Liquid Contact In Plural Serial Stages Patents (Class 95/199)
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Publication number: 20080178733Abstract: A gas cleaning system, which is operative for cleaning a process gas containing carbon dioxide and sulphur dioxide, comprises a combined cooling and cleaning system (16), and a CO2-absorber. The combined cooling and cleaning system (16) comprises a first gas-liquid contacting device (50) located upstream of the CO2-absorber and operative for cooling the process gas by means of a cooling liquid, and for absorbing into the cooling liquid sulphur dioxide of the process gas, such that a cooling liquid containing sulphate is obtained. The combined cooling and cleaning system (16) further comprises a second gas-liquid contacting device (94) located downstream of the CO2-absorber and operative for removing ammonia from the process gas, which has been treated in the CO2-absorber, by means of bringing the process gas containing ammonia into contact with the cooling liquid containing sulphate.Type: ApplicationFiled: January 17, 2008Publication date: July 31, 2008Inventor: Eli Gal
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Patent number: 7374604Abstract: The present invention discloses a system for flue gas treatment, wherein the provided system comprises a quench module, a first control module, a filter collecting module, a wet scribing module and a regeneration module. In this system, parts of the particles contained in flue gas are removed in the quench module and the wet scribing module by a first scrubbing solution, and then in wet scribing module a second scrubbing liquid containing particles is formed. Next, the second scrubbing solution is treated in the regeneration module to form a third scrubbing solution, wherein the third scrubbing solution is then fed back to the quench module and/or the wet scrubbing module to substitute the first scrubbing solution for repeating what originally performed via the first scrubbing solution. Furthermore, this invention discloses a method for flue gas treatment.Type: GrantFiled: December 7, 2004Date of Patent: May 20, 2008Assignee: Chung Yuan Christian UniversityInventor: Chien-Song Chyang
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Patent number: 7288140Abstract: In a wet-process gas treatment method of treating an acid gas by using at least two treating columns connected in series, a ratio of the concentration of an acid gas at an outlet to a concentration of the acid gas at an inlet of a first treating column is set higher than a ratio of the concentration of the acid gas at an outlet to the concentration of acid gas at an inlet of at least one of the other treating columns, thereby preventing deposits from forming in the interior of connecting pipes between the columns and in the interiors of the treating columns, to prevent the connecting pipes from being blocked.Type: GrantFiled: October 8, 2004Date of Patent: October 30, 2007Assignee: Canon Kabushiki KaishaInventors: Hiroshi Echizen, Hiroshi Izawa
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Patent number: 7189282Abstract: This invention relates to a process for cleaning gas, in particular hydrocarbonaceous gas such as e.g. natural gas, which is contaminated with sulfur in the form of H2S and mercaptans as well as CO2. To remove the undesired sulfur-containing substances in the form of H2S and mercaptan from crude gas, it is proposed in accordance with the invention that the crude gas is introduced into an absorption and regeneration column and washed therein, three gas streams being withdrawn from this absorption and regeneration column, a first exhaust gas stream being introduced into a Claus plant, a second sour gas stream with a low H2S concentration being introduced into another absorption plant, and a third gas stream, the valuable gas with the mercaptans, being cooled and supplied to an adsorption plant, that from this adsorption plant a cleaned valuable gas is withdrawn, and a mercaptan-containing gas stream is subjected to washing, that this concentrated mercaptan-containing gas is supplied to the Claus plant.Type: GrantFiled: January 22, 2003Date of Patent: March 13, 2007Assignee: Lurgi AGInventors: Karin Huder, Max-Michael Weiss
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Patent number: 7077884Abstract: A hydrogen sulfide scrubber includes first and second scrubber tanks with scrubber media contained therein. Scrubbing solution circulators each include a dispenser for dispensing scrubbing solution into contact with the scrubber media, a sump for collecting the scrubbing solution after contact with the scrubber media, and a circulating pump for circulating the scrubbing solution from the sump back to the dispenser after contact with the scrubber media. A polymeric amine supply is provided for supplying a polymeric amine to the scrubbing solution in the second tank. The scrubbing solution in the first tank may be charged with the polymeric amine by a charging line extending from the second tank to the first tank. In other embodiments, a regenerative blower and associated nozzle may be used to generate a scrubbing solution mist in the space beneath the scrubber media and above the sump.Type: GrantFiled: June 9, 2004Date of Patent: July 18, 2006Assignee: Precision Control Technology, Inc.Inventors: Jerry M. Davis, James E. Cheshire
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Patent number: 7018450Abstract: The natural gas is successively contacted in column CA with a relatively methanol-rich solvent flowing in through line 4, then with a relatively poor solvent flowing in through line 9. The acid gas-containing solvent recovered through line 3 at the bottom of column CA is expanded through valves V1 and V2 to release acid gases through line 6. A fraction of the expanded solvent is distilled in column CR. The regenerated solvent obtained at the bottom of column CR is sent to the top of column CA through line 9. A second fraction of the expanded solvent is mixed with a solvent drawn off from column CR at an intermediate point between the bottom and the top of this column. This mixture of solvents is sent through line 4 into column CA.Type: GrantFiled: October 6, 2003Date of Patent: March 28, 2006Assignee: Institut Francais du PetroleInventors: Alexandre Rojey, Fabrice Lecomte, Eric Lemaire
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Patent number: 7014684Abstract: A process and a device for cleaning waste gas from pulp production, especially for cleaning waste gases from a bleaching reactor. Aerosols contained in the waste gas are removed and the gaseous impurities are scrubbed out of the waste gas by a scrubbing liquid.Type: GrantFiled: November 30, 2001Date of Patent: March 21, 2006Assignee: Linde AktiengesellschaftInventors: Wolfgang Dietrich, Hans Hiller
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Method and system for increasing the absorption selectivity of H2S from a gas containing CO2 and H2S
Patent number: 6884282Abstract: A system and a method for increasing the selectivity of H2S absorption in an aqueous amine treating processes for streams containing high CO2:H2S ratio mixtures in an absorption column by maintaining the temperature in the absorption column by withdrawing, cooling and returning cooled aqueous amine to the column at at least one location intermediate the sour gas inlet to the column and the lean gas outlet from the column.Type: GrantFiled: May 13, 2003Date of Patent: April 26, 2005Inventors: David K. Stevens, Kevin M. Robertson, Mark R. Tonjes, Lindsay Wedel Dreitzler -
Patent number: 6821317Abstract: In a wet-process gas treatment method of treating an acid gas by using at least two treating columns connected in series, a ratio of the concentration of an acid gas at an outlet to a concentration of the acid gas at an inlet of a first treating column is set higher than a ratio of the concentration of the acid gas at an outlet to the concentration of acid gas at an inlet of at least one of the other treating columns, thereby preventing deposits from forming in the interior of connecting pipes between the columns and in the interiors of the treating columns, to prevent the connecting pipes from being blocked.Type: GrantFiled: December 18, 2002Date of Patent: November 23, 2004Assignee: Canon Kabushiki KaishaInventors: Hiroshi Echizen, Hiroshi Izawa
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Patent number: 6773582Abstract: A drinking water treatment system includes a pump for pumping water from an aquifer, an aerator connected downstream from the pump for generating an outlet water flow and a hydrogen sulfide-containing gas flow, and a hydrogen sulfide scrubber for scrubbing the hydrogen sulfide-containing gas flow from the aerator. The hydrogen sulfide scrubber includes at least one scrubber tank and scrubber media contained therein. A scrubbing solution circulator includes a dispenser for dispensing scrubbing solution into contact with the scrubber media, a sump for collecting the scrubbing solution after contact with the scrubber media, and a circulating pump for circulating the scrubbing solution from the sump back to the dispenser after contact with the scrubber media. A triazine compound supply is provided for supplying a triazine compound to the scrubbing solution.Type: GrantFiled: September 25, 2002Date of Patent: August 10, 2004Assignee: Precision Control Technology, Inc.Inventor: Patrick M. Anthony
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Patent number: 6759018Abstract: A system for abating undesired component(s) from a gas stream containing same, such as halocompounds, acid gases, silanes, ammonia, etc., by scrubbing of the effluent gas stream with an aqueous scrubbing medium. Halocompounds, such as fluorine, fluorides, perfluorocarbons, and chlorofluorocarbons, may be scrubbed in the presence of a reducing agent, e.g., sodium thiosulfate, ammonium hydroxide, or potassium iodide. In one embodiment, the scrubbing system includes a first acid gas scrubbing unit operated in cocurrent gas/liquid flow, and a second “polishing” unit operated in countercurrent gas/liquid flow, to achieve high removal efficiency with low consumption of water. The scrubbing system may utilize removable insert beds of packing material, packaged in a foraminous containment structure. The abatement system of the invention has particular utility in the treatment of semiconductor manufacturing process effluents.Type: GrantFiled: December 15, 1998Date of Patent: July 6, 2004Assignee: Advanced Technology Materials, Inc.Inventors: Jose I. Arno, Mark Holst, Sam Yee, Joseph D. Sweeney, Jeff Lorelli, Jason Deseve
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Patent number: 6726748Abstract: A method of reducing the pressure drop in a downflow/upflow wet flue gas desulfurization (WFGD) system and of improving overall sulfur dioxide collection efficiency by converting the downflow/upflow WFGD system to an upflow single-loop WFGD system. The method includes the replacing of the downflow quencher and related duct work with a bypass for connecting the incoming flue gas duct with the upflow absorber, and the adding of a quenching zone in the absorber comprised of spray headers.Type: GrantFiled: July 16, 2002Date of Patent: April 27, 2004Assignee: The Babcock & Wilcox CompanyInventors: Ronald L. Goode, Dennis W. Johnson, David W. Murphy, Robert B. Myers, John F. Sulek, David R. Burley, Paul J. Lieb
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Patent number: 6719829Abstract: The present invention provides improved systems and methods for scrubbing gas with a venturi scrubber. A dual spray venturi scrubber, in which a scrubbing liquid is injected upstream and counter to the flow through the venturi, provides for improved scrubbing performance, including efficient and economical scrubbing of fine particles. Specifically, the present invention reduces the scrubbing liquid pumping requirements, improves the scrubber performance, and provides better control of the pressure drop across the venturi scrubber. The control of pressure drop across the venturi can be obtained with no internal mechanisms or upstream spray.Type: GrantFiled: April 22, 2002Date of Patent: April 13, 2004Assignee: EnviroCare International, Inc.Inventor: James J. Schwab
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Publication number: 20040011200Abstract: A method of reducing the pressure drop in a downflow/upflow wet flue gas desulfurization (WFGD) system and of improving overall sulfur dioxide collection efficiency by converting the downflow/upflow WFGD system to an upflow single-loop WFGD system. The method includes the replacing of the downflow quencher and related duct work with a bypass for connecting the incoming flue gas duct with the upflow absorber, and the adding of a quenching zone in the absorber comprised of spray headers.Type: ApplicationFiled: July 16, 2002Publication date: January 22, 2004Inventors: Ronald L. Goode, Dennis W. Johnson, David W. Murphy, Robert B. Myers, John F. Sulek, David R. Burley, Paul J. Lieb
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Patent number: 6666908Abstract: Within the scope of a process using two absorption sections for treating a natural gas containing CO2 and/or H2S, as well as mercaptans, COS and/or CS2, the present invention aims to wash the gaseous hydrocarbons desorbed upon expansion of the solvent from the first absorption section with the solvent from the second absorption section.Type: GrantFiled: January 29, 2002Date of Patent: December 23, 2003Assignee: Institut Francais du PetroleInventors: Renaud Cadours, Fabrice Lecomte, Pascal Mougin
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Patent number: 6645273Abstract: A method for removing impurity substances in air flowing in a flow passage includes filtering the air in a first filter for removing solid substances; cooling the air in a first cooler to not higher than its dew-point temperature; capturing gaseous substances in the air in a wet-type impurity removing apparatus; cooling the air in a second cooler; and filtering in a second filter. The wet-type impurity removing apparatus includes a first liquid atomizer having two pluralities of nozzle ports for spraying, arranged mutually spaced apart and facing each other in the direction of the air flow passage; first and second condensing and capturing assemblies located across the first atomizer and spaced apart from each other, with the first assembly being upstream and the second assembly being downstream from the first atomizer; a second atomizer for capturing any remaining gaseous substances in the air; and a third condensing and capturing assembly.Type: GrantFiled: December 23, 2002Date of Patent: November 11, 2003Assignee: Oki Electric Industry Co, LTDInventors: Hidetoshi Wakamatsu, Mikio Matsuki, Norio Tanaka, Hiroshi Ogata
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Patent number: 6623546Abstract: According to the invention, the vapor is taken from the condensation chamber of the dehydrator and, prior to being compressed and at a temperature substantially equal to 100° C., it is caused to pass in succession through a series of purifiers, and in each of the purifiers it is forced through rain containing a purifying solution, at least one of the rain solutions being water, another containing an acid, and another containing a base. The invention is applicable to treating the vapor that results from dehydrating a variety of kinds of matter, such as farmyard manure, in particular.Type: GrantFiled: July 25, 2001Date of Patent: September 23, 2003Assignee: SirvenInventor: Jacques Bourdel
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Publication number: 20030116018Abstract: In a wet-process gas treatment method of treating an acid gas by means of at least two treating columns connected in series, ratio of concentration of acid gas at an outlet to concentration of acid gas at an inlet, of a first treating column is set higher than ratio of concentration of acid gas at an outlet to concentration of acid gas at an inlet, of at least one of other treating columns, thereby preventing deposits from forming in the interior of connecting pipes between the columns and in the interiors of the treating columns, to prevent the connecting pipes from their blockage.Type: ApplicationFiled: December 18, 2002Publication date: June 26, 2003Inventors: Hiroshi Echizen, Hiroshi Izawa
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Patent number: 6551382Abstract: Effluent gas cleaning process and apparatus for effectively removing particulates in the 0.01 micron to 0.1 micron diameter range, and for removing water-soluble gaseous contaminants, by first bringing the effluent to a relatively high temperature and humidity in a first stage, and then exposing the effluent to copious quantities of small cool water droplets in a second stage, for particular combinations of: the first stage relative humidity; the first-to-second stage droplet temperature difference; the stage two water droplet mass flow rate vs. effluent flow rate; the second stage droplet size; the travel time of the effluent during exposure to the cool droplets; and the electrical charge state of the second stage water droplets and opposite charge state of the particulates. The combinations enhance effluent cleaning through the combined operation of up to four distinct physical processes which can be made to occur during the second stage.Type: GrantFiled: May 24, 2002Date of Patent: April 22, 2003Inventor: Clyde N. Richards
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Patent number: 6511529Abstract: The object of the invention is to provide a method of treating wash water resulting from the scrubbing of process gases in smelting plants, according to which method the wash water is brought into intimate contact with the process gas and is circulated when the solids have been deposited. The method according to the invention draws off a partial flow from the wash water, mixes it with fresh water and uses it for rewashing the process gas. According to the invention, the wash water necessary for the scrubbers is drawn from a wash water container. In the sedimentation tank the insoluble portions are removed from the substance-charged wash water which is then introduced into the wash water container. The wash water required for the rewashing stage is removed from the wash water container and mixed with fresh water via the fresh water pipe.Type: GrantFiled: June 7, 2002Date of Patent: January 28, 2003Assignee: Voest-Alpine Industrieanlagenbau GmbHInventors: Karin Pichler, Günter Schrey, Alfred Hirsch
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Patent number: 6506348Abstract: There is provided a heavy oil fired boiler exhaust gas treatment apparatus which removes soot and dust and SO3 in the heavy oil fired boiler exhaust gas efficiently at a low cost without using an excessively large apparatus. The treatment apparatus comprises a charging device 3 provided at the inlet of an absorption tower of a wet type exhaust gas desulfurizer 4 and neutralizer pouring means A provided on the upstream side of the charging device 3 to pour a neutralizer into exhaust gas and neutralize SO3 in the exhaust gas.Type: GrantFiled: November 10, 1998Date of Patent: January 14, 2003Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Eiji Ochi, Takeo Shinoda, Toru Takashina, Masakazu Onizuka
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Publication number: 20020178917Abstract: The loaded wash liquid contains H 2 S, CO, H 2 , CO 2 , nickel carbonyl and/or iron carbonyl. Carbon monoxide is initially and partially removed from the loaded wash liquid and the wash liquid which is low in CO is conducted through a reaction and settling zone. Sludge containing nickel and/or iron sulfide is extracted from the reaction and settling zone and the wash liquid is conducted to a heat regeneration device The regenerated wash liquid can be re-utilized for desulfurization purposes.Type: ApplicationFiled: December 6, 1999Publication date: December 5, 2002Inventors: GERHARD GRUNEWALD, UWE ZWIEFELHOFER
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Patent number: 6458188Abstract: A method of filtering an air or gas stream utilizes a liquid, such as water, to saturate the gas stream. A sufficient quantity of water is presented to the gas stream to saturate the gas stream and knock particulate matter out of the gas stream. The gas stream can be cooled prior to saturating it with liquid. It may be desirable to reduce the flow rate of the gas stream to ensure maximum filtration. After the particulate matter is knocked out of the gas stream, it can be removed and processed as desired.Type: GrantFiled: July 14, 2000Date of Patent: October 1, 2002Inventor: Timothy D. Mace
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Patent number: 6333003Abstract: A treatment apparatus for treating a substrate in an isolated treatment space in an air-conditioned clean room, comprising a removing unit including a plurality of removing sections for recovering at least some of air in the treatment space and removing impurities from the recovered air, the removing sections being arranged in series and each including a supply mechanism for supplying an impurity remover capable of removing the impurities by touching the recovered air, a temperature adjustment unit for adjusting the temperature of the air cleared of the impurities by the removing unit, and a return circuit for returning the air, adjusted in temperature by the temperature adjustment unit, to the treatment space.Type: GrantFiled: May 22, 1998Date of Patent: December 25, 2001Assignee: Tokyo Electron LimitedInventors: Takayuki Katano, Junichi Kitano, Masami Akimoto, Norio Semba
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Patent number: 6325983Abstract: A treatment system for process exhaust streams containing NOx. The system includes a plurality of sequential scrubbing assemblies that collectively receive and contact a process exhaust stream containing NOx and a water stream to produce a product exhaust stream with a concentration of NOx that is below a determined threshold value. The removed NOx forms a portion of a system waste liquid stream that includes a majority of the NOx removed from the process exhaust stream.Type: GrantFiled: April 19, 2000Date of Patent: December 4, 2001Assignee: SEH America, Inc.Inventors: Andrew J. Bomber, Allen R. Boyce, Debasish Mukhopadhyay
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Patent number: 6287367Abstract: This concept concerns a vapor/liquid contacting tray which is useful in distillation and related mass transfer or heat transfer applications where liquid flows down and gas or vapor flows up through a vessel. In this device, the perforated area is relatively small, so the liquid is entrained upward. The liquid flow is then directed downward into a large disengaging area. The downward momentum of the liquid and the large disengaging allow for high liquid and vapor rates without overloading the vapor/liquid disengaging capacity of the device.Type: GrantFiled: December 15, 1999Date of Patent: September 11, 2001Assignee: Mobil Oil CorporationInventors: John Scott Buchanan, Berne Kim Stober
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Patent number: 6235961Abstract: An inline, high-shear mixer is provided in a cracked gas stream upstream of a caustic tower in an ethylene production unit. Spent caustic is withdrawn from the bottom of the caustic tower and pumped to the mixer, where the spent caustic mixes with and absorbs acid gas components from the cracked gas stream. The spent caustic is separated from the cracked gas, forming a partially treated cracked gas stream. The partially treated cracked gas stream is then fed to the caustic tower. Polymer deposition in the caustic tower is reduced because polymeric material is formed when the cracked gas stream is mixed with the spent caustic and is removed before the cracked gas stream is fed to the caustic tower.Type: GrantFiled: January 29, 1999Date of Patent: May 22, 2001Assignee: Stone & Webster Engineering CorporationInventor: Sabah A. Kurukchi
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Patent number: 6221133Abstract: The invention provides a cellular packing including a vapor/liquid separation device that can be stacked vertically with minimum wasted space. The packing uses static vanes in each cell to direct the liquid component of a vapor/liquid mixture to exit slots in a first cell and a recirculation path for the liquid to be contacted with vapor again in a second cell located below the first.Type: GrantFiled: December 29, 1999Date of Patent: April 24, 2001Assignee: Norton Chemical Process Products CorporationInventor: Frank D. Moore
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Patent number: 6183540Abstract: A method is provided for the extraction of aromatic hydrocarbons, including benzene, toluene, ethylbenzene, and xylene, collectively known as “BTEX,” in a continuous process utilizing a glycol contactor to cause absorption of the BTEX upstream of an amine-based gas sweetening process. The preferred glycol for BTEX absorption is triethylene glycol. The glycol used in the glycol contactor for BTEX extraction may either be fully regenerated (dry), or wet glycol from a downstream gas dehydration system. The method may be achieved with the use of a number of separate absorber/contactor vessels, or the method may be achieved within one combination vessel.Type: GrantFiled: August 27, 1999Date of Patent: February 6, 2001Assignee: Kinder Morgan, Inc.Inventor: Jonathan E. Thonsgaard
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Patent number: 6179901Abstract: Hydrogen fluoride production apparatus removes phosphate rock dust from a hot gas mixture exhausted from a phosphate rock defluorination kiln; cools the hot gas mixture in a heat exchanger to a low enough temperature that it can be brought into contact with acid-resistant polymeric materials without destroying them; uses a water spray scrubber for further cooling the gas and absorbing the fluoride values as HF-rich liquor; and pumps the HF liquor to a holding tank. One such plant uses a gas tube steam boiler as the heat exchange and has several series-connected scrubbers to extract the fluorine values from the kiln exhaust so that the residual gas mixture can be exhausted into the atmosphere without exceeding permissible fluorine value levels. In this arrangement water is fed into the scrubber furthest from the boiler to extract HF from the process gas, and an HF-laden process liquor is fed out of the furthest scrubber into the second furthest scrubber, where it is sprayed into the gas stream.Type: GrantFiled: June 14, 1999Date of Patent: January 30, 2001Inventor: Louis J. Lamb
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Patent number: 6063163Abstract: According to the present invention, an inexpensive co-current and counter-current gas dehydration system, contactor apparatus, and operating method is provided which does not result in a need to clean equipment on a frequent basis. More specifically, there is provided a dehydration system, contactor apparatus, and method for removing water from a stream of wet natural gas which minimizes formation or iron sulfide scale within the contactor apparatus to maintain sufficient water removal capacity and to reduce operator cleanup and construction expenses. The instant invention improves the utilization of the water absorbing capabilities of glycol by using partially water laden glycol extracted from the central portion of the contactor apparatus in a co-current flow with wet natural gas to maximize the operating efficiency of the contactor apparatus.Type: GrantFiled: June 4, 1998Date of Patent: May 16, 2000Assignee: Amerada Hess CorporationInventor: Paul Carmody
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Patent number: 6019819Abstract: Disclosed is a contaminated waste steam heat recovery apparatus 10 and method therefore which includes a primary condensing unit 38, a low pressure water washing unit 26, a liquid to liquid heat exchanger 36 and a vent fan 31. Waste gas is ducted from fryer 11 to a de-super-heating chamber 14 wherein superheated steam is converted to saturated steam by spraying water into the steam using spray nozzles 15. The gas is then introduced into a vertically disposed air to liquid heat exchanger 16 and is drafted downward therethrough. As heat is removed from the waste gas, water vapor in the steam condenses and in the process, collects some of the oil and hydrocarbons present. A plurality of condensate trays 19 are disposed below the bottom end of heat exchanger 16 in a cascading fashion to collect hold the condensate in the airflow path such that it will absorb some of the heat still present in the remaining waste gas.Type: GrantFiled: March 17, 1998Date of Patent: February 1, 2000Assignee: Alpha Engineers, Inc.Inventor: Eddy A. Williams
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Patent number: 5938820Abstract: A gas cleaning apparatus is disclosed which comprises a housing having an inlet adjacent a bottom portion thereof and an outlet adjacent a top portion thereof. The housing preferably has at least one radially-extending vane disposed along a longitudinal axis of the housing. A settling tank is fluidly connected at a top portion thereof to the base of the housing, at least one outlet fluidly connected to a waste treatment apparatus, and at least one outlet fluidly connected to the housing between the inlet and the outlet of the housing. The waste treatment apparatus preferably has at least one outlet fluidly connected to the housing between the inlet and the outlet of the housing.Type: GrantFiled: September 26, 1997Date of Patent: August 17, 1999Assignee: CMI-Schneible CompanyInventors: Rodney W. Peters, Dallas V. Bicknell, Richard D. McKibben, Daniel D. Minor
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Patent number: 5879434Abstract: The invention relates to a multi-washer, and to a method of cleaning synthesis gases obtained by the gasification of wastes of the most varied composition. Such multi-washers are used to remove lumpy and adhesive materials from the synthesis gas, such as carbon particles and sulphur. According to the present invention, a horizontal container (1) is sub-divided by partition bulkheads (5) into a plurality of successive wash chambers (2,3,4), which are each provided with a sumpless outflow to a respective pump system (6,7,8). Disposed in each of the wash chambers (2,3,4) is a least one substance exchanger (9) in an oblique position, which is sprayed from both sides with varying quantities of wash liquid. The sprayed wash liquid penetrates into the substance exchangers (9) and, due to the varying quantity, is removed in an directed fashion. As the wash liquid also sprays the wall of the container (1), total self-cleaning of the multi-washer is ensured.Type: GrantFiled: July 18, 1997Date of Patent: March 9, 1999Assignee: Thermoselect AGInventor: Gunter H. Kiss
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Patent number: 5756058Abstract: Impurities such as halides and ammonia are efficiently removed from a gas containing Sox at a high concentration without any substantial addition of fresh water in a process for purifying a sulfur oxides-containing gas. The process involves passing a gas containing sulfur oxides and impurities at a high concentration successively through a first washing column and thence through a second washing column, thereby water washing the gas through the two washing columns to remove the impurities from the gas. The first washing column is operated so that the outlet temperature of the gas from the first washing column is at a temperature at which the gas can have a maximum water content or a temperature near this temperature, and the second washing column is operated such that the outlet temperature of the gas from the second washing column at least 20.degree. C. lower than the outlet temperature of the gas from the first washing column.Type: GrantFiled: January 18, 1996Date of Patent: May 26, 1998Assignee: Sumitomo Heavy Industries, Ltd.Inventors: Teruo Watanabe, Hiromi Tanaka, Kouji Kobayashi
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Patent number: 5660615Abstract: Exhaust gas is brought into contact with a washing liquid chiefly consisting of water in at least two washing stages. In the last washing stage, fresh water and/or a washing liquid containing fresh water is sprayed into the exhaust gas. In the penultimate washing stage, the exhaust gas is brought in contact with a circulating aqueous salt solution, which contains substances supplied by the exhaust gas. In the penultimate washing stage, the exhaust gas is passed through a washing zone at temperatures in the range from 30.degree. to 150.degree. C., where the quantity of aqueous salt solution passed into the washing zone per Nm.sup.3 exhaust gas flowing through the washing zone is 0.1 to 10 liters. The exhaust gas coming from the penultimate washing zone has a temperature in the range from 30.degree. to 80.degree. C., is saturated with steam for 90 to 100%, and does not contain more than 50% by weight of the dust content of the exhaust gas before the same enters the penultimate washing stage.Type: GrantFiled: February 15, 1996Date of Patent: August 26, 1997Assignee: Metallgesellschaft AGInventors: Ulrich Neumann, Wolfgang Willing
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Patent number: 5512084Abstract: A method of removing organic contaminants from a process gas such as raw, untreated landfill gas is disclosed. The steps involve collecting the process gas that includes organic contaminants for removal. An absorption liquid such as a terpene, is injected as a mist into the process gas to form a two-state absorption liquid and process gas fluid. The two-state absorption liquid and gas fluid communicates through a heat exchange module for absorption of organic contaminants in the process gas by the absorption liquid resulting in a cleaned process gas. The absorption liquid then is separated from the cleaned process gas.Type: GrantFiled: September 9, 1994Date of Patent: April 30, 1996Assignee: Contaminant Separations, Inc.Inventor: David Mauterer
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Patent number: 5474597Abstract: In a method for cleaning polluted gas and/or cooling of hot gas, and a device for carrying out the method, the gas is contacted with finely divided liquid. The finely divided liquid is supplied in the form of essentially umbrella-shaped shells or essentially linear curtains, in a regular arrangement, distributed in two or more planes substantially perpendicular to the main flow direction of the gas. The finely divided liquid is supplied such that the gas is alternatively concentrated and spread by the impulse action exerted by the liquid on the gas in directions perpendicular to the main flow direction of the gas. The orthogonal distance between adjacent planes in which finely divided liquid is supplied, is so adjusted that no substantial equalization of the gas flow takes place between the planes.Type: GrantFiled: August 30, 1994Date of Patent: December 12, 1995Assignee: ABB Flakt ABInventor: Claes Halldin
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Patent number: 5434330Abstract: A process and an apparatus for separating desired clathrate forming gases from a gas mixture containing the desired clathrate forming gases. The process includes providing a stream of the gas mixture, contacting the stream of the gas mixture with an aqueous solvent to form a solid clathrate hydrate suspension in the aqueous solvent. The forming of the solid clathrate hydrate suspension in the aqueous solution causing the gaseous stream to be thereafter leaner in the desired clathrate forming gases. The solid clathrate hydrate suspension and the aqueous solution are subjected to an elevated temperature and to a reduced pressure to produce a product gaseous stream which is richer in the desired clathrate forming gases.Type: GrantFiled: June 23, 1993Date of Patent: July 18, 1995Inventors: Miguel A. Hnatow, John Happel
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Patent number: 5401297Abstract: Disclosed is a process for removing emissions from caprolactam polymerization operations and thermoplastic polycaprolactam processing operations by collecting air containing the emissions, directing the air, containing the emissions, to a candle filter in a candle filter housing and rinsing the air, containing the emissions, within the candle filter with an aqueous caprolactam solution, containing at least 4% by weight caprolactam.Type: GrantFiled: September 30, 1993Date of Patent: March 28, 1995Assignee: BASF CorporationInventors: Beth O. Teague, Dennis G. Shealy, William C. Hiatt
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Patent number: 5364604Abstract: A solute gas absorbing procedure employs a parallel flow of liquid absorbing medium to dual-fluid spray nozzles from which are formed fine droplet sprays in which the solute gas is absorbed. The invention is particularly applicable to the removal of acid gases, such as SO.sub.2, using regenerable aqueous alkaline absorbing media, such as amines or amine salts.Type: GrantFiled: November 12, 1992Date of Patent: November 15, 1994Assignee: Turbotak Technologies Inc.Inventors: Donald R. Spink, Kim D. Nguyen
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Patent number: 5330563Abstract: A process is disclosed for recovering a volatile organic compound at a recovery of 90 to 96% by volume from a gas generated from gasoline, kerosine, benzene, and alcohol discharged from storage tanks, tank trucks, and tank lorries. In the process comprising absorption stages followed by desorption stages for the volatile organic compound, the pressure at the desorption stages is controlled within the area below, for instance, curves C' and B in FIG. 1 of the drawings according to the concentration of the volatile organic compound in the gas to be fed to a first absorption stage.Type: GrantFiled: March 19, 1993Date of Patent: July 19, 1994Assignee: Showa Shell Sekiyu Kabushiki KaishaInventors: Osamu Yamase, Yasuyuki Makita, Kazuyoshi Jajima