Pretreatment Before Dyeing Patents (Class 8/930)
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Patent number: 11987931Abstract: The current disclosure provides for a woven or nonwoven textured substrate that is stable in water based solutions. The textured substrate is generated by a controlled placement of ink on to portions of the surface and/or between layers of the textured substrate which is then followed by heat activation which expands the ink to puff out where the ink was applied to the textured substrate.Type: GrantFiled: February 19, 2019Date of Patent: May 21, 2024Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Simon K. Poruthoor, Christopher C. Creagan, Nathan J. Vogel, Jenna L. Bednar, Amanda Thelen
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Patent number: 8475539Abstract: The present disclosure relates to compositions for preparing textile auxiliaries, which are used in particular to enhance the dyeing affinity of textile fibers.Type: GrantFiled: May 12, 2009Date of Patent: July 2, 2013Assignee: Total Raffinage MarketingInventor: Richard Frelechoux
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Patent number: 8021736Abstract: Substantially flame retardant-free carpets comprising poly(trimethylene terephthalate) yarn having minimal carrier and, optionally, minimal antistatic agent, are disclosed, as are methods for making such carpets.Type: GrantFiled: July 6, 2007Date of Patent: September 20, 2011Assignee: E.I. du Pont de Nemours and CompanyInventors: Jing C. Chang, Steven D. Beare, Gregory A. Urove, John J. Kozlowski
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Patent number: 8017662Abstract: A process for producing a synthetic fiber composition with reclaimed post consumer carpet yarn, wherein face yarn is shaved from post consumer carpet using a shaving device to provide shaved face yarn, the shaved face yarn is reduced in size, contaminants are removed using mechanical screeners, the shave face yarn is melt filtered, and then fiber spun.Type: GrantFiled: May 29, 2008Date of Patent: September 13, 2011Assignee: Universal Fibers, Inc.Inventors: George Taylor Hoover, Jr., Milton Keith Roark, Brendan Francis McSheehy, Jr., Matthew Benjamin Studholme
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Patent number: 7503940Abstract: Methods for spot-dyeing a damaged area on a textile employing a selected color loss filter and utilizing at least one of a primary color dye. In one embodiment, the method can include the following: inspecting the damaged area through the selected color loss filter; determining whether a primary color is missing from the damaged area by being able to view the damaged area through the selected color loss filter to, thereby, confirm that the primary color is missing from the damaged area; and applying at least one of a primary color dye, corresponding to the selected color loss filter, to the damaged area, while viewing the damaged area through the color loss filter, until the damaged area is substantially invisible through the color loss filter.Type: GrantFiled: February 13, 2004Date of Patent: March 17, 2009Assignee: Harris Research, Inc.Inventors: Craig Donaldson, Edward E. Durrant
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Patent number: 7235110Abstract: A method for surface dyeing a range of textile materials, in the form of yarn, fabric, or garments, includes: a) preparing a dyebath including dye particles and an additive, such as an anionic acrylic copolymer, causing the particles to become charged; b) preparing the textile material by applying an additive, such as a cationic polyamide, forming a substrate with a charge attracting the particles, c) immersing the textile material in the dyebath; d) chemically reducing the dye particles retained on the textile material to a leuco form; and e) oxidizing the dye material.Type: GrantFiled: November 14, 2005Date of Patent: June 26, 2007Inventor: Melvin Alpert
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Patent number: 7090704Abstract: A method of improving the resistance of dyes on natural or synthetic polyamnide fiber materials to the action of ozone and NOx, which comprises treating the fiber material, before, during or after dyeing, with a liquor comprising a terpolymer containing structural repeating units of formulae (I), (II) and (III) in which R is a radical of formula (IV) wherein A1 and A2 are independently of one another a direct bond, C1–C8alkylene or —CO—NH—C1–C8alkylene, E is vinyl or —OSH3H and n denotes 0 or 1.Type: GrantFiled: November 26, 2002Date of Patent: August 15, 2006Assignee: Ciba Specialty Chemicals CorporationInventor: Philippe Ouziel
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Patent number: 6997962Abstract: A method for dyeing a cellulosic material, such as cotton or a blend including cotton, in the form of yarn, fabric, or garments, includes: a) preparing a dyebath including particles of indigo and an additive, such as an anionic acrylic copolymer, causing the particles to become charged; b) preparing the cellulosic material by applying an additive, such as a cationic polyamide, forming a substrate with a charge attracting the particles, c) immersing the cellulosic material in the dyebath; d) chemically reducing the particles retained on the cellulosic material to a leuco form; and e) oxidizing the dye material.Type: GrantFiled: February 18, 2004Date of Patent: February 14, 2006Inventor: Melvin Alpert
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Patent number: 6911055Abstract: The invention concerns a method which comprises irradiating at least one face of an article with UV radiation, causing the article to be photodegraded over a thickness of at least 1 ?m and contacting the irradiated face of the article with a coloring agent, so as to diffuse the coloring agent in the entire thickness of the photodegraded surface layer of the article. The invention is useful for optical and ophthalmologic articles.Type: GrantFiled: May 12, 2004Date of Patent: June 28, 2005Assignee: Essilor International Compagnie General d'OptiqueInventor: Gilles Baillet
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Patent number: 6858044Abstract: Use of (PA) water-dispersible or colloidally soluble polyamides which contain hydrophilic polyalkylene glycol ether chains in the skeletal structure as wet-acting lubricants in the treatment of textile piece goods in rope or tubular form with a textile treatment agent (T) by exhaust methods from aqueous liquor under conditions which would otherwise in the textile substrate favor the formation of transport folds and/or the occurrence of friction in or on the substrate, particularly as wet-acting lubricants in the dyeing of polyamides in the jet, the corresponding wet-acting lubricants, certain polyamide preparations and certain polyamides, and their production.Type: GrantFiled: September 21, 2000Date of Patent: February 22, 2005Assignee: Clariant Finance (BVI) LimitedInventors: Bernard Danner, Francis Palacin
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Patent number: 6802871Abstract: Compositions which, as well as water, contain certain sulfonate salts or polyhydric alcohols together with ethoxylated/propoxylated alcohols and ethoxylated alcohols are useful for pretreating textile sheet materials. Further ingredients also render them useful for hydrogen peroxide bleaching. The compositions, which provide the textiles with good primary wettability and good rewettability, are low-foaming. Batchwise pretreatment processes, for example in jet machines, therefore represent no problem.Type: GrantFiled: October 13, 2000Date of Patent: October 12, 2004Assignee: Ciba Specialty Chemicals CorporationInventors: Biancamaria Prozzo, Peter Seifert
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Patent number: 6695889Abstract: In textile products (e.g. yarns, woven fabrics, knit fabrics) comprising highly crosslinked polyacrylic fibers (made of acrylic fibers by partially hydrolyzing a nitrile group to generate an amido group and a carboxylic acid group), fibers blended with the highly crosslinked polyacrylic fibers can be dyed in an even hue. A pre-dyeing treatment process for such textile products (e.g. yarns, woven fabrics, knit fabrics) comprising highly crosslinked polyacrylic fibers comprises a pretreatment step of immersing the textile product into an acidic solution and treating it at a high temperature and an elevated pressure. A dyeing process comprises the steps of conducting this pre-dyeing treatment process, and thereafter conventionally dyeing fibers blended with the highly crosslinked polyacrylic fibers. A pretreated and undyed textile product and a dyed textile product are obtained by the pre-dyeing treatment process and the dyeing process mentioned above, respectively.Type: GrantFiled: September 14, 2001Date of Patent: February 24, 2004Assignees: Sakaren Co., Ltd., Mizuno Corp.Inventors: Takamasa Sakamoto, Tsutomu Shiotani, Takeshi Ogino
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Patent number: 6623532Abstract: The present invention provides a method of applying ink containing dyes to fabric composed of synthetic and cellulose fibers using an ink-jet system to print the fabric with high color shade depth and brilliancy and ink-jet printed goods obtained by the ink-jet printing method. The fabric composed of cellulose and synthetic fibers is treated with an acidic aqueous dispersion containing cellulose reactive compound, water-soluble polymer and non-water-soluble inactive organic compound with a melting point of 40° C.-150° C. and the fabric is dried before its ink-jet printing with reactive and disperse dyes.Type: GrantFiled: September 5, 2001Date of Patent: September 23, 2003Assignee: Seiren Co., Ltd.Inventors: Shungaku Nakamura, Ayumi Yamazaki
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Patent number: 6602304Abstract: A novel aqueous dye-accelerant composition that allows for the effective and rapid reaction of a dye with the fibers of a substrate such that the dye becomes evenly attached to the substrate within seconds is provided. The dye-accelerant composition generally comprises: an organic solvent; at least one dispersing agent; a chelating agent; and a vehicle. In another embodiment, a dyeing process utilizing the dye-accelerant composition, which includes five primary treatment processes: a pre-treatment process, a bleaching process, a neutralize and dye accelerant process, a dyeing process, and a dye stop or fixing process is provided.Type: GrantFiled: May 15, 2002Date of Patent: August 5, 2003Inventors: James Jung, Alex Kyuhun Lee, Yoon Gil Kim
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Patent number: 6544300Abstract: A process for improving the colorfastness of dyed thermoplastic textile materials is described. The process involves heatsetting the materials to a temperature which minimizes the amount of semi-crystalline regions, dyeing the material and subjecting it to a reductive clear. The process can be used on a variety of textile materials including fibers, yarns and fabrics. The process is particularly effective in achieving high colorfastness on microdenier products, even when the product is dyed a dark shade. The materials also retain good strength and flexibility characteristics.Type: GrantFiled: December 27, 1999Date of Patent: April 8, 2003Assignee: Milliken & CompanyInventors: James D. Cliver, Dale R. Williams
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Patent number: 6527815Abstract: Textiles made of synthetic fibers and synthetic fiber blended fabrics are constructed in the form of a garment then dyed while avoiding setting permanent creases and permanent wrinkles in the garment. The process includes selecting a synthetic or synthetic blended fabric for the dyeing process by determining the fabric's shrinkage in the warp and fill directions, for instance no greater than 6%, constructing a garment from the fabric selected, then dyeing the constructed garment in an aqueous dyebath at a temperature in the range of 220 to 260° F. for a time sufficient to achieve a desired shade and levelness of color followed by drying and optionally pressing the dyed garment.Type: GrantFiled: September 13, 2000Date of Patent: March 4, 2003Assignee: Burlington Industries, Inc.Inventors: Katherine T. Bryant, John E. Newbern, Earl E. Bradsher, III, Terry L. Currans, G. Lewis Best, III, Ashutosh Karnik, John W. McAnulty
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Patent number: 6413281Abstract: 2-(p-sulphophenyl) amino-1,3 5-triazine derivatives [1] and their alkali salts, wherein R1, represents Cl, F; R2 is &agr;- or &bgr;-naphthylamino, or &agr;- or &bgr;-naphthoxy, and the method for preparing the compound are provided. The compound can be used as a cationic dye auxiliary agent in dyeing animal protein fibers (such as wool, cony hair, camel hair and natural silk) and their textile fabric as well as blended yarn or fabric containing the animal protein fiber.Type: GrantFiled: February 17, 2000Date of Patent: July 2, 2002Inventor: Zhi Wang
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Patent number: 6368361Abstract: Tea polyphenol obtained by the extraction from tea has an antibacterial effect. In methods for producing an antibacterial fiber by fixing the tea polyphenol to fiber, the object of the present invention is to provide a process for manufacturing an antibacterial fiber capable of exerting an excellent antibacterial performance without the use of metal chelates potentially causing metal allergy and environmental problems. In order to achieve the above object, the present invention manufactures an antibacterial fiber by a process comprising the steps of contacting fiber with or immersing fiber in an aqueous solution in which a cationic surfactant with a quaternary ammonium salt group, a water-soluble protein, and an alkaline compound are dissolved; and separating said fiber from the aqueous solution, to immerse the fiber in another aqueous solution containing tea polyphenol.Type: GrantFiled: March 22, 2000Date of Patent: April 9, 2002Assignee: Ito En, Ltd.Inventors: Fumihisa Yayabe, Yasuhiko Ikegawa, Shuichi Takahashi, Yukiko Nonaka, Saburo Sugimoto, Kazuhiko Hayashi, Yuji Higashibata
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Publication number: 20010054209Abstract: A method for dyeing cellulosic materials with reactive dye by pretreating the fabric with a polycationic polymeric agent which is desirably also polynucleophilic is disclosed. The agent can be a polyquaternary amine material especially a poly(DADMAC) or polyvinylpyridine, particularly one including nucleophilic sites such as primary amino groups, e.g. polyallylamine/DADMAC copolymers and polyvinylpyridines quaternisied with w-aminoalkyl groups. The dyes can react with the nucleophilic centres so dyebath exhaustion can be driven by dye fixation rather than substantivity to the substrate. The need to use of salts to drive substantivity can be obviated and post dyeing washing to remove unreacted/hydrolysed dye is much simplified. Material dyed by the method has the good wash fastness properties of materials dyed using reactive dyes. A wide variety of cellulosic substrates can be dyed including lyocell fibre materials and blend/union materials with polyamides.Type: ApplicationFiled: August 23, 1999Publication date: December 27, 2001Inventors: GEOFFREY WILLIAM COLLINS, STEPHEN MARTIN BURKINSHAW, ROY GORDON
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Patent number: 6296901Abstract: An ink transfer sheet and method for using the same. The transfer sheet includes a backing layer, a release layer on the backing layer, and an ink receiving layer on the release layer. The ink receiving layer contains a quaternary ammonium salt thereon or impregnated therein. To use the transfer sheet, an ink containing an anionic coloring agent is applied to the ink receiving layer, preferably using thermal inkjet methods. Thereafter, the transfer sheet is positioned on a fabric substrate. Heat is applied to the sheet which causes the release layer and ink receiving layer to adhere to the substrate. The backing layer is then detached from the release layer leaving the release and ink receiving layers (with the printed image thereon) on the substrate. This process transfers the image to the fabric substrate, with the image being stabilized by interactions between the quaternary ammonium salt and anionic coloring agent.Type: GrantFiled: March 1, 2000Date of Patent: October 2, 2001Assignee: Hewlett-Packard CompanyInventors: Melissa D. Boyd, Mark H. Kowalski
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Patent number: 6280482Abstract: A method of improving the stability to ozone exposure of dyes on natural or synthetic polyamide fiber materials comprises treating the fiber material, before, during or after dyeing, with a liquor comprising a homopolymer or copolymer having structural repeating units of formula (1) in which R1 is unsubstituted or substituted C1-C4alkyl. The resulting dyeings and prints feature improved ozone fastness with no effect on hue, colour yield and other fastness properties such as light fastness, for instance.Type: GrantFiled: July 5, 2000Date of Patent: August 28, 2001Assignee: Ciba Specialty Chemicals CorporationInventors: Philippe Ouziel, Jean-Marie Adam
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Patent number: 6206935Abstract: Described in the present invention is a hair dyeing method comprising treating the hair with a hair bleaching agent and then, without rinsing off the bleaching agent, with a direct hair dye. The present invention makes it possible to color the hair into a vivid color in a short time.Type: GrantFiled: February 24, 2000Date of Patent: March 27, 2001Assignee: Kao CorporationInventors: Satoshi Onitsuka, Kazuhiro Okada, Hajime Miyabe
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Patent number: 6200354Abstract: A method of dyeing cellulosic fibers or fabrics using pre-metallized acid dye by pretreating the fabric with a cationic agent having a plurality of cationic centers and optionally after treating the dyed material with a cationic polymer is disclosed. The cationic polymer is desirably a polyquaternary amine material especially a poly(DADMAC) or polyvinylpyridine. Material dyed by the method has a “washed out” appearance similar to fabrics dyed using the “Jarofast” process, but the availability of a wide range of pre-metallized dyes gives a wider color range, and the method enables a wider range of substrates to be dyed successfully, including lyocell fiber materials e.g. those sold under Courtauld's trademark “Tencel” and blend/union materials with polyamides, easier processing and superior wash and light fastness.Type: GrantFiled: August 23, 1999Date of Patent: March 13, 2001Assignee: Imperial Chemical Industries PLCInventors: Geoffrey William Collins, Stephen Martin Burkinshaw, Roy Gordon
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Patent number: 6113656Abstract: A method for exhaust dyeing a polyester or polyester blend textile article with a disperse dye is provided whereby the article is first treated with an aliphatic amine to reduce the tensile strength of the polyester fibers, followed by dyeing the fabric in a bath containing from 1.0 to 3.0 weight percent based on the weight of the fabric, of a compound selected from the group consisting of:(a) C.sub.8 -C.sub.16 aliphatic fatty acid ethoxylates having from 5 to 15 ethylene oxide residues;(b) C.sub.8 -C.sub.16 alcohol ethoxylates having from 5 to 15 ethylene oxide residues; and(c) C.sub.8 -C.sub.16 aliphatic amine ethoxylates having from 5 to 15 ethylene oxide residues,to achieve a spot free, level dyed fabric, with reduced pilling tendencies.Type: GrantFiled: January 17, 1995Date of Patent: September 5, 2000Assignee: Milliken & CompanyInventor: William C. Kimbrell
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Patent number: 6086636Abstract: Disclosed is a process for printing fibre material with reactive dyes, which comprises the fibre material to be printed first being treated with an aqueous alkaline liquor, optionally dried and then printed with a print paste comprising at least one reactive dye, a thickener and optionally further additives with the exception of an alkali or an alkali donor.Type: GrantFiled: June 2, 1998Date of Patent: July 11, 2000Assignee: Ciba Specialty Chemicals CorporationInventors: Mickael Mheidle, Peter Scheibli
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Patent number: 6056790Abstract: The present invention is a fully automated modified batch dyeing process that provides a process that reduces water consumption, reduces environmental pollution, and reduces the energy and chemical consumption of the conventional batch dyeing process through efficient reuse of spent dyebath. The invention provides a holding tank which stores the spent dyebath, and an analysis system which allows for the analysis of the dyebath in the holding tank so that the dyebath may be reconstituted and used in the batch dyeing process.Type: GrantFiled: May 27, 1998Date of Patent: May 2, 2000Assignee: Georgia Tech Research Corp.Inventors: James Leonard Clark, Wayne Coleman Tincher, Wiley Don Holcombe, Richard A. Carey, Elizabeth Wise White
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Patent number: 6051036Abstract: A printed cloth in which a dye is deposited in dots on the cloth to form a desired printed pattern. Said dot deposition is formed in a length of 0.05 to 0.3 mm to the longitudinal direction of the fiber in single fiber unit of the yarn constituting said cloth. A fine printed pattern is deposited clearly in good reproducibility. The printed pattern can be formed by using the dyes of the three primary colors or of the three primary colors and black color. It is preferred that Dyes I, II and III having a perceived chromaticity index (a) and (b) defined in the color range [CIE 1976 (L, a, b) space] on the cloth within the following range are used as said dyes of three primary colors and DyeIV is used as said black dye.______________________________________ I Yellow: (a) -20.about.0 (b) 50.about.90 II Red: (a) 50.about.70 (b) 0.about.20 III Blue: (a) -50.about.-1 (b) -50.about.-20 IV Black: (a) -6.about.6 (b) -6.about.Type: GrantFiled: June 3, 1997Date of Patent: April 18, 2000Assignee: Kanebo, Ltd.Inventors: Kazuo Kusaki, Toshikazu Fuse, Tohru Morita, Toshihiko Ishihara, Kazuyoshi Morimoto, Kazuo Iwata, Michiyo Nishimura
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Patent number: 6024770Abstract: The invention consists of a process to improve the resistance to stains on yarns, on the basis of wool, silk, polyamide, polyacrilonitrile, natural and artificial cellulosic fibres and in general, all other synthetical fibres which can be dyed. According to the invention the yarns are treated during the dyeing process with an aqueous solution containing up to 5% tannic acid in acid medium. It is economically advisable to add a stabiliser to the solution to avoid oxidation of the solution and the fibres, and possibly a wetting agent. Preferably the treatment is made during the dyeing procedure, before, during or after the effective dyeing step.Type: GrantFiled: March 29, 1996Date of Patent: February 15, 2000Assignee: N.V. Denderland-MartinInventor: Armand de Lathauwer
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Patent number: 6022383Abstract: A leather coloring process for carrying out coloring on a natural leather, or a natural leather which has been subjected to degreasing. The coloring process is accomplished by ink-jet coloring on at least a partial area of the natural leather.Type: GrantFiled: June 27, 1997Date of Patent: February 8, 2000Assignee: Canon Kabushiki KaishaInventors: Nobuyuki Kuwabara, Tokuya Ohta, Yasushi Takatori, Sadayuki Sugama, Hiromitsu Hirabayashi, Yuji Akiyama, Miyuki Fujita
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Patent number: 5942009Abstract: A method for the same-day permanent waving and coloring of hair ("same-day" meaning during a twenty-four hour period and preferably during a single session of only a few hours), which can provide to the hair improved shape retention, color receptivity, color stability, color retention, color evenness, color depth, shine, strength, softness, luster, and/or elasticity. After initial preparation (shampooing, treating with a pre-wrap, and placing on rods if the hair is to be curled), the hair is processed using a waving agent (e.g., thioglycolate), the excess is preferably removed, contacted with a first composition, the excess preferably removed, optionally but preferably contacted with a second composition, heated to dry the hair, and then contacted with a coloring composition containing an oxidative colorant and an oxidizing agent, the oxidizing agent helping develop the color and rebond the hair. The first and second compositions each contain a biologically acceptable metal (preferably a polyvalent metal, e.Type: GrantFiled: March 28, 1997Date of Patent: August 24, 1999Assignee: BRG, Ltd.Inventor: Michael S. Burns
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Patent number: 5925148Abstract: The present invention relates to methods of overdyeing a warp dyed denim textile, comprising treating the textile in an aqueous dye liquor with a dye system which comprises an effective amount of (a) one or more mono-, di- or polycyclic aromatic or heteroaromatic compounds and (b) (i) a hydrogen peroxide source and at least one enzyme exhibiting peroxidase activity and/or (ii) at least one enzyme exhibiting oxidase activity on the one or more aromatic or heteroaromatic compounds.Type: GrantFiled: July 28, 1997Date of Patent: July 20, 1999Assignee: Novo Nordisk A/SInventors: Martin Barfoed, Ole Kirk
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Patent number: 5911902Abstract: The present invention relates to the use of a modified fatty amine of formulaR--NR.sub.3 --(R.sub.1 --O).sub.n --R.sub.2 (1),whereinR is C.sub.9 -C.sub.24 alkyl or acyl, R.sub.1 is C.sub.2 -C.sub.4 alkylene, R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or acyl, R.sub.3 is hydrogen or (R.sub.1 --O).sub.m, n and m are each independently of the other an integer from 2 to 100, and (R.sub.1 --O).sub.n is n identical or different radicals (R.sub.1 --O), and (R.sub.1 --O).sub.m is m identical or different radicals (R.sub.1 --O),for reducing or preventing low molecular weight by-product deposits developing in the course of the polyester fiber material production process on textile materials consisting of polyester fibers or containing these fibers in blends with other fibers.Type: GrantFiled: July 6, 1998Date of Patent: June 15, 1999Assignee: Ciba Specialty Chemicals CorporationInventors: Claudius Brinkmann, Alfred Keller
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Patent number: 5882356Abstract: The fibrillation tendency of solvent-spun cellulose fiber is reduced by treating the previously dried fiber with a chemical reagent containing at least two functional groups which are reactive with cellulose and which are electrophilic carbon--carbon double bonds, particularly vinyl sulfone groups, or precursors thereof or electrophilic three-membered heterocyclic rings or precursors thereof. The chemical reagent is preferably colorless and is preferably applied to the fiber from aqueous solution. The fiber may be contained in a woven or knotted fabric.Type: GrantFiled: July 7, 1997Date of Patent: March 16, 1999Assignee: Courtaulds Fibres (Holdings) LimitedInventor: Christopher David Potter
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Patent number: 5833720Abstract: A method of dyeing cellulosic textile fibers with a dye which normally requires an exhaust salt. The method includes the step of forming a dye site, which includes the steps of treating the fibers with a dilute alkali solution containing an epoxy ammonium compound having an epoxy-reactive group which will permanently attach to cellulose hydroxyl groups to form a permanent cationic dye site, rinsing the fibers to remove any excess epoxy ammonium compound and at least some of the dilute alkali solution, and neutralizing any remaining alkali solution with a mild acid.The method also includes the steps of dyeing the fibers in a dyebath containing a bifunctional reactive dye without a salt and at a temperature at or below 30.degree. C. (86.degree. F.) to dye exhaustion.Type: GrantFiled: July 22, 1997Date of Patent: November 10, 1998Inventors: Johnny Joe Kent, Eric C.S. Lee, Sui-Fung Yu
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Patent number: 5695529Abstract: A 5% strength by weight to saturated aqueous solution of N-(2-sulfatoethyl)piperazine sulfate, having a pH of between 4 and 0, can be used to modify fiber material.Type: GrantFiled: December 20, 1996Date of Patent: December 9, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Schrell, Michael Meier, Heinz Georg Kautz
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Patent number: 5676707Abstract: Provided is a leather treatment process for leather coloring, carried out on a leather to be colored with a liquid ink, the process comprises the steps of, imparting to the coloring surface of the leather a resin soluble in the liquid ink and imparting to the coloring surface an aggregate of particles with a functional group having an affinity for the liquid ink.Type: GrantFiled: September 11, 1996Date of Patent: October 14, 1997Assignee: Canon Kabushiki KaishaInventors: Nobuyuki Kuwabara, Miyuki Fujita
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Patent number: 5667533Abstract: Textile fabrics and garments having a random, irregular heather-like appearance are produced by impregnating a textile fabric with an aqueous pretreaement composition comprising a fiber reactive cationic compound, aging the impregnated fabric in a moistened state for about 4 to 24 hours to allow the fiber reactive cationic compound to react with the fibers of the fabric, rinsing the fabric to remove unreacted cationic compound, immersing the fabric in an aqueous bath at a pH of less than 7 and gradually introducing dyestuffs to the bath over a period of at least 15 minutes, and fully exhausting the dyestuffs onto the fabric. The process is applicable for dyeing either piece goods or garments. Where the fabric is in the form of garments, it is preferred that the aging be carried out by storing the garments in an insulated sealed container.Type: GrantFiled: February 7, 1996Date of Patent: September 16, 1997Assignee: The Virkler CompanyInventors: Peter J. Hauser, Stewart G. Helfrich
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Patent number: 5611822Abstract: This invention provides processes for dyeing fibers with indigo including placing the fibers in a substantially enclosed compartment of a commercial dye apparatus, which is equipped with means for introducing a non-oxidizing gas into the compartment; prior to or following placing the fibers in the compartment, introducing a non-oxidizing gas into the compartment to produce a substantially non-oxidizing atmosphere therein; contacting the fibers with a dye liquor comprising leuco indigo in the compartment such that the leuco (reduced) indigo is taken up by the fibers; and oxidizing the leuco indigo taken up by the fibers to produce a blue color in the fibers.Type: GrantFiled: April 29, 1996Date of Patent: March 18, 1997Assignee: Allegro Natural Dyes LLCInventor: Sally Gurley
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Patent number: 5611819Abstract: A fabric superior in anti-drape stiffness, stiffness and soft handle, which is formed using a spun yarn comprising regenerated fibers having an average polymerization degree of not less than 400 and a modified cross-section, in a proportion of at least 20% by weight of the yarn, wherein at least one regenerated fiber from among the regenerated fibers of said fabric is split and/or fibrilar. According to the present invention, a fabric having a dry touch, which is superior in anti-drape stiffness, stiffness and soft handle, and a method for manufacture thereof are provided.Type: GrantFiled: March 14, 1996Date of Patent: March 18, 1997Assignee: Toyo Boseki Kabushiki KaishaInventors: Yasuhiko Nomura, Ikuharu Nishida, Tadaaki Kashima
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Patent number: 5601621Abstract: Fiber materials can be modified by applying heterocycloaliphatic compounds containing at least one primary, secondary or tertiary amino group or quaternary ammonium group, the hetero portion of which in the ring is a carbonic ester radical of the formula --O--CO--O-- or a carbamic acid radical of the formula --O--CO--NH--, in aqueous alkaline solution by exposing the fiber material to these compounds at a temperature of between 60.degree. and 230.degree. C. The characteristic of the modified fiber material is that it can be dyed with dye solutions of water-soluble, anionic textile dyes which are low in electrolytes or entirely free of electrolytes and/or are low in alkali or entirely free of alkali. The advantage of a dyeing process carried out in this manner, in particular for fiber-reactive dyes, is that fixation of the dyes under alkaline conditions is unnecessary.Type: GrantFiled: February 13, 1995Date of Patent: February 11, 1997Assignee: Hoechst AktiengesellschaftInventors: Andreas Schrell, Werner H. Russ, Thomas Riehm
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Patent number: 5597386Abstract: A hair dye consisting of an anti-hair antibody immobilized on a high bulky coloring material. The coloring material may be a coloring substance such as an inorganic pigment, water-soluble coloring matter, or water-insoluble coloring matter, or a composite of the coloring substance and a macromolecular carrier. Since it provides a good and strong coloring capability specific to hair, the hair dye of the present invention will neither stain the skin nor cause skin irritation. Further, the touch and feel of the hair will be improved.Type: GrantFiled: August 8, 1994Date of Patent: January 28, 1997Assignee: Kanebo, Ltd.Inventors: Shigeru Igarashi, Toshihiro Usui, Junichiro Hiraoka, Keiko Hashimoto, Hideyo Uchiwa, Umeji Murakami, Kenichi Sugimoto, Hiromi Minamino, Toshio Horikoshi
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Patent number: 5580354Abstract: A process is disclosed for providing a solvent-spun cellulose fibre with a reduced fibrillation tendency. The fibre is treated with a chemical reagent, preferably substantially colourless, having 2 to 6 functional groups reactive with cellulose, suitably dissolved in an aqueous solution.Type: GrantFiled: May 25, 1995Date of Patent: December 3, 1996Assignee: Courtaulds PLCInventor: James M. Taylor
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Patent number: 5575821Abstract: A process for the dyeing of fiber materials with water-soluble anionic dyes, in particular those having a fiber-reactive group, is described, according to which dyeing is carried out using low-electrolyte or entirely electrolyte-free and/or low-alkali or entirely alkali-free dye solutions (dye liquors, printing pastes) and in which a fiber material is used which was modified by means of a saturated straight-chain or branched aliphatic or cycloaliphatic compound which is unsubstituted or substituted by one or more hydroxy groups and contains at least one primary, secondary or tertiary amino group or quaternary ammonium group and at least one hydrolyzable ester group, it also being possible for the aliphatic radical in this compound to be interrupted by one or more hetero groups.Type: GrantFiled: June 7, 1995Date of Patent: November 19, 1996Assignee: Hoechst AGInventors: Andreas Schrell, Werner H. Russ, Thomas Riehm
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Patent number: 5560751Abstract: A method for dyeing an optical component such as a lens or filter. A coating of dyeing solution is formed on a surface of a lens and the lens is subjected to a nonuniform heating treatment in dependence on the position within the surface to obtain the desired color density gradient of the lens. In accordance with the positions within such surface, a nonuniform integrated heating amount distribution provides the desired color density gradient with excellent reproducibility.Type: GrantFiled: June 6, 1995Date of Patent: October 1, 1996Assignee: Nikon CorporationInventor: Seiichirou Hoshiyama
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Patent number: 5542954Abstract: A process for the production of aminated cotton fibers by subjecting a raw cotton or cotton-polyester mixture to a modification with a saturated aliphatic compound of 3 to 15 carbon atoms which contains at least one primary, secondary, tertiary, or quaternary amino group and at least one hydrolyzable ester group, in which the saturated radical is straight chain, branched, or cyclic, and may be interrupted by one or more hetero groups and may be substituted by one or more hydroxyl groups. The modification occurs simultaneously with scouring, kiering, or dry mercerizing.Type: GrantFiled: January 24, 1995Date of Patent: August 6, 1996Assignee: Hoechst AktiengesellschaftInventors: Andreas Schrell, Werner H. Russ
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Patent number: 5512062Abstract: A method, apparatus, and related dye compositions for dyeing textiles which operates at atmospheric pressures, is open to the atmosphere, and does not require the steaming of the textile to set or fix the dye to the textile; specifically, a multi-temperature textile dyeing method which achieves a more complete and even dyeing of the textile in a shorter period of time.Type: GrantFiled: July 13, 1995Date of Patent: April 30, 1996Assignee: Ful-Dye, Inc.Inventors: B. Franklin Fuller, Franklin G. Fuller
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Patent number: 5512061Abstract: A process for printing and dyeing sheetlike fiber materials with anionic dyes comprisesa) first applying to the sheetlike fiber material an aqueous solution containing a fixing alkali and a compound which contains a primary, secondary or tertiary amino group or a quaternary ammonium group, which may each also be part of a heterocycle, by using a printing process, thenb) subjecting the sheetlike fiber material to a fixing treatment to modify the sheetlike fiber material, and finally and optionallyc) dyeing the modified sheetlike fiber material one or more times by a customary exhaust or padding method.Type: GrantFiled: March 2, 1994Date of Patent: April 30, 1996Assignee: Hoechst AktiengesellschaftInventors: Andreas von der Eltz, Andreas Schrell, Werner H. Russ
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Patent number: 5500023Abstract: Disclosed herein is an ink-jet printing process comprising at least the steps of:(a) successively applying, as ink droplets, at least two inks of different colors to a cloth to form a color-mixed portion;(b) subjecting the cloth to a heat treatment to fix dyes contained in the inks to the cloth; and(c) washing the cloth to remove unfixed dyes from the cloth,wherein the inks comprise water, an organic solvent and individual reactive dyes different from each other in reaction rate, and the volume of a droplet of the ink containing a slower-reacting dye is made smaller upon the application of the inks.Type: GrantFiled: April 18, 1994Date of Patent: March 19, 1996Assignee: Canon Kabushiki KaishaInventors: Shoji Koike, Masahiro Haruta, Koromo Shirota, Tomoya Yamamoto, Mariko Suzuki
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Patent number: 5496707Abstract: The present invention provides an assay method for hemicellulases comprising a) directly dyeing, using a reactive dye, an insoluble natural product, or a modified form of a natural fibre material; and b) adding the enzyme to the dyed product produced in step a) and, after a specific incubation period, separating the liquid component from the insoluble dyed product, e.g. by a simple filtration, and determining the amount of dyestuff liberated in the the separated solution by spectrophotometric means. A combined mixing and dispensing device for use in the method of the present invention is also provided.Type: GrantFiled: April 5, 1994Date of Patent: March 5, 1996Assignees: Ciba-Geigy Corporation, Genencor International, Inc.Inventors: Beat Freiermuth, Dieter Werthemann, Alfred Gaertner, Spencer Fisk
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Patent number: 5490865Abstract: The present invention is a process for producing two-tone or multi-color effects on animal fibers and the products derived from these fibers. Pretreatment of the fibers to increase the affinity of the fiber relative to metallic salts or dyes for is accomplished by treatment with an ethanolamine solution containing varying amounts of mono-, di-, or triethanolamine. A mordant treatment with a metallic salt exposes the pretreated fibers to an aqueous solution of organic acids and a metallic salt mordant having affinity for the pretreated fiber. The two-tone or multi-colored effect is achieved by combining the treated fibers with untreated fiber and dyeing the fibers in a dyestuff having affinity for the treated fiber. The dyeing process may also include placing treated and untreated fibers in a dye bath containing dye stuffs that have affinity to treated fibers and dyestuffs that have an affinity to untreated fibers.Type: GrantFiled: July 25, 1994Date of Patent: February 13, 1996Inventor: Jurg P. Scheiwiller