogen; R3 is hydrogen, (C1-C6)-alkyl, substituted (C1-C6)-alkyl, (C3-C4)-alkenyl or substituted (C3-C4)-alkenyl or R2 and R3 combine to form the radical —C*H(CH3)CH2C(CH3)2—, where the carbon atom marked * is attached to the phenyl nucleus; R4 is hydrogen or (C1-C6)-alkyl; R5 is hydrogen or (C1-C6)-alkyl; R6 is hydrogen or (C1-C6)-alkyl; X is phenyl, thiophenyl, sulfonylphenyl or phenoxy; n is 0, 1, or 2; and m is 0 or 1. The invention is also related to the process of using the dye and the process of preparing the dye.
    Type: Grant
    Filed: August 1, 2008
    Date of Patent: December 6, 2011
    Assignee: DyStar Colours Deutschland GmbH
    Inventor: Stefan Neubauer
  • Patent number: 8062383
    Abstract: To provide an azo pigment composition having extremely good hue and extremely good light fastness and showing excellent tinctorial strength (color density) and, preferably, to provide an azo pigment composition further containing an azo pigment having characteristic X-ray diffraction peaks at different positions or a tautomer thereof An azo pigment composition which contains at least one azo pigment represented by the following formula (1) and having characteristic peaks at Bragg angles (20±0.2°) of 7.2° and 25.9° in X-ray diffraction with the characteristic Cu K? line, or a tautomer thereof: .
    Type: Grant
    Filed: March 5, 2009
    Date of Patent: November 22, 2011
    Assignee: FUJIFILM Corporation
    Inventor: Keiichi Tateishi
  • Patent number: 8002888
    Abstract: The invention relates to a colorant of the formula (2) where M=Ca, Sr or a combination of Ca and Sr.
    Type: Grant
    Filed: February 12, 2008
    Date of Patent: August 23, 2011
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Arpad Acs, Till Borchert, Ruediger Jung, Steffen Schneider
  • Patent number: 7927380
    Abstract: The disclosure relates to a composition for the oxidation dyeing of keratin fibers comprising: A) at least one fatty substance wherein the at least one fatty substance is present in an amount greater than or equal to 25% by weight relative to the total weight of the composition; B) at least one oxidation base chosen from diaminopyrazolones and acid-addition salts thereof; C) at least one additional dye precursor other than the oxidation base in B); D) at least one oxidizing agent; and optionally E) at least one alkaline agent.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 19, 2011
    Assignee: L'Oreal S.A.
    Inventors: Marie-Pascale Audousset, Isabelle Schlosser
  • Patent number: 7909892
    Abstract: The present invention relates storage stable aqueous dye solutions comprising a) 5 to 30% by weight of a dye of the formula in which K is a residue of a coupling component of the acetoacetanilide, pyridone, pyrazolone or pyrimidine series and M is hydrogen, an alkali metal or alkaline earth metal, ammonium or alkyl ammonium, b) 0.05 to 5% by weight of one or more compounds of the formula or a residue of the formula in which A, X, Y, R, P and Q are defined herein, c) an organic or an inorganic base or mixtures thereof, d) if desired, further additives and e) water, a process for their preparation and the use thereof for the dyeing, in particular of paper.
    Type: Grant
    Filed: January 21, 2003
    Date of Patent: March 22, 2011
    Assignee: BASF SE
    Inventors: Holger Lautenbach, Adolf Käser, Michael Heneghan
  • Patent number: 7871446
    Abstract: A dyestuff of the formula (I) wherein D is a diazo component; R1 is hydrogen, (C1-C4)-alkyl, hydroxy, —NHCOR6 or —NHSO2R6; R2 is hydrogen, halogen or (C1-C4)-alkoxy; R3 is hydrogen or methyl; R4 is hydrogen, (C1-C6)-alkyl, substituted (C1-C6)-alkyl, (C2-C6)-alkyl, which is interrupted by 1, 2 or 3 heteroatoms wherein said heteroatoms are —0—, —S— or —NR7, substituted (C2-C6)-alkyl, which is interrupted by 1, 2 or 3 heteroatoms wherein said heteroatoms are —0—, —S— or —NR7, (C2-C6)-alkenyl, substituted (C2-C6)-alkenyl, benzyl or phenethyl; R5 is hydrogen or methyl; R6 is (C1-C4)-alkyl, phenyl or substituted phenyl; R7 is (C1-C4)-alkyl, phenyl or substituted phenyl; m is 0, 1 or 2; and n is 0 or 1. The invention further relates to use of the dyestuff and the process of making the dyestuff.
    Type: Grant
    Filed: November 2, 2007
    Date of Patent: January 18, 2011
    Assignee: DyStar Colours Deutschland KG
    Inventors: Hartwig Jordan, Wolfgang Koster, Anthony Lawrence
  • Patent number: 7833291
    Abstract: The present invention provides dyes of the general formula (I) where D is the residue of a diazo component; R1 to R7 and L are each as defined in claim 1, processes for their preparation and their use.
    Type: Grant
    Filed: January 14, 2008
    Date of Patent: November 16, 2010
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Hartwig Jordan, Stefan Neubauer, Anthony Lawrence, Nigel Hall
  • Patent number: 7824450
    Abstract: The present invention provides dyes of the general formula (I) where D, R1 to R7 and n are each as defined in claim 1, processes for their preparation and their use.
    Type: Grant
    Filed: October 16, 2007
    Date of Patent: November 2, 2010
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Hartwig Jordan, Stefan Neubauer
  • Patent number: 7637964
    Abstract: Reactive dye mixtures which comprise one or more dyes of the indicated general formula (I) and one or more dyes of the hereinbelow indicated and defined general formula (II) where D1, D2, D3, R0, R*, R**, T, b, f, v and M are each as defined in claim 1, the dyes of the general formulae (I) and (II) containing at least one fiber-reactive group of the formula —SO2-Z or -Z2, their preparation and their use for dyeing and printing hydroxyl- and/or carboxamido-containing fiber material.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: December 29, 2009
    Assignee: DyStar Textilfarben GmbH & Co.
    Inventors: Stefan Meier, Werner Russ, Joachim Eichhorn
  • Patent number: 7413578
    Abstract: The present invention relates to agents comprising cationic azacyanine dyes of the formula (I) for coloring keratin fibers, such as, for example, wool, silk or furs and in particular human hair (where X1 is N—R1, O or S and X2 is N—R2, O or S), and to a method of coloring hair with varying degrees of damage.
    Type: Grant
    Filed: January 25, 2006
    Date of Patent: August 19, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Manuela Javet, Catherine Müller, Anita Roulin, Cécile Pasquíer
  • Patent number: 7410507
    Abstract: The present invention relates to the use of cationic azacyanine dyes of the formula (Ia) or (Ib) for coloring keratin fibers, and to a method of coloring hair with various degrees of damage.
    Type: Grant
    Filed: January 25, 2006
    Date of Patent: August 12, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Manuela Javet, Catherine Müller, Anita Roulin, Cécile Pasquier
  • Patent number: 7407517
    Abstract: The present disclosure relates to the use of cationic azo compounds with julolidine units as direct dyes, for the dyeing of keratin fibers, including human keratin fibers, such as the hair. The present disclosure also relates to a dyeing composition for the dyeing of keratin fibers, including human keratin fibers such as the hair, containing at least one cationic direct azo dye with julolidine units, in a suitable dyeing medium. The present disclosure also relates to a method of dyeing of keratin fibers, including human keratin fibers such as the hair, employing the dyeing composition according to the disclosure. The present disclosure also relates to cationic azo compounds with julolidine units.
    Type: Grant
    Filed: August 23, 2006
    Date of Patent: August 5, 2008
    Assignee: L'Oreal S.A.
    Inventors: Nicolas Daubresse, Andrew Greaves
  • Patent number: 7381228
    Abstract: The present invention relates to processes for mono-, di- or trichromatic dyeing or printing of natural or synthetic polyamide fiber materials, these processes utilizing a) blue-dyeing dye mixture, b) a red-dyeing dye mixture and/or c) a yellow-dyeing dye mixture, and also blue-dyeing, red-dyeing and yellow-dyeing dye mixtures and processes for their preparation.
    Type: Grant
    Filed: April 30, 2007
    Date of Patent: June 3, 2008
    Assignee: DyStar Textilfarben GmbH & Co. Deutschland KG
    Inventors: Stefan Ehrenberg, Andreas Giehl, Jörg Wörner
  • Patent number: 7374583
    Abstract: The present invention relates to agents containing cationic azacyanine dyes having formula (I) for dyeing fibers, such as, for example, keratin fibers, wool, silk or fleeces, and in particular human hair, as well as to new asymmetrical azacyanine dyes.
    Type: Grant
    Filed: April 3, 2007
    Date of Patent: May 20, 2008
    Assignee: The Procter & Gamble Company
    Inventors: Manuela Javet, Catherine Müller
  • Patent number: 7358345
    Abstract: The present invention claims dyestuffs of formula (I), wherein D, R1 to R7 and n are defined as given in claim 1, a process for their preparation and their use
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: April 15, 2008
    Assignee: Dystar Textilfarben GmbH & Co. Deutschland KG
    Inventor: Nigel Hall
  • Patent number: 7358344
    Abstract: An azo dye represented by formula (I): A-N?N—B??formula (I) wherein, A represents a group having a substituent required for inducing an intramolecular nucleophilic substitution reaction with a nitrogen atom of a reduced azo group as a nucleophilic species when the azo group is reductively decomposed, the group forming a compound containing the nitrogen atom in a ring structure, and B represents an aromatic or hetero ring which is bound to the azo group through a carbon atom.
    Type: Grant
    Filed: November 4, 2004
    Date of Patent: April 15, 2008
    Assignee: Fujifilm Corporation
    Inventors: Yasuhiro Shimada, Yasuhiro Ishiwata, Makiko Yokoi
  • Patent number: 7297168
    Abstract: Five-membered heteroaromatic keratin dyeing compounds with one, two, or three heteroatoms. This invention further relates to a composition for the oxidative dyeing of keratin fibers, comprising a medium suitable for dyeing and one or more 5-membered heteroaromatic keratin dyeing compounds with one, tow, or three heteroatoms. This invention further relates to a method for oxidative dyeing of keratin fibers, comprising applying such compositions in the presence of an oxidizing agent, for a period sufficient to develop the desired coloration.
    Type: Grant
    Filed: January 12, 2005
    Date of Patent: November 20, 2007
    Assignee: The Procter & Gamble Company
    Inventors: Bryan Patrick Murphy, Robert Wayne Glenn, Jr., Mu-Ill Lim, John Michael Gardlik, Stevan David Jones, William David Laidig, John David Shaffer, Charles Wayne Rees
  • Patent number: 7070629
    Abstract: The invention relates to a dye composition comprising a first oxidation base of the diaminopyrazole type, a second oxidation base of the para-phenylenediamine type containing a cyclic amino group, and a coupler. The invention also relates to the use of this composition for dyeing keratin fibers and also to the dyeing process using this composition.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: July 4, 2006
    Assignee: L'Oreal, S.A.
    Inventors: Sylvain Kravtchenko, Alain Lagrange
  • Patent number: 7018426
    Abstract: The object of the invention is an agent for the oxidative dyeing keratin fibers, wherein it contains (a) at least one 4,5-diaminopyrazole derivative of Formulas (I), (II) or (III) or its salt with organic or inorganic acids as well as (b) at least one resorcinol derivative of the general Formula (IV)
    Type: Grant
    Filed: September 13, 2001
    Date of Patent: March 28, 2006
    Assignee: Wella AG
    Inventors: Manuela Javet, Christel Dousse
  • Patent number: 7004979
    Abstract: The invention relates to a dye composition comprising an oxidation base of the diaminopyrazole type and a pyrazolo-azole coupler. The invention also relates to the use of this composition for dyeing keratin fibres and also to the dyeing process using this composition.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: February 28, 2006
    Assignee: L'Oreal S.A.
    Inventors: Sylvain Kravtchenko, Alain Lagrange
  • Patent number: 6962610
    Abstract: Provided is a hair dye composition containing a dissociative direct dye represented by the following formula (1): wherein, R1 to R4 each represents H or substituent, X represents OH or —NHSO2R5, R5 represents an alkyl, aryl or heterocyclic group, and A represents a divalent group capable of forming a methine dye as a whole compound, together with the portion other than A. The hair dye composition of the present invention is capable of strongly dyeing the hair with a vivid color tone without causing decomposition of the dye during the dyeing process, exhibits an excellent resistance against sunlight, hair washing, perspiration, friction and heat, has a high stability against an alkali agent and an oxidizing agent, has a high dyeing property, and has less color fade after the passage of time.
    Type: Grant
    Filed: September 12, 2003
    Date of Patent: November 8, 2005
    Assignees: Kao Corporation, Fuji Photo Film Co., Ltd.
    Inventors: Dominic Pratt, Toshio Kawagishi
  • Patent number: 6905522
    Abstract: Dye compositions comprising, in a medium suitable for dyeing: at least one first oxidation base chosen from 4,5-diaminopyrazole derivatives of formula (I) and addition salts thereof, at least one second cationic oxidation base chosen from monobenzenic, dibenzenic and heterocyclic oxidation bases, and the addition salts thereof, comprising at least one cationic group Z chosen from aliphatic chains optionally bearing at least one ring chosen from saturated and unsaturated rings; wherein said at least one cationic group Z is linked directly to at least one benzenic ring or to at least one heterocycle of said at least one second cationic oxidation base or linked to at least one amine functional group borne by said at least one benzenic ring or said at least one heterocycle; and at least one coupler; as well as the use of this composition for dyeing keratin fibers and the dying process using this composition.
    Type: Grant
    Filed: February 11, 2003
    Date of Patent: June 14, 2005
    Assignee: L'Oreal S.A.
    Inventors: Sylvain Kravtchenko, Alain Lagrange
  • Patent number: 6783558
    Abstract: The present invention is directed to a hair coloring method by using a composition comprising a specified ring-fused heterocycle direct dyestuff having the general formula (1) or a salt thereof wherein the formulas are as defined in the patent claims. Furthermore, the present invention is also directed to the composition. This composition has a surprisingly good hair coloring performance and compatibility with peroxides. The use of this composition leads to long lasting brilliant colors wherein the color is stable against washing of the hair and environmental influences.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: August 31, 2004
    Assignees: Kao Corporation, Fuji Photo Film Co., Ltd.
    Inventors: Dominic Pratt, Toshio Kawagishi
  • Publication number: 20030172478
    Abstract: A bipyrrolinonylidene-type compound is provided which is useful as colorants such as dyes and pigments, or other organic chemical products or intermediates thereof. A method of producing the bipyrrolinonylidene-type compound is also provided, which is suitable for large-scale industrial production with high yield. The bipyrrolinonylidene-type compound is represented by general formula (1).
    Type: Application
    Filed: March 11, 2003
    Publication date: September 18, 2003
    Applicant: DAINIPPON INK AND CHEMICALS, INC.
    Inventor: Yuji Ohashi