Li Ion In Dye Bath Patents (Class 8/937)
  • Patent number: 5609650
    Abstract: An oxidation dye composition for keratin fibers containing component A and component B wherein component A is an oxidation dye precursor indoline derivative of the formula I: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; each of R.sup.4 and R.sup.5 is hydrogen or an alkyl group having from 1 to 4 carbon atoms or together with the oxygen atom to which they are attached represent an alkylenedioxy group containing 1 to 4 carbon atoms; or a salt thereof; and wherein component B is a metal salt having a non-oxidizing anion selected from the group consisting of a lithium, magnesium, calcium, aluminum and a zinc salt.
    Type: Grant
    Filed: January 5, 1996
    Date of Patent: March 11, 1997
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Georg Knuebel, Horst Hoeffkes, Winifried Neuhaus, Edgar Lieske, deceased
  • Patent number: 5487761
    Abstract: The dyestuffs of the formula ##STR1## in which A, R.sub.1, M and n are as defined in claim 1, are suitable for dyeing paper with good light-fastness.
    Type: Grant
    Filed: April 20, 1994
    Date of Patent: January 30, 1996
    Assignee: Ciba-Geigy Corporation
    Inventor: Adolf Kaser
  • Patent number: 5466265
    Abstract: Improved dyeings or prints on cellulose, regenerated cellulose and/or mixtures of cellulose with natural or synthetic fiber materials using one or more reactive and/or direct dyes are obtained in the presence of a lithium compound.
    Type: Grant
    Filed: May 13, 1994
    Date of Patent: November 14, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Riegels, Joachim Grutze
  • Patent number: 5256161
    Abstract: An improved aqueous dyestuff preparation which is suitable for the dyeing or printing of substrates contains a water-soluble lithium compound and an alkali, in particular sodium hydroxide.
    Type: Grant
    Filed: April 28, 1992
    Date of Patent: October 26, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Grutze, Friedhelm Buse, Johannes Haas, Manfred Hobohm
  • Patent number: 5096458
    Abstract: Stable aqueous solutions of anionic dyestuffs, preferably reactive dyestuffs, are obtained at very low costs by pressure permeation, if the feed solution for the pressure permeation is prepared by stirring the optionally dried presscake or the suspension of the crude dyestuff in an electrolyte solution.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: March 17, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Martin Michna, Hans-Werner Zillger, Dietrich Tegtmeyer
  • Patent number: 5032140
    Abstract: A reactive dye represented by the formula (I), ##STR1## wherein R represents --NH.sub.2 or --NHC.sub.2 H.sub.4 SO.sub.3 M, and M's independently represent Li.sup..sym., Na.sup..sym., K.sup..sym. or .sup..sym. NH(C.sub.2 H.sub.4 OH).sub.3, provided that at least one of M's represents Li.sup..sym. or .sup..sym. NH(C.sub.2 H.sub.4 OH).sub.3. This reactive dye easily gives a stable liquid composition and is useful to dye cellulosic or polyamide fibers.
    Type: Grant
    Filed: October 24, 1989
    Date of Patent: July 16, 1991
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Nobuyuki Yamanaka, Kazuo Hanawa, Eiichi Ogawa
  • Patent number: 4832698
    Abstract: An aqueous liquid dye composition comprising a dye represented by the following formula in a free acid form, ##STR1## wherein Y is --CH.dbd.CH.sub.2 or --CH.sub.2 CH.sub.2 X in which X is a group splittable by the action of an alkali, and a pH buffer, the dye being in the form of a lithium salt, and the liquid dye composition having a pH value of from 3 through 7 and a dye content of from 5 through 50% by weight based on the weight of the liquid dye composition, which can be stored stably for a long period of time even at a low temperature such as 0.degree. C. or lower, and a high temperature such as 40.degree. C. or higher.
    Type: Grant
    Filed: April 8, 1987
    Date of Patent: May 23, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shinei Ikeou, Takemi Tokieda, Noriaki Yamauchi, Kunihiko Imada, Yutaka Kayane
  • Patent number: 4808192
    Abstract: In accordance with this invention an aqueous solution of a water-soluble dye containing lithium sulfonate group or ammonium sulfonate group can be obtained by a very simple and economical process in such a way that an aqueous solution of a water-soluble dye containing sodium sulfonate group is fed to a packed column packed with acid type cation exchange resin (H-form) to form an aqueous solution of a dye containing a free sulfonic acid group, and after neutralizing the resulting solution with LiOH or NH.sub.4 OH, the aqueous solution of the dye thus obtained is concentrated according to a process for separation through reverse osmotic membrane.
    Type: Grant
    Filed: September 15, 1986
    Date of Patent: February 28, 1989
    Assignee: Mitsubishi Chemical Industries Limited
    Inventors: Yoshihiro Narita, Hiroshi Takimoto, Hideo Sano
  • Patent number: 4802888
    Abstract: The present invention is concerned with improving the solubility of anionic water soluble dyestuff powders. The solubility of these powders particularly in cold water, is enhanced by adding (i) a chelating agent which has at least two free acid groups and (ii) a Lewis base in an amount sufficient to bring the pH of the water solution of the powder to a value of about 7-10.
    Type: Grant
    Filed: November 6, 1987
    Date of Patent: February 7, 1989
    Assignee: Mobay Corporation
    Inventors: Charles W. Sandefur, Thomas J. Thomas
  • Patent number: 4783195
    Abstract: A process for the preparation of a concentrated storage-stable aqueous solution of the dyestuff of the formula ##STR1## is characterized in that the reaction mixture obtainable from the quinone derivative of the formula ##STR2## by sulphation and subsequent oxidation cyclization, preferably with ammonium, sodium or potassium peroxodisulphate, in oleum is diluted with water or sulphuric acid to a sulphuric acid concentration of 37-50%, preferably 41-43%, and the product which thereby precipitates is separated off and brought to a pH of about 2-6, preferably 3-4, in water with basic lithium compounds, preferably lithium carbonate or lithium hydroxide.
    Type: Grant
    Filed: January 22, 1988
    Date of Patent: November 8, 1988
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Steinbeck, Wolfgang Harms
  • Patent number: 4702744
    Abstract: Stable, concentrated aqueous solutions of, in particular, anionic reactive dyestuffs are obtained in a comparatively simple manner by freeing from salts, preferably by means of membrane separation processes, solutions of these substances just as they are obtained in the course of synthesis, and by replacing, with the aid of ion exchangers, the cations which cause sparing solubility.
    Type: Grant
    Filed: May 27, 1986
    Date of Patent: October 27, 1987
    Assignee: Bayer Aktiengesellschaft
    Inventors: Joachim Wolff, Jochen Koll, Karlheinz Wolf, Reinhold M. Klipper, Peter M. Lange
  • Patent number: 4673410
    Abstract: The present disclosure is concerned with enhancing the solubility of dispersed anionic dyes upon the dilution of their dispersions with room temperature water. Concentrated dispersions of such dyes with acceptable stability and low shear viscosities are disclosed which are more readily diluted to dissolve the dispersed dyestuff because they contain certain chelating agents are described. These agents have at least one free or appropriately neutralized acid group, with carboxylic acid groups being preferred. The appropriae cations include ammonium or lithium ions. The free acid groups are subsequently neutralized with these appropriae cations so that the final dispersions are preferably about neutral, i.e have pH values about 7. A further improvement to the dilutability by the addition of a surfactant, preferably a non-ionic surfactant, is also discssed.
    Type: Grant
    Filed: November 19, 1985
    Date of Patent: June 16, 1987
    Assignee: Mobay Corporation
    Inventors: Charles W. Sandefur, Thomas J. Thomas
  • Patent number: 4631067
    Abstract: Disperse dyes are dischargeable to white with a print paste including a thickening agent, lithium hydroxide, an organic acid, a polyethylene glycol compound, a polyoxyethylene sorbitan fatty acid ester and a polyalkyleneglycol ether. The print paste discharges a number of known disperse dyes, some which have been conventionally thought of as being alkali-resistant. A method of discharge printing of synthetic textile materials (e.g. polyester) is also disclosed.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: December 23, 1986
    Assignee: Burlington Industries, Inc.
    Inventor: Samir Hussamy
  • Patent number: 4300901
    Abstract: A liquid dyestuff composition, especially suitable for dyeing paper, comprises:(a) 5-40% by weight of a dyestuff having the formula: ##STR1## wherein X is hydrogen or an alkali metal cation, n represents an integer from 1 to 2, Q and Q.sub.1 together form a fused benzene or naphthalene residue, and Y is a residue having the formula ##STR2## whereby ring A, the fused residue formed by Q and Q.sub.1, or the residue Y can each be further substituted by one or more alkyl, alkoxy, hydroxy, carboxy or dehydrothio-p-toluidine groups or halogen atoms;(b) 1-10% by weight of an alkali metal hydroxide;(c) 45-75% by weight of a polyhydric alcohol or a water-soluble ether thereof; and(d) 0-40% by weight of water.
    Type: Grant
    Filed: May 27, 1980
    Date of Patent: November 17, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Brian L. Yates, Malcolm C. Clark
  • Patent number: 4260391
    Abstract: There is described a stable concentrated solution of a dye of the disazo class, which solution contains 15 to 30 percent by weight of the dye of the formula ##STR1## in the form of the lithium salt, optionally in admixture with up to 75 percent by weight of the sodium, potassium or ammonium salt, dissolved in 5 to 35 percent by weight of water, 2 to 10 percent by weight of pyrrolidone or of N-alkyl-(C.sub.1 -C.sub.4)-pyrrolidone and 35 to 50 percent by weight of a diethylene glycol monoalkyl ether; a process for producing this liquid preparation, and its use for dyeing and printing cellulose and regenerated cellulose, particularly however for dyeing paper.
    Type: Grant
    Filed: March 1, 1979
    Date of Patent: April 7, 1981
    Assignee: Ciba-Geigy Corporation
    Inventor: Roger Lacroix