Wool Or Silk Patents (Class 8/917)
-
Patent number: 8979947Abstract: The present invention relates to dyes of the formula (I) in which R1 to R10, D1 and D2 are defined as given in claim 1, a process for preparing them, and their use for dyeing and printing hydroxyl- and/or carboxamido-containing materials.Type: GrantFiled: November 24, 2011Date of Patent: March 17, 2015Assignee: DyStar Colours Distribution GmbHInventors: Roxana Barbieru, Vajiravelu Sivamurugan
-
Mixtures of fibre-reactive dyes and their use in a method for di- or trichromatic dyeing or printing
Patent number: 8911509Abstract: Reactive dye mixtures comprising at least one red dyeing dye and at least one blue, yellow, orange or brown dyeing dye and their use in methods for the dichromatic or trichromatic dyeing or printing of cellulosic fiber materials are described. The reactive dye mixtures yield dyeings or prints having good reproducibility and good all-round fastness properties.Type: GrantFiled: January 13, 2011Date of Patent: December 16, 2014Assignee: Huntsman International LLCInventors: Athanassios Tzikas, Georg Roentgen, Marco Casartelli, Remo Codemo, Jean-Francois Landre -
Patent number: 8556995Abstract: A composition comprising (a) a betaine of formula wherein R1 is a monovalent radical of an aliphatic C4-C30-hydrocarbon, R2 and R3 independently of one another represent C1-C12alkyl and X and Y independently of one another denote a bivalent radical of an aliphatic C1-C12-hydrocarbon, (b) a quaternary ammonium salt of formula (2) wherein R4 is a monovalent radical of an aliphatic C4-C30-hydrocarbon, R5, R6 and R7 independently of one another represent C1-C12alkyl, C5-C24aryl or C6-C30aralkyl, A? is halogenide, nitrate, hydrogensulfate or sulfonate, and (c) an alkoxylated fatty alcohol, is suitable as shade enhancer for the EL portion in PA/EL blends in the dyeing process using dark shade dyes.Type: GrantFiled: September 6, 2010Date of Patent: October 15, 2013Assignee: Huntsman International LLCInventors: Hans Peter Haerri, Franz Gruener, Edvard Ham, Huiya Yuan, Xiaolong Lu
-
Patent number: 8187342Abstract: A process for indigo dyeing of wool and wool blends comprising the steps of subjecting the wool and wool blends to a step of pretreatment by impregnation with a shrink resistance agent, subjecting the pretreated wool and wool blend yarns to the step of indigo dyeing and post dyeing, wherein the step of dyeing and post dyeing includes a single step or a plurality of steps of impregnation of the pretreated wool and wool blends in an indigo dye bath followed each time by the step of oxidation.Type: GrantFiled: September 18, 2003Date of Patent: May 29, 2012Assignee: Malwa Industries LimitedInventors: Jangi Lal Oswal, Rishi Oswal
-
Patent number: 8167958Abstract: The present invention relates to a process for dyeing sheetlike textile materials with a dye, which comprises a concentrated dye system being applied in a total amount of 1% to 25% by weight, based on the textile material, to the textile material in two or more sub-steps and the dye being fixed on the textile material after each and every sub-step.Type: GrantFiled: August 14, 2009Date of Patent: May 1, 2012Assignee: DyStar Colours Deutschland GmbHInventors: Christian Meyer, Wolfgang Schrott, Franz Sütsch
-
Patent number: 8137416Abstract: Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates are described.Type: GrantFiled: April 2, 2007Date of Patent: March 20, 2012Assignee: Clariant Finance (BVI) LimitedInventor: Rainer Nusser
-
Patent number: 8038736Abstract: The present invention provides dye mixtures containing a dye of the formula (I) and a dye of the formulae (II) where Z is —CH?CH2 or —CH2CH2Z1 and Z1 is hydroxyl or an alkali-eliminable group; and M is hydrogen, an alkali metal or one equivalent of an alkaline earth metal. The invention also relates to a process for their preparation and their use.Type: GrantFiled: March 3, 2010Date of Patent: October 18, 2011Assignee: DyStar L.P.Inventors: Ronald Pedemonte, Antonio Torrentera, Tiffany Chambers
-
Patent number: 7927384Abstract: Compounds of the general formula (I) a process for their preparation and their use for dyeing and/or printing organic substrates are described.Type: GrantFiled: June 21, 2007Date of Patent: April 19, 2011Assignee: Clariant Finance (BVI) LimitedInventor: Rainer Nusser
-
Patent number: 7381806Abstract: The objects of the present invention are novel cationic azo azine dyes of the generic formula (I), as well as colorants for keratin fibers that contain these compounds.Type: GrantFiled: September 7, 2006Date of Patent: June 3, 2008Assignee: The Procter & Gamble CompanyInventors: Markus Speckbacher, Hans-Jürgen Braun
-
Patent number: 7259259Abstract: Reactive dyes of formula (1): wherein R1, is optionally substituted C1-C4 alkyl, R2 is halogen, C1-C4 alkyl, C1-C4 alkoxy or sulfo, Z1 is a radical of formula —SO2—Y (2a), —CO—NH—(CH2)K—SO2—Y (2b), —NH—CO—CH(Hal)—CH2—Hal (2c) —NH—CO—C(Hal)?CH2 or (2d) wherein Hal is chlorine or bromine, Y is vinyl or a radical —CH2CH2—U and U is a group removable under alkaline conditions, k is the number 2, 3, 4, 5 or 6, n is the number 0, 1 or 2 and m is the number 0 or 1, are suitable for dyeing or printing cellulose-containing fibre materials, preferably natural or synthetic polyamide fibre materials, and produce, with a high colour yield, dyeings and prints having good fastness propertiesType: GrantFiled: November 24, 2003Date of Patent: August 21, 2007Assignee: Huntsman International LLCInventors: Jürgen Schmiedl, Damien Schoehn, Klaus Koch
-
Patent number: 7244278Abstract: The object of the present invention is a ready-to-use agent for coloring keratin fibers containing (i) at least one heterocyclic hydrazone derivative of formula (I), (ii) at least one aromatic enamine of formula (IIa) or an acid addition compound thereof (IIb) and (iii) at least one oxidant, a multicomponent kit and a method for coloring keratin fibers by use of said agentType: GrantFiled: November 11, 2004Date of Patent: July 17, 2007Assignee: Wella AGInventors: Cecile Pasquier, Veronique Buclin, Caroline Kiener, Nadja Duc-Reichlin, Hans-Juergen Braun
-
Patent number: 7056348Abstract: A method for the synthesis of 5-aryl-1,3,3,-trimethyl-2-methylene-indoline derivatives of Formula (I) or its salts of Formula (Ia) wherein 1 mole of a 5-aryl-2,3,3-trimethyl-3H-indole derivative of Formula (VII) is reacted for 1 to 44 hours at a temperature of 20° to 180° C. in an apolar, aprotic or polar, protic or polar aprotic solvent with 1 to 50 moles of a compound of Formula R1-A; new compounds of Formulas (I)/(Ia) and (V), obtainable by this method as well as an agent containing at least one compound of Formula (I)/(Ia) and a carbonyl/imine compound for dyeing keratinic fibers and a method for temporarily dyeing keratin fibers, for which the keratin fiber is dyed with the aforementioned agent and the dyeing, so obtained, is removed again at any later time by a sulfite preparation.Type: GrantFiled: January 24, 2002Date of Patent: June 6, 2006Assignee: Wella AGInventors: Guido Sauter, Hans-Juergen Braun, Nadia Reichlin
-
Patent number: 6989038Abstract: The invention relates to novel mixtures of sulfuric esters and specific sulfuric esters that are useful as leveling agents for the dyeing of nitrogenous fiber materials and to a process for their preparation by reacting sulfuryl chloride with specific alcohols.Type: GrantFiled: May 25, 2001Date of Patent: January 24, 2006Assignee: Bayer AktiengesellschaftInventor: Uwe Vogt
-
Patent number: 6896705Abstract: The invention relates to novel mixtures of sulfuric esters and specific sulfuric esters that are useful as leveling agents for the dyeing of nitrogenous fiber materials and to a process for their preparation by reacting sulfuryl chloride with specific alcohols.Type: GrantFiled: July 29, 2004Date of Patent: May 24, 2005Assignee: Bayer AktiengesellschaftInventor: Uwe Vogt
-
Patent number: 6869453Abstract: A reactive dye compound comprising: (a) at least one chromophore moiety; (b) at least one nitrogen-containing heterocycle; (c) a linking group to link each chromophore moiety to each nitrogen-containing heterocycle; characterised in that at least one nitrogen-containing heterocycle is substituted with at least one Y group wherein Y is a phosphonate or a borate derivative. The compounds herein have high Exhaustion Values (E), high Fixation Values (F) and high Efficiency Values (T) and show significant improvements in terms of reducing spent dyestuff in effluent, increasing dye affinity to the substrate, increasing the dye-substrate covalent bonding, increasing the ability to dye substrates at room temperature, decreasing the amount of dye that is removed during the post dyeing “soaping off process” and therefore simplifying the post dyeing “soaping off process” traditionally associated with dyeing cotton with fibre reactive dyes and reduction of staining of adjacent white fabrics.Type: GrantFiled: September 29, 2000Date of Patent: March 22, 2005Assignee: North Carolina State UniversityInventors: David Malcolm Lewis, Dong Wei He, Taher Iqbal Yousaf, Gilles Yves Marie Fernand Genain
-
Patent number: 6736864Abstract: A reactive dye compound comprising: (a) at least one chromophore moiety; (b) at least one SO2C2H4 group which is attached to the chromphore moiety either directly via the sulphur atom of the SO2C2H4 group or via a linking group L; characterized in that at least one SO2C2H4 group is substituted on its terminal carbon atom with at least one Y group wherein Y is a phosphonate or borate derivative.Type: GrantFiled: March 27, 2002Date of Patent: May 18, 2004Assignee: North Carolina State UniversityInventors: David Malcolm Lewis, Dong Wei He, Taher Iqbal Yousaf, Gilles Yves Marie Fernand Genain
-
Patent number: 6652601Abstract: The object of the present invention is an agent for dyeing fibers obtained by mixing two components and characterized in that one component (component A2) contains at least one carbonyl compound and the other component (component A1) contains at least one indoline derivative of formula (I) or a 3H-indoline derivative of formula (Ia) as well as a multicomponent kit for dyeing and later decolorizing fibers, said kit containing both an agent according to the invention for producing a coloration on the fiber and an agent for the reductive removal of said coloration.Type: GrantFiled: October 17, 2001Date of Patent: November 25, 2003Assignee: Wella AktiengesellschaftInventors: Guido Sauter, Hans-Juergen Braun, Nadia Reichlin
-
Patent number: 6620211Abstract: In a method for dyeing textile material with one or more fiber-reactive disperse dyestuffs in a supercritical or almost critical fluid, such as CO2, which textile material is selected from the group consisting of silk, wool and cellulose, combinations thereof and combinations of one or more thereof with synthetic fibers, such as polyester and/or polyamide, the relative humidity of the fluid is in the range from 10-100% during dyeing. Textile materials which have been dyed with the aid of this method have properties which are at least equal to those of textile materials of the same type which have been dyed in the traditional manner using water-soluble dyestuffs. A device for carrying out the dyeing method is also disclosed.Type: GrantFiled: February 9, 2001Date of Patent: September 16, 2003Assignee: Stork Prints B.V.Inventors: Wilhelmus J. T. Veugelers, Geert Feye Woerlee, Hendrik Gooijer, Jan Willem Gerritsen
-
Patent number: 6562115Abstract: Monoazo dyes of formulas (III) wherein R1, R2, R3, D1 and M are as defined in the specification, are excellent dyes for dyeing and printing of cellulose containing materials and especially for the preparation of inks for ink jet printing.Type: GrantFiled: May 29, 2001Date of Patent: May 13, 2003Assignee: Ilford Imaging Switzerland GmbHInventors: Kurt Baettig, Gérald Jan
-
Publication number: 20020083532Abstract: Anionic coloring agents comprising at least one spacer arm bounded to their chemical structure. These anionic coloring agents have the following general formula: CA-BE, wherein, CA is an anionic coloring agent comprising at least a cromophore group; and BE is the spacer arm, which has the following chemical structure: —(X—R—Z)r, wherein X is a direct link or a group having the formula —S(O)s, wherein s is 0, 1 or 2; or —NR1—, wherein, R1 is hydrogen or a C1-C10 alkyl group; R is a C1-C10 straight or branched alkylene group: Z is a polar group; and r is an integer equal or higher than 1.Type: ApplicationFiled: December 18, 2001Publication date: July 4, 2002Inventor: Jorge Mazza
-
Patent number: 6413281Abstract: 2-(p-sulphophenyl) amino-1,3 5-triazine derivatives [1] and their alkali salts, wherein R1, represents Cl, F; R2 is &agr;- or &bgr;-naphthylamino, or &agr;- or &bgr;-naphthoxy, and the method for preparing the compound are provided. The compound can be used as a cationic dye auxiliary agent in dyeing animal protein fibers (such as wool, cony hair, camel hair and natural silk) and their textile fabric as well as blended yarn or fabric containing the animal protein fiber.Type: GrantFiled: February 17, 2000Date of Patent: July 2, 2002Inventor: Zhi Wang
-
Patent number: 6350862Abstract: Reactive Dye compound having formula (I) wherein: D is a chromophore group; L is a linking moiety; Q is a quaternized nitrogen derivative; X and Y are independently selected from chlorine, bromine, fluorine or hydrogen; A is selected from halogen, preferably chlorine or fluorine; provided that at least one of X and Y is fluorine; A is selected from halogen, preferably chlorine or fluorine; and salts and esters thereof.Type: GrantFiled: October 2, 2000Date of Patent: February 26, 2002Assignee: The Procter & Gamble CompanyInventors: Earl David Brock, David Malcolm Lewis, Taher Iqbal Yousaf
-
Publication number: 20020017218Abstract: 1Type: ApplicationFiled: May 29, 2001Publication date: February 14, 2002Applicant: ILFORD IMAGING SWITZERLAND GmbHInventors: Kurt Baettig, Gerald Jan
-
Patent number: 6320031Abstract: Monoazo dyes of formula (3) wherein A, R1, R2, M and n are as defined in the specification, are excellent dyes for dyeing and printing of cellulose containing materials and especially for the preparation of inks for ink jet printing.Type: GrantFiled: February 23, 2000Date of Patent: November 20, 2001Assignee: Ilford Imaging Switzerland GmbHInventors: Kurt Baettig, Gérald Jan
-
Patent number: 6319289Abstract: Compounds of formula (I) wherein A is hydrogen or a descretionary radical, a novel process for their preparation and their use for the dyeing of organic substrates.Type: GrantFiled: March 31, 1999Date of Patent: November 20, 2001Assignee: Clariant Finance (BVI) LimitedInventor: Georg Schöfberger
-
Patent number: 6319290Abstract: Compounds of the general formula (I) wherein R1 represents hydrogen or a C1-C4-alkyl group, X represents the radical of aliphatic, cyclic or aromatic diamines and Y represents hydrogen or an alkali metal, and a process for their preparation and their use for dyeing organic substrates, and organic substrates dyed with these compounds.Type: GrantFiled: December 9, 1999Date of Patent: November 20, 2001Assignee: Clariant Finance (BVI) LimitedInventors: Detlef Kalweit, Martin Oberholzer
-
Patent number: 6302922Abstract: There is provided a process for manufacturing woven or knitted fabrics comprising modifying the woven or knitted fabrics by applying a skeleton triazine cross-linking reaction using a sericin fixing method of raw silk to enhance its shrink and crease resistance and shape stability and thereafter removing the sericin using a special scouring. The process for manufacturing a woven or knitted fabric, comprises the steps of finishing and treating raw silk and/or cellulose fibers by using a silk sericin fixing method; doubling and twisting thus finished/treated raw silk and/or cellulose fibers; weaving or knitting the doubled and twisted yarns; swelling the woven or knitted fabric forming a cloth by dipping it in a bath; and, scouring the woven or knitted fabric swelled in the bath with an enzyme whereby the woven or knitted fabric is provided with shrink and crease resistance and shape stability.Type: GrantFiled: December 17, 1998Date of Patent: October 16, 2001Assignee: Sumitomo CorporationInventor: Keiichiro Kanehisa
-
Patent number: 6296672Abstract: The present invention relates to methods of dyeing a material which involve contacting the material with a dyeing system which comprises: (a) a mixture of (i) an aromatic diamine and (ii) one or more of a naphthol and an aminonaphthalene and (b) an oxidation system comprising (i) a hydrogen peroxide source and an enzyme exhibiting peroxidase activity or (ii) an enzyme exibiting oxidase activity on one or more of the compounds of mixture (a). The material may be a fabric, yarn, fiber, garment or film made of fur, hide, leather, silk or wool, or made of cationic polysaccharide, cotton, diacetate, flax, linen, lyocel, polyacrylic, synthetic polyamide, polyester, ramie, rayon, triacetate, or viscose.Type: GrantFiled: December 14, 1999Date of Patent: October 2, 2001Assignees: Novozymes A/S Patents, Novozymes North AmericaInventors: Martin Barfoed, Ole Kirk, Sonja Salmon
-
Patent number: 6228132Abstract: Modified silk processed according to an embodiment of the present invention is an all-natural stretchable silk textile processed without synthetics. The modified silk includes commercially-advantageous physical properties such as stretchability and it is machine washable, wrinkle resistant, stain resistant, and water proof/repellant, which render the silk very versatile and wearable. The process comprises collecting silk, boiling the silk in a water and vinegar solution, whereupon the silk becomes stretchable or elastic. The silk may then be soaked in water and vinegar to add a wrinkle resistant effect. The silk is then fabricated into a silk textile for example in a cross weave configuration, adding an elastic quality without synthetics. The finished product may then be soaked in lemon grass and water to make it stain resistant.Type: GrantFiled: December 17, 1999Date of Patent: May 8, 2001Assignee: Innovative ProductsInventors: Phillip Prince, Irene Cheng
-
Patent number: 6143039Abstract: The present invention provides a dye mixture comprising one or more copper complex formazan dyes conforming to the formula (1) ##STR1## and one or more copper complex formazan dyes conforming to the formula (2) ##STR2## wherein R1, R2, Y1, Y2 and M are defined as given in claim 1, methods for preparing said dye mixtures and methods for dyeing and printing hydroxy- and/or carboxamido-containing materials using said dye mixtures.Type: GrantFiled: April 12, 1999Date of Patent: November 7, 2000Assignee: Dystar Textilfarben GmbH & Co.Inventors: Ron Pedemonte, Werner Russ
-
Patent number: 6120560Abstract: A method and apparatus for pattern dyeing of textile substrates in which the dyeing is done in two stages. In the first stage, a dye is uniformly applied in a manner that allows the dye to fix on contact. The uniformly dyed substrate is then moved under a series of spaced arrays, each array being associated with a separate color and being comprised of a plurality of individually controlled liquid dye applicators. Liquid dye of a given color is selectively applied through one or more dye applicators as the substrate passes under the array associated with that color. The applied dye remains unfixed until the substrate passes under all the arrays and the patterning is complete, whereupon all dye applied by the dye applicators is fixed by steaming or other appropriate application of energy to the substrate.Type: GrantFiled: March 8, 1999Date of Patent: September 19, 2000Assignee: Milliken & CompanyInventors: Scott C. Miller, Frank W. Teaster, Matthew R. Walker
-
Patent number: 6090165Abstract: Dye mixtures which contain a dye of the formula ##STR1## together with a dye of the formula ##STR2## in which M.sup.+ in the dyes of the formulae (1) and (2) are ammonium cations ##STR3## which are identical to or different from one another, of an amine of the formula ##STR4## where R.sub.1 and R.sub.2 independently of one another are hydrogen, C.sub.1 --C.sub.6 alkyl or C.sub.2 --C.sub.6 alkyl substituted by hydroxyl or amino and, if appropriate, interrupted by an oxygen atom, and R.sub.3 is C.sub.2 --C.sub.6 alkyl substituted by hydroxyl or amino and, if appropriate, interrupted by an oxygen atom, afford dyeings having good fastnesses on nitrogen-containing or hydroxyl group-containing fibre materials.Type: GrantFiled: February 10, 1998Date of Patent: July 18, 2000Assignee: Ciba Specialty Chemicals CorporationInventor: Roger Lacroix
-
Patent number: 6080689Abstract: A process is provided for manufacturing a high quality cloth having a width of 150 cm or any width in which likelihood of occurrence of defects such as color shading, rub marks, wrinkles and creases due to fabric dyeing method is eliminated and color fastness is enhanced.A process for manufacturing a woven or knit fabric using yarn dyed silk comprises the steps of dyeing (step 3) sericin which covers the periphery of silk fibers and fibroin which is located inside thereof into the same color; making yarn dyed silk (step 4, 5) by doubling and twisting the dyed silk fibers; making a cloth (step 6) by weaving or knitting the yarn dyed silk; swelling (step 7) the yarn dyed silk which constitutes the cloth by dipping the cloth into hot water in a tub; and decomposing (step 8) sericin of the yarn dyed silk of the cloth with an enzyme in hot water in a tub.Type: GrantFiled: August 12, 1998Date of Patent: June 27, 2000Assignee: Sumitomo CorporationInventor: Keiichiro Kanehisa
-
Patent number: 6036729Abstract: The present invention relates to methods of dyeing a material, comprising (a) soaking the material in an aqueous solution which comprises one or more mono-, di- or polycyclic aromatic or heteroaromatic compounds; and (b) treating the soaked material in an aqueous solution with (i) a hydrogen peroxide source and an enzyme exhibiting peroxidase activity or (ii) an enzyme exibiting oxidase activity on the one or more aromatic or heteroaromatic compounds; wherein the material is a fabric, yarn, fiber, garment or film made of fur, hide, leather, silk or wool.Type: GrantFiled: December 19, 1996Date of Patent: March 14, 2000Assignees: Novo Nordisk A/S, Novo Nordisk Biochem North America, Inc.Inventors: Martin Barfoed, Ole Kirk
-
Patent number: 6010542Abstract: A method of dyeing a substrate in carbon dioxide comprises the steps of (a) providing a dye composition comprising carbon dioxide, a dye, and a surfactant, the surfactant included in an amount sufficient to solubilize, emulsify or disperse the dye in the carbon dioxide; and then (b) dyeing said substrate with said dye composition.Type: GrantFiled: August 28, 1998Date of Patent: January 4, 2000Assignee: Micell Technologies, Inc.Inventors: James P. DeYoung, James B. McClain, Joseph M. DeSimone, Timothy J. Romack
-
Patent number: 5989297Abstract: Dye mixtures comprising at least one compound of the formula ##STR1## and at least one compound of the formula ##STR2## in which the variables are as defined in the claims,which are suitable as fibre-reactive dyes for dyeing widely varying fibre materials, are described.Type: GrantFiled: July 15, 1996Date of Patent: November 23, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Hans Reichert, Bernhard Muller, Athanassios Tzikas
-
Patent number: 5958086Abstract: Dye mixtures, which comprise at least one dye of formula ##STR1## and at least one dye of formulae (2) and (3) ##STR2## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 R.sub.5, R.sub.6 R.sub.7, X.sub.1, X.sub.2, A.sub.1, A.sub.2, A.sub.3 and A.sub.4 are as defined in claim 1.The dye mixtures according to this invention are particularly suitable for dyeing or printing natural or synthetic polyamide fiber material.Type: GrantFiled: August 26, 1997Date of Patent: September 28, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Jean-Marie Adam, Rudolf Hurter
-
Patent number: 5948125Abstract: A method of fixing dyes on natural or synthetic polyamide fiber material, wherein the fiber material is treated, before, during or after dyeing, with a liquor comprising a homo- or co-polymer having structural repeating units of at least one of formulae (1), (2) and (3) ##STR1## wherein the variables are as defined in the claims. The resulting dyeings and prints are distinguished by improved fastness to wetting, without the shade and the fastness to light being affected, and by improved fastness to ozone.Type: GrantFiled: May 11, 1998Date of Patent: September 7, 1999Assignee: Ciba Specialty Chemicals CorporationInventor: Philippe Ouziel
-
Patent number: 5948122Abstract: The present invention relates to methods for dyeing a material, comprising (a) treating the material with a dyeing system which comprises one or more reduced vat dyes and/or one or more reduced sulfur dyes; and (b) oxidizing the one or more reduced vat dyes or one or more reduced sulfur dyes adsorbed onto the treated material with an oxidation system comprising (i) an oxygen source and one or more enzymes exhibiting oxidase activity or (ii) a hydrogen peroxide source and one or more enzymes exhibiting peroxidase activity, to convert the one or more reduced dyes to their original oxidized insoluble colored forms; wherein the material is a fabric, yarn, fiber, garment or film made of cotton, diacetate, flax, fur, hide, leather, linen, lyocel, polyacrylic, polyamide, polyester, ramie, rayon, silk, tencel, triacetate, viscose or wool.Type: GrantFiled: November 24, 1998Date of Patent: September 7, 1999Assignees: Novo Nordisk Biotech, Inc., Novo Nordisk BioChem North America Inc., Novo Nordisk A/SInventors: Feng Xu, Sonja Irene Salmon
-
Patent number: 5944855Abstract: Process for dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fiber material, which comprises using at least one blue-dyeing fiber-reactive anthraquinone dye of the formula in which R.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.12 alkyl, X.sub.1 is halogen, B.sub.1 is an organic bridge member and V.sub.1 is an aliphatic or aromatic amine containing a fibre-reactive group, together with at least one fiber-reactive sulfo group containing yellow- or orange-dyeing dye or together with at least one fiber-reactive sulfo group containing red-dyeing dye. Level dyeings with good fastness properties are obtained.Type: GrantFiled: May 8, 1998Date of Patent: August 31, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Urs Lehmann, Marcel Frick, Klaus Hannemann
-
Patent number: 5931975Abstract: Dyes of the formula ##STR1## in which A.sub.1 and A.sub.2 independently of one another are the radical of a monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, naphthoquinone, pyrenequinone or perylenetetracarbimide dye,R.sub.1, R.sub.2, R.sub.3 and R.sub.4 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,Y.sub.1 and Y.sub.2 independently of one another are halogen, carboxypyridinium, substituted or unsubstituted amino or a heterocyclic radical bonded via a nitrogen atom andn is a number from 1 to 7,are particularly suitable for dyeing or printing fiber materials containing hydroxyl groups or nitrogen. Dyeings with good fastness properties are obtained with a high dyeing yield.Type: GrantFiled: October 16, 1997Date of Patent: August 3, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Bernhard Muller, Patric Nowack
-
Patent number: 5931974Abstract: A dye mixture comprising one or more disazo dyes composed of 1-amino-3,6-disulfo-8-naphthol as the coupling component and of two diazo components of the aniline series containing each a fiber-reactive group of the vinylsulfone series, one or more monoazo dyes composed of a carboxy-substituted benzoylamino-sulfo-naphthol coupling component and a diazo component of the aniline series, containing a fiber-reactive group of the vinylsulfone series and optionally one or two monoazo dyes with 1-amino-3,6-disulfo-8-naphthol as a coupling component to which is coupled in the ortho-position to the amino group a diazo component of the aniline series substituted by a fiber-reactive group of the vinylsulfone series. The dye mixtures yield on hydroxy- and/or carboxamido-containing fiber materials, such as cellulose fibers, in particular cotton, or on, for example, wool and synthetic polyamide fibers, deep black dyeings.Type: GrantFiled: July 28, 1998Date of Patent: August 3, 1999Assignee: Dystar Textilfarben GmbH & Co.Inventor: Ronald P. Pedemonte
-
Patent number: 5928386Abstract: A process for dyeing or printing natural or synthetic polyamide fiber material by the trichromatic technique, which comprises using at least one blue-dyeing dye of formula ##STR1## together with at least one red-dyeing dye of formula ##STR2## together with at least one yellow- or orange-dyeing dye of formula ##STR3##Type: GrantFiled: May 21, 1997Date of Patent: July 27, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Rudolf Hurter, Jean-Marie Adam, Francine Casi
-
Patent number: 5922865Abstract: Process for dyeing natural or synthetic polyamide fibre materials, which comprises dyeing these fibre materials with at least one anionic acid dye of the formula ##STR1## and treating the fibre material mentioned, during or after the dyeing process, with a colourless fixing agent which contains sulfo or sulfato groups and contains at least two fibre-reactive groups, whereR.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl,X.sub.1 is substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl,or the radical of the formula --N(R.sub.2)--X.sub.1 is a ring, which may contain further heteroatoms,Y.sub.1 is a radical of the formula ##STR2## in which B.sub.1 is a colourless organic bridge member,R.sub.3 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.4 alkyl andR.sub.4 is hydrogen or substituted or unsubstituted C.sub.1 -C.sub.8 alkyl, C.sub.5 -C.sub.7 cycloalkyl, phenyl or naphthyl, andA.sub.Type: GrantFiled: June 2, 1998Date of Patent: July 13, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Jean-Marie Adam, Jean-Pierre Bacher, Francine Casi
-
Patent number: 5922085Abstract: A process of preparing a dye composition and a resultant dye composition. The process includes preparing a mixture comprising a triphenylmethane dye and oxidation products by reacting methylenedianiline, aniline, an oxidation catalyst, and an oxidant; separating the oxidation products from the triphenylmethane dye to produce an aqueous solution of oxidation products; treating the solution of oxidation products with a basic compound; separating unreacted aniline from the solution of oxidation products and forming a mixture of oxidation products; and sulfonating the mixture of oxidation products to form a dye composition.Type: GrantFiled: September 30, 1997Date of Patent: July 13, 1999Assignee: BASF CorporationInventors: Gray D. Ellis, Belinda J. DiMarcello, Debra J. Bradshaw
-
Patent number: 5914445Abstract: The present invention relates to novel dyeing assistant preparations comprising, as component (a), at least one amine oxide of the formula ##STR1## in which R is an aliphatic radical having 8 to 24 carbon atoms andR.sub.1 is an aliphatic radical which is unsubstituted or substituted by hydroxyl and has 1 to 24 carbon atoms, preferably 1 to 6 carbon atoms,as component (b), at least one compound of the formulaR.sub.2 --U--(R.sub.3 --O).sub.m --W (2),in whichR.sub.2 is an aliphatic radical having 8 to 24 carbon atoms,R.sub.3 is alkylene having 2 to 4 carbon atoms,U is --O-- or ##STR2## in which Z is a direct bond, (R.sub.3 --O)).sub.r or C.sub.1 -C.sub.6 alkylene andW.sub.1 is hydrogen or C.sub.1 -C.sub.6 alkyl which is unsubstituted or substituted by hydroxyl, carboxyl, isocyanato, phenyl, benzyloxymethylene or phenethyloxymethylene, m and r independently of one another are a number from 2 to 25,(R.sub.3 --O).sub.m is m identical or different radicals (R.sub.3 --O) and(R.sub.3 --O).sub.Type: GrantFiled: September 23, 1997Date of Patent: June 22, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Jorg Binz, Bruno Saladin, Martin Jollenbeck
-
Patent number: 5908474Abstract: The present invention provides a dye-fixing agent, obtainable by reacting in a first reaction step, either a homopolymer of diallylamine or N-methyl-diallylamine or a copolymer of diallylamine and N-methyl-diallylamine, with an epihalohydrin, the reaction optionally taking place in the presence of an aliphatic amine or polyamine, or reacting the homopolymer or copolymer with a product obtainable by a reaction of epihalohydrin with an aliphatic amine or polyamine, optionally followed by partial quaternization of the reaction product of the first reaction step, characterized in that the end product possesses at least 10 mol % of tertiary amino groups of the following formula (I), based on the total number of amino groups ##STR1## wherein X=halogen, with the provisos that when the homopolymer is an N-methyl-diallylamine, the presence of an aliphatic amine or a polyamine is obligatory in the reaction with the epihalohydrin and when the homopolymer is a homopolymer of diallylamine, partial quaternisation of the reType: GrantFiled: September 15, 1997Date of Patent: June 1, 1999Assignee: Clariant Finance (BVI) LimitedInventors: Bernard Danner, Jurg Heller
-
Patent number: 5869731Abstract: There has been found1) a method for reducing the toxicity of spent liquors from dyeing with cationic dyes or mixtures thereof, characterized by the step of dyeing with cationic dyes having a computed electrostatic shielding energy (idealized hydration energy) of .gtoreq.50 kcal/mol,2) cationic, generally low toxicity dyes, their preparation and use for dyeing.Type: GrantFiled: September 25, 1997Date of Patent: February 9, 1999Assignee: Bayer AktiengesellschaftInventors: Henry Giera, Felix Reichel, Horst Berneth
-
Patent number: 5849040Abstract: A process is provided for manufacturing a high quality cloth having a width of 150 cm or any width in which likelihood of occurrence of defects such as color shading, rub marks, wrinkles and creases due to fabric dyeing method is eliminated and color fastness is enhanced.A process for manufacturing a woven or knit fabric using yarn dyed silk comprises the steps of dyeing (step 3) sericin which covers the periphery of silk fibers and fibroin which is located inside thereof into the same color; making yarn dyed silk (step 4, 5) by doubling and twisting the dyed silk fibers; making a cloth (step 6) by weaving or knitting the yarn dyed silk swelling (step 7) the yarn, tyed silk which constitutes the cloth by dipping the cloth into hot water in a tub; and decomposing (step 8) sericin of the yarn dyed silk of the cloth with an enzyme in hot water in a tub.Type: GrantFiled: May 22, 1997Date of Patent: December 15, 1998Assignee: Kanehisa Inc.Inventor: Keiichiro Kanehisa
-
Patent number: 5810891Abstract: A process is described for dyeing wool-containing fibre materials with anionic dyes, which comprises dyeing said materials in the presence of a wool protective agent containing at least one acrylamide homo- or copolymer. Rubfast level dyeings having reduced setting can be obtained according to this process.Type: GrantFiled: January 7, 1997Date of Patent: September 22, 1998Assignee: Ciba Specialty Chemicals CorporationInventors: Edvard Ham, Philippe Ouziel