Polyamide Fiber Patents (Class 8/924)
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Patent number: 4923481Abstract: Aqueous dispersion of a sulfonated metallizable dye containing(a) based on the total weight at least 10% of the sulfonated metallizable dye and(b) a sulfonated condensation product obtained by reacting an aromatic compound having at least two replaceable ring-positioned hydrogen atoms in any desired order with a compound of the formula ##STR1## in which X is a direct bond or oxygen, Hal is chlorine or bromine and n is 1 to 4, and sulfonation.Type: GrantFiled: December 16, 1988Date of Patent: May 8, 1990Assignee: Ciba-Geigy CorporationInventors: Roberto Galli, Ernst Tempel
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Patent number: 4921505Abstract: In the process for the preparation of the dyestuff of the formula I ##STR1## by diazotization and coupling, the aqueous suspension present when the coupling has ended is heated to temperatures of 50.degree. C. up to the boiling point of the aqueous phase in the presence of a dispersing agent.Type: GrantFiled: December 12, 1988Date of Patent: May 1, 1990Assignee: Cassella AktiengesellschaftInventors: Gunther Effenberger, Hubert Kruse
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Patent number: 4917705Abstract: The invention relates to a process for dyeing or printing natural or synthetic polyamide fiber materials which comprises dyeing or printing these fiber materials with reactive dyes of the formula ##STR1## where each M is a cation, R.sub.1 and R.sub.2 are independently of each other hydrogen or C.sub.1 -alkyl, and X.sub.1 and X.sub.2 are independently of each other .alpha.,.beta.-dibromopropionyl, .alpha.-bromoacryloyl, chloroacetyl or a mono-, di- or trihalopyrimidinyl radical.Type: GrantFiled: September 21, 1988Date of Patent: April 17, 1990Assignee: Ciba-Geigy Corp.Inventors: Dieter Mausezahl, Peter Loew
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Patent number: 4902299Abstract: A surprising improvement in dye-lightfastness of dyed nylon automotive fabrics is achieved by a combination of a copper salt and of an oxanilide light stabilizer. The oxanilide is effective with a surprisingly broad range of copper derivatives. Both the copper and the oxanilide may conveniently be applied from the dyebath, or, surprisingly, the copper provides improvements even if melt-spun into the fiber.Type: GrantFiled: February 28, 1989Date of Patent: February 20, 1990Assignee: E. I. Du Pont de Nemours and CompanyInventor: Anthony Anton
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Patent number: 4891047Abstract: A process for dyeing fibers. Fibers are dyed in a dye liquor containing granules of silica gel.Type: GrantFiled: November 19, 1986Date of Patent: January 2, 1990Assignee: Director-General of the Sericultural Experiment station, Ministry of Agriculture, Forestry and Fisheries of JapanInventors: Hrioshi Kato, Keiichi Komatsu
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Patent number: 4888028Abstract: A water-soluble dye mixture comprising a blue anthraquinone reactive dye represented in its free acid form by the formula: ##STR1## wherein X is --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 W wherein W is a group removable by action of alkali and from 0.2 to 5 times by weight to said anthraquinone reactive dye of a blue formazan reactive dye represented in its free acid form by the formula: ##STR2## wherein R is a hydrogen atom or a C.sub.1 -C.sub.4 alkyl group, Y is a halogen atom, --NHC.sub.2 H.sub.4 SO.sub.3 H or ##STR3## and X is --CH.dbd.CH.sub.2 or --C.sub.2 H.sub.4 W wherein W is a group removable by action of alkali.Type: GrantFiled: June 15, 1988Date of Patent: December 19, 1989Assignee: Mitsubishi Kasei CorporationInventors: Toshio Hihara, Riyouichi Sekioka
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Patent number: 4881941Abstract: A textile substrate is dyed by immersing it in a gathered configuration into an oil medium containing a dissolved or dispersed dye for a sufficient time to allow the oil medium to come into contact with part but not all of the surface of the substrate and the thus-treated substrate is then preferably immersed in an aqueous medium having another dye dissolved or dispersed therein.Type: GrantFiled: July 12, 1988Date of Patent: November 21, 1989Assignee: Sandoz Ltd.Inventor: Michael W. Dixon
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Patent number: 4880431Abstract: A monoazo compound of the following formula, ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are independently hydrogen or alkyl, R.sub.4 is alkyl or carboxy, A is ##STR2## in which R.sub.5 is hydrogen, methyl, methoxy, ethoxy, sulfo or carboxy, X is hydrogen or sulfo, n is 0 or 1, and the asterisked linkage bonds to the azo group, B.sub.1 and B.sub.2 are independently phenylene or naphthylene, W is hydrogen, carbamoyl, sulfoalkyl, cyano, sulfo, chloro or bromo, and Y.sub.1 and Y.sub.2 are independently --CH.dbd.CH.sub.2, --CH.sub.2 CH.sub.2 OSO.sub.3 H or the like, which is useful for dyeing hydroxy group- or carbonamide group-containing materials in a deep yellow color excellent in various fastness properties such as light fastness, perspiration-light fastness and chlorine fastness.Type: GrantFiled: December 8, 1987Date of Patent: November 14, 1989Assignee: Sumitomo Chemical Company, LimitedInventors: Kazufumi Yokogawa, Naoki Harada, Takashi Omura
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Patent number: 4878920Abstract: Described is a process for continuously dyeing high tenacity nylon 6,6 fabrics including the sequential steps of applying to a high tenacity, highly crystalline nylon 6,6 fabric whose fibers have a breaking tenacity in the range of 6.0 to 10 g/denier and an aqueous dyebath containing a tinctorial amount of at least one dye. The dyed fabric is then steamed with superheated steam at atmospheric pressure and at temperatures greater than 100.degree. C., e.g., 100.degree. to 160.degree. C., for a time sufficient to fix the dye to the fabric, usually up to 3 minutes. Following steaming, the dyed fabric is washed to remove any unfixed dye, then dried.Type: GrantFiled: April 28, 1987Date of Patent: November 7, 1989Assignee: Burlington Industries, Inc.Inventors: Ernest J. Russell, Tanya E. FitzGerald
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Patent number: 4877411Abstract: A method is provided for temporary coloration of textile materials which comprises applying to said textile materials an amine-reducible tint in an amount sufficient to provide coloration to said textile material, said tint being characterized by the formula:R{A[alkeneoxy constituent).sub.n X].sub.m }.sub.pwhere RA is the organic, easily reducible dyestuff radical, A is a linking moiety in said organic, easily reducible dyestuff radical selected from the group consisting of --N--, --O--, --S--, or --CO.sub.2 --, the alkenyl moiety of said alkyleneoxy constituent contains from 2 to about 4 carbon atoms, n is an integer of from 2 to about 300, m is 1 when A is --O--, --S--, --CO.sub.2 -- and 2 when A is --N--, p is an integer of from 1 to 5, and X is a member of the group consisting of --H--, alkyl, -alkylcarboxylate, or -arylcarboxylate; and contacting said amine-reducible tint with an amine compound in an amount sufficient to reduce said tint whereby said coloration of said textile material is removed.Type: GrantFiled: August 29, 1988Date of Patent: October 31, 1989Assignee: Milliken Research CorporationInventors: John B. Hines, Jeffery R. Harris
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Patent number: 4874391Abstract: A process for the photochemical stabilization of polyamide fiber material or mixtures thereof with other fiber materials which comprises treating the fiber material with a mixture of (A) a water-soluble copper complex dye or a mixture of copper complex compounds, at least one component being a water-soluble copper complex dye, (B) a light stabilizer and if desired (C) an antioxidant, an agent for carrying out the process and the fiber material treated therewith are described.Type: GrantFiled: July 20, 1987Date of Patent: October 17, 1989Assignee: Ciba-Geigy CorporationInventor: Gerhard Reinert
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Patent number: 4874392Abstract: A Monoazo compounds of the formula ##STR1## wherein D is a diazo component radical of the 4-nitrophenyl series, thienyl-2 series, thiazolyl-2 series or 5-nitrobenzoisothiazolyl-3 series,R.sub.1 is hydrogen; C.sub.1-2 alkyl; C.sub.1-2 alkoxy; formylamino; (C.sub.1-4 alkyl)carbonylamino; (C.sub.1-4 alkyl)carbonylamino the alkyl group of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-3 alkoxy, cyano, phenyl, phenoxy and benzyloxy; (C.sub.2-4 alkenyl)carbonylamino; halo(C.sub.2-4 alkenyl)carbonylamino; benzoylamino; benzoylamino the phenyl group of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-4 alkyl and C.sub.1-4 alkoxy; (C.sub.1-4 alkoxy)carbonylamino; (C.sub.1-4 alkoxy)carbonylamino the alkyl moiety of which is substituted by 1 to 3 substituents independently selected from halo, C.sub.1-3 alkoxy, cyano, phenyl, phenoxy and benzyloxy; (C.sub.8-14 alkyl)carbonylamino or (C.sub.8-14 alkoxy)carbonylamino,R.sub.2 is C.sub.Type: GrantFiled: July 29, 1987Date of Patent: October 17, 1989Assignee: Sandoz Ltd.Inventor: Beat Henzi
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Patent number: 4872883Abstract: The mixture of monoazo dyestuffs which contains one or more dyestuffs of the formula I ##STR1## and one or more dyestuffs of the formula II ##STR2## wherein R.sup.1 and R.sup.2 independently of one another denote linear or branched alkyl with 1 to 6 carbon atoms and R denotes linear or branched alkyl with 1 to 3 carbon atoms, is outstandingly suitable for dyeing and printing hydrophobic materials a deep blue color.Type: GrantFiled: January 27, 1988Date of Patent: October 10, 1989Assignee: Bayer AktiengesellschaftInventors: Ulrich Buhler, Klaus Hofmann, Manfred Hahnke
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Patent number: 4861343Abstract: Flock is prepared by introducing a flockmaking tow into a sleeve, subjecting it in this form to at least one treatment bath, then removing it from the sleeve and subsequently cutting it into flock.Type: GrantFiled: May 26, 1987Date of Patent: August 29, 1989Assignee: Bayer AktiengesellschaftInventor: Franz-Theo Neunzig
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Patent number: 4861342Abstract: Dyeing or finishing process characterized in that textile materials are impregnated in a padding machine with aqueous dyeing or finishing baths which contain, besides graft polymers, which may be obtained from a product of addition of an alkylene oxide to an at least trivalent aliphatic alcohol containing from 3 to 10 carbon atoms and methacrylamide or acrylamide, and in that the fixing of the dyes or of the finish is then performed continuously by a treatment with microwaves for 5 to 30 seconds.The process permits an excess water input on all the textile materials and a rapid fixing by the microwaves.Type: GrantFiled: June 3, 1988Date of Patent: August 29, 1989Assignee: Ciba-Geigy CorporationInventor: Paul Danel
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Patent number: 4859207Abstract: A process for dyeing textile planar fabrics made from natural or synthetic polyamides with anionic dyes by(a) locally applying a resist agent by itself or in conjunction with an anionic dye of fluorescent whitening agent,(b) subjecting the textiles to a heat treatment, and(c) carrying out ground dyeing with a dye liquor that contains a further anionic dye,which process comprises using, as resist agent, a melamine compound of formula ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently phenyl or naphthyl, each of which may be substituted by halogen, hydroxy, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, Z is an acid water-solubilizing group, and m is 1 to 6.Type: GrantFiled: July 19, 1988Date of Patent: August 22, 1989Assignee: Ciba-Geigy CorporationInventors: Thys Bouwknegt, Heinz Abel
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Patent number: 4852991Abstract: The invention relates to a process for dyeing synthetic or natural polyamide fibers with anionic dyestuffs, comprising (i) bringing the polyamide fibers into contact with an aqueous dyeing liquor which contains in addition to one or more dyestuffs a cationic dyeing assistant having affinity for anionic polyamide dyestuffs, and dyeing the polyamide fibers at a temperature of from 60.degree. to 105.degree. C., and (ii) adding an anionic dyeing assistant to the dyeing liquor 15 to 60 minutes after reaching the dyeing temperature, to complete the dye exhaustion. Surface and fibre level dyeings with a good dye penetration are thus obtained.Type: GrantFiled: March 3, 1988Date of Patent: August 1, 1989Assignee: Sandoz Ltd.Inventors: Josef Frauenknecht, Dieter Schwer
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Patent number: 4851012Abstract: A mixture of monoazo dyestuffs which contains one or more dyestuffs of the formula I ##STR1## and one or more dyestuffs of the formula II ##STR2## wherein R.sup.1 and R.sup.2 independently of one another each denote linear or branched alkyl with 1 to 6 carbon atoms, R denotes linear or branched alkyl with 1 to 5 carbon atoms and Hal denotes chloro or bromo, are outstandingly suitable for dyeing and printing hydrophobic materials.Type: GrantFiled: February 1, 1988Date of Patent: July 25, 1989Assignee: Cassella AktiengesellschaftInventors: Ulrich Buhler, Hubert Kruse, Reinhard Kuhn, Margareta Boos
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Patent number: 4840642Abstract: Compounds of the formula ##STR1## and salts thereof, useful for dyeing and printing hydroxy group - or nitrogen-containing organic substrates, for example, leather and fibrous materials containing or consisting of natural or synthetic polyamides or natural or regenerated cellulose; preferably textile material containing or consisting of cotton which is preferably dyed using the exhaust dyeing method.Type: GrantFiled: September 4, 1987Date of Patent: June 20, 1989Assignee: Sandoz Ltd.Inventors: Gunther Auerbach, Helmut A. Moser
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Patent number: 4840643Abstract: A trichromatic dye combination especially suited for the continuous dyeing of synthetic polyamide materials; the system including an acid red dye component, an acid blue dye component and an acid yellow dye component, each of said dye components being selected on the basis of minimum and compatible cold strike and compatible on tone strike rates.The trichromatic combination according to the invention dyes synthetic polyamide fibers from aqueous liquors, producing level dyeings having excellent fastness properties including good lightfastness and good ozone fastness.Type: GrantFiled: March 16, 1988Date of Patent: June 20, 1989Assignee: Crompton & Knowles CorporationInventor: Jay E. Rowe
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Patent number: 4836827Abstract: The compounds of the formula (1) given in claim 1 are suitable for use as dyes for dyeing a wide range of textile and non-textile materials and in particular for dyeing leather and pelts.Type: GrantFiled: January 29, 1988Date of Patent: June 6, 1989Assignee: Ciba-Geigy CorporationInventor: Alois Puntener
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Patent number: 4836828Abstract: Fabrics constructed of high-modulus, high-tenacity, low-shrinkage polyamide fabrics are continuously dyed with acid dyes by applying at ambient temperatures a pad bath solution formulated to provide a continuous film on the fabric surface followed by drying and dry heat curing or thermosoling at elevated temperatures to fix the dye molecules inside the fibers.Type: GrantFiled: November 24, 1987Date of Patent: June 6, 1989Assignee: Burlington Industries, Inc.Inventor: Samir Hussamy
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Patent number: 4832699Abstract: Filament nylon 6 and 66 fabrics are dyed in a multi-step continuous aqueous dyeing process. Uniformly dyed fabrics having a high degree of fiber bundle penetration result.Type: GrantFiled: December 17, 1987Date of Patent: May 23, 1989Assignee: Burlington Industries, Inc.Inventors: M. K. Choi, Ernest J. Russell
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Patent number: 4828571Abstract: The present invention provides a non-aqueous process for the dyeing of a dyeable material at an elevated temperature by contacting a dyeable material with a dye composition at an elevated temperature in a non-reactive environment. The dye composition temperature and the time of contact between the dye composition and the dyeable material are sufficient to effectuate the dyeing of the material. The dye composition comprises a substantially non-aqueous solvent and a dyestuff.Type: GrantFiled: May 9, 1986Date of Patent: May 9, 1989Inventors: Ildo E. Pensa, C. Duff Hughes, Nicholas S. Hood, Eugene M. Saunders
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Patent number: 4828572Abstract: The invention relates to a process for dyeing or printing textile fibre materials in stable shades with reactive dyes which produce grey or black dyeings or prints, which process comprises dyeing or printing textile fibre materials with a mixture of heavy metal-containing, water-soluble reactive dyes which produce grey or black dyeings or prints, each component of which mixture, under identical dyeing, printing and fixation conditions, produces dyeings or prints with a tinge different from the tinge of the dyeings or prints produced by the other component, and carrying out subsequent fixation.Type: GrantFiled: October 13, 1987Date of Patent: May 9, 1989Assignee: Ciba-Geigy CorporationInventors: Wolfgang Sutterlin, Rainer Begrich
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Patent number: 4820311Abstract: A solid formulation comprising at least one water-soluble anionic dye, additional optional assistants and a combination of an ethoxylated stearyl diphenyloxyethyl diethylenetriamine and at least one anionic dispersant. Such formulations are distinguished in particular by very good hot water solubility.Type: GrantFiled: May 25, 1988Date of Patent: April 11, 1989Assignee: Ciba-Geigy CorporationInventor: Ernst Tempel
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Patent number: 4816034Abstract: A water soluble direct black polyazo dyestuffs mixture comprising trisazo dyestuffs, polyazo dyestuffs and disazo dyestuff.Type: GrantFiled: August 12, 1986Date of Patent: March 28, 1989Assignee: The Atul Products LimitedInventors: Girish I. Bhatt, Subrao S. Kulkarni, Chandrashekhar B. Upasani, Mukundbhai Bhatt
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Patent number: 4813972Abstract: The invention relates to chromium complexes of the formula ##STR1## in which A is the radical of a dicyclically metallizable azo or azomethine dye, B is the radical of a potentially at least bidentate bianionic complexible organic compound which contains no azo or azomethine group, L is a colorless monofunctional ligand, X is a fibre-reactive radical, Ka is a cation, K is 0 or 1, m is 1, 2 or 3, n is 1 or 2, and the X radical and the SO.sub.3.sup..crclbar. Ka group are each bonded to the radicals A and B, to a process for preparing the chromium complexes of the formula (1), and to a combined preparation and dyeing process.Type: GrantFiled: October 7, 1987Date of Patent: March 21, 1989Assignee: Ciba-Geigy CorporationInventors: Hans U. Schutz, Ulrich Schlesinger, Gerhard Back
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Patent number: 4813971Abstract: Textile materials made of natural or synthetic polyamides or mixtures thereof are dyed in the presence of a cyclic ester of sulfurous acid with an aliphatic 1,2-diol in place of a customary pH regulant.Type: GrantFiled: February 4, 1988Date of Patent: March 21, 1989Assignee: BASF AktiengesellschaftInventors: Sigismund Heimann, Michele Vescia, Attila Bereck, Hermann Sulz, Ingrid Steenken
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Patent number: 4812140Abstract: High-tenacity nylon fabrics are dyed in a multi-step continuous aqueous dyeing process. Uniformly dyed fabrics having a high degree of fiber bundle penetration result.Type: GrantFiled: July 15, 1987Date of Patent: March 14, 1989Assignee: Burlington Industries, Inc.Inventors: Ernest J. Russell, M. K. Choi
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Patent number: 4804386Abstract: A chromium complex dye of the formula ##STR1## and salts thereof are used for dyeing polyamides or leather.Type: GrantFiled: February 2, 1988Date of Patent: February 14, 1989Assignee: BASF AktiengesellschaftInventor: Klaus Grychtol
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Patent number: 4800118Abstract: A light stabile composition for imparting stain resistance to polyamide fiber-containing textile articles (e.g. nylon, wool or silk carpets) comprises a halogenated (e.g. brominated or chlorinated) aryl group-containing product of the condensation polymerization of a hydroxyaryl sulfonic acid (e.g., para-hydroxyphenyl sulfonic acid), a dihydroxydiaryl sulfone (e.g., dihydroxydiphenyl sulfone) and an aldehyde (e.g., formaldehyde). The polyamide fiber-containing textile articles are converted to a stain resistant product by containing the fibers with an acidified aqueous solution of the aforesaid composition.Type: GrantFiled: November 4, 1987Date of Patent: January 24, 1989Assignee: West Point PepperellInventors: John W. Reed, Richard D. Smith
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Patent number: 4799935Abstract: Textiles, especially polyester, nylon and high-tenacity nylon, are continuously dyed in an organic medium containing a high-boiling, nonionic solvent admixed with one or more lower-boiling organic solvents and at least one dyestuff dissolved in the solvent media. The lower-boiling solvent acts as a carrier to entrain the dye and allows the dye to enter the fiber evenly. The non-aqueous dyestuff medium allows the process to be conducted above the boiling point of water which facilitates dye penetration into the fiber and, in turn, shortens the dyeing process. Atmospheric pressure may be used, thus avoiding the constraints of a batch-type operation of pressurized dyeing procedures, as is conventionally used in this art. Fabric may be dyed in open width under restraint at elevated temperatures thereby achieving uniform coloring of the fabric without shade variations from end-to-end or "tailing".Type: GrantFiled: April 21, 1987Date of Patent: January 24, 1989Assignee: Burlington Industries, Inc.Inventors: James K. Davis, Robert S. Craycroft, Tina V. Lorenzo
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Patent number: 4790043Abstract: A chemical, such as a dye, is applied to a textile substrate, such as carpet, by continuously moving the substrate past an application position. At the application position a liquid formulation containing the chemical, heated to a temperature below the boiling point thereof, is sprayed toward the substrate, thereby driving the chemical into the substrate. The temperature of the spray is controlled such that the dye contacts the substrate at a temperature sufficient to achieve substantially instantaneous fixation.Type: GrantFiled: January 21, 1987Date of Patent: December 13, 1988Assignee: Ciba-Geigy CorporationInventor: Joseph S. Chappell
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Patent number: 4787912Abstract: An assistant for dyeing or whitening synthetic nitrogen-containing fibre material, which comprises(A) a sulfonated polycarboxylate,(B) an anionic surfactant,(C) a nonionic surfactant, and(D) a water-soluble organic, polar solvent.The assistant is especially useful for dyeing or whitening polyamide fibres.Type: GrantFiled: January 28, 1987Date of Patent: November 29, 1988Assignee: Ciba-Geigy CorporationInventors: Heinz Abel, Helmut Raisin
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Patent number: 4780104Abstract: An aqueous liquid dye composition comprising 5 to 50% by weight of a reactive dye represented by the following formula, ##STR1## wherein D denotes a sulfo group-containing organic dye residue, R.sub.1 and R.sub.2 independently of one another denote a hydrogen atom or a C.sub.1 to C.sub.4 alkyl group unsubstituted or substituted with a halogen atom or a hydroxyl, cyano, C.sub.1 to C.sub.4 alkoxy, carboxy, carbamoyl, C.sub.1 to C.sub.4 alkoxycarbonyl, C.sub.1 to C.sub.4 alkylcarbonyloxy, sulfo or sulfamoyl group, A denotes a phenylene group unsubstituted or substituted with one or two members selected from methyl, ethyl, methoxy, ethoxy, chlorine, bromine and sulfo, or a naphthylene group unsubstituted or substituted with one sulfo group, X denotes a halogen atom, and Y is a group of --SO.sub.2 CH.dbd.CH.sub.2 or --SO.sub.2 CH.sub.2 CH.sub.2 Z in which Z is a splittable group by the action of an alkali, 0.1 to 10% by weight of .epsilon.Type: GrantFiled: February 20, 1987Date of Patent: October 25, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Noriaki Yamauchi, Kunihiko Imada, Shinei Ikeou
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Patent number: 4775748Abstract: Novel reactive colorants being the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are selected from halogen, carboxylic acid, alkanoyl, aryloyl, carbocyclic forming polymethylene chains, alkyl, aryl, cyano, thioalkyl, dithioalkyl, thioaryl, dithioaryl, thiocyano, carboxyalkyl, carboxyaryl, amidoalkyl, amidodialkyl, amidoaryl, amidodiaryl, oxyalkyl, thioamidoalkyl, thioamidodialkyl, or hydrogen when an adjacent group is isobutyryl; R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are selected from hydrogen, alkyl, oxyalkyl, oxyaryl, sulfonamidoalkyl, sulfonamidoaryl, amidoalkyl, amidodialkyl, amidoaryl, amidodiaryl, halogen, thioalkyl and thioaryl; and R.sub.8 and R.sub.9 are selected from polyalkylene oxide, copolymers of polyalkylene oxides, and hydroxyalkylenes.Type: GrantFiled: June 1, 1987Date of Patent: October 4, 1988Assignee: Milliken Research CorporationInventors: Edward W. Kluger, Patrick D. Moore
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Patent number: 4775386Abstract: A process for the photochemical stabilization of undyed and dyed polyamide fibre material or blends thereof with other fibre materials, which comprises treating the fibre material with a mixture of (A) an organic copper complex, (B) a light stabilizer and, if desired, (C) an antioxidant, an agent for carrying out the process and the fibre material treated with the agent are described.Type: GrantFiled: April 27, 1987Date of Patent: October 4, 1988Assignee: Ciba-Geigy CorporationInventors: Gerhard Reinert, Kurt Burdeska
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Patent number: 4773914Abstract: Dyestuffs which are highly suitable for use as the blue component in the trichromatic dyeing of polyamide fibre materials have the formula ##STR1## in which R.sub.1 and R.sub.2 denote alkyl, the total number of the C atoms in the radicals R.sub.1 and R.sub.2 being at least three.The dyeings obtained are distinguished, inter alia, by good ozone fastness and the absence of the catalytic fading effect.Type: GrantFiled: December 30, 1986Date of Patent: September 27, 1988Assignee: Bayer AktiengesellschaftInventors: Wolfgang Harms, Hans-Gunter Otten
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Patent number: 4762524Abstract: This invention is directed to a dyestuff composition comprising the reaction product of a water-soluble, vinyl-sulfone type, reactive dye and a N-alkyl-amino-alkyl sulfonic acid and/or carboxylic acid or the salts thereof wherein the N-alkyl-amino-alkyl acid or salt is reacted with said dye in an amount of about 0.5 to 1.0 mole per mole of dye. This dyestuff composition is used to dye synthetic polyamides according to a process where said composition is applied to a polyamide fiber from an aqueous solution having a pH from about 3 to about 4; preferably 3.5 and then fixed to said fiber by heat.Type: GrantFiled: February 5, 1987Date of Patent: August 9, 1988Assignee: Hoechst Celanese CorporationInventors: Thomas V. Chambers, Manfred Deicke, Suzanne C. Fleming
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Patent number: 4737156Abstract: Cationic cellulose graft copolymers obtained by the graft polymerization of a cellulose substrate and a cationic monomer are useful as textile treatment agents, especially as dye enchancers. As pretreatment agents, they improve dye yield, dye levelness and dye fastness properties and as after-treatment agents, they improve dye fastness and crock resistance properties.Type: GrantFiled: October 27, 1986Date of Patent: April 12, 1988Assignee: National Starch and Chemical CorporationInventors: Martin Tambor, Jerry L. Cope, John L. Jerome
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Patent number: 4737155Abstract: This invention relates to the use of compounds such as 3,5-dibutyl-1,3,5-oxadiazine-4-thione and tetrahydro-5-(2-butyl)-(S)-triazinethione as stabilizers to improve the dye fastness of colored fibers.Type: GrantFiled: June 5, 1987Date of Patent: April 12, 1988Assignee: The Goodyear Tire & Rubber CompanyInventors: Kevin L. Rollick, Joseph A. Kuczkowski
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Patent number: 4722735Abstract: A process is described for the continuous dyeing of textiles in which an aqueous solution of an ionic, water-soluble dye is applied to a fabric in open width. The textile is dried to reduce the water content to at most about 1% and it is then contacted with a nonionic, high-boiling organic liquid in which the ionic dye is substantially completely insoluble while the liquid is maintained at an elevated temperature, i.e., about 325.degree. F.-450.degree. F., for a period of time sufficient to cause the dye to diffuse into the fibers and to fix the ionic dye to the fibers of the textile. Any remainig high-boiling liquid is subsequently removed from the fabric.Type: GrantFiled: January 9, 1987Date of Patent: February 2, 1988Assignee: Burlington Industries, Inc.Inventor: George L. Brodmann
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Patent number: 4722738Abstract: A waterless dye composition for apparel and other articles, made from thermoplastic materials, comprises an aliphatic polyester of a higher alkanoic acid and a polyol, of the formula (ACOO).sub.2-6 B, wherein A is alkyl of 8-22 carbon atoms and B is the residue of a polyhydric alcohol, other than glycerol, of 2-6 hydroxyl groups and an organic colorant. The compositions can further comprise an aromatic polyester of the formula C.sub.6 H.sub.z' --COOR.sub.1).sub.z, wherein z is 3, 4, 5, or 6; z' is 6-z; and R.sub.1 is higher alkyl; and/or a cycloaliphatic diester of the formula ##STR1## wherein R is substituted or unsubstituted straight or branched chain alkyl of 4-20 carbon atoms, polyoxyalkylene of the formula HO(C.sub.x H.sub.y O).sub.n C.sub.x H.sub.y --or phosphated polyoxyalkylene of the formula (HO).sub.2 P(.dbd.O)O(C.sub.x H.sub.2x O).sub.n C.sub.x H.sub.2x or a salt thereof, wherein (C.sub.x H.sub.2x O).sub.n is (CH.sub.2 CH.sub.2 O).sub.n, (C.sub.3 H.sub.6 O).sub.n or (CH.sub.2 CH.sub.2 O).sub.p (C.Type: GrantFiled: July 25, 1986Date of Patent: February 2, 1988Assignee: Crucible Chemical CompanyInventor: Robert B. Wilson
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Patent number: 4718918Abstract: Polymeric compounds (A) obtained by the reaction of epihalo-hydrin with a polyalkylene polyamine are useful as textile treatment agents. As pretreatment agents they improve the color yield of the subsequent dyeing, as aftertreatment agents they improve fastness properties. Certain of the products (A) are novel.Type: GrantFiled: June 16, 1986Date of Patent: January 12, 1988Assignee: Sandoz Ltd.Inventors: Jurg Heller, Bruno Kissling, Tibor Robinson, Salvatore Valenti
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Patent number: 4715863Abstract: A process is described for dyeing hydrophobic fibre material with unfinished disperse dyes from an aqueous liquor, which comprises dissolving one or more such dyes in water at a temperature of 50.degree. to 150.degree. C. by means of a surfactant or surfactant mixture with a hydrotroping or solubilizing action on disperse dyes, bringing the dye solution together with the substrate in a dyeing apparatus, then heating the dyeing liquor to the dyeing temperature and completing the dyeing at that temperature and then removing the substrate and restoring the exhausted dyeing liquor to the original composition by adding water, surfactant and dye and using it again for dyeing.Type: GrantFiled: May 9, 1986Date of Patent: December 29, 1987Assignee: Ciba-Geigy CorporationInventors: Josef Navratil, Heinz Abel
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Patent number: 4713082Abstract: A process for dyeing or printing textile fibre materials with reactive dyes, which comprises using reactive dyes which contain at least one radical of the formula--SO.sub.2 --CH.dbd.CH.sub.2 (1a)or--SO.sub.2 --CH.sub.2 CH.sub.2 --X (1b)and at least one radical of the formula ##STR1## in which X is an inorganic or organic radical detachable under alkaline conditions, R is hydrogen or substituted or unsubstituted C.sub.1-4 -alkyl, Y is oxygen or sulfur and R.sub.1 is a substituted or unsubstituted aliphatic radical, gives dyeings or prints having good fastness properties.Type: GrantFiled: August 20, 1986Date of Patent: December 15, 1987Assignee: Ciba-Geigy CorporationInventors: Peter Scheibli, Karl Seitz
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Patent number: 4713084Abstract: Gel particle dye liquors for imparting color to textiles are disclosed. The gel particles are prepared by mixing a first composition comprising a alginic acid or an alginic acid derivative with a second composition comprising a mixture of at least one monovalent chloride salt and at least one polyvalent metal salt.At least one of the compositions contains a dye resulting in the formation of a colored suspension of gel particles in water.Type: GrantFiled: October 24, 1985Date of Patent: December 15, 1987Assignee: Armstrong World Industries, Inc.Inventors: Walter J. Bohrn, Robert D. Lewis, William A. Moggio
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Patent number: 4710198Abstract: A process of dyeing polyamide-containing material is disclosed using dyes of the following formula: ##STR1## wherein Me is cobalt or chromium,Ka.sup..sym. is a cation,p is 0 or 1,R and R' are each independently of the other hydrogen or a group of the formula --CO--(O).sub.n --Y, wheren is 0 or 1, andY is C.sub.1 -C.sub.5 alkyl, or phenyl which may be substituted by nitro, halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy,with the proviso that R and R' may not both be hydrogen if p is 1.Novel dyes within this class are also disclosed. The process is especially useful for dyeing leather.Type: GrantFiled: December 9, 1985Date of Patent: December 1, 1987Assignee: Ciba-Geigy CorporationInventors: Fabio Beffa, Hans U. Schutz
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Patent number: 4707161Abstract: A process for improving the lightfastness of dyeings obtained with acid dyes and/or metal complex dyes on polyamide textile materials, by treating the latter with 0.01-1% by weight of a copper hydroxamate before, during or after dyeing.Type: GrantFiled: July 21, 1986Date of Patent: November 17, 1987Assignee: BASF AktiengesellschaftInventors: Michael Thomas, Peter Neumann, Dieter Wegerle, Reinhold Krallmann