Abstract: A process for removing halogen compounds, particularly chlorine compounds, from a process fluid, includes the steps of (i) passing a process fluid containing hydrogen halide over a first sorbent to remove hydrogen halide and generate a hydrogen halide depleted process fluid and then, (ii) passing the hydrogen halide depleted process fluid over a second different sorbent to remove organic halide compounds therefrom. A purification system suitable for removing hydrogen halide and organic halide compounds from process fluids is also described.

Abstract: A method and system for waste water treatment and disposal includes the use of a sealed chamber having a plurality of sealed light transmitting windows and a relatively large basin connected to the chamber by a large multi-channel conduit. A large fan exhausts gases, humidity and odor from the chamber into a lower portion of the basin. An upper portion of the basin includes a multi-layer grid including layers of hydro stones and/or artificial hydro stones, sand, fertilizer and earth together with a plurality of shallow rooted trees. Any carbon dioxide produced by the waste water is ultimately converted to oxygen.

Abstract: The reaction exhaust gas from which chlorosilanes and hydrogen chloride have been removed in a hydrogen chloride absorption unit (30) is introduced to an adsorption unit (50) to recover a purified hydrogen (S105). Activated carbon is packed in the adsorption unit (50), the gas, which is mainly composed of hydrogen, is passed through the activated carbon-packed layer during which unseparated chlorosilanes, hydrogen chloride, nitrogen, carbon monoxide, methane, and monosilane contained in the gas are adsorbed on the activated carbon and removed from the gas, and thereby the purified hydrogen is obtained. Nitrogen, carbon monoxide, methane and monosilane are a compressed gas in the state of adsorption, whereas hydrogen chloride and chlorosilanes are a liquid in the state of adsorption, and require a vaporization heat during desorption. Using these properties, the separation of hydrogen chloride and chlorosilanes from other impurity components is possible merely by separating the pathways for the desorbed gas.

Abstract: An apparatus and a method for recovery of sulfur hexafluoride is provided. Sulfur hexafluoride (SF6) may be separated with high-concentration and improved recovery ratio through a multi-stage separation and recovery processes using a plurality of separation membrane modules, and as well, SF6 gas may be concentrated to maximize the SF6 recovery ratio before the separation and recovery processes through the separation membrane modules. Furthermore, sulfur dioxide (SO2) and moisture included in the SF6 waste gas may be removed effectively so as to extend the service life of the separation membrane modules.

Abstract: Embodiments of the present disclosure provide for collection devices, methods of making collection devices, methods of collecting gases and aerosol particles, and the like.

Abstract: With a method and a system for treatment of a hot crude gas generated by an entrained flow gasification system, removal of the compounds that contain sulfur and carbon is supposed to be undertaken in such a manner that hot gas is made available for further use. This is achieved in that a desulfurization (7) follows the gasifier (2), in series, in the flow path of the hot gas, followed by a solid separation (8, 9), whereby behind the solid separation (8, 9), a partial stream (13) of the gas is provided downstream by way of a water quench (14), a Venturi scrubber (15), a crude gas cooler (16), as well as an H2O separation (17) and a compressor (18), the flow path (19) of which is passed back, cooled, into the circuit, behind the gasification (2) and ahead of the desulfurization system.

Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.

Abstract: A method for making a slow releasing device for slowing releasing chlorine dioxide includes sending gaseous chlorine dioxide into a receiving container containing a plurality of particulate carriers. Each particulate carrier has a plurality of pores in a surface thereof. The receiving container is placed in a low-temperature environment below 30° C. The gaseous chlorine dioxide is absorbed by the particulate carriers. The particulate carries is packaged in at least one container that is subsequently sealed. The gaseous chloride dioxide can be purified before entering the receiving container. Superfluous chloride dioxide can be dissolved or absorbed in water in an absorbing tank on a circulating pipeline connected to the receiving container via an outlet pipe.

Abstract: A method for the purification of a feed gas stream containing CO2 and water and at least one impurity chosen from NOx and SOx, comprising the incorporation of a purification step for the preferential elimination of water is provided.

Abstract: A filter for filtering a fluid in a substrate processing apparatus comprises first and second stages that are connected to one another. A delivery system provides a vaporized liquid to the filter. The first stage of the filter comprises a basic compound, and the second stage of the filter comprises a desiccant. A second filter comprises a permeation filter with permeable membrane to filter the fluid. Methods of filtering the fluid to reduce formation of undesirable process residues using the filter(s) are also described.

Abstract: The reaction exhaust gas from which chlorosilanes and hydrogen chloride have been removed in a hydrogen chloride absorption unit (30) is introduced to an adsorption unit (50) to recover a purified hydrogen (S105). Activated carbon is packed in the adsorption unit (50), the gas, which is mainly composed of hydrogen, is passed through the activated carbon-packed layer during which unseparated chlorosilanes, hydrogen chloride, nitrogen, carbon monoxide, methane, and monosilane contained in the gas are adsorbed on the activated carbon and removed from the gas, and thereby the purified hydrogen is obtained. Nitrogen, carbon monoxide, methane and monosilane are a compressed gas in the state of adsorption, whereas hydrogen chloride and chlorosilanes are a liquid in the state of adsorption, and require a vaporization heat during desorption. Using these properties, the separation of hydrogen chloride and chlorosilanes from other impurity components is possible merely by separating the pathways for the desorbed gas.

Abstract: Purified SiHCl3 and/or SiCl4 are used as a sweep gas across a permeate side of a gas separation membrane receiving effluent gas from a polysilicon reactor. The combined sweep gas and permeate is recycled to the reactor.

Abstract: A method and apparatus for simultaneously removing alkali chlorides from an industrial process and purifying vaporizable contaminants such as mercury from a particulate material. Gases containing alkali chlorides are cooled to a temperature above the boiling point of the contaminants and below the boiling point of the alkali chlorides. Particulates rich in alkali chlorides are removed from the gas stream with a first dust collector. The gas stream cleaned of alkali chlorides is directed to a reaction area where particulate material containing mercury contaminants is inserted into the gas stream to vaporize the contaminants from the material and entrain the cleaned material in the gases. The gases are directed to a second dust collector to remove the entrained particulate material, after which a sorbent or chemical reagent is injected in the gases to interact with the contaminants and form a contaminant containing product that is entrained in the gases and thereafter separated from the gases.

Abstract: Dry-scrubbing media compositions, methods of preparing same, and methods of use are provided. The compositions contain activated alumina and potassium carbonate. Optionally, activated carbon and other impregnates, such as sulfates of group 1A metals, are included in the compositions. The compositions exhibit improved efficiency and capacity for the removal of compounds such as chlorine or sulfur dioxide from an air-stream. The compositions are particularly useful for reducing or preventing the release of toxic gaseous compounds from the areas such as petroleum storage areas, refineries, drinking water systems, sewage treatment facilities, swimming pools, hospital morgues, animal rooms, and pulp and paper production sites.

Abstract: A method for removing negatively-charged gas molecules includes the steps of: adsorbing negatively-charged gas molecules by a substrate carrying a positively-charged substance or a positively-charged substance and a negatively-charged substance on the surface of the substrate or in a surface layer of the substrate; and desorbing the aforementioned negatively-charged gas molecules adsorbed on the aforementioned substrate, from the substrate using a fluid. According to the present invention, negatively-charged gas molecules are removed or detoxified by adsorbing the same by a substrate carrying a positively-charged substance, or a positively-charged substance and a negatively-charged substance, on the surface of the substrate. Thereby, it is possible to provide a simple process by which negatively-charged gas molecules are able to be effectively and economically removed or detoxified.

Abstract: The invention provides a water gas shift process comprising a reaction stage. The reaction stage comprises (a) providing a gas mixture comprising CO, H2O and an acid gas component to a reactor containing an adsorbent, and (b) subjecting the gas mixture to water gas shift reaction conditions to perform the water gas shift reaction. The adsorbent comprises an alkali promoted alumina based material. The acid gas component comprises H2S.

Abstract: The disclosure provides methods and systems for sequestering and/or reducing sulfur oxides, nitrogen oxides and/or carbon dioxide present in industrial effluent fluid streams. A solid particulate material comprising a slag component, a binder component (distinct from the slag component), and optionally water is formed and then contacted with the effluent fluid stream to reduce at least one of the sulfur oxides, nitrogen oxides, and/or carbon dioxide. The contacting of the effluent stream may occur in a packed bed reactor with the solid dry particulate material. Methods of reducing pollutants from exhaust generated by combustion sources, lime and/or cement kilns, iron and/or steel furnaces, and the like are provided.

Abstract: The method for reducing organic chlorine compounds in the cement production facility of the present invention is a method for reducing organic chlorine compounds in cement production facility by which a quantity of organic chlorine compounds contained in cement raw materials is reduced in the cement production facility, which is provided with an organic matter adsorbing step in which an adsorbing powder is supplied into exhaust gas generated on calcination of cement clinker from the cement raw materials, thereby the organic chlorine compounds are adsorbed on the adsorbing powder and an adsorbing-powder removing step in which the adsorbing powder, which has adsorbed the organic chlorine compounds, is collected, thereby removing the adsorbing powder from the exhaust gas.

Abstract: An adsorptive filter material for the adsorption of acids or acid forming substances from the air is presented, which comprises an ion exchange material. The ion exchange material comprises a strong alkaline anion exchange resin with a ratio of at least 60% in the hydrogencarbonate form and a cation exchange resin in the H form with a ratio of not more than 15%.

Abstract: A process is provided for separating one or more light gases from bromine or chlorine using one or more physical separations and contact with a chemical scrubber to recover additional halogen. In one aspect, the process comprises (a) providing a feed of halogen containing one or more light gases to a distillation column or flash vaporizer; (b) operating the distillation column or flash vaporizer to separate the feed into (i) a first liquid containing a major amount of halogen and no more than a minor amount of light gas(es), and (ii) a first vapor containing a major amount of light gas(es) and no more than a minor amount of halogen; and (c) providing the vapor to a chemical scrubber to recover halogen from the vapor.

Abstract: The present disclosure relates to a method for purifying exhaust gases from a waste incineration plant by utilizing a sorption method in a circulating fluidized bed. According to the disclosure, the mass flow of the supplied fresh sorbent is regulated as a function of the concentration of fresh sorbent and/or at least one sorbed pollutant in the recirculated solid matter.

Abstract: A method and apparatus for adsorbing perchlorate in a fluid and successively destroying it. Perchlorate in the fluid is removed by adsorption on an adsorbent in a column. The adsorbent is then regenerated by desorbing perchlorate, and the perchlorate in the regenerant is then chemically destroyed.

Abstract: Wide mesoporous alumina composites are produced by an “in situ reaction” route comprising agglomeration of an alumina powder that is capable of rehydration together with a second reactive powder such as carbonate. In one method of production, the powders are fed to a rotating forming device that is continuously sprayed with liquid under conditions to form particulates. The discharging beads are then subjected to curing and thermal activation to produce the final catalyst or adsorbent. The alumina participates in a pore altering process involving the carbonate component upon formation of hydroxycarbonate intermediates such as Dawsonite. Large fraction of the pore volume of the final product consists of wide mesopores in the 15-50 nanometers range. The alumina composites exhibit a characteristic trimodal pore structure that includes also small micro-meso pores and macropores larger than 200 nanometers.

Abstract: A novel regenerable composition for removing hydrogen chloride and hydrogen sulfide from a gas stream, the sorbent comprising a mixture containing from about 5 wt % manganese oxide to about 99 wt. % manganese oxides where manganese can exist in various oxidation states.

Abstract: A process and apparatus is provided for the purification of binary halide fluid. The process and apparatus purifies the binary halide fluid by selectively removing Bronsted acid impurities and/or volatile oxygen containing impurities present in the binary halide. A regenerable adsorbent polymer is utilized to remove the Bronsted acid impurities from the binary halide fluid and a volatile oxide adsorbent having a specific adsorption capacity for the volatile oxide impurity is utilized to remove the volatile oxide from the binary halide when in gaseous form.

Abstract: Methods and apparatuses are described for removing a contaminant, such as a vaporous trace metal contaminant like mercury, from a gas stream. In one embodiment, a primary particulate collection device that removes particulate matter is used. In this embodiment, a sorbent filter is placed within the housing of the primary particulate collection device, such as an electrostatic precipitator or a baghouse, to adsorb the contaminant of interest. In another embodiment, a sorbent filter is placed within or after a scrubber, such as a wet scrubber, to adsorb the contaminant of interest. In some embodiments, the invention provides methods and apparatuses that can advantageously be retrofit into existing particulate collection equipment. In some embodiments, the invention provides methods and apparatuses that in addition to removal of a contaminant additionally remove particulate matter from a gas stream.

Abstract: The instant application provides apparatus and methods for the generation of chlorine dioxide. The methods and apparatus of the invention use a water dissolvable membrane to allow the reaction of precursor chemicals, e.g., chlorite salt and an acid. The methods and compositions of the invention provide chlorine dioxide for a number of personal and commercial applications.

Abstract: Method for the process-integrated gas purification of a synthesis gas, including the following steps: gasification of the feed in a reactor by the use of pulse heaters; addition of additives to the reactor or to the gas section downstream of the reactor in order to remove sulphur-containing gas components in order to achieve in-situ removal; separation of dust content of the synthesis gas in the downstream gas section; recycling of the dust content separated off to the reactor.

Abstract: Pollution reduction processes may be incorporated with, or retrofit to fit with, existing combustion processes to assist with the reduction of pollutants produced in the combustion process. The thermal treatment of oil shale in the pollution reduction process produces kerogen, shale sorbent particles, or mixtures thereof, which may be reacted with a pollutant-containing gas or pollutant-containing gas having particulate matter entrained therein to reduce the pollutants in the gas. Apparatuses employing the processes are also disclosed.

Abstract: The present invention relates to adsorbent honeycomb monoliths and other porous monoliths impregnated with alkaline and/or caustic salts of alkaline metal or alkaline earth metal. The impregnated monoliths have high adsorption capacity and low flow resistance, yet with minimized flammability, suitable for use in removal of acidic, malodorous and/or harmful gases.

Abstract: The present disclosure relates to a method for purifying exhaust gases from a waste incineration plant by utilizing a sorption method in a circulating fluidized bed. According to the disclosure, the mass flow of the supplied fresh sorbent is regulated as a function of the concentration of fresh sorbent and/or at least one sorbed pollutant in the recirculated solid matter.

Abstract: Disclosed herein are articles for removing contaminants from a fluid, such as a liquid or gas, the article comprising carbon nanotubes, which comprise at least one molecule or cluster attached thereto or located therein, wherein the carbon nanotubes are present in the article in an amount sufficient to reduce the concentration of contaminants in fluid that come into contact with the article. A method of making the nanomesh material used in such articles is also disclosed, as are methods of purifying fluids using these articles.

Abstract: Dry-scrubbing media compositions, methods of preparing same, and methods of use are provided. The compositions contain activated alumina and potassium carbonate. Optionally, activated carbon and other impregnates, such as sulfates of group 1A metals, are included in the compositions. The compositions exhibit improved efficiency and capacity for the removal of compounds such as chlorine or sulfur dioxide from an air-stream. The compositions are particularly useful for reducing or preventing the release of toxic gaseous compounds from the areas such as petroleum storage areas, refineries, drinking water systems, sewage treatment facilities, swimming pools, hospital morgues, animal rooms, and pulp and paper production sites.

Abstract: An apparatus and process for abating at least one acid or hydride gas component or by-product thereof, from an effluent stream deriving from a semiconductor manufacturing process, comprising, a first sorbent bed material having a high capacity sorbent affinity for the acid or hydride gas component, a second and discreet sorbent bed material having a high capture rate sorbent affinity for the same gas component, and a flow path joining the process in gas flow communication with the sorbent bed materials such that effluent is flowed through the sorbent beds, to reduce the acid or hydride gas component. The first sorbent bed material preferably comprises basic copper carbonate and the second sorbent bed preferably comprises at least one of, CuO, AgO, CoO, CO3O4, ZnO, MnO2 and mixtures thereof.

Abstract: A method for removing a halogen series gas, which comprises contacting a gas containing a halogen series gas forming at least one kind selected from the group consisting of HF, HCl, HBr and HI by water with a granule containing from 60 to 99.9 mass % of a solid base and from 0.1 to 40 mass % of a carbonaceous material to the total mass amount of the granule in the presence of water.

Abstract: The collecting filter can capture and collect various chlorinated organic compounds in both particulate form and gaseous form contained in a fluid at the same time, and is easy to extract the collected chlorinated organic compounds therefrom. This collecting filter 7 is provided with a fluid-permeable molded body containing fibers and an inorganic binder for binding the fibers to one another, and a hydrophobic material having higher hydrophobicity than that of the fibers and the inorganic binder, which is retained in the molded body. Various chlorinated organic compounds such as dioxins in both particulate form and gaseous form contained in the sample gas are captured and collected upon passage through the collecting filter 7.

Abstract: A fluid storage and dispensing apparatus including a fluid storage and dispensing vessel having a rectangular parallelepiped shape, and an integrated gas cabinet assembly including such fluid storage and dispensing apparatus and/or a point-of-use ventilation gas scrubber in the vented gas cabinet. By the use of physical adsorbent and chemical sorbent media, the gas cabinet can be enhanced in safety of operation, e.g., where the process gas supplied from the gas cabinet is of a toxic or otherwise hazardous character.

Abstract: An apparatus and a method for purifying the air used in cryogenic air separation are described, which are capable of effectively removing nitrogen oxides and/or hydrocarbons. The apparatus comprises an adsorber comprising an adsorption cylinder that has a first adsorbing layer and a second adsorbing layer therein. The first adsorbing layer is composed of a first adsorbent capable of selectively adsorbing water in the air. The second adsorbing layer is composed of a second adsorbent capable of selectively adsorbing nitrogen oxide and/or hydrocarbon in the air passing the first adsorbing layer, wherein the second adsorbent comprises an X zeolite containing magnesium ion as an ion-exchangeable cation.

Abstract: This invention relates to a novel method, which can be carried out according to industrial standards, for producing high-purity hydrochloric acid with a very low particle content, for use in the production of semiconductors.

Abstract: A method of treating exhaust gases containing halogen compound, the improvement in that the exhaust gases containing halogen compounds such as halogen gases and/or hydrogen halide gases (halogenated acid gases) are brought into contact with simple metals. The halogen compounds such as acid gases and halogen gases can thereby effectively be removed from the exhaust gases.

Abstract: This invention is directed to a method for purifying argon from an impure argon stream. If the oxygen concentration in the impure argon is less than about 10 mole percent of oxygen, the invention is proceeded in the sequential steps of a) removing chlorine from the impure argon stream; b) adding hydrogen to the impure argon stream; c) removing carbon dioxide and water from the impure argon stream; d) removing hydrogen from the impure argon stream; and e) removing nitrogen from the impure argon stream to form a purified argon stream.

Abstract: The present invention provides a process for eliminating halogen-containing compounds contained in a gas or a liquid, characterized in that the gas or liquid is brought into contact with a composition based on an alumina and/or a hydrated alumina and at least one compound (A) comprising at least one metallic element selected from metals from groups VIII, IB and/or IIB of the periodic table, and in that the total metallic element(s) content is at most 45% by weight with respect to the total composition weight, the complement by weight preferably comprising in a major part alumina and/or hydrated alumina.

Abstract: The filter contains about 1-15% lithium hydroxide and about 85-99% hopcalite material, having a particle size of approximately 20 to 100 mesh, and can be used in combination with a chemical oxygen generator for removing chlorine gas and carbon monoxide.

Abstract: A process for the purification of a gaseous hydrogen flow containing one or more gaseous impurities from the group consisting of carbon monoxide, water vapor, nitrogen, H2S, chlorine, C1-C3 light alcohols, ammonia, carbon dioxide and linear, branched or cyclic hydrocarbons, saturated and unsaturated, C1-C8. The hydrogen flow is placed in contact with a porous carbonated adsorbent having an adsorption limit volume (W0) and an energy parameter of (E0) according to the Dubinin relationship, such that: 0.18 ml.g−1≦W0≦1.50 ml.g−1 and 15 kJ.mole−1≦E0≦45 kJ.mole−1. The porous carbonated adsorbent is selected from active carbons. The gas rich in hydrogen is a reforming gas, an electrolysis gas, a gas from ammonia cracking or from alcohol cracking.

Abstract: A method for removing trace moisture from a gas is disclosed. The method involves heating a zeolite having a high silica-to-alumina ratio to about 400° C. to remove physically adsorbed water from the zeolite, followed by heating the zeolite to a temperature in excess of 650° C., to form a superheated zeolite. The superheated zeolite is contacted with the gas, thereby adsorbing water from the gas. A dehydroxylated zeolite for removing trace moisture from a gas wherein the zeolite has a high silica-to-alumina ratio and a low level of metallic impurities is also disclosed. A method for removing metallic impurities from a gas using the low metals zeolite is also disclosed. The zeolites and methods of the invention are particularly useful for removing trace water and trace metal impurities from acid gases such as hydrogen chloride and hydrogen bromide.

Abstract: A method and a device for selective catalytic NOx reduction in oxygen-containing exhaust gases using ammonia and a reduction catalyst (9) are described, according to which gaseous ammonia is made available by heating a solid storage medium (2) in a container (1). The method and the device are suitable for use in motor vehicles in particular.

Abstract: A cleaning agent and a cleaning process for efficiently removing noxious halogen-based gases such as fluorine, chlorine, boron trifluoride, boron trichloride and tungsten hexafluoride from exhaust gases from semiconductor fabrication processes. The cleaning agent is produced by adherently adding alkali metal formate and/or alkaline earth metal formate to activated carbon, or adherently adding alkali metal hydroxide and/or alkaline earth metal hydroxide together with alkali metal formate and/or alkaline earth metal formate to activated carbon. By exposing exhaust gases to the cleaning agent, noxious halogen-based gases in the exhaust gases are efficiently removed with little desorption of halogen-based gases adsorbed on the cleaning agent. Also, the cleaning treatment is further improved in safety and efficiency by a pre-treatment cleaning agent comprising a metal oxide or a metal hydroxide and a post-treatment cleaning agent prepared by adherently adding sodium formate to a metal oxide.

Abstract: The filer contains about 1-15% lithium hydroxide and about 85-99% hopcalite material, having a particle size approximately 20 to 100 mesh, and can be used in combination with a chemical oxygen generator for removing chlorine gas and carbon monoxide.

Abstract: Processes are disclosed for increasing the condensed phase production of BCl3 comprising less than about 10 ppm phosgene, less than 10 ppm chlorine, and less than 10 ppm HCl. In one embodiment the process comprises injecting an inert gas into a container having condensed BCl3 therein, the condensed BCl3 having therein a minor portion of phosgene impurity. A major portion of the phosgene in the condensed BCl3 is decomposed to carbon monoxide and chlorine by increasing temperature to produce a phosgene deficient stream. The temperature of the phosgene deficient stream is then decreased, and contacted with an adsorbent to remove the chlorine in the stream by adsorption to form a chlorine and phosgene free condensed stream. The chlorine and phosgene free stream is stripped using an inert gas to form a BCl3 product condensed stream, and an inert gas is used to pump the BCl3 product condensed stream to a product receiver.

Abstract: An adsorbent for removing HCl from fluid streams comprising activated alumina impregnated with alkaline oxide and promoted with phosphate or organic amine or a mixture thereof. A method of making such adsorbent and a method of removing HCl from fluid streams using such adsorbent.