Sulfur Dioxide Or Sulfur Trioxide Sorbed Patents (Class 95/137)
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Publication number: 20080127822Abstract: Dry-scrubbing media compositions, methods of preparing same, and methods of use are provided. The compositions contain activated alumina and potassium carbonate. Optionally, activated carbon and other impregnates, such as sulfates of group 1A metals, are included in the compositions. The compositions exhibit improved efficiency and capacity for the removal of compounds such as chlorine or sulfur dioxide from an air-stream. The compositions are particularly useful for reducing or preventing the release of toxic gaseous compounds from the areas such as petroleum storage areas, refineries, drinking water systems, sewage treatment facilities, swimming pools, hospital morgues, animal rooms, and pulp and paper production sites.Type: ApplicationFiled: November 30, 2007Publication date: June 5, 2008Applicant: Purafil, Inc.Inventor: William G. England
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Patent number: 7241430Abstract: An activated carbon-metal oxide matrix is disclosed. The activated carbon-metal oxide matrix may be obtained by a method including the steps of: preoxidizing a carbon material, grinding the preoxidized carbon material; mixing the ground preoxidized material with a metal oxide to form a carbon mixture; extruding the carbon mixture; carbonizing and activating the extrudate. The activated carbon-metal oxide matrix may be used to remove odorous compounds, acidic gases, and volatile organic compounds from a gas.Type: GrantFiled: March 29, 2006Date of Patent: July 10, 2007Assignee: Siemens Water Technologies Holding Corp.Inventors: James Richard Graham, Jianyuan Cheng
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Patent number: 7238223Abstract: An apparatus for removing constituents from a fluid stream is provided. The apparatus includes a duct, a collection device, a sorbent injector, and an acoustic generator. The duct has a fluid passageway to receive a fluid stream having constituents. The collection device filters the fluid stream. The sorbent injector injects a sorbent in the fluid passageway of the duct. The acoustic generator generates an acoustic field in the fluid passageway of the duct to promote sorption of the constituents for collection by the collection device. Additionally, a method is provided for removing constituents from a fluid stream.Type: GrantFiled: November 3, 2003Date of Patent: July 3, 2007Assignee: Board of the Regents, The University of Texas SystemInventor: G. Douglas Meegan, Jr.
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Patent number: 7153345Abstract: High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn—OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.Type: GrantFiled: February 4, 2004Date of Patent: December 26, 2006Assignee: Battelle Memorial InstituteInventors: Liyu Li, David L. King
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Patent number: 7141093Abstract: A method of scrubbing a gas stream with re-circulated kiln dust when the kiln dust is hydrated to form a sorbent. The sorbent is re-circulated with un-reacted flue gas stream for scrubbing.Type: GrantFiled: July 21, 2004Date of Patent: November 28, 2006Assignee: Graymont QC Inc.Inventor: Alain Charette
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Patent number: 7101416Abstract: A method and composition for the removal of contaminants in a gas stream used in the contamination sensitive processes of photolithography and metrology are described. The synergistic effect of a combination of an electropositive metal component, a high silica zeolite, and a late transition metal compound effects removal or reduction of the contaminates in the gas which interfere with light transmittance to the ppb or ppt levels necessary for the gas to be suitable for these uses. The removal of neutral polar molecules, neutral polar aprotic molecules, protic and aprotic alkaline molecules, acidic polar species, and neutral non-polar aprotic molecules is accomplished with the claimed composition. Depending on the type of contaminant, the composition components are each varied from 10 to 80 parts by volume, with the total composition limited to 100 parts by volume.Type: GrantFiled: October 23, 2003Date of Patent: September 5, 2006Assignee: Mykrolis CorporationInventors: Daniel Alvarez, Jr., Jeffrey J. Spiegelman
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Patent number: 7014831Abstract: Sulfuryl fluoride, which is useful as a fumigant, may be contaminated with sulfur dioxide and possibly other impurities such as sulfuryl chloride, depending on the way it is produced. According to the invention, sulfur dioxide and, if applicable, sulfuryl chloride fluoride are removed from a contaminated sulfuryl fluoride product by using aluminum oxide as an adsorbing agent. The method of the invention is highly advantageous because it eliminates the need to use activated carbon as an additional adsorbent.Type: GrantFiled: August 6, 2004Date of Patent: March 21, 2006Assignee: Solway Fluor und Derivate GmbHInventors: Johannes Eicher, Matthias Marek, Lore Hirsch
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Patent number: 6962616Abstract: A method of making an adsorbent which includes: a) thermally drying dewatered sewage sludge to form granulated organic fertilizer; b) treating the fertilizer with mineral oil; and c) pyrolyzing the treated fertilizer at temperatures between about 600° C. and about 1000° C. The disclosure is also directed to adsorbents made by this method and to the processes of removing acidic gas or gases from wet gas streams by putting an adsorbent in contact with the wet gas stream and allowing the adsorbent to adsorb the acidic gas or gases.Type: GrantFiled: August 8, 2003Date of Patent: November 8, 2005Assignee: Research Foundation of The City University of New YorkInventors: Teresa J. Bandosz, Andriy Bahryeyev
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Patent number: 6911064Abstract: A method and apparatus for preventing contamination of a substrate or a substrate surface, and particularly relates to prevention of contamination of raw materials, semi-finished products, base materials of products and substrate surface in a high-tech industry such as an in the production of semiconductors and liquid crystals. A gas coming into contact with a base material or substrate is purified by dust removing apparatus and adsorption and/or absorption apparatus so that the concentration of fine particles in the gas is below class 1,000 and a non-methane hydrocarbon concentration is below 0.2 ppm. Thereafter, the base material or the substrate surface is exposed to this gas.Type: GrantFiled: December 29, 2003Date of Patent: June 28, 2005Assignee: Ebara Research Co., Ltd.Inventors: Toshiaki Fujii, Tsukuru Suzuki, Hidetomo Suzuki, Kazuhiko Sakamoto
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Patent number: 6858192Abstract: An activated carbon-metal oxide matrix is disclosed. The activated carbon-metal oxide matrix may by obtained by a method including the steps of: preoxidizing a carbon material, grinding the preoxidized carbon material; mixing the ground preoxidized material with a metal oxide to form a carbon mixture; extruding the carbon mixture; carbonizing and activating the extrudate. The activated carbon-metal oxide matrix may be used to remove odorous compounds, acidic gases, and volatile organic compounds from a gas.Type: GrantFiled: December 11, 2001Date of Patent: February 22, 2005Assignee: USFilter CorporationInventors: James Richard Graham, Cheng Jian Yuan
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Patent number: 6824589Abstract: Regenerable gas purifier materials are provided capable of reducing the level of contaminants such as oxygen and water in an inert, nonreactive or reactive gas stream to parts-per-billion levels or sub-parts-per-billion levels. The purifier materials of this invention comprise a thin layer of one or more reduced forms of a metal oxide coated on the surface of a nonreactive substrate. The thin layer may further contain the completely reduced form of the metal.Type: GrantFiled: October 29, 2002Date of Patent: November 30, 2004Assignee: Matheson Tri-GasInventors: Tadaharu Watanabe, Dan Fraenkel, Robert Torres, Jr.
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Patent number: 6773490Abstract: A process for reversible sorption of sulfur trioxide onto a sorbent comprising a) contacting from about 15% to 100% sulfur trioxide with the sorbent under anhydrous conditions at a temperature of from about 35° C. to about 150° C. thereby sorbing the sulfur trioxide onto the sorbent, b) desorbing sulfur trioxide from the sorbent at a temperature of from about 150° C. to about 350° C. at about atmospheric pressure, or under a vacuum pressure, and c) recycling said sorbent by continuously repeating steps a) and b), wherein said sorbent consists essentially of silica or zeolite having a silicon to aluminum ratio in the ranges of from about 1 to about 4.4 or greater than about 5.1, and having a pore size of at least 0.5 nm is disclosed.Type: GrantFiled: May 4, 2001Date of Patent: August 10, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Stephen Ernest Jacobson, Howard M. Blank, David Richard Corbin
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Patent number: 6743271Abstract: An air filter for gasoline and diesel engines that drastically improves the burning efficiency of gasoline and diesel engines is provided. The air filter includes a, replaceable filtering member made of natural fibres or synthetic fibres inside an outer box. The natural or synthetic fibres are adhered with naturally radioactive rare earth element minerals that release negative ions. The element minerals are in the form of fine powders with average diameter of 0.1 &mgr;m˜100 &mgr;m, such that when air passes through the filtering member, it is purified by the released negative ions and becomes oxygen-rich air for use in the combustion chambers of gasoline or diesel engines.Type: GrantFiled: August 13, 2002Date of Patent: June 1, 2004Assignee: Yi-Ting HsuInventor: Kawaji Takimoto
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Patent number: 6733570Abstract: A method and apparatus for preventing contamination of a substrate or a substrate surface, and particularly relates to prevention of contamination of raw materials, semi-finished products, base materials of products and substrate surface in a high-tech industry such as in the production of semiconductors and liquid crystals. A gas coming into contact with a base material or substrate is purified by dust removing apparatus and adsorption and/or absorption apparatus so that the concentration of fine particles in the gas is below class 1,000 and a non-methane hydrocarbon concentration is below 0.2 ppm. Thereafter, the base material or the substrate surface is exposed to this gas.Type: GrantFiled: June 2, 1995Date of Patent: May 11, 2004Assignee: Ebara Research Co., Ltd.Inventors: Toshiaki Fujii, Tsukuru Suzuki, Hidetomo Suzuki, Kazuhiko Sakamoto
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Patent number: 6602324Abstract: A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, pSO2*, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.Type: GrantFiled: November 15, 2001Date of Patent: August 5, 2003Assignee: Air Products and Chemicals, Inc.Inventors: VanEric Edward Stein, Robin Edward Richards, David Douglas Brengel, Michael Francis Carolan
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Patent number: 6576044Abstract: A gas mixture comprised of nitric oxide and one or more impurities selected from nitrous oxide, nitrogen dioxide, nitrous acid, sulfur dioxide, carbonyl sulfide, water vapor and carbon dioxide is purified by pressure swing adsorption or temperature swing adsorption using a porous, metal-free polymer adsorbent that does not promote the disproportionation of nitric oxide to nitrogen dioxide and nitrogen or nitrous oxide. The adsorption step is preferably carried out at tempereatures in the range of about −120 to about 0° C.Type: GrantFiled: November 27, 2000Date of Patent: June 10, 2003Assignee: The BOC Group, Inc.Inventors: Dustin Wenpin Ho, Deming Tang, Walter H. Whitlock
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Publication number: 20020197198Abstract: A process for reversible sorption of sulfur trioxide onto a sorbent comprising a) contacting from about 15% to 100% sulfur trioxide with the sorbent under anhydrous conditions at a temperature of from about 35° C. to about 150° C. thereby sorbing the sulfur trioxide onto the sorbent, b) desorbing sulfur trioxide from the sorbent at a temperature of from about 150° C. to about 350° C. at about atmospheric pressure, or under a vacuum pressure, and c) recycling said sorbent by continuously repeating steps a) and b), wherein said sorbent consists essentially of silica or zeolite having a silicon to aluminum ratio in the ranges of from about 1 to about 4.4 or greater than about 5.1, and having a pore size of at least 0.5 nm is disclosed.Type: ApplicationFiled: May 4, 2001Publication date: December 26, 2002Inventors: Stephen Ernest Jacobson, Howard M. Blank, David Richard Corbin
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Patent number: 6464757Abstract: The filter contains about 1-15% lithium hydroxide and about 85-99% hopcalite material, having a particle size of approximately 20 to 100 mesh, and can be used in combination with a chemical oxygen generator for removing chlorine gas and carbon monoxide.Type: GrantFiled: August 17, 2001Date of Patent: October 15, 2002Assignee: BE Intellectual Property, Inc.Inventors: Yunchang Zhang, Michael J. Brumely, James C. Cannon, John E. Ellison, Girish S. Kshirsagar
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Publication number: 20020100367Abstract: The invention is directed to an adsorbent comprising: a) 20-30% porous carbon with incorporated organic nitrogen species; and b) 70-80% inorganic matter. The invention is directed to a method of making an adsorbent which comprises: a) thermally drying dewatered sewage sludge to form granulated organic fertilizer; and b) pyrolyzing said the organic fertilizer at temperatures between 600 and 1000° C. The invention is additionally directed to the process of removing acidic gases from wet air streams comprising putting an adsorbent in contact with the wet air stream and allowing the adsorbent to adsorb the acidic gases.Type: ApplicationFiled: November 29, 2001Publication date: August 1, 2002Applicant: The Research Foundation of the City Universtiy of New YorkInventors: Teresa J. Bandosz, Andriy Bahryeyev, David C. Locke
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Patent number: 6402819Abstract: The present invention relates to a fresh air filter that comprises a highly air-permissive two- or three-dimensional support made of a cross-linked polymeric foam which includes pores of large dimensions. The support comprises joining portions which are coated with a layer of ion-exchange globules.Type: GrantFiled: March 16, 2000Date of Patent: June 11, 2002Assignee: MHB Filtration GmbH & Co. KGInventors: Ernest De Ruiter, Jonas Toernblom
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Patent number: 6391090Abstract: A method and composition for the removal of contaminants in a gas stream used in the contamination sensitive processes of photolithography and metrology are described. The synergistic effect of a combination of an electropositive metal component, a high silica zeolite, and a late transition metal compound effects removal or reduction of the contaminates in the gas which interfere with light transmittance to the ppb or ppt levels necessary for the gas to be suitable for these uses. The removal of neutral polar molecules, neutral polar aprotic molecules, protic and aprotic alkaline molecules, acidic polar species, and neutral non-polar aprotic molecules is accomplished with the claimed composition. Depending on the type of contaminant, the composition components are each varied from 10 to 80 parts by volume, with the total composition limited to 100 parts by volume.Type: GrantFiled: April 2, 2001Date of Patent: May 21, 2002Assignee: Aeronex, Inc.Inventors: Daniel Alvarez, Jr., Jeffrey J. Spiegelman
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Patent number: 6340381Abstract: A method and apparatus for preventing contamination of a substrate or a substrate surface, and particularly relates to prevention of contamination of raw materials, semi-finished products, base materials of products and substrate surface in a high-tech industry such as in the production of semiconductors and liquid crystals. A gas coming into contact with a base material or substrate is purified by dust removing apparatus and adsorption and/or absorption apparatus so that the concentration of fine particles in the gas is below class 1,000 and a non-methane hydrocarbon concentration is below 0.2 ppm. Thereafter, the base material or the substrate surface is exposed to this gas.Type: GrantFiled: July 20, 2000Date of Patent: January 22, 2002Assignee: Ebara Research Co., Ltd.Inventors: Toshiaki Fujii, Tsukuru Suzuki, Hidetomo Suzuki, Kazuhiko Sakamoto
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Patent number: 6296689Abstract: The filer contains about 1-15% lithium hydroxide and about 85-99% hopcalite material, having a particle size approximately 20 to 100 mesh, and can be used in combination with a chemical oxygen generator for removing chlorine gas and carbon monoxide.Type: GrantFiled: March 16, 2000Date of Patent: October 2, 2001Assignee: BE Intellectual Property, Inc.Inventors: Yunchang Zhang, Michael J. Brumely, James C. Cannon, John E. Ellison, Girish S. Kshirsagar
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Publication number: 20010005981Abstract: A process for removing hydrogen sulfide from a gas stream wherein the filtering media consists essentially of calcined diatomite and between 5% and 30% by weight of ferric ions bonded to the calcined diatomite. This process is particularly efficient due to the fact that the removal of hydrogen sulfide from the gas stream is effected with a single pass adsorption performance of up to 45 mg of H2S per gram of filtering media. Other advantages include the fact that the process has the ability to remove H2S form a gaseous mixture, from a concentration of 30,000 ppm down to non-detectable levels in a single pass. Repeated in-situ regeneration of the filtering media has been proven to be a simple matter of blowing ambient air through the filtering media.Type: ApplicationFiled: February 7, 2001Publication date: July 5, 2001Inventors: Eric L. Winchester, Michael J. McMullin, Jeffrey K. Hum
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Patent number: 6221241Abstract: A process for the purification of a fluid stream containing a sulphur contaminant, such as hydrogen sulphide, and mercury, phosphine, stibine, and/or arsenic compounds as a second contaminant wherein said fluid stream is passed through a bed of a particulate absorbent containing a sulphide of a variable valency metal, especially copper, that is more electropositive than mercury, to remove said second contaminant and then the sulphur contaminant is removed from at least part of the effluent from that bed by passing that part of the effluent through a bed of a particulate sulphur absorbent comprising a compound selected from oxides, hydroxides, carbonates and basic carbonates of said variable valency metal is disclosed. The removal of the sulphur contaminant converts said variable valency metal compound to the corresponding sulphide. The resulting bed of variable valency metal sulphide is subsequently used for the removal of the second contaminant.Type: GrantFiled: October 26, 1999Date of Patent: April 24, 2001Assignee: Imperial Chemical Industries PLCInventors: Peter John Herbert Carnell, Edwin Stephen Willis
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Patent number: 6210466Abstract: According to the present invention, a process is provided which overcomes historical limitations to the capacity of PSA units for a wide variety of gas separations. Capacities in excess of about 110 thousand normal cubic meters per hour (100 million standard cubic feet per day) can now be achieved in a single integrated process train. The corresponding significant equipment reduction results from a departure from the accepted principle in the PSA arts that the length of the purge step must be equal to or less than the length of the adsorption step.Type: GrantFiled: August 10, 1999Date of Patent: April 3, 2001Assignee: UOP LLCInventors: Michael Whysall, Ludovicus Jan Marie Wagemans
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Patent number: 6203598Abstract: This invention relates to a flue gas treating process including a heat recovery step for recovering heat from flue gas by means of a heat exchanger (4) and thereby cooling the flue gas, and a subsequent absorption step for bringing the flue gas into gas-liquid contact with an absorbing fluid (D) in absorption towers (12, 13) so as to remove at least SO2 present in the flue gas by absorption into the absorbing fluid (D), which is characterized, for example, in that a powder addition step for spraying a powder collectable in the absorption step into the flue gas is provided prior to the heat recovery step. This invention makes it possible to provide a flue gas treating process in which a countermeasure against SO3 present in flue gas can be easily achieved without resorting to ammonia injection and the flue gas can further be purified without the disadvantage of causing the injected substance to remain in the treated flue gas.Type: GrantFiled: February 8, 1999Date of Patent: March 20, 2001Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Shigeo Hasegawa, Naohiko Ukawa, Susumu Okino, Koichiro Iwashita, Kazuaki Kimura, Atsushi Yoshioka, Yoshimitsu Kawanishi, Shoichi Onishi, Toru Takashina, Toyoshi Nakagawa
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Patent number: 6174510Abstract: A process for the absorbing of a hot, dry gas stream of sulfur trioxide (SO3) in a stream of strong sulfuric acid. The process includes the steps of passing the hot, dry gas stream of SO3 into a sulfuric acid absorption tower above a packed bed held within the tower and below a liquid collection floor. A stream of strong sulfuric acid is introduced into the tower above the packed bed and allowed to pass cocurrently downwardly through the packed bed with the stream of SO3, thereby allowing the SO3 to be absorbed in the stream of strong sulfuric acid. The resulting concentrated sulfuric acid passes through a packing support into a lower plenum and the spent gas is fed upwardly through a gas conduit to an upper plenum located above the liquid collection floor and from there through a mist eliminator.Type: GrantFiled: August 27, 1999Date of Patent: January 16, 2001Inventor: Marcos D. Riano
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Patent number: 6114273Abstract: An improved process is provided for the removal of sulfur oxides from gas or vapor media containing oxygen and H.sub.2 O by contacting the media with a catalytically-active carbonaceous char. The improvement is provided by the use of a catalytically-active carbonaceous char prepared by low-temperature carbonization and oxidation of a bituminous coal or bituminous material at temperatures below 700.degree. C., followed by contact of the carbonized, oxidized char with one or more nitrogen-containing compounds at a temperature which is stable at, or is increasing to, temperatures less than 700.degree. C., and then increasing the temperature of the resultant material to or above 700.degree. C.Type: GrantFiled: September 19, 1997Date of Patent: September 5, 2000Assignee: Calgon Carbon CorporationInventor: Richard A. Hayden
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Patent number: 6104855Abstract: A terminal assembly for an optic cable equipped with terminal connectors is provided with a housing having a small through-hole and a large through-hole. A plug for keeping optical fibers within the housing to prevent the optical fibers from getting entangled with one another is mounted within the housing. Through the use of a nut member fixed to the cable, the housing is fixed to the cable. A flexible cap member for enclosing the optical fibers and the terminal connectors is combined with the housing to enclose them.Type: GrantFiled: September 30, 1998Date of Patent: August 15, 2000Assignee: Daewoo Telecom Ltd.Inventor: Yong Han Jeon
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Patent number: 6071329Abstract: The filter contains about 1-5% lithium hydroxide and about 85-99% hopcalite material, having a particle size of approximately 20 to 100 mesh, and can be used in combination with a chemical oxygen generator for removing chlorine gas and carbon monoxide.Type: GrantFiled: January 30, 1998Date of Patent: June 6, 2000Assignee: BE Intellectual Property, Inc.Inventors: Yunchang Zhang, Michael J. Brumely, James C. Cannon, John E. Ellison, Girish S. Kshirsagar
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Patent number: 6007706Abstract: A process for the purification of a fluid stream containing a sulphur contaminant, such as hydrogen sulphide, and mercury, phosphine, stibine, and/or arsenic compounds as a second contaminant wherein said fluid stream is passed through a bed of a particulate absorbent containing a sulphide of a variable valency metal, especially copper, that is more electropositive than mercury, to remove said second contaminant and then the sulphur contaminant is removed from at least part of the effluent from that bed by passing that part of the effluent through a bed of a particulate sulphur absorbent comprising a compound selected from oxides, hydroxides, carbonates and basic carbonates of said variable valency metal is disclosed. The removal of the sulphur contaminant converts said variable valency metal compound to the corresponding sulphide. The resulting bed of variable valency metal sulphide is subsequently used for the removal of the second contaminant.Type: GrantFiled: September 2, 1998Date of Patent: December 28, 1999Assignee: Imperial Chemical Industries PLCInventors: Peter John Herbert Carnell, Edwin Stephen Willis
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Patent number: 6001152Abstract: The present invention provides compositions including a salt selected from the group consisting essentially of sodium nitrate, sodium nitrite, ammonium nitrate, lithium nitrate, barium nitrate, cerium nitrate, and mixtures thereof, as flue gas conditioning formulations for use in controlling particulates, hazardous substances, NO.sub.x, and SO.sub.x. For the purpose of obtaining greater yields of particulate and hazardous substance removal, the compositions may further include a polyhydroxy compound, preferably selected from the group consisting essentially of sucrose, fructose, glucose, glycerol, and mixtures thereof. Methods are also provided for adding these compositions to the flue gas stream to control particulate, hazardous substance, NO.sub.x, and SO.sub.x emissions.Type: GrantFiled: May 29, 1997Date of Patent: December 14, 1999Inventor: Rabindra K. Sinha
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Patent number: 5944874Abstract: A process for separating a feed gas stream containing elemental oxygen and nitrogen to produce a purified nitrogen gas stream by removing oxygen from the feed gas stream using an ion transport membrane to produce a retentate gas stream and a permeate gas stream, wherein the feed gas stream or the retentate gas stream is purified to remove impurities either before or after the separation step to produce the purified nitrogen gas stream.Type: GrantFiled: June 23, 1997Date of Patent: August 31, 1999Assignee: Praxair Technology, Inc.Inventors: Ravi Prasad, Christian Friedrich Gottzmann, Homer Fay
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Patent number: 5928496Abstract: Hydrotalcite-like materials are stable in the crystalline oxide structure and essentially reversible in anion exchange. A novel process of sulfur oxide sorption is provided utilizing these hydrotalcite materials as contact solids. Large crystalline sheet materials having increased sorption of SO.sub.x are provided by incorporation of certain organic acid anionic species to modify the hydrotalcite/brucite structure. Typical industrial applications include sulfur removal from fluid catalyst cracking process, cold-side combustion gas sulfur abatement and cleaner coal gasification.Type: GrantFiled: June 13, 1997Date of Patent: July 27, 1999Assignee: Contract Materials Processing, Inc.Inventors: Edwin W. Albers, Harry W. Burkhead, Jr.
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Patent number: 5922105Abstract: A method and apparatus for preventing contamination of a substrate or a substrate surface, and particularly relates to prevention of contamination of raw materials, semi-finished products, base materials of products and substrate surface in a high-tech industry such as in the production of semiconductors and liquid crystals. A gas coming into contact with a base material or substrate is purified by dust removing apparatus and adsorption and/or absorption apparatus so that the concentration of fine particles in the gas is below class 1,000 and a non-methane hydrocarbon concentration is below 0.2 ppm. Thereafter, the base material or the substrate surface is exposed to this gas.Type: GrantFiled: March 19, 1998Date of Patent: July 13, 1999Assignee: Ebara Research Co., Ltd.Inventors: Toshiaki Fujii, Tsukuru Suzuki, Hidetomo Suzuki, Kazuhiko Sakamoto
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Patent number: 5906429Abstract: An optical illumination device reflects and condenses light from a mercury-arc lamp by a light reflecting and condensing member and then reflects and deflects the light, thereafter the reflected and deflected light is transferred to a relay-lens system through a collimator lens or input lens, band-pass filter and fly-eye lens. Gas from which impurities are removed by a filter is flown around optical elements to separate the optical elements from air containing material causing clouding of the optical elements to thereby restrain clouding of the optical elements. On the other hand, or in addition, the reflectance of the light reflecting and condensing member and/or miller for the light of the absorption band of sulfur dioxide is made small to prevent the optical elements from clouding.Type: GrantFiled: July 25, 1997Date of Patent: May 25, 1999Assignee: Nikon CorporationInventors: Takashi Mori, Jin Yamada, Jun Nagatsuka, Shinichi Hasegawa, Shigeru Hagiwara
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Patent number: 5858068Abstract: Industrial grade carbon dioxide may contain unacceptable amounts of sulfur-containing materials, oxygen, and organic materials particularly detrimental to food-related uses of CO.sub.2. These can be effectively removed by a bed of silver-exchanged faujasite and an MFI-type molecular sieve. This permits an on-site, on-demand method of purifying CO.sub.2 ranging from laboratory to tank car seals.Type: GrantFiled: October 9, 1997Date of Patent: January 12, 1999Assignee: UOP LLCInventors: James R. Lansbarkis, Jon S. Gingrich
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Patent number: 5733515Abstract: The present invention discloses an improved method for filtration of air within enclosed spaces. Improvement is achieved by the use of a high-temperature carbonaceous char that is catalytically active for the removal of certain undesirable constituents from contaminated air under ambient temperature conditions. This carbonaceous char is used as an air filtration medium and incorporated into an air filtration device by any of a number of technologies. Such devices may be used for removal of contaminants such as NO.sub.x, NO.sub.2, SO.sub.x, SO.sub.2, H.sub.2 S, mercaptans, light aliphatic gases such as butane and propane and other compounds such as benzene, hexane, toluene, xylene, amines and the like from enclosed or confined structures such as buildings or vehicles including automobiles, aircraft, trucks, farm equipment, and the like.Type: GrantFiled: February 28, 1996Date of Patent: March 31, 1998Assignee: Calgon Carbon CorporationInventors: David T. Doughty, Richard A. Hayden, John W. Cobes, III, Thomas M. Matviya
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Patent number: 5730781Abstract: According to the invention, regeneration is performed by filtering and by regenerating simultaneously the used absorbent; two stages are carried out for the regeneration: one, which is a rough stage, is performed in the presence of a regeneration gas; the other, a free stage, is performed in the presence of a fresh regeneration gas.Type: GrantFiled: February 13, 1996Date of Patent: March 24, 1998Assignee: Institut Francais du PetroleInventors: Gerard Martin, Luc Nougier, Jean-Christophe Dolignier
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Patent number: 5700436Abstract: The present invention discloses an improved method for filtration of air within enclosed spaces. Improvement is achieved by the use of a high-temperature carbonaceous char that is catalytically active for the removal of certain undesirable constituents from contaminated air under ambient temperature conditions. This carbonaceous char is used as an air filtration medium and incorporated into an air filtration device by any of a number of technologies. Such devices may be used for removal of contaminants such as NO.sub.x, NO.sub.2, SO.sub.x, SO.sub.2, H.sub.2 S, mercaptans, light aliphatic gases such as butane and propane and other compounds such as benzene, hexane, toluene, xylene, amines and the like from enclosed or confined structures such as buildings or vehicles including automobiles, aircraft, trucks, farm equipment, and the like.Type: GrantFiled: June 2, 1994Date of Patent: December 23, 1997Assignee: Calgon Carbon CorporationInventors: David T. Doughty, Richard A. Hayden, John W. Cobes, III, Thomas M. Matviya
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Patent number: 5647892Abstract: An improved apparatus and process is provided for scrubbing sulphur oxide gas from combustion flue gas with wet limestone particles as a reactive scrubbing agent. The process is carried out in a moving bed reactor having louvered inlet and outlet sides which permit the flue gas to pass through the reactor while the limestone particles move downward. The flue gas may be flowed through the moving bed reactor at a high velocity to permit scrubbing of large volumes of gas in a thorough and efficient manner. The high velocity of flue gas passing through the reactor causes some of the scrubbing particles to be ejected from the outlet side of the reactor. Problems associated with the ejection of the scrubbing particles are avoided by providing a slot alongside the outlet side of the reactor. The slot is sized so that the flue gas passing therethrough will have insufficient velocity to entrain the ejected scrubbing particles therein.Type: GrantFiled: September 6, 1996Date of Patent: July 15, 1997Assignee: ETS International, Inc.Inventors: John D. McKenna, Kenneth W. Appell, John C. Mycock, Joseph F. Szalay
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Patent number: 5591417Abstract: Removing sulfur oxide, carbon monoxide and nitrogen oxide in a flue gas stream by combusting fuel in the combustor with a reduced amount of oxygen to convert all sulfur-containing species in the flue gas stream to sulfur oxide, and to partially convert carbon monoxide therein to carbon dioxide, thus forming a sulfur oxide enriched gas stream having between at least about 500 ppm carbon monoxide and a consequential reduced amount of nitrogen oxide. The sulfur oxide enriched gas stream is contacted with a solid adsorbent bed for adsorbing the sulfur oxides in the form of inorganic sulfates and/or sulfur oxides. The solid adsorbent contains a catalytic oxidation promoter for oxidizing the carbon monoxide gas stream to carbon dioxide, thus forming a sulfur oxide and carbon monoxide depleted stream with the consequential reduced amount of nitrogen oxide for disposal.Type: GrantFiled: January 21, 1994Date of Patent: January 7, 1997Assignee: Mobil Oil CorporationInventors: John S. Buchanan, Mark F. Mathias, Joseph F. Sodomin, III, Gerald J. Teitman
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Patent number: 5591418Abstract: A collapsed composition is described which is substantially composed of microcrystallites collectively of the formula:m.sub.2m.sup.2+ Al.sub.2-p M.sub.p.sup.3+ T.sub.r O.sub.7+r.multidot.swhere M.sup.2+ is a divalent metal, M.sup.3+ is a trivalent metal, and T is vanadium, tungsten, or molybdenum. The microcrystallites are so small as to be undetectable through conventional x-ray diffraction techniques, yet high resolution electron microscopy reveals that a substantial portion of the microcrystallites are composed of a solid solution having aluminum oxide molecularly dispersed in a divalent metal monoxide crystal structure. Another portion of the microcrystallites are constituted by a spinel phase. The collapsed composition is suitable as a sulfur oxide absorbent, having comparatively high capacity and comparatively fast absorption and desorption rates, and is also suitable as a nitrogen oxide reduction catalyst.Type: GrantFiled: June 9, 1995Date of Patent: January 7, 1997Assignee: Amoco CorporationInventors: Alakananda Bhattacharyya, Michael J. Foral, William J. Reagan
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Patent number: 5547585Abstract: A method for reducing contaminant concentrations in a fluid stream including the steps of forming a metal-complexed material having a surface suitable for exchange with the contaminant, contacting the fluid stream with the metal-complexed material, immobilizing at least a portion of the contaminant on the surface of the metal-complexed material, and regenerating the metal-complexed material so as to remove the contaminant from the surface of the metal-complexed material. The metal-complexed material is formed by the encapsulating of a core of ferromagnetic material with an ion exchange material. The metal-complexed material is magnetically affixed to a metallic mesh retaining surface.Type: GrantFiled: March 28, 1994Date of Patent: August 20, 1996Inventors: Samuel L. Shepherd, Anthony M. Wachinski
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Patent number: 5547648Abstract: Removing sulfur oxide and carbon monoxide in a flue gas stream by combusting fuel in the combustor with a reduced amount of oxygen to partially convert carbon monoxide therein to carbon dioxide and sufficient to convert all sulfur-containing species in the flue gas stream to sulfur oxide and thus form a sulfur oxide enriched gas stream having between at least about 500 ppm carbon monoxide. The sulfur oxide enriched gas stream is contacted with a solid adsorbent bed for adsorbing the sulfur oxides in the form of inorganic sulfates and/or sulfur oxides. The solid adsorbent contains a catalytic oxidation promoter for oxidizing the carbon monoxide gas stream to carbon dioxide, thus forming a sulfur oxide and carbon monoxide depleted stream for disposal. The adsorbent bed is then contacted with a reducing gas stream for regenerating the adsorbent bed to form a hydrogen sulfide and/or sulfur dioxide bearing stream.Type: GrantFiled: May 5, 1995Date of Patent: August 20, 1996Assignee: Mobil Oil CorporationInventors: John S. Buchanan, Mark F. Mathias, Joseph F. Sodomin, III, Gerald J. Teitman
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Patent number: 5538537Abstract: A method of desulphurizing flue gases polluted with SO.sub.2 comprising cooling the gases to a temperature of about 0.5 to 20.degree. above the dew point of the gases and flowing the gases through a granular sorbent prepared from a mixture of commercial cement and water.Type: GrantFiled: January 3, 1995Date of Patent: July 23, 1996Assignee: Krupp Polysius AGInventors: Michael Schmidt, Detlev Kupper, J urgen Schneberger
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Patent number: 5527514Abstract: A desulfurizing and denitrating apparatus wherein an inner space of a tower body, which has an introduction port for a gas to be processed and a processed gas discharge port formed respectively in opposite side walls, is partitioned in a direction from the side wall having the processed gas introduction port toward the side wall having the processed gas discharge port by an inlet louver, a perforated plate and an outlet louver all extending vertically parallel to each other, a constant-rate discharging device for setting a moving speed of a carbon-base adsorbent in a small chamber defined between the inlet louver and the perforated plate and a constant-rate discharging device for setting a moving speed of a carbon-base adsorbent in a large chamber defined between the perforated plate and the outlet louver are provided, the moving speed of the carbon-base adsorbent in the small chamber is set to be 2 to 4 times greater than an average moving speed, and the distance from the inlet louver to the perforated plateType: GrantFiled: October 7, 1994Date of Patent: June 18, 1996Assignee: Sumitomo Heavy Industries, Ltd.Inventors: Teruo Watanabe, Hiromi Tanaka, Kouji Kobayashi
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Patent number: 5500195Abstract: A method for reducing gaseous emission of halogen compounds in a fluidized bed reactor in which the fine particles entrained in flue gases are used to form a temporary layer of particles on the baghouse filter to absorb halogen gases.Type: GrantFiled: September 26, 1994Date of Patent: March 19, 1996Assignee: Foster Wheeler Energy CorporationInventor: Juan A. Garcia-Mallol
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Patent number: 5482536Abstract: An apparatus for containing and scrubbing toxic or corrosive gases from a leaking pipe or cylinder is provided. A gas passageway attaches at one end to a leakage location on a pipe or cylinder, and at the other end to an air operated exhauster. The air operated exhauster, through the input of a non-flammable purge gas, creates an exhaust flow from the leakage location to a drum which is attached to the air operated exhauster. The drum contains a scrubbing media which, when it contacts the leaked gas, cleans or removes the harmful component, thus allowing release to the atmosphere of the cleaned air.Type: GrantFiled: April 12, 1994Date of Patent: January 9, 1996Assignee: Solvay Specialty Chemicals, Inc.Inventors: Eugene Y. Ngai, Lester S. Gerver