Liquid Recycled Or Reused Patents (Class 95/179)
  • Patent number: 10213732
    Abstract: A method for treatment of a flue gas involves feeding the flue gas and a lean solvent to an absorber. The method further involves reacting the flue gas with the lean solvent within the absorber to generate a clean flue gas and a rich solvent. The method also involves feeding the clean flue gas from the absorber and water from a source, to a wash tower to separate a stripped portion of the lean solvent from the clean flue gas to generate a washed clean flue gas and a mixture of the water and the stripped portion of the lean solvent. The method further involves treating at least a portion of the mixture of the water and the stripped portion of the lean solvent via a separation system to separate the water from the stripped portion of the lean solvent.
    Type: Grant
    Filed: August 14, 2017
    Date of Patent: February 26, 2019
    Assignee: GENERAL ELECTRIC COMPANY
    Inventors: Irina Pavlovna Spiry, Benjamin Rue Wood, Surinder Prabhjot Singh, Robert James Perry, John Brian McDermott
  • Patent number: 9943775
    Abstract: The invention concerns a flexible process for purifying a solvent which inhibits the formation of hydrates during gas processing, in particular monoethylene glycol (MEG), said solvent having a boiling point which is higher than that of water and, at least at one point in time, being mixed with water and salts, the process operating in a different manner with the same facility as a function of the quantity of salts in the MEG to be treated. The process operates in accordance with a phase known as reclaiming (separation of salts under vacuum followed by vacuum distillation) when the salts content exceeds the precipitation threshold and if not, the process operates in a regeneration phase (absence of separation of salts and no operation under vacuum). Advantageously, the change is made under the control of means for testing the salts.
    Type: Grant
    Filed: November 19, 2014
    Date of Patent: April 17, 2018
    Assignee: PROSERNAT
    Inventors: Jeremie Esquier, Bernard Chambon, Christian Streicher
  • Patent number: 9021810
    Abstract: A power plant includes a boiler, a stream turbine generator, a post combustion processing system, a feed water regeneration processing system and a heat exchanger. Heat from the heat exchanger is used to regenerate (a) a reagent that absorbs carbon dioxide from flue gas and (b) a water-lean desiccant used to increase plant operating efficiency.
    Type: Grant
    Filed: January 15, 2013
    Date of Patent: May 5, 2015
    Assignee: The University of Kentucky Research Foundation
    Inventors: Kunlei Liu, James K. Neathery
  • Publication number: 20140360369
    Abstract: An absorption medium comprising water and at least one amine of formula (I) where R2 is hydrogen or an alkyl radical having 1 to 4 carbon atoms, R2 is an alkyl radical having 1 to 4 carbon atoms, R3 and R5 are each independently alkyl radicals having 1 to 6 carbon atoms and R4 and R6 are each independently hydrogen or alkyl radicals having 1 to 6 carbon atoms where R3 and R4 may combine to form the bridging radical —(CH2)n—, —CH2CH2OCH2CH2— or —CH2CH2NR7CH2CH2— with n=2 to 5 and R2=hydrogen or an alkyl radical having 1 to 6 carbon atoms, brings about an improved CO2 absorption capacity in the absorption of CO2 from a gas mixture by contacting the gas mixture with the absorption medium.
    Type: Application
    Filed: November 30, 2012
    Publication date: December 11, 2014
    Applicant: Evonik Degussa GmbH
    Inventors: Alexander Schraven, Stefanie Rinker, Benjamin Willy, Jöm Rolker, Rolf Schneider, Daniel Dembkowski, Manfred Neumann, Jochen Niemeyer
  • Patent number: 8906149
    Abstract: The present application relates to a system for removal of gaseous contaminants from a gas stream. The system includes an absorber for contacting the gas stream with a wash solution to form a used wash stream, a regenerator for regenerating the used wash solution, a reboiler and at least two heat exchangers in fluid communication with the absorber, regenerator and reboiler.
    Type: Grant
    Filed: August 26, 2014
    Date of Patent: December 9, 2014
    Assignee: ALSTOM Technology Ltd
    Inventors: Barath Baburao, Jonathan W. Leister, Frederic Vitse
  • Patent number: 8864878
    Abstract: The present invention relates to methods and systems for improving the utilization of energy in a cement manufacturing plant comprising an absorption based contaminant, e.g. CO2, capture process using thermal regeneration of a liquid absorbent. The methods and systems of the present invention are characterized in that the thermal regeneration of the liquid absorbent is at least partially effected using a hot exhaust gas stream generated in the kiln of the cement manufacturing plant.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: October 21, 2014
    Assignee: ALSTOM Technology Ltd
    Inventors: Nareshkumar B. Handagama, Rasesh R. Kotdawala, Ajay Vajpeyi
  • Publication number: 20140301927
    Abstract: In one embodiment, a carbon dioxide capturing system includes an absorption tower configured to bring a treatment target gas containing carbon dioxide into contact with an absorption liquid, and to discharge the absorption liquid having absorbed the carbon dioxide. The system further includes a regeneration tower configured to make the absorption liquid discharged from the absorption tower dissipate the carbon dioxide, and to discharge the absorption liquid having dissipated the carbon dioxide. The system further includes a treatment target gas line configured to introduce the treatment target gas into the absorption tower, a first introduction module configured to introduce a first gas having a higher carbon dioxide concentration than the treatment target gas into the treatment target gas line, and a second introduction module configured to introduce a second gas having a lower carbon dioxide concentration than the treatment target gas into the treatment target gas line.
    Type: Application
    Filed: March 21, 2014
    Publication date: October 9, 2014
    Applicant: KABUSHIKI KAISHA TOSHIBA
    Inventors: Mitsuru Udatsu, Masatoshi Hodotsuka, Hideo Kitamura, Satoshi Saito, Haruki Fujimoto, Noriko Chiba
  • Patent number: 8845790
    Abstract: A method and system for removing gaseous contaminants from a gas stream by contacting the gas stream with a wash solution and regenerating the wash solution in a regeneration system for future use in removing gaseous contaminants from the gas stream.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: September 30, 2014
    Assignee: ALSTOM Technology Ltd
    Inventors: Jonathan W. Leister, Barath Baburao, Frederic Vitse
  • Patent number: 8845789
    Abstract: The present application relates to systems and processes for removal of gaseous contaminants from gas streams. In particular, the application relates to a process for removal of gaseous contaminants from a gas stream comprising contacting the gas stream with a wash solution to remove gaseous contaminants from the gas stream by absorption into the wash solution; and regenerating the used wash solution to remove gaseous contaminants from the used wash solution, to provide a regenerated wash solution and a gas comprising removed contaminants, wherein in a first regeneration stage the gas comprising removed contaminants is cooled to minimize loss of water vapor from the regeneration step.
    Type: Grant
    Filed: March 26, 2010
    Date of Patent: September 30, 2014
    Assignee: ALSTOM Technology Ltd
    Inventors: Barath Baburao, Jonathan W. Leister, Frederic Vitse
  • Publication number: 20140260979
    Abstract: A process for the recovery of an amine acid gas absorbent used in an acid gas recovery unit, comprising obtaining an amine-containing waste stream from a heat stable salt (HSS) removal unit wherein a HSS containing amine acid gas absorbent stream is contacted with a base and subjected to a first phase separation step whereby a light regenerated amine absorbent stream and the amine-containing waste stream are produced; contacting the amine-containing waste stream with an organic solvent and obtaining an amine rich organic solvent stream and an amine reduced waste stream; and contacting the amine rich organic solvent stream with an acid and obtaining a protonated amine stream and an amine reduced organic solvent stream.
    Type: Application
    Filed: March 14, 2013
    Publication date: September 18, 2014
    Applicant: CANSOLV TECHNOLOGIES INC.
    Inventor: Mélina Infantino
  • Patent number: 8821615
    Abstract: The disclosure relates to a process for treating a gas mixture containing carbon dioxide and hydrogen sulphide, including the following steps: deacidificating the gas mixture by bringing the gas mixture into contact with a first lean absorbent solution stream, delivering a deacidified gas mixture, and a first rich absorbent solution stream; regenerating the first rich absorbent solution stream, delivering the first lean absorbent solution stream and a sour gas stream; distillating the sour gas stream, delivering a first carbon-dioxide-rich stream and a hydrogen-sulphide-rich stream; purifying the first carbon-dioxide-rich stream by bringing the first carbon-dioxide-rich stream into contact with a second lean absorbent solution stream, delivering a second carbon-dioxide-rich stream and a second rich absorbent solution stream, the molar concentration of carbon dioxide in the second carbon-dioxide-rich stream being greater than the molar concentration of carbon dioxide in the first carbon-dioxide-rich stream.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: September 2, 2014
    Assignee: Total S.A.
    Inventors: Claire Weiss, Renaud Cadours, Kamal Bouzalmata
  • Patent number: 8814988
    Abstract: The present invention relates to a process for the recovery of ammonia contained in a gaseous stream, said process comprising the following phases: (a) subjecting the gaseous stream containing ammonia to a washing with an aqueous washing solution having a pH lower than 7.0, with the formation of a purified gaseous stream and an aqueous solution containing an ammonium salt; (b) treating the aqueous solution containing the ammonium salt coming from phase (a) in a vertical falling film heat exchanger at a temperature from 50 to 250° C. and an absolute pressure ranging from 50 KPa to 4 MPa with the formation of a regenerated washing solution and a gaseous stream comprising NH3 and H2O; (c) recycling said regenerated washing solution to phase (a). The present invention also relates to equipment for effecting the above process.
    Type: Grant
    Filed: July 27, 2010
    Date of Patent: August 26, 2014
    Assignee: Saipem S.p.A.
    Inventor: Paolo Casara
  • Patent number: 8801835
    Abstract: In some implementations, a method for dehydrating carbon dioxide includes identifying a stream including at least carbon dioxide and water. At least a portion of the stream is dehydrated using an initial lean sorbent including glycerol and a polyhydric alcohol to generate dry carbon dioxide stream and rich sorbent including water. The polyhydric alcohol reduces an amount of glycerol lost to the dry carbon dioxide stream during dehydration. This process may result in the beneficial reduction in the amount of glycerol that leaves the system with the dry carbon dioxide. The dry carbon dioxide and the rich sorbent are separated. The glycerol is recycled by dehydrating the rich sorbent to produce recycled lean sorbent.
    Type: Grant
    Filed: July 13, 2011
    Date of Patent: August 12, 2014
    Assignee: Denbury Onshore, LLC
    Inventor: Kevin S. Fisher
  • Patent number: 8764892
    Abstract: A method for removal of CO2 from a flue gas stream, comprising the steps of: a) contacting a flue gas stream comprising CO2 with a first absorption liquid comprising NH3 such that the flue gas stream is depleted in CO2; b) contacting the flue gas stream depleted in CO2 of step a) with a second absorption liquid such that NH3 from the flue gas stream is absorbed in said second absorption liquid to form a flue gas stream depleted in CO2 and NH3; c) separating NH3 from the second absorption liquid such that a gas stream comprising NH3 is obtained; d) contacting said gas stream comprising NH3 separated in step c) with a third absorption liquid such that NH3 is absorbed in said third absorption liquid. A system for removal of CO2 from a flue gas stream, the system comprising: a CO2 absorption stage; an NH3 absorption stage; and a reabsorption stage.
    Type: Grant
    Filed: February 25, 2013
    Date of Patent: July 1, 2014
    Assignee: ALSTOM Technology Ltd
    Inventors: Peter Ulrich Koss, Frederic Zenon Kozak
  • Publication number: 20140090558
    Abstract: An absorption medium which comprises water, an amine (A) of formula (I) in which R is an n-alkyl radical having 1 to 4 carbon atoms, and an alkanolamine (B) which is a tertiary amine or a sterically hindered primary or secondary amine has a high absorption capacity for CO2 with a high absorption rate. In the absorption of acid gases from a gas mixture a separation of the absorption medium into two liquid phases or the precipitation of a solid upon absorption of CO2 and regeneration of the absorption medium can be avoided with the absorption medium, even without addition of a solvent.
    Type: Application
    Filed: May 25, 2012
    Publication date: April 3, 2014
    Applicant: Evonik Degussa GmbH
    Inventors: Jörn Rolker, Matthias Seiler, Rolf Schneider, Thibaut Lenormant
  • Patent number: 8673062
    Abstract: A method of removing acid gases from raw gas is disclosed in which the raw gas is supplied to an absorption column where it is contacted with a physical absorption agent, having a boiling point lower than 100° C. at atmospheric pressure, under elevated operating pressure to load, the physical absorption agent with acid gases and usable gases and then the physical absorption agent loaded with acid gases and usable gases is driven from the absorption column at its sump while drawing off at the head of the absorption column a purified top gas containing up to a few ppm of acid-gas components. Following the absorption, the physical absorption agent undergoes stripping to remove usable gases, and regeneration to remove the acid gases as well as to provide a regenerated physical absorbent which may be used to treat additional raw gas.
    Type: Grant
    Filed: November 4, 2009
    Date of Patent: March 18, 2014
    Assignee: UHDE GmbH
    Inventor: Johannes Menzel
  • Patent number: 8656719
    Abstract: A thermal power plant includes a boiler for burning fossil fuel to generate steam, a steam turbine including a high-pressure turbine, an intermediate-pressure turbine, and a low-pressure turbine which are driven by steam generated in the boiler, an absorber for absorbing and capturing CO2 contained in boiler exhaust gas discharged from the boiler in an absorbing liquid, a desorber for circulating the absorbing liquid between the desorber and the absorber and separating CO2 from the absorbing liquid that has absorbed CO2, a reboiler for feeding a heating source for separating CO2 from the absorbing liquid to the desorber, a steam pipe system for feeding steam taken out from the high-pressure turbine and the intermediate-pressure turbine to the reboiler, and a steam feed source switching device.
    Type: Grant
    Filed: January 5, 2012
    Date of Patent: February 25, 2014
    Assignee: Hitachi, Ltd.
    Inventors: Tetsuya Kosaka, Nobuyoshi Mishima, Takashi Sugiura
  • Publication number: 20130340611
    Abstract: The invention relates to a method and apparatus for reducing nitrosamines, formed in removal of CO2 from off-gases by means of an aqueous amine solution. A substream of the aqueous amine solution, loaded with nitrosamines, is branched off from a washing fluid circulation and is concentrated by evaporating water and low-boiling constituents. The concentrated amine solution is retained at the boiling point in a unit in which a liquid phase and a vapor phase are in contact to establish a vapor/fluid equilibrium between the phases. The vapor phase is irradiated with UV light, which decomposes nitrosamines entering the vapor phase. Following decomposition of nitrosamines, the concentrated amine solution is recycled to the washing fluid circulation for further use in the scrubber.
    Type: Application
    Filed: July 18, 2013
    Publication date: December 26, 2013
    Inventor: JOHANNES MENZEL
  • Publication number: 20130255496
    Abstract: An ionic liquid solvent and gas purification method using the same are provided. The ionic liquid solvent consists of a main absorbent, a regulator for the main absorbent, an auxiliary absorbent, an activator, an antioxidant and water. The ionic liquid involves a low synthetic cost, low viscosity and high absorption capacity, and can be easily regenerated and recycled. The method, compared with traditional processes, has advantages such as a greater absorption capability and lower operation cost.
    Type: Application
    Filed: September 26, 2010
    Publication date: October 3, 2013
    Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMY
    Inventors: Xiangping Zhang, Yansong Zhao, Shaojuan Zeng, Suojiang Zhang, Haifeng Dong, Yingpeng Zhen, Lei Huang
  • Publication number: 20130247758
    Abstract: CO2 is absorbed from a gas mixture by contacting the gas mixture with an absorption medium which comprises at least water as solvent and at least one amine of formula (I) where R1 is an aliphatic radical, having 2 to 6 carbon atoms and at least one amino group, and R2 is hydrogen, a C1-4 alkyl radical or a radical R1.
    Type: Application
    Filed: November 10, 2011
    Publication date: September 26, 2013
    Applicant: Evonik Degussa GmbH
    Inventors: Matthias Seiler, Rolf Schreider, Jörn Rolker, Daniel Dembkowski, Manfred Neumann, Daniel Witthaut, Michael Keup, Volker Brehme, Muhammad Irfan
  • Publication number: 20130192465
    Abstract: A process for recovering a processing liquid used in gas purification systems, e.g., to remove greenhouse gases, and containing water, the processing liquid, components having higher and lower boiling points than water and a component less volatile than the processing liquid, wherein the feed mixture is heated and introduced into a first separation zone, a portion of the water and the processing liquid being volatilized to produce a hot vapor stream comprising volatilized water and processing liquid. There is also produced a first residuum stream which contains some of the less volatile components and the unvolatilized portion of the water in the processing liquid. The hot vapor stream is introduced into the separation system forming part of a gas purification system. The majority of the energy in the hot vapor stream is recovered for use in the separation system forming part of the gas purification system.
    Type: Application
    Filed: August 23, 2011
    Publication date: August 1, 2013
    Inventors: Terrance Trofimuk, Steven Ayres, Shaun M. Hill, Raymond G.F. Abry
  • Patent number: 8425655
    Abstract: The present invention provides a gas pressurized separation system to strip a product gas from a liquid stream and yield a high pressure gaseous effluent containing the product gas. The system comprises a gas pressurized stripping apparatus, such as a column, with at least one first inlet allowing flow of one or more liquid streams in a first direction and at least one second inlet allowing flow of one or more high pressure gas streams in a second direction, to strip the product gas into the high pressure gas stream and yield through at least one outlet a high pressure gaseous effluent containing the product gas; and two or more heat supplying apparatuses provided at different locations along the column. Processes for separating a product gas from a gaseous mixture to yield a high pressure gaseous effluent containing the product gas, utilize the gas pressurized separation system described above.
    Type: Grant
    Filed: July 9, 2010
    Date of Patent: April 23, 2013
    Assignee: Carbon Capture Scientific, LLC
    Inventors: Shiaoguo Chen, Zijiang Pan
  • Publication number: 20130092026
    Abstract: Systems and processes for reducing the energy requirements of an ammonia recovery stripper in a chilled ammonia-based CO2 removal system. The systems and processes include a nanofiltration or reverse osmosis unit for physically separating the washed liquid from a wash vessel configured to receive an ammonia slip feed stream from the main absorber of the chilled ammonia-based CO2 removal system and provide first and second feed streams. Relative to the washed liquid from the wash vessel, the first feed stream has a decreased ammonia molarity whereas the second feed stream has an increased ammonia molarity. The second feed stream is then fed to the ammonia recovery stripper, which reduces steam consumption. The reduced steam consumption translates to significant energy savings, among numerous other advantages. Additionally, the systems and process provide a reduction of equipment sizes related to the stripper unit as may be desired in some applications.
    Type: Application
    Filed: October 18, 2011
    Publication date: April 18, 2013
    Applicant: ALSTOM Technology Ltd.
    Inventor: Sanjay Kumar Dube
  • Patent number: 8414694
    Abstract: Provided are a CO2 absorber that reduces CO2 contained in flue gas; a regenerator that reduces CO2 contained in rich solvent absorbing CO2 to regenerate the rich solvent, so that lean solvent having the CO2 reduced in the regenerator is reused in the CO2 absorber; a heat exchanger that allows the rich solvent to exchange heat with the lean solvent; and a controller that controls to extract rich solvent portion that is part of the rich solvent, to allow the rich solvent portion to by pass the heat exchanger, and to be supplied into the top of the regenerator without exchanging heat so as to minimize a sum of an enthalpy that is taken out of the regenerator as CO2 gas accompanying steam and an enthalpy of the lean solvent after heat exchange with the rich solvent in the heat exchanger.
    Type: Grant
    Filed: December 23, 2009
    Date of Patent: April 9, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Masaki Iijima, Kouki Ogura, Masahiko Tatsumi, Yasuyuki Yagi
  • Patent number: 8404027
    Abstract: A method for removal of CO2 from a flue gas stream, comprising the steps of: a) contacting a flue gas stream comprising CO2 with a first absorption liquid comprising NH3 such that the flue gas stream is depleted in CO2; b) contacting the flue gas stream depleted in CO2 of step a) with a second absorption liquid such that NH3 from the flue gas stream is absorbed in said second absorption liquid to form a flue gas stream depleted in CO2 and NH3; c) separating NH3 from the second absorption liquid such that a gas stream comprising NH3 is obtained; d) contacting said gas stream comprising NH3 separated in step c) with a third absorption liquid such that NH3 is absorbed in said third absorption liquid. A system for removal of CO2 from a flue gas stream, the system comprising: a CO2 absorption stage; an NH3 absorption stage; and a reabsorption stage.
    Type: Grant
    Filed: July 28, 2009
    Date of Patent: March 26, 2013
    Assignee: ALSTOM Technology Ltd
    Inventors: Peter Ulrich Koss, Frederic Zenon Kozak
  • Patent number: 8398748
    Abstract: Contemplated configurations and methods include a solvent regenerator (58) that has an upper (93) and a lower stripping section (94). Cooled rich solve is used as reflux while heated rich solvent (11) is used as a source of stripping agent in the upper section (91). A reboiler (62) in the lower section provides further stripping agent, hi especially preferred configurations, a portion of lean solved from the regenerator (58) is further stripped in a separate or integrated regenerator (62) to form an ultra-lean solvent. Both lean and ultra-lean solvents are preferably used in a two-stage absorber (52) to thereby from the rich solvent and an offgas that is very low in acid gas.
    Type: Grant
    Filed: April 18, 2006
    Date of Patent: March 19, 2013
    Assignee: Fluor Technologies Corporation
    Inventor: John Mak
  • Patent number: 8361424
    Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions in BS1: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution. According to the invention, an absorbent solution portion circulating in C1 is cooled in E2 in order to prevent demixing of the solution in column C1.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: January 29, 2013
    Assignee: IFP
    Inventors: Pierre-Antoine Bouillon, Marc Jacquin, Ludovic Raynal
  • Publication number: 20130019751
    Abstract: A separation apparatus for carbon dioxide is provided which includes an absorption unit for absorbing flue gas from a fossil-fueled power station, a desorption unit and a heat exchanger which on the primary feed side is connected via an inlet-side feedback line to the desorption unit, and on the discharge side is connected via an outlet-side feedback line to the absorption unit. On the secondary feed side, the heat exchanger is connected via an inlet-side feed line to the absorption unit, and on the discharge side is connected via an outlet-side feed line to the desorption unit. A first bypass line connects the inlet-side feedback line to the outlet-side feed line so that a mostly closed first circuit with the desorption unit is formed, and a second bypass line connects the inlet-side feed line to the outlet-side feedback line so a mostly closed second circuit with the absorption unit is formed.
    Type: Application
    Filed: March 3, 2011
    Publication date: January 24, 2013
    Inventors: Mike Rost, Ruediger Schneider, Henning Schramm
  • Patent number: 8349056
    Abstract: A system includes a direct contact absorber configured to circulate a flow of a liquid desiccant solution for absorbing moisture from a gas stream flowing through the direct contact absorber.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: January 8, 2013
    Assignee: General Electric Company
    Inventor: Robert Warren Taylor
  • Publication number: 20120325089
    Abstract: In accordance with an embodiment, a carbon dioxide capturing device includes an absorption tower, a regeneration tower, and a cooling unit. A gas containing carbon dioxide and a lean liquid is introduced to the absorption tower which brings the gas and the lean liquid into contact with each other to generate a rich liquid. The regeneration tower generates a lean liquid by diffusing vapor containing carbon dioxide from the rich liquid from the absorption tower, and then returns the lean liquid to the absorption tower. The cooling unit cools at least one of the gas, the lean liquid, and the rich liquid. The cooling unit includes first and second coolers connected in series to each other, by first and second cooling mediums, respectively. The first cooling medium is generated outside the device without using power for cooling in the device. The first cooler is located upstream of the second cooler.
    Type: Application
    Filed: June 14, 2012
    Publication date: December 27, 2012
    Applicant: Kabushiki Kaisha Toshiba
    Inventors: Mitsuru UDATSU, Kensuke Suzuki, Satoshi Saito, Masatoshi Hodotsuka, Hideo Kitamura, Norihide Egami
  • Publication number: 20120318141
    Abstract: A CO2 recovery unit includes an absorber that reduces CO2 in flue gas (101) discharged from a combustion facility (50) by absorbing CO2 by an absorbent, a regenerator that heats the absorbent having absorbed CO2 to emit CO2, and regenerates and supplies the absorbent to the absorber, and a regenerating heater that uses steam (106) supplied from the combustion facility (50) for heating the absorbent in the regenerator and returns heated condensed water (106a) to the combustion facility (50). The CO2 recovery unit further includes a condensed water/flue gas heat exchanger (57) that heats the condensed water (106a) to be returned from the regenerating heater to the combustion facility (50) by heat-exchanging the condensed water (106a) with the flue gas (101) in a flue gas duct (51) in the combustion facility (50).
    Type: Application
    Filed: January 11, 2011
    Publication date: December 20, 2012
    Applicants: THE KANSAI ELECTRIC POWER CO., INC., MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Tatsuya Tsujiuchi, Hiromitsu Nagayasu, Takuya Hirata, Keiji Fujikawa, Tetsuya Imai, Hiroshi Tanaka, Tsuyoshi Oishi, Masahiko Tatsumi, Yasuyuki Yagi, Kazuhiko Kaibara
  • Patent number: 8318114
    Abstract: This invention provides novel compositions comprising substituted polyamines as acid gas scrubbing solutions and methods of using the compositions in an industrial system. The invention relates to the use of such polyamine compounds in industrial processes to remove acidic contaminants from natural and industrial fluid streams, such as natural gas, combustion gas, natural gas, synthesis gas, biogas, and other industrial fluid streams. The compositions and methods of the invention are useful for removal, absorption, or sequestration of acidic contaminants and sulfide contaminants including CO2, H2S, RSH, CS2, COS, and SO2.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: November 27, 2012
    Inventors: Alan M. Blair, Keith N. Garside, William J. Andrews, Kailas B. Sawant
  • Publication number: 20120279394
    Abstract: A method and apparatus for drying a natural gas or an industrial gas that contains acidic gas components, wherein gas drying is followed by the removal of the acidic gas components from the dried gas. The same physical solvent is used for both of the process steps of gas drying and of acidic gas removal. The gas to be dried is brought into contact with the physical solvent, which absorbs most of the water contained in the gas. The physical solvent, loaded with water, is transferred into a solvent regenerating device to be heated where the water contained in the solvent is stripped from the solvent in the countercurrent by acidic gas that is removed from the dried useful gas during the acidic gas absorption. The acidic gas being released again in the acidic gas solvent regenerating device, stripped from the solvent, and discharged from the solvent regenerating device.
    Type: Application
    Filed: September 22, 2010
    Publication date: November 8, 2012
    Applicant: ThyssenKrupp Uhde GmbH et al.
    Inventor: Johannes Menzel
  • Patent number: 8287626
    Abstract: A method for treating a gas mixture containing acid gases, including: contacting the gas mixture with an absorbing solution, to obtain a de-acidified gas mixture and an absorbing solution with acid gases. To regenerate the absorbing solution with acid gases, the absorbing solution is passed into a first regenerator at a first pressure, then the solution is passed into a second regenerator at a second pressure, and finally to a third regenerator at a third pressure, the third pressure being less than the second pressure which is less than the first pressure. The gases from the second and third regenerator are compressed and recycled to the first and second regenerator, respectively. Gases from the second and/or the third regenerator are drawn off to provide a gas mixture rich in hydrogen sulfide. Gases from the first regenerator are drawn off to provide a gas mixture rich in carbon dioxide.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: October 16, 2012
    Assignee: Total S.A.
    Inventors: Viep Hoang-Dinh, Damien Roquet, Kenza Habchi-Tounsi, Olivier Chazelas, Claire Weiss
  • Publication number: 20120180521
    Abstract: A system for scrubbing acid gases from a gas stream, and particularly adapted for scrubbing CO2 from flue gas and recovering the CO2 at high pressure and good purity using an aqueous scrubbing medium such as aqueous ammonia scrubbing solution. A scrubber, regenerator, and stripper are provided, with each having two parts that are each multistage countercurrent vapor-liquid contactors. The required compression energy is minimized by providing necessary refrigeration from an ammonia absorption refrigeration plant that is powered by heat extracted from the gas being scrubbed. The amount of reboil required for the regenerator and stripper is minimized by providing internal heat exchangers (non-adiabatic distillation) in those components.
    Type: Application
    Filed: January 18, 2012
    Publication date: July 19, 2012
    Inventor: Donald Charles Erickson
  • Patent number: 8206489
    Abstract: The present invention relates to a method of deacidizing a gaseous effluent, wherein the following stages are carried out: a) contacting the gaseous effluent with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property to form two separable phases when it absorbs an amount of acid compounds, b) separating the absorbent solution laden with acid compounds into two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds, c) regenerating the second fraction so as to release part of the acid compounds, d) mixing a predetermined amount of water with the first absorbent solution fraction obtained in stage b) or with the regenerated absorbent solution fraction obtained in stage c), then e) recycling the first absorbent solution fraction and the regenerated absorbent solution as the absorbent solu
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: June 26, 2012
    Assignee: Institut Francais du Petrole
    Inventors: Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
  • Publication number: 20120152119
    Abstract: A system and process are disclosed for selective removal and recovery of H2S from a gaseous volume, e.g., from natural gas. Anhydrous organic, sorbents chemically capture H2S gas to form hydrosulfide salts. Regeneration of the capture solvent involves addition of an anti-solvent that releases the captured H2S gas from the capture sorbent. The capture sorbent and anti-solvent are reactivated for reuse, e.g., by simple distillation.
    Type: Application
    Filed: December 17, 2010
    Publication date: June 21, 2012
    Applicant: BATTELLE MEMORIAL INSTITUTE
    Inventors: David J. Heldebrant, Phillip K. Koech, James E. Rainbolt, Mark D. Bearden, Feng Zheng
  • Patent number: 8192530
    Abstract: A system (10) for regenerating a rich absorbent solution (26), the system including: an absorber (20) facilitating interaction between a process stream (22) and an absorbent solution, wherein the process stream comprises an acidic component, and interaction of the process stream with the absorbent solution produces a reduced acidic component stream (28) and a rich absorbent solution; at least one heat exchanger accepting at least one of said reduced acidic component stream and the process stream to transfer heat to a heat transfer fluid (60); and at least one mechanism (60a) to transfer the heat transfer fluid from said at least one heat exchanger to a regenerator (34) regenerating the rich absorbent solution, wherein each of the at least one mechanisms is fluidly coupled to each of the at least one heat exchangers.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: June 5, 2012
    Assignee: ALSTOM Technology Ltd
    Inventors: Nareshkumar B. Handagama, Rasesh R. Kotdawala
  • Patent number: 8182576
    Abstract: The present invention is a biogas processing system having a compressor having a biogas input and output, a pump having a water input and output, a scrubber tower having a mixing chamber connected to a biogas input, a water pump input, a water output, and a processed biogas output, and a filtration member connected to the water output to remove contaminants from the water exiting the first scrubber tower. The system also includes devices for heating and cooling the recycled flow of water to enhance the ability of the water to absorb contaminants from the biogas and the ability of a stripper to remove absorbed contaminants from the water in a closed loop water system, and a controller for closely controlling the operating parameters of the system to achieve safe and optimal operation of the system.
    Type: Grant
    Filed: August 22, 2011
    Date of Patent: May 22, 2012
    Assignee: A&B Process Systems Corporation
    Inventors: Kevin L. Roe, David J. Mandli, Amanda M. Neuhalfen
  • Patent number: 8088200
    Abstract: In a method for removing acid gases from a fluid stream, the fluid stream, which is in contact with an absorption medium within an absorber, is passed through a first absorption zone in the absorber to remove a majority of acid gases from the fluid stream. The fluid stream is susequently passed through a second absorption zone in the absorber to further remove acid gases from the fluid stream. The loaded absorption medium is passed into a first regeneration zone to obtain a partially regenerated absorption medium, and a part of the partially regenerated absorption medium is passed into the first absorption zone. The other part of the partially regenerated absorption medium is passed into a second regeneration zone to obtain a regenerated absorption medium. A part of the regenerated absorption medium is passed into the first absorption zone and the other part is passed into the second absorption zone.
    Type: Grant
    Filed: February 14, 2007
    Date of Patent: January 3, 2012
    Assignee: BASF SE
    Inventors: Rupert Wagner, Randolf Hugo
  • Publication number: 20110308389
    Abstract: A method for eliminating or substantially reducing emission of amines (amineslip) and alkaline degradation products to the atmosphere from a plant for CO2 capture from a flue gas, where the CO2 is captured by counter-current flow to an absorbent in an absorption zone, the absorbent comprising an aqueous solution of one or more amine(s), to give a CO2 lean flue gas that is released into the surroundings, and a CO2 rich absorbent that is regenerated in a regeneration column to give a CO2 rich gas that is treated further, and regenerated absorbent that is recycled to the absorption zone, wherein the CO2 lean flue gas is washed with an acidic aqueous solution to remove or substantially reduce the amount of amine(s) and alkaline degradation products thereof in the gas, is described.
    Type: Application
    Filed: February 12, 2010
    Publication date: December 22, 2011
    Applicant: Aker Clean Carbon AS
    Inventors: Oscar Fredrik Graff, Otto Morten Bade, Oddvar Gorset, Simon Woodhouse
  • Patent number: 8052948
    Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A compressor compresses CO2 that is removed from the rich solution and discharged through a head of the regeneration tower. Heat is generated while the compressor compresses the CO2. A heat supplying unit supplies the heat to the regeneration tower for heating the lean solution.
    Type: Grant
    Filed: September 5, 2007
    Date of Patent: November 8, 2011
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventor: Masaki Iijima
  • Patent number: 8043588
    Abstract: This invention relates to a method and plant for energy-efficient removal of CO2 from a gas phase by means of absorption. The invention is particularly suitable for use in connection with thermal power plants fired by fossil fuels, and is also well-suited for retrofitting in existing thermal power plants. A processing plant according to the invention comprises three sections: a primary CO2-generating process that serves as main product supplier; a CO2-capture and separation plant based on absorption and desorption of CO2 respectively by/from at least one absorbent; and a second CO2-generating process where combustion of carbonaceous fuel in pure oxygen atmosphere serves as energy supply to at least a part of the thermal energy necessary to drive the regeneration of the absorbent in the desorption column(s).
    Type: Grant
    Filed: January 12, 2007
    Date of Patent: October 25, 2011
    Assignees: CO2-Norway AS, Nebb Engineering AS
    Inventors: Carl W. Hustad, Ingo Tronstad
  • Publication number: 20110247494
    Abstract: A method for sorbing a gas using an ionic liquid to sorb a vapor having an electric multi-pole moment. The ionic liquid comprises an anion and a cation. The electric multi-pole moment may be an electric dipole moment and/or an electric quadru-pole moment. The sorption may be an adsorption or an absorption. The ionic liquid may be a liquid that substantially contains only anions and cations, while not containing other components, such as water. Alternatively, a solution containing the ionic liquid and a solvent or further compound, such as water, may be used.
    Type: Application
    Filed: June 22, 2011
    Publication date: October 13, 2011
    Applicant: VTU Holding GmbH.
    Inventors: Paul DINNAGE, Roland KALB
  • Publication number: 20110229393
    Abstract: An improved process for deacidizing a gaseous mixture using phase enhanced gas-liquid absorption is described. The process utilizes a multiphasic absorbent that absorbs an acid gas at increased rate and leads to reduced overall energy costs for the deacidizing operation.
    Type: Application
    Filed: April 13, 2011
    Publication date: September 22, 2011
    Inventor: Liang HU
  • Patent number: 8016919
    Abstract: A solution contained in a regeneration tower is supplied to a filtering unit. The filter unit filters out solid particles contained in the solution. A washing unit washes out with backwash water solid particles filtered out by the filter unit. An evaporating unit receives the backwash water containing the solid particles, and heats received backwash water thereby obtaining solid-particles concentrated backwash water.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: September 13, 2011
    Assignee: Mitsubishi Heavy Industries, Ltd.
    Inventors: Masaki Iijima, Takashi Kamijo
  • Patent number: 8007567
    Abstract: The present invention is a biogas processing system having a compressor having a biogas input and output, a pump having a water input and output, a scrubber tower having a mixing chamber connected to a biogas input, a water pump input, a water output, and a processed biogas output, and a filtration member connected to the water output to remove contaminants from the water exiting the first scrubber tower. The system also includes devices for heating and cooling the recycled flow of water to enhance the ability of the water to absorb contaminants from the biogas and the ability of a stripper to remove absorbed contaminants from the water in a closed loop water system, and a controller for closely controlling the operating parameters of the system to achieve safe and optimal operation of the system.
    Type: Grant
    Filed: August 13, 2008
    Date of Patent: August 30, 2011
    Assignee: A & B Process Systems Corporation
    Inventors: Kevin L. Roe, David J. Mandli, Amanda M. Neuhalfen
  • Patent number: 7998248
    Abstract: Process for the dehydration of gases, comprising: absorbing water vapor by means of a hygroscopic liquid consisting essentially of one or more C2-C8 glycols and an additive capable of forming a minimum type azeotrope with water; distilling the glycol/water/additive mixture to obtain a top product consisting mainly of the water/additive azeotropic mixture and a bottom product consisting mainly of glycol and additive (hygroscopic liquid); recycling the regenerated hygroscopic liquid to the absorption stage.
    Type: Grant
    Filed: November 29, 2005
    Date of Patent: August 16, 2011
    Assignee: ENI S.p.A.
    Inventors: Angelo Carugati, Roberto Pea, Liberato Giampaolo Ciccarelli
  • Patent number: 7938888
    Abstract: A liquid desiccant regenerator system, including a desiccant/air heat exchanger having a first desiccant inlet and a desiccant reservoir. The reservoir has a first desiccant outlet, a second desiccant outlet and a second desiccant inlet. The first desiccant inlet and the first desiccant outlet are connectable to a heat source, the second desiccant inlet conducts diluted desiccant of the reservoir and the second desiccant outlet conducts concentrated desiccant from the reservoir. The second desiccant inlet and the desiccant outlet are connected to a desiccant/desiccant heat exchanger for applying heat to the diluted desiccant flowing into the reservoir. A dehumidification method is also provided.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: May 10, 2011
    Assignee: Agam Energy Systems Ltd.
    Inventor: Gad Assaf
  • Publication number: 20110100217
    Abstract: A method for recovering carbon dioxide (CO2) from a gas stream is disclosed. The method includes the step of reacting CO2 in the gas stream with fine droplets of a liquid absorbent, so as to form a solid material in which the CO2 is bound. The solid material is then transported to a desorption site, where it is heated, to release substantially pure CO2 gas. The CO2 gas can then be collected and used or transported in any desired way. A related apparatus for recovering carbon dioxide (CO2) from a gas stream is also described herein.
    Type: Application
    Filed: October 30, 2009
    Publication date: May 5, 2011
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Grigorii Lev Soloveichik, Robert James Perry, Benjamin Rue Wood, Sarah Elizabeth Genovese