Sulfur Compound Removed Patents (Class 95/181)
  • Patent number: 11826699
    Abstract: Embodiments may include a hydrogen sulfide scrubber system that includes a charging chamber, a reaction vessel, and a treated gas trap. Embodiments may include a mobile vehicle, vessel, or platform that includes a mobile vehicle, vessel, or platform with a mounted hydrogen sulfide scrubber system. The hydrogen sulfide scrubber system is configured as previously described. Embodiments may include a method of using a hydrogen sulfide scrubber system.
    Type: Grant
    Filed: June 4, 2021
    Date of Patent: November 28, 2023
    Assignee: SAUDI ARABIAN OIL COMPANY
    Inventors: Feng Hu Lu, Mohanned A. Ghamdi, Owaidh S. Harthi, Abdullah S. Hajri, Jaffar Mohammad Al-Dubaisi, Mohammad A. Alrowaie
  • Patent number: 11725153
    Abstract: A process for recovering catalyst from a fluidized catalytic reactor effluent is disclosed comprising reacting a reactant stream by contact with a stream of fluidized catalyst to provide a vaporous reactor effluent stream comprising catalyst and products. The vaporous reactor effluent stream is contacted with a liquid coolant stream to cool it and transfer the catalyst into the liquid coolant stream. A catalyst lean vaporous reactor effluent stream is separated from a catalyst rich liquid coolant stream. A return catalyst stream is separated from the catalyst rich liquid coolant stream to provide a catalyst lean liquid coolant stream, and the return catalyst stream is transported back to said reacting step.
    Type: Grant
    Filed: April 14, 2021
    Date of Patent: August 15, 2023
    Assignee: UOP LLC
    Inventors: Joseph A. Montalbano, John J. Senetar, Nasim Ghazinoor, Richard A. Johnson, II, Lev Davydov
  • Patent number: 11167238
    Abstract: A packed bed for a heat exchanger may comprise a frame and a first fin layer disposed within the frame. A second fin layer may be disposed within the frame. A first perforated sheet may be disposed between the first fin layer and the second fin layer. A sorbent material may be disposed within a volume of at least one of the first fin layer or the second fin layer.
    Type: Grant
    Filed: November 5, 2019
    Date of Patent: November 9, 2021
    Assignee: Hamilton Sunstrand Corporation
    Inventors: James R. O'Coin, William G Papale, Jr.
  • Patent number: 10207217
    Abstract: A process for removing hydrogen sulfide and carbon dioxide from a fluid stream comprises a) an absorption step in which the fluid stream is contacted with an absorbent comprising an aqueous solution (i) of an amine of the general formula (I) in which R1, R2 and R3 are each independently selected from C1-4-alkyl and C1-4-hydroxyalkyl; each R4 is independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl; each R5 is independently selected from hydrogen, C1-4-alkyl and C1-4-hydroxyalkyl; X is OH or NH(CR1R2R3); m is 2, 3, 4 or 5; n is 2, 3, 4 or 5; and o is 0 or 1; and optionally (ii) at least one tertiary amine, where the molar ratio of (i) to (ii) is greater than 0.
    Type: Grant
    Filed: August 20, 2015
    Date of Patent: February 19, 2019
    Assignee: BASF SE
    Inventors: Thomas Ingram, Ralf Notz, Gerald Vorberg, Georg Sieder
  • Patent number: 8932388
    Abstract: The present invention is related to an apparatus and a method for converting gas into fuel. The apparatus for converting gas into fuel in accordance with an embodiment of the present invention can include: a first gas processing unit discharging first fuel gas by removing hydrogen sulfide in the raw gas by spraying a solution; a second gas processing unit discharging second fuel gas by removing moisture in the first fuel gas; a third gas processing unit discharging third fuel gas by removing hydrogen sulfide remaining in the second fuel gas; and a solution reservoir supplied with the solution from at least one of the second gas processing unit and the third gas processing unit and storing the solution.
    Type: Grant
    Filed: March 15, 2011
    Date of Patent: January 13, 2015
    Assignee: Korea Electric Power Corporation
    Inventors: Jung-Keuk Park, Kwang-Beom Hur, Sang-Gyu Rhim, Jung-Bin Lee
  • Patent number: 8845787
    Abstract: Acid compounds are removed from a gaseous effluent in an absorption method using an aqueous solution of N,N,N?,N?-tetramethylhexane-1,6-diamine formulated with a particular primary or secondary amine, allowing to obtain a single-phase absorbent solution under the absorption conditions of acid gases such as CO2. The method is advantageously applied to the treatment of natural gas and of gas of industrial origin.
    Type: Grant
    Filed: July 21, 2009
    Date of Patent: September 30, 2014
    Assignee: IFP Energies Nouvelles
    Inventors: Marc Jacquin, Julien Grandjean, Thierry Huard
  • Patent number: 8821615
    Abstract: The disclosure relates to a process for treating a gas mixture containing carbon dioxide and hydrogen sulphide, including the following steps: deacidificating the gas mixture by bringing the gas mixture into contact with a first lean absorbent solution stream, delivering a deacidified gas mixture, and a first rich absorbent solution stream; regenerating the first rich absorbent solution stream, delivering the first lean absorbent solution stream and a sour gas stream; distillating the sour gas stream, delivering a first carbon-dioxide-rich stream and a hydrogen-sulphide-rich stream; purifying the first carbon-dioxide-rich stream by bringing the first carbon-dioxide-rich stream into contact with a second lean absorbent solution stream, delivering a second carbon-dioxide-rich stream and a second rich absorbent solution stream, the molar concentration of carbon dioxide in the second carbon-dioxide-rich stream being greater than the molar concentration of carbon dioxide in the first carbon-dioxide-rich stream.
    Type: Grant
    Filed: June 25, 2010
    Date of Patent: September 2, 2014
    Assignee: Total S.A.
    Inventors: Claire Weiss, Renaud Cadours, Kamal Bouzalmata
  • Patent number: 8784532
    Abstract: Methods and apparatus relate to recovery of carbon dioxide and/or hydrogen sulfide from a gas mixture. Separating of the carbon dioxide, for example, from the gas mixture utilizes a liquid sorbent for the carbon dioxide. The liquid sorbent contacts the gas mixture for transfer of the carbon dioxide from the gas mixture to the liquid sorbent. The carbon dioxide then desorbs from the liquid sorbent using hollow-fiber contactors as a source of heat to liberate the carbon dioxide further separated by the hollow-fiber contactors from the liquid sorbent.
    Type: Grant
    Filed: March 1, 2012
    Date of Patent: July 22, 2014
    Assignee: Phillips 66 Company
    Inventors: Imona C. Omole, George F. Schuette
  • Publication number: 20140150652
    Abstract: A flue gas treatment system includes a CO2 absorber having an inlet for receiving a SO3 aerosol containing gas in the CO2 absorber. An amine solvent is supplied to the CO2 absorber. The CO2 absorber has a high temperature region and a lower temperature region. The high temperature region is configured to create an amine vapor and the lower temperature region is configured to cause the amine vapor to condense on the SO3 aerosol creating SO3/amine droplets. A SO3 aerosol removal device is positioned downstream of the CO2 absorber for removing the SO3/amine droplets from the gas.
    Type: Application
    Filed: November 30, 2012
    Publication date: June 5, 2014
    Applicant: ALSTOM TECHNOLOGY LTD.
    Inventor: Stephen Alan Bedell
  • Patent number: 8652237
    Abstract: A system and process are disclosed for selective removal and recovery of H2S from a gaseous volume, e.g., from natural gas. Anhydrous organic, sorbents chemically capture H2S gas to form hydrosulfide salts. Regeneration of the capture solvent involves addition of an anti-solvent that releases the captured H2S gas from the capture sorbent. The capture sorbent and anti-solvent are reactivated for reuse, e.g., by simple distillation.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: February 18, 2014
    Assignee: Battelle Memorial Institute
    Inventors: David J. Heldebrant, Phillip K. Koech, James E. Rainbolt, Mark D. Bearden, Feng Zheng
  • Patent number: 8551220
    Abstract: A sulfur dioxide absorbent comprising an ionic liquid comprised of alkyl ether-substituted imidazolium cation and an alkanesulfonate anion moieties possesses a high thermal/chemical stability, high SO2 absorption rate and low regeneration temperature, and is useful for an effective separation of SO2 from a combustion exhaust gas mixture or the like.
    Type: Grant
    Filed: April 20, 2011
    Date of Patent: October 8, 2013
    Assignee: Korea Institute of Science and Technology
    Inventors: Kwang Deog Jung, Hong Gon Kim, Chang Soo Kim, Hoon Sik Kim, Minserk Cheong, Sung Yun Hong
  • Publication number: 20130247755
    Abstract: An absorber that uses a gasified gas containing CO2 and H2S formed by gasifying coal, for example, as an introduced gas, and that makes the CO2 and H2S absorbed from the introduced gas by bringing the introduced gas into contact with an absorbent for absorbing C02 and H2S; an absorbent regenerator-that extracts absorbent that has absorbed CO2 and H2S from the bottom of the absorber and introduces the absorbent from the top of the absorber, and that regenerates the absorbent by releasing the CO2 and H2S; a second supply line that returns the regenerated absorbent from the regenerator to the absorber; and a third supply line that extracts the absorbent (semi-rich solution) that has absorbed a part of the CO2 and H2S from the vicinity of the middle of the absorber, and that introduces the semi-rich solution in the vicinity of the middle of the regenerator.
    Type: Application
    Filed: September 22, 2011
    Publication date: September 26, 2013
    Applicant: MITSUBISHI HEAVY INDUSTRIES, LTD.
    Inventors: Kouji Horizoe, Shinya Tachibana, Moritoshi Murakami, Masaki Yushima, Kazuo Ishida
  • Patent number: 8523978
    Abstract: A method of deacidizing a gaseous effluent comprising acid compounds where the gaseous effluent is contacted in C1 with an adsorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. These two fractions are then separated in BS1. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution.
    Type: Grant
    Filed: March 9, 2007
    Date of Patent: September 3, 2013
    Assignee: Institut Francais du Petrole
    Inventors: Alexandre Rojey, Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
  • Patent number: 8506683
    Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.
    Type: Grant
    Filed: June 11, 2010
    Date of Patent: August 13, 2013
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
  • Patent number: 8500865
    Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. According to the invention, the absorbent solution is regenerated in at least two stages in regeneration zones Z1 and Z2. At the end of the first regeneration stage in Z1, at least part of the partly regenerated absorbent solution is separated into two fractions in B1: a fraction rich in acid compounds and a fraction depleted in acid compounds. Fraction 10 rich in acid compounds is sent to the second regeneration stage in Z2. The fraction depleted in acid compounds and regenerated absorbent solution 6 from the second regeneration stage are recycled to absorption column C1. The method can be applied to combustion fumes decarbonation and to natural gas or synthesis gas deacidizing.
    Type: Grant
    Filed: November 20, 2009
    Date of Patent: August 6, 2013
    Assignee: IFP
    Inventors: Pierre-Antoine Bouillon, Marc Jacquin, Alain Methivier
  • Patent number: 8435325
    Abstract: Disclosed are methods for recovering CO2 and H2S from a feed gas including at least CO2 and H2S.
    Type: Grant
    Filed: October 19, 2009
    Date of Patent: May 7, 2013
    Assignee: Hitachi, Ltd.
    Inventor: Tomoko Akiyama
  • Patent number: 8419843
    Abstract: In one embodiment, a system includes a hydrogen sulfide (H2S) absorber, a first flash tank, a flash gas treatment column, and a CO2 absorber. The system also includes a first fluid path extending sequentially through the H2S absorber, the first flash tank, the flash gas treatment column, the H2S absorber, and the CO2 absorber.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: April 16, 2013
    Assignee: General Electric Company
    Inventors: Arnaldo Frydman, Pradeep Stanley Thacker, Sachin Suhas Naphad
  • Patent number: 8388747
    Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas and the helium is recovered and sold. Excess nitrogen is vented.
    Type: Grant
    Filed: August 22, 2008
    Date of Patent: March 5, 2013
    Inventor: Donald Leo Stinson
  • Patent number: 8388737
    Abstract: A method and apparatus for recovering a gaseous component from an incoming gas stream is described. The incoming gas stream is contacted with a lean aqueous absorbing medium to absorb at least a portion of the gaseous component from the incoming gas stream to form a lean treated gas stream and a rich aqueous absorbing medium. At least a portion of the gaseous component is desorbed from the rich aqueous absorbing medium at a temperature to form an overhead gas stream and a regenerated aqueous absorbing medium. At least a portion of the overhead gas stream is treated to recover a condensate stream. At least a portion of the condensate stream is used to form a heated stream. At least a portion of the heated stream is recycled back to the desorbing step. Novel absorbing medium compositions to recover carbon dioxide and/or hydrogen sulfide are also described.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: March 5, 2013
    Assignee: University of Regina
    Inventors: Don Gelowitz, Paitoon Tontiwachwuthikul, Raphael Idem
  • Patent number: 8361424
    Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions in BS1: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution. According to the invention, an absorbent solution portion circulating in C1 is cooled in E2 in order to prevent demixing of the solution in column C1.
    Type: Grant
    Filed: September 23, 2009
    Date of Patent: January 29, 2013
    Assignee: IFP
    Inventors: Pierre-Antoine Bouillon, Marc Jacquin, Ludovic Raynal
  • Patent number: 8303685
    Abstract: An improved acid gas regeneration and injection process wherein the separated acid gas stream emerging from a regenerator is compressed and injected into subsurface reservoir, the improvement comprising conducting the acid gas separation in the regenerator under pressure that exceeds 50 psia and does not exceed 300 psia.
    Type: Grant
    Filed: June 21, 2004
    Date of Patent: November 6, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Craig N. Schubert, Timothy C. Frank
  • Patent number: 8287625
    Abstract: Embodiments of the present invention are directed to systems and methods for treating landfill gas using landfill leachate. In one embodiment of the present invention, a method includes receiving landfill leachate from at least one of a plurality of sources, and pretreating the landfill leachate to adjust at least one chemical property of at least one component of the landfill leachate. The leachate contacts landfill gas, so that at least one component of the landfill gas chemically reacts with at least one component of the landfill leachate to form a spent landfill leachate and a treated landfill gas. The method also includes recycling a first portion of the spent landfill leachate, recirculating a second portion of the spent landfill leachate to at least one of the plurality of sources, and subjecting the treated landfill gas to flare.
    Type: Grant
    Filed: June 3, 2011
    Date of Patent: October 16, 2012
    Assignee: Casella Waste Systems, Inc.
    Inventor: Douglas R. Casella
  • Patent number: 8287626
    Abstract: A method for treating a gas mixture containing acid gases, including: contacting the gas mixture with an absorbing solution, to obtain a de-acidified gas mixture and an absorbing solution with acid gases. To regenerate the absorbing solution with acid gases, the absorbing solution is passed into a first regenerator at a first pressure, then the solution is passed into a second regenerator at a second pressure, and finally to a third regenerator at a third pressure, the third pressure being less than the second pressure which is less than the first pressure. The gases from the second and third regenerator are compressed and recycled to the first and second regenerator, respectively. Gases from the second and/or the third regenerator are drawn off to provide a gas mixture rich in hydrogen sulfide. Gases from the first regenerator are drawn off to provide a gas mixture rich in carbon dioxide.
    Type: Grant
    Filed: January 18, 2008
    Date of Patent: October 16, 2012
    Assignee: Total S.A.
    Inventors: Viep Hoang-Dinh, Damien Roquet, Kenza Habchi-Tounsi, Olivier Chazelas, Claire Weiss
  • Patent number: 8231706
    Abstract: A method for separating methane and carbon dioxide from biogas and a device are intended for purifying biogas, wherein carbon dioxide is separated off from the biogas. The method is distinguished by an energetically favorable mode of operation. The biogas is passed under atmospheric pressure and standard temperature into an absorption column. While the biogas ascends through a packed bed, which has a surface area of 600 to 1200 m2/m3, and at a space velocity of 5 to 40 Nm3/m3h, carbon dioxide present in the biogas is bound in a wash liquid by chemosorption. The purified methane gas is taken off at the top of the absorption column at a defined flow velocity. Carbon dioxide bound in the wash liquid is removed by desorption at a relatively high pressure of 2 to 30 bar and a temperature of at least 120° C. Biogas may be separated into methane and CO2.
    Type: Grant
    Filed: March 19, 2007
    Date of Patent: July 31, 2012
    Assignee: MT-Biomethan GmbH
    Inventor: Lothar Günther
  • Patent number: 8231719
    Abstract: An absorbent liquid according to the present invention is an absorbent liquid for absorbing CO2 or H2S or both from gas, in which the absorbent liquid includes an alkanolamine as a first compound component, and a second component including a nitrogen-containing compound having in a molecule thereof two members or more selected from a primary nitrogen, a secondary nitrogen, and a tertiary nitrogen or a nitrogen-containing compound having in a molecule thereof all of primary, secondary, and tertiary nitrogens. The absorbent liquid has an excellent absorption capacity performance and an excellent absorption reaction heat performance, as compared to an aqueous solution containing solely an alkanolamine and a nitrogen-containing compound in the same concentration in terms of wt %, and can recover CO2 or H2S or both from gas with smaller energy.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: July 31, 2012
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Ryuji Yoshiyama, Masazumi Tanoura, Noriko Watari, Shuuji Fujii, Yukihiko Inoue, Mitsuru Sakano, Tarou Ichihara, Masaki Iijima, Tomio Mimura, Yasuyuki Yagi, Kouki Ogura
  • Patent number: 8226748
    Abstract: A CO2 reducing system (10A) is constituted by a low-temperature CO2 reducing apparatus (11-1) that includes a low-temperature absorber (1006-1) that reduces at least one of CO2 and H2S by bringing flue gas (1002) including at least one of CO2 and H2S into contact with a low-temperature absorbing solution (1005-1), a low-temperature regenerator (1008-1) that regenerates a low-temperature rich solution (1007-1), a low-temperature rich-solution supply line (12-1) that feeds the low-temperature rich solution (1007-1) to the low-temperature regenerator (1008-1), and a low-temperature lean-solution supply line (13-1) that feeds a low-temperature lean solution (1009-1) to the low-temperature absorber (1006-1) from the low-temperature regenerator (1008-1); and a high-temperature CO2 reducing apparatus (11-2) that is arranged on a side at which the flue gas (1002) is discharged, and that has the same configuration as the low-temperature CO2 reducing apparatus (11-1).
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: July 24, 2012
    Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.
    Inventors: Yukihiko Inoue, Ryuji Yoshiyama, Tsuyoshi Oishi, Masaki Iijima, Masazumi Tanoura, Tomio Mimura, Kouki Ogura, Yasuyuki Yagi
  • Patent number: 8206489
    Abstract: The present invention relates to a method of deacidizing a gaseous effluent, wherein the following stages are carried out: a) contacting the gaseous effluent with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property to form two separable phases when it absorbs an amount of acid compounds, b) separating the absorbent solution laden with acid compounds into two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds, c) regenerating the second fraction so as to release part of the acid compounds, d) mixing a predetermined amount of water with the first absorbent solution fraction obtained in stage b) or with the regenerated absorbent solution fraction obtained in stage c), then e) recycling the first absorbent solution fraction and the regenerated absorbent solution as the absorbent solu
    Type: Grant
    Filed: December 19, 2006
    Date of Patent: June 26, 2012
    Assignee: Institut Francais du Petrole
    Inventors: Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
  • Patent number: 8192530
    Abstract: A system (10) for regenerating a rich absorbent solution (26), the system including: an absorber (20) facilitating interaction between a process stream (22) and an absorbent solution, wherein the process stream comprises an acidic component, and interaction of the process stream with the absorbent solution produces a reduced acidic component stream (28) and a rich absorbent solution; at least one heat exchanger accepting at least one of said reduced acidic component stream and the process stream to transfer heat to a heat transfer fluid (60); and at least one mechanism (60a) to transfer the heat transfer fluid from said at least one heat exchanger to a regenerator (34) regenerating the rich absorbent solution, wherein each of the at least one mechanisms is fluidly coupled to each of the at least one heat exchangers.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: June 5, 2012
    Assignee: ALSTOM Technology Ltd
    Inventors: Nareshkumar B. Handagama, Rasesh R. Kotdawala
  • Publication number: 20120132443
    Abstract: A process for the removal of CO2 and/or H2S from a gas comprising CO2 and/or H2S. The process comprises contacting the gas in an absorber with an absorbing solution wherein the absorbing solution absorbs at least part of the CO2 and/or H2S so as, to produce a CO2 and/or H2S lean gas and a CO2 and/or H2S rich absorbing solution. At least part of the CO2 and/or H2S rich absorbing solution is heated to produce a heated CO2 and/or H2S rich absorbing solution. At least part of the CO2 and/or H2S is removed from the heated CO2 and/or H2S rich absorbing solution in a regenerator to produce a CO2 and/or H2S rich gas and a CO2 and/or H2S lean absorbing solution. In the process, at least part of the heat for heating the CO2 and/or H2S rich absorbing solution in step b) is obtained in a sequence of multiple heat exchangers.
    Type: Application
    Filed: June 18, 2010
    Publication date: May 31, 2012
    Inventor: Jiri Peter Thomas Van Straelen
  • Publication number: 20120042778
    Abstract: A sulfur dioxide absorbent comprising an ionic liquid comprised of alkyl ether-substituted imidazolium cation and an alkanesulfonate anion moieties possesses a high thermal/chemical stability, high SO2 absorption rate and low regeneration temperature, and is useful for an effective separation of SO2 from a combustion exhaust gas mixture or the like.
    Type: Application
    Filed: April 20, 2011
    Publication date: February 23, 2012
    Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY
    Inventors: Kwang Deog JUNG, Hong Gon KIM, Chang Soo KIM, Hoon Sik KIM, Minserk CHEONG, Sung Yun HONG
  • Patent number: 8088200
    Abstract: In a method for removing acid gases from a fluid stream, the fluid stream, which is in contact with an absorption medium within an absorber, is passed through a first absorption zone in the absorber to remove a majority of acid gases from the fluid stream. The fluid stream is susequently passed through a second absorption zone in the absorber to further remove acid gases from the fluid stream. The loaded absorption medium is passed into a first regeneration zone to obtain a partially regenerated absorption medium, and a part of the partially regenerated absorption medium is passed into the first absorption zone. The other part of the partially regenerated absorption medium is passed into a second regeneration zone to obtain a regenerated absorption medium. A part of the regenerated absorption medium is passed into the first absorption zone and the other part is passed into the second absorption zone.
    Type: Grant
    Filed: February 14, 2007
    Date of Patent: January 3, 2012
    Assignee: BASF SE
    Inventors: Rupert Wagner, Randolf Hugo
  • Publication number: 20110315014
    Abstract: A method for removing SOx (x=2 and/or 3) from gas using a solution having polyethylene glycol as the main ingredient. First, SOx in the gas is absorbed by the solution of polyethylene glycol. Second, the solution of polyethylene glycol which has absorbed SOx is regenerated by one or more of the heating, vacuum, ultrasonic, microwave or radiation methods, thereby releasing the by-products of sulfur dioxide and sulfur trioxide. The regenerated solution of polyethylene glycol is recycled. When the water content of the regenerated solution of polyethylene glycol is high enough to affect the desulfurization, it needs to be removed. Removal methods include heating and rectification, absorption using a water absorbent, or a combination of these methods. The polyethylene glycol solution is recycled after dehydration.
    Type: Application
    Filed: February 10, 2010
    Publication date: December 29, 2011
    Applicants: BEIJING BOYUAN-HENGSHENG HIGH-TECHNOLOGY CO., LTD., PEKING UNIVERSITY, YONGFENG BOYUAN INDUSTRY CO., LTD.
    Inventors: Xionghui Wei, Fang Han, Jianbin Zhang, Pengyan Zhang, Daolong Gao, Jinfei Wang, Chuan Zou, Chun Hu
  • Patent number: 8007569
    Abstract: The invention relates to a method for removing hydrogen sulphide and other acidic gas components from pressurized technical gases by means of a physical detergent and for obtaining sulphur from hydrogen sulphide by using a Claus system. The hydrogen sulphide and the other acidic gas components are removed in an absorbent manner from the physical detergent, the physical detergent undergoes multi-step regeneration, said multi-step regeneration comprising at least one device for CO enrichment, a device for H2S enrichment, a device for CO2 stripping and a device for thermal regeneration. The various regeneration steps consist of various pressure steps and have a lower pressure than that of the absorption. A hydrogen sulphide rich Claus gas is withdrawn from one of the regeneration steps and is guided to a Claus system where sulphur is produced. The residual gas exiting from the Claus system is hydrated and is condensed under pressure, corresponding to one of the regeneration steps.
    Type: Grant
    Filed: July 12, 2004
    Date of Patent: August 30, 2011
    Assignee: Uhde GmbH
    Inventors: Georg Saecker, Johannes Menzel
  • Patent number: 7988767
    Abstract: Contemplated configurations and methods for elemental sulfur removal from various gases, and especially well acid gases employ a hydrocarbon solvent that dissolves the sulfur to form a rich solvent and that is then regenerated by hydrotreating. Thus, sulfur is removed from the rich solvent as H2S that may then be processed (e.g., in Claus unit or absorption unit) while the regenerated solvent is routed back to the well and associated production pipes.
    Type: Grant
    Filed: August 28, 2007
    Date of Patent: August 2, 2011
    Assignee: Fluor Technologies Corporation
    Inventors: Curt Graham, Robert Henderson, Richard B. Nielsen, Michael Debest
  • Patent number: 7967895
    Abstract: For regenerating the loaded washing (scrubbing) agent (6, 7) from a physical gas wash (T1), in which one or more gas components are removed, to a large extent selectively, from a gas mixture (1) to be purified at least in a first of at least two successive washing steps, the loaded washing agent (7) withdrawn from the first washing step is, independently of the remaining quantity of loaded washing agent (6), subjected to a regeneration step (T2a) for separating the gas components (11) which have been selectively removed from the raw gas in the first washing step.
    Type: Grant
    Filed: March 27, 2007
    Date of Patent: June 28, 2011
    Assignee: Linde AG
    Inventors: Ulrich Prüssner, Horst Weiss
  • Patent number: 7964025
    Abstract: Systems and techniques for the reclamation of carbon dioxide from boiler flue gas as well as for the liquefaction of the reclaimed carbon dioxide for well injection oil recovery are provided. A system can include a boiler, tower scrubber, carbon dioxide absorber, regenerator, reboiler, rectifying tower, condenser and mixing tank. Mixed gases of carbon dioxide and nitrogen for well injection may be reclaimed from boiler flue gas when steam is produced resulting in an increase of crude oil output increase while lessening environmental impact. Related systems, apparatus, methods, and articles are also described.
    Type: Grant
    Filed: November 14, 2007
    Date of Patent: June 21, 2011
    Assignee: Liaohe Petroleum Exploration Bureau, CNPC
    Inventors: Fengshan Zhang, Yuanwen Gao
  • Patent number: 7955419
    Abstract: Embodiments of the present invention are directed to systems and methods for treating landfill gas using landfill leachate. In one embodiment of the present invention, a method includes receiving landfill leachate from at least one of a plurality of sources, and pretreating the landfill leachate to adjust at least one chemical property of at least one component of the landfill leachate. The leachate contacts landfill gas, so that at least one component of the landfill gas chemically reacts with at least one component of the landfill leachate to form a spent landfill leachate and a treated landfill gas. The method also includes recycling a first portion of the spent landfill leachate, recirculating a second portion of the spent landfill leachate to at least one of the plurality of sources, and subjecting the treated landfill gas to flare.
    Type: Grant
    Filed: July 25, 2007
    Date of Patent: June 7, 2011
    Assignee: Casella Waste Systems, Inc.
    Inventor: Douglas R. Casella
  • Patent number: 7935323
    Abstract: The invention describes a system and method for hydrogen sulfide decontamination of natural gas using a scavenging reagent. The system uses a scavenging reagent within two reactors wherein the consumption of scavenging reagent is optimized by the control of flow of clean and partially-consumed scavenging reagent within and between the two reactors.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: May 3, 2011
    Assignee: Cody Liners Ltd.
    Inventors: Marc Schulz, Leonard McKeary
  • Patent number: 7909914
    Abstract: The present invention relates to a method of removing acid gases, notably carbonyl sulfide, contained in gaseous effluents, comprising: an acid gas absorption stage by contacting the gaseous effluent with an aqueous solution comprising 2-[2-amino-1-(aminomethyl)ethoxy]ethanol, and possibly another alkanolamine and an organic compound, and at least one aqueous solution regeneration stage. The method can comprise a second aqueous solution regeneration stage. The regeneration stages are carried out by expansion and/or thermal regeneration.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: March 22, 2011
    Assignee: IFP
    Inventors: Renaud Cadours, Julia Magne-Drisch, Bruno Delfort
  • Patent number: 7883569
    Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas; and the helium is recovered and sold. Excess nitrogen is vented.
    Type: Grant
    Filed: February 12, 2007
    Date of Patent: February 8, 2011
    Inventor: Donald Leo Stinson
  • Publication number: 20110008229
    Abstract: A process for the removal of hydrogen sulfide from a gas stream in which the gas stream is first passed through a Claus unit operating at a sub-stoichiometric ratio (H2S:SO2) of greater than 2:1 to produce a tail gas stream comprising less than 2000 vppm SO2. This tail gas stream is then treated to increase the sulfur recovery to at least 99.5% by first directly cooling the tail gas stream by contact with water as a coolant, followed by contacting the gas stream with a circulating stream of a dilute, absorbent solution of a severely sterically hindered secondary aminoether alcohol to further cool the gas stream, and then removing the H2S from the stream using a stronger absorbent solution of a severely sterically hindered secondary aminoether alcohol.
    Type: Application
    Filed: June 29, 2010
    Publication date: January 13, 2011
    Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Jagannathan N. IYENGAR, David PERRY, Robert B. FEDICH
  • Patent number: 7857891
    Abstract: Novel solvent composition for selective removal of COS from a gas stream containing same, said composition comprising a) at least one polyalkylene glycol alkyl ether of the formula (I) or 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone or a mixture of N-formylmorpholine and N-acetylmorpholine Wherein R1 is an alkyl group having from 1 to 6 carbon atoms; R2 is hydrogen or an alkyl group having from 1 to 4 carbon atoms; Alk is an alkylene group, branched or unbranched, having from 2 to 4 carbon atoms, and n is from 1 to 10; and b) at least one alkanolamine compound of the formula (II) or at least one piperazine compound of formula (III) wherein R3 is hydrogen, an alkyl group having from 1 to 6 carbon atoms, or the R4OH group; R4 is a branched or unbranched alkylene group having from 1 to 6 carbon atoms; R5, independently in each occurrence, is hydrogen or an hydroxyalkyl group having from 1 to 4 carbon atoms; and R6 is hydrogen, an alkyl group having from 1 to 6 carbon atoms or an hydroxyalkyl group having f
    Type: Grant
    Filed: March 11, 2004
    Date of Patent: December 28, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Craig N. Schubert, Arnold C. Ashcraft
  • Publication number: 20100288125
    Abstract: An absorption medium for the removal of acid gases from a fluid stream comprises an aqueous solution a) of at least one amine and b) at least one phosphonic acid, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The phosphonic acid is, e.g., 1-hydroxyethane-1,1-diphosphonic acid. The absorption medium exhibits a reduced regeneration energy requirement compared with absorption media based on amines or amine/promoter combinations, without significantly decreasing the absorption capacity of the solution for acid gases.
    Type: Application
    Filed: October 9, 2009
    Publication date: November 18, 2010
    Inventors: Gerald Vorberg, Torsten Katz, Georg Sieder, Christian Riemann, Erika Dengler
  • Patent number: 7754102
    Abstract: This invention discloses a method for the reclaim of carbon dioxide and nitrogen from boiler flue gas, which includes: the flue gas enters into the water-washing and desulfurizing tower from the inferior part and contacts the sulfide solution flowing backward for the cleaning and desulfurizing of the flue gas; the desulfurized flue gas is introduced to the inferior part of the chemical absorber, where the contained carbon dioxide contacts the carbon dioxide adsorption liquid (containing, by the total weight of the liquid, of, besides water, 20-60% water solution of compound amine, 5-10% polyoxinolum, 1-5% antioxygen and 1-5% corrosion inhibitor) flowing backward; The adsorption liquid coming from the bottom of the absorber and having absorbed carbon dioxide, after heated when passing through heat exchangers, is sent to the top of the carbon dioxide regenerator and flows down through the packing layer; carbon dioxide is emitted out from the top of the regenerator; Nitrogen separated out from the top of the che
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: July 13, 2010
    Assignee: CNPC Greatwall Drilling Engineering Company Ltd.
    Inventors: Fengshan Zhang, Yuanwen Gao, Yongchun Zhang
  • Patent number: 7749309
    Abstract: Disclosed is a method for deacidifying a fluid stream containing acidic gases as contaminants, according to which the fluid stream is brought into intimate contact with a washing liquid in at least one absorption step. Said washing liquid represents an aqueous solution containing a) tertiary aliphatic alkanolamines (alkanolamine A), at least 30 percent by weight of said tertiary aliphatic alkanolamines being 3-dimethylamino-1-propanol, and b) secondary aliphatic amines (activator B), at least 20 percent by weight of said secondary aliphatic amines being piperazin. The fluid stream which has been essentially purified of the acidic gases is then separated from the washing liquid that is loaded with acidic gases.
    Type: Grant
    Filed: March 4, 2003
    Date of Patent: July 6, 2010
    Assignee: BASF Aktiengesellschaft
    Inventors: Norbert Asprion, Christoph Grossmann
  • Patent number: 7604686
    Abstract: The invention relates to a method for cooling rising vapor (3) in a desorption column (2) by means of a condenser, which is situated at the head of the desorption column, is configured as an indirect heat exchanger and is traversed by a coolant (1). According to said method, the coolant enters at the bottom of the condenser (1) and flows upwards through conduits (8) that are arranged vertically in the condenser. The coolant is enriched with hydrogen sulphide prior to its entry into the condenser (1) and after the absorption of heat, escapes as an overflow (6) from the top of the condenser (1) through upper openings (10) of the conduits (8). The invention also relates to a desorption column (2) for carrying out said method.
    Type: Grant
    Filed: August 6, 2003
    Date of Patent: October 20, 2009
    Assignee: Uhde GmbH
    Inventor: Holger Thielert
  • Patent number: 7604684
    Abstract: With the help of a method of selective removal of hydrogen sulphides, organic sulphur components and CO2 from crude gases, by using a first and second absorption stage (41 or 49) for separating almost pure CO2, a solution has to be found, with which, among other things, hydrogen sulphides and organic sulphur compounds can be removed in as selective a manner as possible. This is achieved as follows: the absorption agent coming out of the first absorption stage (41) and enriched with hydrogen sulphide and CO2 a.o.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: October 20, 2009
    Assignee: Uhde GmbH
    Inventor: Johannes Menzel
  • Patent number: 7597746
    Abstract: A gas (1) comprising hydrogen sulfide, carbon dioxide, and hydrocarbon contaminants is treated in a plant (FIG. 2) in a configuration in which waste streams are recycled to extinction. In especially preferred aspects of contemplated methods and configurations, hydrogen sulfide and other sulfurous components are converted to a sulfur product (37), carbon dioxide (44A) is separated at a purity sufficient for enhanced oil recovery or sale, and hydrocarbon contaminants are purified to a marketable hydrocarbon product (49).
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: October 6, 2009
    Assignee: Fluor Technologies Corporation
    Inventors: John Mak, Curt Graham
  • Patent number: 7550033
    Abstract: A method for removing organic sulfur compounds from a vent gas is described. Also described is an apparatus for absorbing organic sulfur compounds from vent gas.
    Type: Grant
    Filed: January 21, 2002
    Date of Patent: June 23, 2009
    Assignee: ConocoPhillips Company
    Inventors: Samuel Henry Beuke, Richard Sadok, Alfred Keller
  • Publication number: 20090101868
    Abstract: This invention discloses a method for the reclaim of carbon dioxide and nitrogen from boiler flue gas, which includes: the flue gas enters into the water-washing and desulfurizing tower from the inferior part and contacts the sulfide solution flowing backward for the cleaning and desulfurizing of the flue gas; the desulfurized flue gas is introduced to the inferior part of the chemical absorber, where the contained carbon dioxide contacts the carbon dioxide adsorption liquid (containing, by the total weight of the liquid, of, besides water, 20-60% water solution of compound amine, 5-10% polyxinolum, 1-5% antioxygen and 1-5% corrosion inhibitor) flowing backward; The adsorption liquid coming from the bottom of the absorber and having absorbed carbon dioxide, after heated when passing through heat exchangers, is sent to the top of the carbon dioxide regenerator and flows down through the packing layer; carbon dioxide is emitted out from the top of the regenerator; Nitrogen separated out from the top of the c
    Type: Application
    Filed: November 9, 2007
    Publication date: April 23, 2009
    Inventors: Fengshan Zhang, Yuanwen Gao