Abstract: A gas separation method and apparatus that recovers efficiently principal gas components from a feed gas that includes a plurality of components, and enables supplying the product gases continuously at a stable flow rate and component concentration. A first separation step using a first adsorption column and a second separation step using a second adsorption column are provided, a circulating feed gas, consisting of the recovered exhaust gases discharged in each of the steps and the feed gas, is used as a gas to be separated. The outflow rate and component concentration of a second gas product are maintained constant by controlling the outflow rate of the first gas product.

Abstract: An adsorbent composition containing a modified carbonaceous material capable of adsorbing an adsorbate is disclosed, wherein at least one organic group is attached to the carbonaceous material. Furthermore, methods to increase the adsorption capacity of a carbonaceous material capable of adsorbing an adsorbate and methods to adsorb an adsorbate using the above-described adsorbent composition are also disclosed.

Abstract: Krypton and/or xenon is separated crudely from a mixture comprising oxygen and at least one rare gas selected from the group consisting of krypton and xenon in a process comprising feeding said mixture or a mixture derived therefrom to a rare gas recovery system and separating said mixture feed in said rare gas recovery system into rare gas-lean gaseous oxygen (“GOX”) and rare gas-enriched product. The process is characterized in that at least about 50 mol % of said mixture is fed to the rare gas recovery system in the gaseous phase provided that, when said mixture feed is separated by selective adsorption, the concentration of xenon in the mixture feed is no greater than 50 times the concentration of xenon in air. One advantage of a preferred embodiment of the present invention is that it can easily be retrofitted to existing pumped LOX cycle ASUs.

Abstract: The gas separation and purification process can recover efficiently a valuable gas such as krypton and xenon to be used as an atmospheric gas in a semiconductor manufacturing equipment etc. by means of PSA process. In the process for separating a valuable gas in the form of purified product from a mixed gas, used as a raw gas, containing the valuable gas by means of pressure swing adsorption process, the valuable gas is separated and purified by using as the pressure swing adsorption process a combination of equilibrium pressure swing adsorption process for separating gas components based on the difference in equilibrium adsorption and rate-dependent pressure swing adsorption process for separating the gas components based on the difference in adsorption rates.

Abstract: A pressure swing adsorption process for recovering a product gas from a feed gas, includes: supplying a pressure swing adsorption apparatus including an adsorbent composition containing activated carbon as a major ingredient, wherein the adsorbent composition and the apparatus are substantially free of zeolite adsorbents; feeding a feed gas into the pressure swing adsorption apparatus during a feed period not exceeding 20 seconds; and recovering the product gas from the pressure swing adsorption apparatus. The process and apparatus are particularly suitable for use with fuel cells and other applications requiring compact, rapid cycling systems for producing high purity hydrogen.

Abstract: Pressure swing adsorption process for the recovery of high purity oxygen from a feed gas comprising oxygen, nitrogen, and argon. The process includes a forward flow stage which comprises (a) passing the feed gas into a first adsorption zone containing an adsorbent selective for the adsorption of nitrogen over oxygen and argon, and withdrawing therefrom a nitrogen-depleted intermediate gas; (b) passing the nitrogen-depleted intermediate gas into a second adsorption zone containing an adsorbent which is selective for the adsorption of nitrogen over argon and selective for the adsorption of argon over oxygen; (c) withdrawing an oxygen-enriched product gas from the second adsorption zone; and (d) terminating the passing of feed gas into the first adsorption zone and withdrawing an oxygen-enriched depressurization gas from the second adsorption zone in the same flow direction as (c).

Abstract: A raw gas containing a gas component A with low affinity with an adsorbent and a gas component C with high affinity with the adsorbent are sequentially supplied to at least three adsorption columns, while a desorption gas containing a gas component D which differs from the gas components A and C is supplied to each of the adsorption columns other than the one to which the raw gas is being supplied. When the raw gas is supplied to the adsorption columns, the gas component A having lower affinity with the adsorbent exits the adsorption columns earlier than the gas component C having higher affinity. The gas components A and C can thus be separated from each other. When a gas including an enriched gas component A is discharged from the outlet of each adsorption column, the full amount is extracted out of the system. When a gas including an enriched gas component C is discharged from the outlet of each adsorption column, the full amount is extracted out of the system.

Abstract: A method for purifying a minority constituent and concentrating it in a majority constituent of a gas mixture that also contains one or more other minority constituent(s) employs (i) a selective permeation step, (ii) next, a purification step, and (iii) finally a concentration step. In the selective permeation step, an initial gas mixture is passed through a membrane to yield a gas mixture that is enriched in the first minority constituent. In the purifying step, the first minority constituent is absorbed by a solid adsorbent which has a strong affinity for the first minority constituent, then following an elution step, a gas mixture that contains essentially only the majority constituent and the first minority constituent is formed.

Abstract: An AgX-type zeolite having a silver exchange level of 20-70% and a Ar/O2 Henry's law selectivity ratio at 23° C. of 1.05 or greater has an optimum combination of selectivity for argon over oxygen at lower cost than higher silver exchange levels. This material can be used in oxygen VSA/PSA processes to produce oxygen at purities above 97%.

Abstract: An AgX-type zeolite having a silver exchange level of 20-70% and a Ar/O2 Henry's law selectivity ratio at 23° C. of 1.05 or greater has an optimum combination of selectivity for argon over oxygen at lower cost than higher silver exchange levels. This material can be used in oxygen VSA/PSA processes to produce oxygen at purities above 97%.

Abstract: A chromatograph includes an inlet for receiving a sample and a pressurized hydrogen gas flow and in response providing a sample/fluid mixture; a separation column located in a temperature-controlled zone for receiving the sample/fluid mixture and for providing a column effluent stream; a detector for receiving the effluent stream and for providing a detector output stream; and a gas storage system for receiving the detector output stream (and optionally a split flow and a septum purge flow in the instance of a split/splitless inlet) and for storing the received gas stream for subsequent reuse. In the preferred embodiments of the gas storage system, a plurality of metal hydride storage (MHS) systems are used.

Abstract: The present invention provides a pressure swing adsorption process. The process includes providing a pressure swing adsorption apparatus having a discharge end adsorption layer of activated carbon, feeding through the apparatus a feed gas including hydrogen, carbon monoxide and at least one of argon and oxygen, and collecting a product gas from the apparatus, wherein the product gas is high purity hydrogen. Also provided is a method for decreasing an amount of impurities in a product gas from a pressure swing adsorption process for separating hydrogen from impurities including carbon monoxide, and at least one of argon and oxygen.

Abstract: A process and an apparatus for recovering a noble gas, which can recover a noble gas exhausted from a noble gas employing system efficiently and also can supply the noble gas of a predetermined purity to the noble gas employing system and which can reduce consumption of the noble gas. In the process and apparatus for recovering a noble gas, when a noble gas contained in an exhaust gas exhausted from a noble gas employing system operated under reduced pressure is recovered, switching between introduction of the exhaust gas to a recovery system and exhaustion of the exhaust gas to an exhaust system is carried out under reduced pressure, and this switching operation is carried out depending on the content of impurity components contained in the exhaust gas or on the running state of the noble gas employing system.

Abstract: Adsorbent composites composed of microparticulate zeolites at least 90% of whose particles have a characteristic particle dimension not greater than about 0.6 micron and a macropore inert binder. The composites are useful for separating strongly adsorbed gas components from gas mixtures. Microparticulate type X zeolites composites are particularly useful for separating nitrogen or carbon dioxide from air.

Abstract: This invention is directed to the synthesis of high bulk density high gas absorption capacity adsorbents for gas storage applications. Specifically, this invention is concerned with novel gas absorbents with high gravimetric and volumetric gas adsorption capacities which are made from fullerene-based materials. By pressing fullerene powder into pellet form using a conventional press, then polymerizing it by subjecting the fullerene to high temperature and high inert gas pressure, the resulting fullerene-based materials have high bulk densities and high gas adsorption capacities. By pre-chemical modification or post-polymerization activation processes, the gas adsorption capacities of the fullerene-based adsorbents can be further enhanced. These materials are suitable for low pressure gas storage applications, such as oxygen storage for home oxygen therapy uses or on-board vehicle natural gas storage.

Abstract: A method and apparatus for testing and remediating the effects of radon infiltration in buildings. The method of this invention places fiber glass materials over radon-emitting surfaces in order to entrap radon and radon progeny. The fiber glass materials can be formed into mats having a packed geometry. Each mat has fiber bundles having several thousand individual fibers. Each fiber has an approximate diameter size of about 50 microns. The glass fiber consists of a silicon oxide glass that may be doped, for example, with trivalent cerium ions. The mats can be of any geometrical configuration, such as rectangular.

Abstract: A silica embedded metal hydride composition and a method for making such a composition. The composition is made via the following process: A quantity of fumed silica is blended with water to make a paste. After adding metal hydride particles, the paste is dried to form a solid. According to one embodiment of the invention, the solid is ground into granules for use of the product in hydrogen storage. Alternatively, the paste can be molded into plates or cylinders and then dried for use of the product as a hydrogen filter. Where mechanical strength is required, the paste can be impregnated in a porous substrate or wire network.

Abstract: Applicant has discovered a new zeolite containing composition and a process for preparing the same. The composition is unique in that the zeolite crystals making up one layer of the composition pack in a manner such that the composition is essentially continuous with no large scale voids even when the zeolite layer is <10 .mu.m thick. Thus, the present invention is directed toward a composition comprised of a porous substrate and a layer of zeolite crystals wherein said layer of zeolite crystals is a polycrystalline layer with at least 99% of said zeolite crystals having at least one point between adjacent crystals that is .ltoreq.20 .ANG. and wherein at least 90% of said crystals have widths of from about 0.2 to about 100 microns (preferably about 2 to about 50 microns) and wherein at least 75% of said crystals have a thickness of within 20% of the average crystal thickness. Preferably the composition has at most 1 Volume % voids in the zeolite layer. Use of the composition is also described.

Abstract: Krypton present in a trace amount in a gaseous oxygen/nitrogen mixture is effectively enriched by an adsorption/desorption process of the pressure variation mode using a system including at least three fixed bed adsorption columns packed with hydrogenated mordenite. At the end of adsorption operation in one column, a desorbed gas from another column is fed to the one column under substantially the same pressure as the pressure during adsorption operation for fully washing the one column. Thereafter, the one column is subject to desorption operation.

Abstract: A process system with an integrated gas storage and delivery unit comprising an adsorption-desorption apparatus, for storage and dispensing of a gas wherein the gas is dispensed by pressure differential desorption of the sorbate gas from the sorbent material. A motive fluid driver, e.g., a pump, blower, compressor, eductor, or the like, is arranged for flowing the dispensed gas to a gas-utilizing unit, such as an ion-implant unit, wastewater treatment unit, gas-liquid contacting chamber, chemical vapor deposition reactor, gas laser assembly, etc.

Abstract: A process for the recovery of carbon monoxide from a purge gas from acetic acid synthetic containing at least carbon monoxide, nitrogen and hydrogen, wherein the purge gas (6) containing at least carbon monoxide, nitrogen and hydrogen is separated into a gas fraction (11) rich in carbon monoxide and a residual gas fraction (12, 13) rich in nitrogen and hydrogen by an adsorption process (G), preferably by a pressure change absorption process, and the gas fraction (11) rich in carbon monoxide is returned upstream of the acetic acid.

Abstract: A system for recovery of adsorbed gas remaining in a used storage and dispensing vessel containing sorbent material having residual sorbate gas thereon, when the vessel is taken out of service, in which the used storage and dispensing vessel is coupled in flow communication with at least one fresh storage and dispensing vessel containing sorbent material therein having sorptive capacity for the residual sorbate gas. The fresh vessel is maintained in a first zone and the used vessel is maintained in a second zone, at temperature and/or pressure conditions relative to one another that cause the residual sorbate gas to desorb from the sorbent material in the used storage and dispensing vessel and flow into the fresh storage and dispensing vessel for sorption of the residual sorbate gas on the sorbent material in the fresh storage and dispensing vessel.

Abstract: A method and apparatus for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes.

Abstract: A system for adsorbing a plurality of contaminants from a workstream composed of a first stage open-ended activated carbon monolith adsorber, a second stage open ended activated carbon monolith adsorber downstream of the first stage. The first stage activated carbon has an average pore size that is larger than the average pore size of the second stage activated carbon.

Abstract: A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed.

Abstract: A process for removing argon from a feed gas stream comprising oxygen and argon to yield a high purity oxygen stream and the system for carrying out the process. The process includes the steps of: (a) providing a feed gas of oxygen and argon at a temperature between -30.degree. C. and 100.degree. C. and a pressure between 5 psia and 160 psia; and (b) passing the feed gas over an adsorbent bed comprising a Ag ion exchanged type X zeolite wherein at least 80% of the available ion sites are occupied by Ag such that at least a portion of the argon in the feed gas is adsorbed by the adsorbent bed thereby leaving an oxygen-enriched gas stream.

Abstract: A method of filtering a natural gas stream, at the end user's home, business or the like, in which at least a single gas appliance is located, is described in which natural gas odorants have been concentrated in the stream at sufficient levels to be a significant health hazard and/or an adverse environmental threat, such method comprising the steps of: (a) introducing the stream to a filter selected from a group that includes at least activated charcoal and/or impingement adsorbing media wherein in the odorant in the gas stream at sufficient levels to be a significant health hazard and/or an adverse environmental threat due to aperiodic loading of the network occurring as a result of dampening effects of compressor-driven equipment and multiple customer outlet usage causing the ordorant to become clumped into packets, is filtered from the gas stream and captured irrespective of mode of transport, (b) passing the filtered natural gas stream to the end user's gas appliance wherein safe use of the energy associa

Abstract: The invention relates to a method for producing ceramic composites obtained by oxidation of a parent metal to form a polycrystalline ceramic material by providing a filler having a coating of a silicon source on at least a portion of the filler different in composition from the primary composition of the filler, said silicon source possessing intrinsic doping properties. A body of molten parent metal, adjacent a mass of the filter material, reacts with an oxidant to form an oxidation reaction product which infiltrates the adjacent mass of filler, thereby forming the ceramic composite.

Abstract: A process for separation of a gas mixture containing three components, e.g. a mixture comprising hydrogen, carbon monoxide and carbon dioxide produced by steam reforming a hydrocarbon, by pressure swing adsorption is disclosed.