Abstract: Herein are disclosed adducts of amines and polycarboxylic acids, and methods of making such adducts. Such adducts can be used to remove cyanogen chloride. Also disclosed are methods of providing such adducts on supports to form filter media. Also disclosed are methods of combining such filter media with catalysts and/or with porous polymeric webs to form filter systems.

Abstract: Provided herein are adsorbents and methods of using the adsorbents to at least partially remove one or more adsorbates. In an aspect, an adsorbate within a phase is at least partially removed by providing an adsorbent material and contacting the adsorbent material with the phase having an adsorbate, to at least partially remove the adsorbate. Various adsorbents are disclosed having the chemical formula RE1-x-y-zBxB?yB?zOw, where RE is RE is a rare earth metal, B is a trivalent metal ion, B? is a transition metal ion or an alkaline earth element, B? is a transition metal ion, 0?x?0.25, 0?y?0.95, 0?z?0.75, w is a number which results in charge balance, and x+y+z<1.

Abstract: Pollution reduction processes may be incorporated with, or retrofit to fit with, existing combustion processes to assist with the reduction of pollutants produced in the combustion process. The thermal treatment of oil shale in the pollution reduction process produces kerogen, shale sorbent particles, or mixtures thereof, which may be reacted with a pollutant-containing gas or pollutant-containing gas having particulate matter entrained therein to reduce the pollutants in the gas. Apparatuses employing the processes are also disclosed.

Abstract: The adsorption of CO2 from flue gas streams using temperature swing adsorption. Adsorbent contactors are used in the temperature swing adsorption unit that contain a plurality of substantially parallel channels comprised of or coated with an adsorbent material that is selective for adsorbing CO2 from flue gas.

Abstract: A packed bed of granulated porous glass is used to purify a gas mixture comprising two gases whose boiling points or sublimation points at one atmosphere are least 10° K apart.

Abstract: An oxygen concentrator comprises a vacuum swing adsorption (VSA) gas separation system which includes a cartridge containing a mass of adsorbent material for producing oxygen, a drive which activates the gas separation system, and a power source comprising a mass. A ratio of the mass of the power source to a flow rate of oxygen produced by the oxygen concentrator is between 0.047 and 0.29 kg/LPM·hr.

Abstract: The method serves for operating an air fractionization installation for obtaining oxygen on board an aircraft, with at least two molecular sieve chambers. A part mass flow of the oxygen obtained in the respective adsorbing molecular sieve chamber is supplied for flushing a desorbing molecular sieve chamber. The quantity of the flushing oxygen led to the desorbing molecular sieve chamber is controlled by way of this.

Abstract: A method of identifying, detecting and/or chemically using NOX compounds is provided, wherein calixarene complexes are exposed to a nitrogen-oxide gas containing samples and form calixarene-nitrosonium complexes that are readily identified and detectable. Importantly, the process of forming one or more calixarene-nitrosonium (NO+) complexes is reversible. The calixarene-nitrosonium complexes dissociate upon decoloration enabling the parent calixarenes to be recovered.

Abstract: Gas supplying method and system in which effective component gas in exhaust gas can be separated and purified efficiently to be resupplied regardless of variation in the flow rate or composition of the exhaust gas and consumed gas can be replenished efficiently. In a method for collecting exhaust gas discharged from a gas using facility, separating/purifying effective component gas contained in the exhaust gas and supplying the effective component gas thus obtained to the gas using facility, the exhaust gas discharged from the gas using facility is added with a replenishing gas of the same components as the effective component gas before the effective component gas is separated and purified.

Abstract: A chemical reaction is performed with separation of the product(s) and reactant(s) by pressure swing adsorption (PSA), using an apparatus having a plurality of adsorbers cooperating with first and second valve assemblies in a PSA module. The PSA cycle is characterized by multiple intermediate pressure levels between higher and lower pressure of the PSA cycle. Gas flows enter or exit the PSA module at the intermediate pressure levels as well as the higher and lower pressure levels, entering from compressor stage(s) or exiting into exhauster or expander stages, under substantially steady conditions of flow and pressure. The PSA module comprises a rotor containing the adsorbers and rotating within a stator, with ported valve faces between the rotor and stator to control the timing of the flows entering or exiting the adsorbers in the rotor. The reaction may be performed within a portion of the rotor containing a catalyst.

Abstract: An apparatus for removing constituents from a fluid stream is provided. The apparatus includes a duct, a collection device, a sorbent injector, and an acoustic generator. The duct has a fluid passageway to receive a fluid stream having constituents. The collection device filters the fluid stream. The sorbent injector injects a sorbent in the fluid passageway of the duct. The acoustic generator generates an acoustic field in the fluid passageway of the duct to promote sorption of the constituents for collection by the collection device. Additionally, a method is provided for removing constituents from a fluid stream.

Abstract: An apparatus for separating a first gas from a mixture of the first gas and at least one second gas comprises a housing having an inlet port and an outlet port and an adsorbent which is positioned in the housing. The adsorbent comprising a carbon based foam monolith that has an affinity for the first gas. Thus, as the gas mixture flows through the housing, the first gas will be adsorbed onto the adsorbent and the second gas will exit the housing through the outlet port. In this manner, the first gas is separated from the second gas.

Abstract: A product pump for pumping separated product gas from an oxygen concentrator which produces oxygen-rich product gas by utilizing a vacuum swing adsorption (VSA) process. The oxygen concentrator comprises a cartridge containing an adsorbent material for separating the product gas from ambient air, a vacuum pump which provides a vacuum source, a valve for selectively connecting the vacuum pump to the cartridge and product pump, and a reservoir. The product pump comprises a pumping chamber having a product gas inlet and a product gas outlet, a piston movable in the chamber, a vacuum inlet in the chamber on an opposite side of the piston from the product gas inlet and outlet for providing a vacuum to cause the piston to draw product gas through the product gas inlet into the chamber, and a spring for providing a spring force to force the product gas out the product gas outlet.

Abstract: Process for purifying or separating a gas or gas mixture using a monolithic adsorbent for the separation or purification of gases or gas mixtures, having a cellular structure with open porosity in the form of a solid foam permeable to the gas molecules. The gas phase of the adsorbent possesses an essentially convex structure and the solid phase an essentially concave structure. The solid foam has a density of greater than or equal to 500 kg/m3 and an open porosity of between 20 and 60%. The gas is air or an H2/CO mixture. The process is of the VSA, PSA or TSA type. This process can be used in particular in OBOGS-type systems to supply passengers of the vehicle or a device participating in the traction of the vehicle and/or in its electrical supply, in particular a fuel cell. This process can also be used in medical oxygen concentrators.

Abstract: A pivoting vane rotary compressor includes a housing having a generally pear-shaped chamber. A rotor mounted within the chamber defines a main and constricted chamber regions. Reversible intake and exhaust ports alternately introduce air into and exhaust air from the chamber. The rotor carries pivotable vanes and a motor drives the rotor alternately in opposing first and second directions to open the vanes and define compartments that transmit the air through the chamber between the ports. Air introduced through one of the ports is compressed and discharged through the other port. A concentrator employs a pair of these compressors as well as associated filters and crossover valves.

Abstract: A method is described for rapid and economical activation and/or preconditioning of gas purification substrates by providing forced convection of the preconditioning or activating gas through the pores of the substrate. The gas is pumped into the substrate-containing vessel and raised to an elevated pressure, which is maintained for a short predetermined time, followed by venting of contents of the vessel. The vessel is again pressurized with the purging gas to an elevated level, and the elevated pressure is maintained for a short predetermined time, followed by venting of the vessel. This cycle is repeated as often as needed or desired. Activation and/or preconditioning can be accomplished in a much shorter time and with much less gas usage compared to diffusion preconditioning and activation processes. This process is particularly suited for preconditioning and activation of gas purifier substrates for decontamination of gases down to ?1 ppm contaminants.

Abstract: An adsorbent composition containing a modified carbonaceous material capable of adsorbing an adsorbate is disclosed, wherein at least one organic group is attached to the carbonaceous material. Furthermore, methods to increase the adsorption capacity of a carbonaceous material capable of adsorbing an adsorbate and methods to adsorb an adsorbate using the above-described adsorbent composition are also disclosed.

Abstract: A process for removal of ethylene oxide (EO) from ambient air laden with EO is passed through a zeolite-based removal media, which preferrably consists of the acid form of zeolite ZSM-5, herein referred to as “H-ZSM-5.” The process described herein may be applied to many forms, configurations and uses, such as, for example, gas masks, fume hood ventilation filters, cartridge filters, etc. Preferably, the H-ZSM-5 is configured within an apparatus in such a manner that the stream containing EO is brought into sufficient contact with the zeolite to remove the EO from the airstream.

Abstract: The invention relates to ammonia synthesis loops containing gases, which do not react and would accumulate if they were not purged out. By the present invention ammonia in a purge gas is recovered by an absorption agent operating at the full synthesis loop pressure. The absorption agent is chosen in such a way that the ammonia can be removed again by passing a gas comprising hydrogen and nitrogen through it at the same elevated pressure as the loop pressure. This enables the adsorption agent to be regenerated by fresh synthesis gas coming from the synthesis gas compressor just before this gas enters the synthesis loop. Thereby, the regeneration requires an absolute minimum of energy consumption and equipment.

Abstract: The present invention is to provide a method for regenerating inorganic porous particles, a method for purifying water and a continuous water purification device, which can be easily applied as a recycling system of water in special environments such as space environment, by safely removing impurities contained in water and water vapor with a usage of a compact facility without using any chemicals. The method for regenerating inorganic porous particles is characterized in that adsorbed products such as ammonia and/or amines, are reduced by heating to 100-200° C. under a reduced pressure of 10 Pa or less. The method for purifying water and the continuous water purification device are characterized in that a dense membrane having cationic groups and/or a composite membrane in which a hydrophilic membrane is layered on a surface of a hydrophobic porous membrane is used as a permeable membrane are used as a permeable membrane.

Abstract: Method and system on board an aircraft for the production of an oxygen-enriched gas stream from an oxygen/nitrogen gas mixture, particularly air, comprising at least one adsorber containing at least one adsorbent for adsorbing at least some of the nitrogen molecules contained in the oxygen/nitrogen feed mixture, characterized in that the said adsorbent comprises a faujasite-type zeolite, having an Si/Al ratio of 1 to 1.50, exchanged to at least 80% with lithium cations. Aircraft equipped with such a system, in particular an airliner, especially an airliner of the long-range, large-capacity type.

Abstract: A method is described for rapid and economical activation and/or preconditioning of gas purification substrates by providing forced convection of the preconditioning or activating gas through the pores of the substrate. The gas is pumped into the substrate-containing vessel and raised to an elevated pressure, which is maintained for a short predetermined time, followed by venting of contents of the vessel. The vessel is again pressurized with the purging gas to an elevated level, and the elevated pressure is maintained for a short predetermined time, followed by venting of the vessel. This cycle is repeated as often as needed or desired. Activation and/or preconditioning can be accomplished in a much shorter time and with much less gas usage compared to diffusion preconditioning and activation processes. This process is particularly suited for preconditioning and activation of gas purifier substrates for decontamination of gases down to ≦1 ppm contaminants.

Abstract: The invention relates to ammonia synthesis loops containing gasses, which do not react and would accumulate if they were not purged out. By the present invention ammonia in a purge gas is recovered by an adsorption agent operating at the full synthesis loop pressure. The adsorption agent is chosen in such a way that the ammonia can be removed again by passing a gas comprising hydrogen and nitrogen through it at the same elevated pressure as the loop pressure. This enables the adsorption agent to be regenerated by fresh synthesis gas coming from the synthesis gas compressor just before this gas enters the synthesis loop. Thereby, the regeneration requires an absolute minimum of energy consumption and equipment.

Abstract: Commonly available carbon dioxide may contain unacceptable amounts of compounds containing greater than about ten carbon atoms, sulfur-containing materials, and nitrogen-containing materials which are particularly detrimental to semiconductor and silicon wafer processing-related uses of carbon dioxide. These impurities can be effectively removed by a combination of metal oxide, silica gel, and activated carbon, thus permitting an on-site, on-demand, convenient, and economic method of purifying carbon dioxide ranging from laboratory scale operations to tank car scale operations.

Abstract: A process for the purification of a gaseous hydrogen flow containing one or more gaseous impurities from the group consisting of carbon monoxide, water vapor, nitrogen, H2S, chlorine, C1-C3 light alcohols, ammonia, carbon dioxide and linear, branched or cyclic hydrocarbons, saturated and unsaturated, C1-C8. The hydrogen flow is placed in contact with a porous carbonated adsorbent having an adsorption limit volume (W0) and an energy parameter of (E0) according to the Dubinin relationship, such that: 0.18 ml.g−1≦W0≦1.50 ml.g−1 and 15 kJ.mole−1≦E0≦45 kJ.mole−1. The porous carbonated adsorbent is selected from active carbons. The gas rich in hydrogen is a reforming gas, an electrolysis gas, a gas from ammonia cracking or from alcohol cracking.

Abstract: The present invention relates to a fresh air filter that comprises a highly air-permissive two- or three-dimensional support made of a cross-linked polymeric foam which includes pores of large dimensions. The support comprises joining portions which are coated with a layer of ion-exchange globules.

Abstract: A process for treating NF3 useful as a dry etching gas and cleaning gas in processes for producing LSI, TFT, and solar cell and in an electron photographic processes.

Abstract: Provided are a system and method for nitrous oxide purification, wherein the nitrous oxide product for use in semiconductor manufacturing. The system and process involve a first sub-system having a purification tank for holding a liquefied nitrous oxide, therein; a vaporizer in communication with the purification tank to receive, vaporize and convey a nitrous oxide vapor back to the purification tank; a distillation column disposed on a distal end of the purification tank to receive a nitrous oxide vapor; a condenser disposed on the distillation column, wherein light impurities are removed and wherein a nitrous oxide devoid of light impurities is conveyed and converted into vapor in the vaporizer. A second sub-system having a first dry bed vessel is disposed downstream of the vaporizer to receive the vapor and reacting the acid gas therein; a second dry bed vessel downstream of the first dry bed vessel for removing water and ammonia in the vapor.

Abstract: The present invention provides for a multi-composite adsorbent mixture which will remove H2O, CO2 and nitrogen oxides and/or hydrocarbons from a feed gas stream. The improvement lies in the use of a third adsorbent which is selective for nitrogen oxides, hydrocarbons or both.

Abstract: Activated carbon filters containing transition metals, are prepared by (a) exchanging the transition metal with a cellulose ion exchange material to produce a cellulose material containing the transition metal; (b) charring of the product of (a); activating the product of (b) to form an activated carbon filter having a pore network throughout; and removing surface carbon substantially throughout the pore network of the filter formed in (c). Methods of filtering an atmosphere containing a gaseous contaminant by passing the contaminated atmosphere through a filter made by this process are described.

Abstract: A method and a device for selective catalytic NOx reduction in oxygen-containing exhaust gases using ammonia and a reduction catalyst (9) are described, according to which gaseous ammonia is made available by heating a solid storage medium (2) in a container (1). The method and the device are suitable for use in motor vehicles in particular.

Abstract: Apparatus, materials, and methods for removing ammonia from fluids using metal hydroxides (e.g. zinc hydroxide) and metal loaded media (e.g. zinc loaded ion exchange resins); the metal hydroxides and metal loaded media may be regenerated with a weak acid (pKa between 3 and 7). Alternatively, ammonia is removed from fluids by using H2SO4 and ZnSO4 and metal loaded media; the metal loaded media may be regenerated with H2SO4 and ZnSO4; the ammonia containing H2SO4 and ZnSO4 may be concentrated as necessary to form (NH4)2SO4.ZnSO4.6H2O (ammonium zinc sulfate hexahydrate) crystals. These crystals are removed from the mother liquor and heated to temperatures exceeding 200° C. releasing NH3 and H2O vapor upon the decomposition of the crystals.

Abstract: The invention relates to a process for the purification of a gas stream containing one or more gaseous impurities from the group formed by carbon dioxide, water vapor, H2S, alcohols, S02 and C1-C8 saturated or unsaturated, linear, branched or cyclic hydrocarbons. The gas stream is brought into contact with several different porous carbon adsorbents, that is to say active carbons having different properties and characteristics. The gas is air, nitrogen, hydrogen produced by the reforming or cracking of ammonia or the cracking of alcohols or hydrocarbons, natural gas, combustion gas or fermentation gas.

Abstract: There are disclosed a process for recovering ammonia which comprises installing a shell and multi-tube adsorber which is equipped with plural adsorption tubes each packed inside with an ammonia adsorbent (e.g. synthetic zeolite) and equipped with a flow mechanism for a heat transfer medium for performing heat exchange through the adsorption tubes, passing an ammonia-containing gas through the adsorption tubes, while cooling the adsorbent with a heat transfer medium (e.g. water) to adsorb the ammonia, and thereafter collecting the adsorbed ammonia through desorption, while heating the adsorbent with a heat transfer medium (e.g. hot water) under reduced pressure; and an apparatus for the above process.

Abstract: A sorber heat exchanger is provided with a substrate material incorporating a sorbent for reacting with a polar gas refrigerant or hydrogen. A preferred sorbent is a metal salt capable of reacting with the polar gas refrigerant to form a complex compound. The sorbent incorporating substrate is loaded into the reactor space between the heat transfer surfaces. Incorporating the sorbent into the substrate reduces sorbent migration thereby improving performance and life expectancy of the heat exchanger.

Abstract: A CVD device A is provided which is equipped with a gas introduction part A3 having an inert gas supply part G1 for supplying a diluting inert gas and a cleaning gas supply path G2 for supplying a cleaning gas, each connected therewith, and equipped with an exhaust gas discharge part A4 for releasing an exhaust gas; an exhaust gas circulation part D1 for circulating an exhaust gas from the CVD device, a cooling part D4 for cooling down and liquefying the cleaning gas in the exhaust gas, and a recovery part 4 for recovering the cleaning gas liquefied in said cooling part D4; the diluting inert gas is composed of a gas having a boiling point lower than that of the cleaning gas; a supply part 6 for supplying a cooling inert gas having the same composition as the diluting inert gas in a liquid state, an inert gas circulation part D3 which is cooled down by heat of evaporation of the cooling inert gas, and an inert gas discharge part 7 for discharging the cooling inert gas evaporated in the inert gas circulation p

Abstract: A process for recovering volatile, generally bad smelling low molecular, low polar substances called VLC, contained in gas streams, by capturing the same by in contacting the gaseous environment with a calixarene or a resorcinol calixarene present in the form of particles, granules, as a coating or impregnation on or in a solid support, or as an organic or aqueous solution.

Abstract: This invention is directed to the synthesis of high bulk density high gas absorption capacity adsorbents for gas storage applications. Specifically, this invention is concerned with novel gas absorbents with high gravimetric and volumetric gas adsorption capacities which are made from fullerene-based materials. By pressing fullerene powder into pellet form using a conventional press, then polymerizing it by subjecting the fullerene to high temperature and high inert gas pressure, the resulting fullerene-based materials have high bulk densities and high gas adsorption capacities. By pre-chemical modification or post-polymerization activation processes, the gas adsorption capacities of the fullerene-based adsorbents can be further enhanced. These materials are suitable for low pressure gas storage applications, such as oxygen storage for home oxygen therapy uses or on-board vehicle natural gas storage.

Abstract: Pelletized adsorbent compositions and methods of adsorbing toxic target compounds are provided for the destructive adsorption or chemisorption of toxic or undesired compounds. The pelletized adsorbents are formed by pressing together powder nanocrystalline particles comprising a metal hydroxide or a metal oxide at pressures of from about 50 psi to about 6000 psi to form discrete self-sustaining bodies. The pelletized bodies should retain at least about 25% of the surface area/unit mass and total pore volume of the starting metal particles.

Abstract: This invention relates to the manufacture of a molecular sieve adsorbent for selectively separating methane from its gaseous mixture with nitrogen. More particularly, the invention relates to the manufacture of novel molecular sieve adsorbents useful for the separation of methane-nitrogen gaseous mixture.

Abstract: A fluid storage and dispensing system, comprising: a fluid storage and dispensing vessel constructed and arranged for selective dispensing of fluid therefrom; a solid-phase support in the vessel; and an affinity medium on the solid-phase support, wherein the affinity medium reversibly takes up the fluid when contacted therewith, and from which the fluid is disengagable under dispensing conditions. The affinity medium may be a liquid, oil, gel, or solid (porous solid, thin film solid, or bulk solid). The system of the invention may be employed for the storage and dispensing of fluids such as hydride, halide and dopant gases for manufacturing of semiconductor products.

Abstract: A gas phase adsorption process in which a gas phase containing water vapor or a basic gas is brought into contact with activated carbon fiber to adsorb the water vapor or basic gas. The activated carbon fiber comprises pitch-based oxidized activated carbon fiber having oxygen-containing functional groups and an oxygen content of 3-18% by weight, based on the weight of the fiber. The oxidized activated carbon fiber is prepared by oxidizing pitch-based activated carbon fiber having a specific surface area of 200-2500 m.sup.2 /g.

Abstract: A process for the separation of ammonia dissolved in a gaseous solvent is used to recover ammonia during the production of ammonia from a synthesis gas. The process may be used to extract and recover ammonia in either the supercritical region or the subcritical region. The process can be used to remove ammonia from synthesis gas, or other gaseous solvents, by removing ammonia whose chemical potential decreases as the density of the solvent increases. The process utilizes a sorbent to remove the ammonia followed by an in situ regeneration of the sorbent and recovery of the ammonia. Typically, a gaseous solvent containing the ammonia is passed through a bed of sorbent to sorb the ammonia onto the bed of sorbent, thereby producing a purified gaseous solvent. At least a portion of the gaseous solvent is then acted upon to increase its solvent capacity for the ammonia.

Abstract: A process for removing nitrogen oxides, as well as water and carbon dioxide, from gas streams containing at least 0.2 ppm by volume of nitrogen oxides by passing the gas stream through an alumina adsorbent and a zeolite adsorbent, preferably 13X-zeolite. The process has utility in front end cleanup of air prior to cryogenic distillation of the air where nitrogen oxides would otherwise freeze under the cryogenic processing.

Abstract: Disclosed is an ammonia adsorption apparatus for removing ammonia contained in a treated gas discharged from a denitrator for decomposing nitrogen oxides present in exhaust gas using ammonia as a reducing agent, comprising at least two adsorption towers into which ammonia-containing exhaust gas is introduced in a vertical direction for removing the ammonia by adsorption, wherein, during regeneration of each adsorption tower, hot gas used for desorption purposes flows from a top toward a bottom of the adsorption tower and cooling gas flows from the bottom toward the top of the adsorption tower.

Abstract: Processes and systems to recover at least one perfluorocompound gas from a gas mixture are provided. In one embodiment the inventive process comprises the steps of a) providing a gas mixture comprising at least one perfluorocompound gas and at least one carrier gas, the gas mixture being at a predetermined pressure; b) providing at least one glassy polymer membrane having a feed side and a permeate side; c) contacting the feed side of the at least one membrane with the gas mixture; d) withdrawing from the feed side of the membrane as a non-permeate stream at a pressure which is substantially equal to the predetermined pressure a concentrated gas mixture comprising essentially the at least one perfluorocompound gas; and e) withdrawing from the permeate side of the membrane as a permeate stream a depleted gas mixture comprising essentially the at least one carrier gas.

Abstract: The present invention is directed to a catalytic process for the synthesis of ammonia in an ammonia synthesis reactor wherein a dilute ammonia stream is withdrawn from the reactor and subjected to a treatment step to concentrate ammonia adsorbed (or extracted) from said dilute ammonia stream.Specifically, the invention is an improvement in the ammonia concentration treatment step. This improvement includes passing the dilute ammonia stream from the reactor into an adsorber in which is housed particulate adsorbent effective in adsorbing ammonia from the dilute ammonia stream passed through the adsorber. Desirably, adsorber conditions include a pressure close to those prevailing in the dilute ammonia stream withdrawn from the reactor with the temperature being as low as that of the feed to the reactor. Next, an effluent stream diminished in ammonia content is withdrawn from the adsorber. Finally, enriched ammonia is recovered from the adsorber.

Abstract: A method and apparatus for the purification and collection of hydrogen isotopes in a flowing inert gaseous mixture containing impurities, wherein metal alloy getters having the capability of sorbing non-hydrogen impurities such as oxygen, carbon dioxide, carbon monoxide, methane, ammonia, nitrogen and water vapor are utilized to purify the gaseous mixture of impurities. After purification hydrogen isotopes may be more efficiently collected. A plurality of parallel process lines utilizing metal getter alloys can be used to provide for the continuous purification and collection of the hydrogen isotopes.

Abstract: An apparatus capable of providing rapid cooling and/or freezing comprises a cabinet or container having a cooling chamber, one or more reactors each containing a complex compound formed by adsorbing a polar gas on a metal salt, in which the polar gas is alternately adsorbed and desorbed on the complex compound, and in which the complex compound is formed by restricting the volumetric expansion and controlling the density during adsorption of the polar gas on the metal salt, whereby the complex compound is capable of adsorbing said polar gas at a rate of greater than 15 moles per mole hour of the complex compound in about 20 minutes or less, a condenser for condensing the polar gas, an evaporator thermally exposed to the cooling chamber for providing cooling therein, and conduits and one or more valves for directing said polar gas from the one or more reactors to the condenser, from the condenser to the evaporator and from the evaporator to the one or more reactors.

Abstract: The present invention relates to the separation of one or more components from a multi-component gaseous stream. The component(s) being separated are relatively small molecular diameter gas components. They are separated by sorption techniques wherein the sorbent is a unique class of layered nanostructure materials, such as carbon nanofibers, characterized as having; (i) a surface area from about 0.2 to 3,000 m.sup.2 /g as determined by N.sub.2 adsorption at -196.degree. C., (ii) a crystallinity from about 5% to about 100%, and (iii) interstices from about 0.335 nm to about 0.67 nm.