By Heating (e.g., Fractional Distillation, Etc.) Patents (Class 95/209)
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Patent number: 11536390Abstract: A subplate mounted (SPM) valve includes a valve body having pilot port, a piston configured to be actuated by fluid from the pilot port, a first control chamber and second control chamber each formed in the valve body and fluidicly isolated from the pilot port, a first flow restrictor fluidicly disposed between the first control chamber and the second control chamber and configured to restrict flow in at least one direction between the first control chamber and the second control chamber, a cage coupled to the valve body and having a supply port, a return port, and a work port, and a spool slidably engaged with the cage and configured to selectively restrict flow between the supply port and the return port by actuation of the piston.Type: GrantFiled: May 13, 2019Date of Patent: December 27, 2022Assignee: National Oilwell Varco, L.P.Inventors: James Ray Landrith, II, Frank B. Springett, Eric Trevor Ensley, Jonathan Lewis Buelow, James W. Weir, Travis James Miller
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Patent number: 11325063Abstract: Disclosed is a production device and production method of electronic grade hydrofluoric acid. The method includes vaporizing the raw material industrial anhydrous hydrogen fluoride by an evaporator, transporting the vaporized hydrogen fluoride to a purification tower, obtaining a high purity hydrogen fluoride gas through rectification, transporting the high purity hydrogen fluoride gas to an absorption tower for absorption by a certain concentration of hydrofluoric acid in the liquid phase, obtaining the crude electronic grade hydrofluoric acid, and obtaining the electronic grade hydrofluoric acid product through ultrapure filtration. The disclosure overcomes the technical problems of small yield and low purity of the prior art. The production process meets the requirements of environmental protection. The disclosure is suitable for industrialized large-scale production.Type: GrantFiled: September 25, 2020Date of Patent: May 10, 2022Assignee: Beijing University of Chemical TechnologyInventor: Qunsheng Li
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Patent number: 8961665Abstract: There is provided an exhaust gas treatment system including a CO2 recovery unit with further enhanced energy efficiency. The exhaust gas treatment system (1) includes: a CO2 recovery unit (10) including a CO2 absorption column (11), an absorbing solution regeneration column (16), a condensate supply pipeline (15) for supplying condensate, which contains CO2 absorbing solution discharged from the CO2 absorption column (11) to a bottom portion of the absorbing solution regeneration column (16), and a CO2 separation section (22) for performing heat exchange, via a heat exchanger (23), between the CO2 discharged from the absorbing solution regeneration column (16) and the condensate; and an exhaust gas heat exchanger (5) provided on a gas upstream side of the CO2 recovery unit (10) for performing heat exchange between exhaust gas before flowing into the CO2 recovery unit (10) and the condensate.Type: GrantFiled: September 5, 2012Date of Patent: February 24, 2015Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Tatsuya Tsujiuchi, Shintaro Honjo, Takahito Yonekawa, Satoru Sugita, Motofumi Ito, Takashi Kamijo, Tatsuto Nagayasu, Takuya Okamoto
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Patent number: 8961664Abstract: A carbon dioxide recovery unit is provided with: an absorption tower for bringing an exhaust gas into contact with a CO2 absorbing liquid to thereby absorb and recover CO2 from the exhaust gas; a regeneration tower for taking out the CO2 from the CO2 absorbing liquid; a CO2 delivery line L3 for delivering the taken-out CO2 to a storage process; and a CO2 return line L5 for returning the taken-out CO2 to the absorption tower. When a CO2 recovery unit and a CO2 compressing device are activated, if a storage process side has some kind of trouble and cannot receive the CO2, a destination part to which the CO2 is delivered from the regeneration tower is switched from the CO2 delivery line L3 to the CO2 return line L5, whereby the CO2 gas is mixed with the exhaust gas in the absorption tower.Type: GrantFiled: September 20, 2012Date of Patent: February 24, 2015Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Koji Nakayama, Takahito Yonekawa, Masayuki Inui, Tatsuya Tsujiuchi, Yoshiki Sorimachi
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Patent number: 8961663Abstract: An apparatus that separates and recovers CO2 from a CO2 absorbent that has absorbed CO2 includes a regeneration tower configured to apply heat to the CO2 absorbent that has absorbed CO2, configured to separate and remove CO2 from the CO2 absorbent, configured to exhaust CO2 gas, and configured to regenerate the CO2 absorbent, a plurality of compressors configured to compress the CO2 gas exhausted from the regeneration tower, a dehydration device provided between the plurality of compressors and configured to remove moisture from the compressed CO2, and a line configured to supply air or N2 gas into the dehydration device to preliminarily operate the dehydration device until a stable state is achieved before starting the compressor.Type: GrantFiled: September 6, 2012Date of Patent: February 24, 2015Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Taku Asano, Tatsuya Tsujiuchi, Richard Reinke
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Patent number: 8906149Abstract: The present application relates to a system for removal of gaseous contaminants from a gas stream. The system includes an absorber for contacting the gas stream with a wash solution to form a used wash stream, a regenerator for regenerating the used wash solution, a reboiler and at least two heat exchangers in fluid communication with the absorber, regenerator and reboiler.Type: GrantFiled: August 26, 2014Date of Patent: December 9, 2014Assignee: ALSTOM Technology LtdInventors: Barath Baburao, Jonathan W. Leister, Frederic Vitse
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Patent number: 8906141Abstract: An apparatus for separating and recovering CO2 from a CO2 absorbent, includes: a regeneration tower for regenerating the absorbent that has absorbed CO2 by heating it to separate and remove CO2 therefrom and to exhaust CO2 gas; a compressor for compressing the CO2 gas exhausted from the tower; and a heat exchanger for heating the absorbent in the tower by exchanging heat with a part of the compressed CO2 by the compressor which is introduced into the tower. The apparatus may include a plurality of the compressors and a plurality of the heat exchangers. The plurality of compressors is arranged in series to sequentially compress the CO2 gas exhausted from the tower. The plurality of heat exchangers is configured so that each part of the CO2 compressed by the plurality of compressors is introduced to the tower in parallel to exchange heat with the absorbent in the tower.Type: GrantFiled: August 9, 2012Date of Patent: December 9, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Tatsuya Tsujiuchi, Shintaro Honjo, Takahito Yonekawa, Satoru Sugita
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Patent number: 8900355Abstract: Impure carbon dioxide (“CO2”) comprising a first contaminant selected from the group consisting of oxygen (“O2”) and carbon monoxide (“CO”) is purified by separating expanded impure carbon dioxide liquid in a mass transfer separation column system. The impure carbon dioxide may be derived from, for example, flue gas from an oxyfuel combustion process or waste gas from a hydrogen (“H2”) PSA system.Type: GrantFiled: November 5, 2010Date of Patent: December 2, 2014Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Patent number: 8864887Abstract: A slug-containing vapor recovery system wherein pressure and/or fluid level sensors are provided which monitor for conditions caused by the entry of a slug of hydrocarbon liquid, including that caused by a plunger-lift system. The system can be configured to accommodate virtually any anticipated slug-events.Type: GrantFiled: September 30, 2011Date of Patent: October 21, 2014Inventors: Rodney T. Heath, Forrest D. Heath, Gary Heath
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Patent number: 8845789Abstract: The present application relates to systems and processes for removal of gaseous contaminants from gas streams. In particular, the application relates to a process for removal of gaseous contaminants from a gas stream comprising contacting the gas stream with a wash solution to remove gaseous contaminants from the gas stream by absorption into the wash solution; and regenerating the used wash solution to remove gaseous contaminants from the used wash solution, to provide a regenerated wash solution and a gas comprising removed contaminants, wherein in a first regeneration stage the gas comprising removed contaminants is cooled to minimize loss of water vapor from the regeneration step.Type: GrantFiled: March 26, 2010Date of Patent: September 30, 2014Assignee: ALSTOM Technology LtdInventors: Barath Baburao, Jonathan W. Leister, Frederic Vitse
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Patent number: 8845790Abstract: A method and system for removing gaseous contaminants from a gas stream by contacting the gas stream with a wash solution and regenerating the wash solution in a regeneration system for future use in removing gaseous contaminants from the gas stream.Type: GrantFiled: September 21, 2011Date of Patent: September 30, 2014Assignee: ALSTOM Technology LtdInventors: Jonathan W. Leister, Barath Baburao, Frederic Vitse
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Patent number: 8834609Abstract: A method for separating carbon dioxide from a flue gas of a fossil fuel-operated power plant is provided. In the method, a fossil fuel is initially burned in a combustion process, wherein a hot waste gas containing carbon dioxide is produced. In a next process step, waste gas containing carbon dioxide is brought into contact with an absorption medium in an absorption process, wherein carbon dioxide is absorbed by the absorption medium, thus forming a charged absorption medium. Next, gaseous carbon dioxide is thermally expelled from the charged absorption medium in a desorption process. For this purpose, a vapor is supplied to the desorption process, the vapor is injected into the charged absorption medium, wherein the condensation heat released by the condensation of the vapor is transferred to the charged absorption medium, and the partial pressure of the carbon dioxide is simultaneously reduced in the desorption unit.Type: GrantFiled: May 14, 2009Date of Patent: September 16, 2014Assignee: Siemens AktiengesellschaftInventors: Ralph Joh, Rüdiger Schneider, Henning Schramm
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Patent number: 8821615Abstract: The disclosure relates to a process for treating a gas mixture containing carbon dioxide and hydrogen sulphide, including the following steps: deacidificating the gas mixture by bringing the gas mixture into contact with a first lean absorbent solution stream, delivering a deacidified gas mixture, and a first rich absorbent solution stream; regenerating the first rich absorbent solution stream, delivering the first lean absorbent solution stream and a sour gas stream; distillating the sour gas stream, delivering a first carbon-dioxide-rich stream and a hydrogen-sulphide-rich stream; purifying the first carbon-dioxide-rich stream by bringing the first carbon-dioxide-rich stream into contact with a second lean absorbent solution stream, delivering a second carbon-dioxide-rich stream and a second rich absorbent solution stream, the molar concentration of carbon dioxide in the second carbon-dioxide-rich stream being greater than the molar concentration of carbon dioxide in the first carbon-dioxide-rich stream.Type: GrantFiled: June 25, 2010Date of Patent: September 2, 2014Assignee: Total S.A.Inventors: Claire Weiss, Renaud Cadours, Kamal Bouzalmata
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Patent number: 8814988Abstract: The present invention relates to a process for the recovery of ammonia contained in a gaseous stream, said process comprising the following phases: (a) subjecting the gaseous stream containing ammonia to a washing with an aqueous washing solution having a pH lower than 7.0, with the formation of a purified gaseous stream and an aqueous solution containing an ammonium salt; (b) treating the aqueous solution containing the ammonium salt coming from phase (a) in a vertical falling film heat exchanger at a temperature from 50 to 250° C. and an absolute pressure ranging from 50 KPa to 4 MPa with the formation of a regenerated washing solution and a gaseous stream comprising NH3 and H2O; (c) recycling said regenerated washing solution to phase (a). The present invention also relates to equipment for effecting the above process.Type: GrantFiled: July 27, 2010Date of Patent: August 26, 2014Assignee: Saipem S.p.A.Inventor: Paolo Casara
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Patent number: 8808429Abstract: A method for reclaiming CO2 absorbing chemical(s) from a lean aqueous CO2 absorbent leaving a regeneration column (8), where lean absorbent (30) is withdrawn and flashed (31) to generate a vapor that is compressed (34) and returned into the regeneration column as stripper gas (37), where a part of the lean absorbent (20) is withdrawn and introduced into a reclaimer (21) in which the lean absorbent is boiled to generate a gas phase (23) that is withdrawn and returned into the regeneration column as reclaimed absorbent, and a liquid phase containing impurities (24), wherein the gaseous phase that is withdrawn from the reclaimer is compressed (34) together with the vapor part (33) from the flashing of the lean absorbent, to generate a pressure in the reclaimer that is lower than the pressure in the regeneration column, and a reboiler (11) for carrying out the method, are described.Type: GrantFiled: June 9, 2010Date of Patent: August 19, 2014Assignee: Aker Clean Carbon ASInventors: Simon Woodhouse, Otto Morten Bade, Anne-Helene Haaland, Oddvar Gorset, Bjorn Magnus Berg
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Patent number: 8801836Abstract: The present invention relates to a method for recovery of carbon dioxide from a gas (G3), in particular the present invention relates to a method for recovery of carbon dioxide using a process gas (G1) heated reboiler (A1) for carbon dioxide removal in a stripper (A3).Type: GrantFiled: February 1, 2010Date of Patent: August 12, 2014Assignee: Union Engineering A/SInventor: Rasmus Find
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Patent number: 8801835Abstract: In some implementations, a method for dehydrating carbon dioxide includes identifying a stream including at least carbon dioxide and water. At least a portion of the stream is dehydrated using an initial lean sorbent including glycerol and a polyhydric alcohol to generate dry carbon dioxide stream and rich sorbent including water. The polyhydric alcohol reduces an amount of glycerol lost to the dry carbon dioxide stream during dehydration. This process may result in the beneficial reduction in the amount of glycerol that leaves the system with the dry carbon dioxide. The dry carbon dioxide and the rich sorbent are separated. The glycerol is recycled by dehydrating the rich sorbent to produce recycled lean sorbent.Type: GrantFiled: July 13, 2011Date of Patent: August 12, 2014Assignee: Denbury Onshore, LLCInventor: Kevin S. Fisher
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Patent number: 8795415Abstract: A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapor entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange.Type: GrantFiled: May 25, 2010Date of Patent: August 5, 2014Assignees: BASF SE, JGC CorporationInventors: Torsten Katz, Georg Sieder, Koji Tanaka
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Patent number: 8758483Abstract: A process for removing carbon dioxide from a fluid comprises the steps of: (a) treating the fluid by bringing it into countercurrent contact with a liquid absorbent in a first absorption zone and thereafter in a second absorption zone to absorb at least part of the carbon dioxide contained in the fluid into the absorbent; (b) depressurizing the loaded absorbent to release a first stream of carbon dioxide and yield a partially regenerated absorbent; (c) recycling a first stream of the partially regenerated absorbent into the first absorption zone; (d) heating a second stream of the partially regenerated absorbent to release a second stream of carbon dioxide and yield a regenerated absorbent; (e) recycling the regenerated absorbent into the second absorption zone; (f) condensing water vapor entrained in the second stream of carbon dioxide by cooling the second stream of carbon dioxide and transferring at least part of the heat recovered to the partially regenerated absorbent by indirect heat exchange.Type: GrantFiled: May 25, 2010Date of Patent: June 24, 2014Assignees: BASF SE, JGC CorporationInventors: Torsten Katz, Georg Sieder, Koji Tanaka
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Patent number: 8741034Abstract: An object of the present invention is to provide an exhaust gas treatment system that effectively use heat recovered from an exhaust gas without any limitation in a CO2 chemical absorption equipment that requires enormous heat energy, and thus enabling reduction in running cost of the CO2 chemical absorption equipment.Type: GrantFiled: April 19, 2011Date of Patent: June 3, 2014Assignee: Babcock-Hitachi Kabushiki KaishaInventors: Tomoyuki Konishi, Takanori Nakamoto, Naoki Oda, Nobuo Morimoto
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Patent number: 8728209Abstract: A method for reducing energy requirements of a CO2 capture system comprises: contacting a flue gas stream with a CO2 lean absorbent stream in an absorber, thereby removing CO2 from the flue gas and providing a CO2 rich absorbent stream; heating a first portion of the CO2 rich absorbent stream using heat from the CO2 lean absorbent stream, and providing the heated first portion of the CO2 rich absorbent stream to a regenerator; providing a second portion of the CO2 rich absorbent stream to the regenerator, wherein the heated first portion is hotter than the second portion and the heated first portion is provided to the regenerator at a lower elevation in the regenerator relative to that of the second portion.Type: GrantFiled: August 2, 2011Date of Patent: May 20, 2014Assignee: ALSTOM Technology LtdInventors: Joseph P. Naumovitz, Michael Koch
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Patent number: 8702839Abstract: Provided are a CO2 absorber that reduces CO2 contained in flue gas; a regenerator that reduces CO2 contained in rich solvent absorbing CO2 to regenerate the rich solvent, so that lean solvent having the CO2 reduced in the regenerator is reused in the CO2 absorber; a heat exchanger that allows the rich solvent to exchange heat with the lean solvent; and a controller that controls to extract rich solvent portion that is part of the rich solvent, to allow the rich solvent portion to bypass the heat exchanger, and to be supplied into the top of the regenerator without exchanging heat so as to minimize a sum of an enthalpy that is taken out of the regenerator as CO2 gas accompanying steam and an enthalpy of the lean solvent after heat exchange with the rich solvent in the heat exchanger.Type: GrantFiled: March 11, 2013Date of Patent: April 22, 2014Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Masaki Iijima, Kouki Ogura, Masahiko Tatsumi, Yasuyuki Yagi
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Patent number: 8690992Abstract: Processes for operating an ammonia stripper at a low pressure in a gas purification system include providing a first side-draw stream from the ammonia stripper; heating the first side-draw stream with a second side-draw stream from a regenerator; providing a stripper offgas stream from the ammonia stripper to a stripper overhead condenser; and utilizing the stripper offgas stream as a heat source for a regenerating system fluidly coupled to the stripper overhead condenser. Also disclosed are systems for implementing the processes.Type: GrantFiled: March 19, 2013Date of Patent: April 8, 2014Assignee: ALSTOM Technology LtdInventors: Sanjay Kumar Dube, Daniel Nicolaus Secundus Mattstedt, Joseph P. Naumovitz
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Patent number: 8673062Abstract: A method of removing acid gases from raw gas is disclosed in which the raw gas is supplied to an absorption column where it is contacted with a physical absorption agent, having a boiling point lower than 100° C. at atmospheric pressure, under elevated operating pressure to load, the physical absorption agent with acid gases and usable gases and then the physical absorption agent loaded with acid gases and usable gases is driven from the absorption column at its sump while drawing off at the head of the absorption column a purified top gas containing up to a few ppm of acid-gas components. Following the absorption, the physical absorption agent undergoes stripping to remove usable gases, and regeneration to remove the acid gases as well as to provide a regenerated physical absorbent which may be used to treat additional raw gas.Type: GrantFiled: November 4, 2009Date of Patent: March 18, 2014Assignee: UHDE GmbHInventor: Johannes Menzel
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Patent number: 8647420Abstract: [Problem] To provide a system for recovering carbon dioxide from flue gas, in which a reboiler in a regenerator can be compactly installed, and a method therefor, in facilities where CO2 or the like contained in flue gas is recovered. [Solving Means] To include an absorber 1006 that absorbs CO2 contained in flue gas 1002, a regenerator 1008 that strips CO2 from CO2 absorbent (rich solution) 1007 to regenerate absorbent, internal shells 101 provided at a bottom of the regenerator 1008 with a predetermined interval therebetween, into which regenerated CO2 absorbent is introduced by a feeding unit 102 from a bottom side thereof so that the CO2 absorbent overflows from an upper end of the internal shell thereof toward the bottom of the regenerator, and a reboiler that is inserted into the internal shells 101 in a direction orthogonal to a vertical axis and includes a heat-transfer tube 103 that reboils absorbent.Type: GrantFiled: April 7, 2011Date of Patent: February 11, 2014Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Hiroshi Tsubone, Toyoshi Nakagawa, Takashi Kamijo, Tsuyoshi Oishi, Katsufumi Inoue, Osamu Miyamoto
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Patent number: 8628643Abstract: A fermentation liquid feed including water and a product alcohol and optionally CO2 is at least partially vaporized such that a vapor stream is produced. The vapor stream is contacted with an absorption liquid under suitable conditions wherein an amount of the product alcohol is absorbed. The portion of the vapor stream that is absorbed can include an amount of each of the water, the product alcohol and optionally the CO2. The temperature at the onset of the absorption of the vapor stream into the absorption liquid can be greater than the temperature at the onset of condensation of the vapor stream in the absence of the absorption liquid. The product alcohol can be separated from the absorption liquid whereby the absorption liquid is regenerated. The absorption liquid can include a water soluble organic molecule such as an amine.Type: GrantFiled: August 10, 2011Date of Patent: January 14, 2014Assignee: Butamax Advanced Biofuels LLCInventors: Michael Charles Grady, William D. Parten, Robert W. Sylvester, Joseph J. Zaher
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Publication number: 20130247758Abstract: CO2 is absorbed from a gas mixture by contacting the gas mixture with an absorption medium which comprises at least water as solvent and at least one amine of formula (I) where R1 is an aliphatic radical, having 2 to 6 carbon atoms and at least one amino group, and R2 is hydrogen, a C1-4 alkyl radical or a radical R1.Type: ApplicationFiled: November 10, 2011Publication date: September 26, 2013Applicant: Evonik Degussa GmbHInventors: Matthias Seiler, Rolf Schreider, Jörn Rolker, Daniel Dembkowski, Manfred Neumann, Daniel Witthaut, Michael Keup, Volker Brehme, Muhammad Irfan
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Patent number: 8540803Abstract: A method and apparatus for drying a natural gas or an industrial gas that contains acidic gas components, wherein gas drying is followed by the removal of the acidic gas components from the dried gas. The same physical solvent is used for both of the process steps of gas drying and of acidic gas removal. The gas to be dried is brought into contact with the physical solvent, which absorbs most of the water contained in the gas. The physical solvent, loaded with water, is transferred into a solvent regenerating device to be heated where the water contained in the solvent is stripped from the solvent in the countercurrent by acidic gas that is removed from the dried useful gas during the acidic gas absorption. The acidic gas being released again in the acidic gas solvent regenerating device, stripped from the solvent, and discharged from the solvent regenerating device.Type: GrantFiled: September 22, 2010Date of Patent: September 24, 2013Assignee: ThyssenKrupp Uhde GmbHInventor: Johannes Menzel
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Patent number: 8535428Abstract: To include an absorber (1006) that brings CO2 absorbent that absorbs CO2 contained in flue gas (1002) into contact with the flue gas to remove CO2 from the flue gas, a regenerator (1008) that strips CO2 from CO2 absorbent (rich solution), which is fed from the absorber through a first feed line L1 and has absorbed CO2, to regenerate CO2 absorbent, thereby acquiring regenerated CO2 absorbent (lean solution) (1009), falling film reboilers (1101-1 and 1101-2) that draw off CO2 absorbent (amine solution) (1033) from near the bottom of the regenerator and reheats regenerated CO2 absorbent via steam (1031), a first liquid-vapor separator (1103) that separates the CO2 absorbent reheated by the falling film reboilers into regenerated CO2 absorbent in which CO2 has been removed and vapor containing CO2, and a second feed line L2 for supplying the separated regenerated CO2 absorbent to the absorber.Type: GrantFiled: January 26, 2009Date of Patent: September 17, 2013Assignee: Mitsubishi Heavy Industries, Ltd.Inventors: Katsufumi Inoue, Takashi Kamijo, Tsuyoshi Oishi, Takahito Yonekawa, Hiroshi Tanaka
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Patent number: 8535419Abstract: A modular amine plant having a front-end module and a back-end module in fluid communication with each other. The front-end module having pre-fabricated connections for the association of various equipment including: a filter, an absorption tower, and a flash tank. The back-end module having pre-fabricated connections for the association of other various equipment including: a heat exchanger, a distillation tower, and a reboiler. The modular amine plant capable of being installed at a site in less than about 5 days. The modular amine plant further having moment forces sufficient to withstand wind speeds of about 100 miles per hour.Type: GrantFiled: April 1, 2010Date of Patent: September 17, 2013Assignee: Zephyr Gas Services LLCInventors: Glen Wind, John Kenton Thompson, Lance Perryman
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Patent number: 8523978Abstract: A method of deacidizing a gaseous effluent comprising acid compounds where the gaseous effluent is contacted in C1 with an adsorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. The absorbent solution laden with acid compounds is then heated in E1 and E3 so as to separate two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds. These two fractions are then separated in BS1. The second fraction is regenerated in C2 so as to release part of the acid compounds, and the first absorbent solution fraction and the regenerated absorbent solution are recycled as absorbent solution.Type: GrantFiled: March 9, 2007Date of Patent: September 3, 2013Assignee: Institut Francais du PetroleInventors: Alexandre Rojey, Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
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Patent number: 8523979Abstract: A process for removing acid gases from a fluid stream in which a) the fluid stream is treated with an absorption liquid which comprises at least one amine, a stripping aid, and water, wherein the stripping aid is selected from water-miscible liquids, the boiling temperature of which at atmospheric pressure is lower than that of water, b) the treated fluid stream is treated with a liquid aqueous phase in order to convert entrained stripping aid at least in part to the aqueous phase, c) the loaded aqueous phase is heated in order to expel the stripping aid at least in part, and d) the regenerated aqueous phase is cooled and at least in part recycled to step b). The stripping aid promotes the regeneration of the absorbent by stripping. Emissions of the stripping aid via the treated fluid stream are avoided by the treated fluid stream being scrubbed with a liquid aqueous phase.Type: GrantFiled: June 21, 2010Date of Patent: September 3, 2013Assignee: BASF SEInventors: Hugo Rafael Garcia Andarcia, Ralf Notz, Georg Sieder, Oliver Spuhl, Hans Hasse, Inga Toennies, Sebastian Hoch, Hari Prasad Mangalapally
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Patent number: 8518156Abstract: A process and system (100) for removing contaminants from a solution to regenerate the solution within the system. The process includes providing a solution (165) from a wash vessel (160) to a stripping column (181), the solution (165) including contaminants removed from a flue gas stream (150) present in the wash vessel (160) and contacting the solution with steam (185) inside the stripping column (181) thereby removing the contaminants from the solution and regenerating the solution. The stripping column (181) is operated at a pressure less than about 700 kilopascal.Type: GrantFiled: August 3, 2010Date of Patent: August 27, 2013Assignee: ALSTOM Technology LtdInventors: Frederic Z. Kozak, Arlyn V. Petig, Ritesh Agarwal, Rameshwar S. Hiwale
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Patent number: 8500865Abstract: The gaseous effluent to be treated is contacted in C1 with an absorbent solution selected for its property of forming two separable phases when it has absorbed an amount of acid compounds and when it is heated. According to the invention, the absorbent solution is regenerated in at least two stages in regeneration zones Z1 and Z2. At the end of the first regeneration stage in Z1, at least part of the partly regenerated absorbent solution is separated into two fractions in B1: a fraction rich in acid compounds and a fraction depleted in acid compounds. Fraction 10 rich in acid compounds is sent to the second regeneration stage in Z2. The fraction depleted in acid compounds and regenerated absorbent solution 6 from the second regeneration stage are recycled to absorption column C1. The method can be applied to combustion fumes decarbonation and to natural gas or synthesis gas deacidizing.Type: GrantFiled: November 20, 2009Date of Patent: August 6, 2013Assignee: IFPInventors: Pierre-Antoine Bouillon, Marc Jacquin, Alain Methivier
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Patent number: 8475566Abstract: The present invention relates to a method for recovery of carbon dioxide from a gas stream. The method is a two-step method in which carbon dioxide is compressed in the first step, while the residual carbon dioxide is recovered by an absorption process in a subsequent step. The present invention also relates to the use of the method for the recovery of carbon dioxide and a plant for recovery of carbon dioxide.Type: GrantFiled: June 6, 2005Date of Patent: July 2, 2013Assignee: Union Engineering A/SInventor: Rasmus Find
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Patent number: 8470077Abstract: Processes for operating an ammonia stripper at a low pressure in a gas purification system include providing a first side-draw stream from the ammonia stripper; heating the first side-draw stream with a second side-draw stream from a regenerator; providing a stripper offgas stream from the ammonia stripper to a stripper overhead condenser; and utilizing the stripper offgas stream as a heat source for a regenerating system fluidly coupled to the stripper overhead condenser. Also disclosed are systems for implementing the processes.Type: GrantFiled: November 17, 2011Date of Patent: June 25, 2013Assignee: ALSTOM Technology LtdInventors: Sanjay Kumar Dube, Daniel Nicolaus Secundus Mattstedt, Joseph P. Naumovitz
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Patent number: 8470079Abstract: The present invention relates to a process for separating off CO2 from a gas stream, wherein in a second step the CO2 is removed from the CO2-absorbing agent by means of phase separation.Type: GrantFiled: July 31, 2007Date of Patent: June 25, 2013Assignee: Universital DortmundInventors: David Agar, Yudy Halim Tan, Zhang Xiaohui
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Patent number: 8435330Abstract: A system and process is provided primarily for use in hot climates, using ammonia solution to remove carbon dioxide from desulphurised water-vapor-containing flue gases of a fossil fuel power plant, while outputting useful streams of water and fertilizer.Type: GrantFiled: October 30, 2008Date of Patent: May 7, 2013Assignee: ALSTOM Technology LtdInventors: Otto M. Bade, Charles D. Soothill
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Patent number: 8414694Abstract: Provided are a CO2 absorber that reduces CO2 contained in flue gas; a regenerator that reduces CO2 contained in rich solvent absorbing CO2 to regenerate the rich solvent, so that lean solvent having the CO2 reduced in the regenerator is reused in the CO2 absorber; a heat exchanger that allows the rich solvent to exchange heat with the lean solvent; and a controller that controls to extract rich solvent portion that is part of the rich solvent, to allow the rich solvent portion to by pass the heat exchanger, and to be supplied into the top of the regenerator without exchanging heat so as to minimize a sum of an enthalpy that is taken out of the regenerator as CO2 gas accompanying steam and an enthalpy of the lean solvent after heat exchange with the rich solvent in the heat exchanger.Type: GrantFiled: December 23, 2009Date of Patent: April 9, 2013Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Masaki Iijima, Kouki Ogura, Masahiko Tatsumi, Yasuyuki Yagi
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Patent number: 8409339Abstract: A CO2 recovery system includes an absorption tower and a regeneration tower. CO2 rich solution is produced in the absorption tower by absorbing CO2 from CO2-containing gas. The CO2 rich solution is conveyed to the regeneration tower where lean solution is produced from the rich solution by removing CO2. A regeneration heater heats lean solution that accumulates near a bottom portion of the regeneration tower with saturated steam thereby producing steam condensate from the saturated steam. A steam-condensate heat exchanger heats the rich solution conveyed from the absorption tower to the regeneration tower with the steam condensate.Type: GrantFiled: January 25, 2011Date of Patent: April 2, 2013Assignees: Mitsubishi Heavy Industries, Ltd., Kansai Electric Power Co., Inc.Inventors: Masaki Iijima, Takashi Kamijo, Takahito Yonekawa, Tomio Mimura, Yasuyuki Yagi
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Patent number: 8398748Abstract: Contemplated configurations and methods include a solvent regenerator (58) that has an upper (93) and a lower stripping section (94). Cooled rich solve is used as reflux while heated rich solvent (11) is used as a source of stripping agent in the upper section (91). A reboiler (62) in the lower section provides further stripping agent, hi especially preferred configurations, a portion of lean solved from the regenerator (58) is further stripped in a separate or integrated regenerator (62) to form an ultra-lean solvent. Both lean and ultra-lean solvents are preferably used in a two-stage absorber (52) to thereby from the rich solvent and an offgas that is very low in acid gas.Type: GrantFiled: April 18, 2006Date of Patent: March 19, 2013Assignee: Fluor Technologies CorporationInventor: John Mak
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Patent number: 8388737Abstract: A method and apparatus for recovering a gaseous component from an incoming gas stream is described. The incoming gas stream is contacted with a lean aqueous absorbing medium to absorb at least a portion of the gaseous component from the incoming gas stream to form a lean treated gas stream and a rich aqueous absorbing medium. At least a portion of the gaseous component is desorbed from the rich aqueous absorbing medium at a temperature to form an overhead gas stream and a regenerated aqueous absorbing medium. At least a portion of the overhead gas stream is treated to recover a condensate stream. At least a portion of the condensate stream is used to form a heated stream. At least a portion of the heated stream is recycled back to the desorbing step. Novel absorbing medium compositions to recover carbon dioxide and/or hydrogen sulfide are also described.Type: GrantFiled: May 29, 2008Date of Patent: March 5, 2013Assignee: University of ReginaInventors: Don Gelowitz, Paitoon Tontiwachwuthikul, Raphael Idem
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Patent number: 8377403Abstract: Contemplated configurations and methods employ COS hydrolysis and a downstream H2S removal unit to produce a treated feed gas that is then further desulfurized in an absorber using two lean oil fluids. The so produced mercaptan enriched hydrocarbon fluid is fed to a distillation column that produces a light overhead vapor that is preferably combined with the treated feed gas and a sulfur rich bottom product that is in most cases preferably directly fed to a hydrocarbon processing unit comprising a hydrotreater. In further especially preferred aspects, the hydrocarbon processing unit produces at least one and more typically both of the two lean oil fluids, and the treated gas is optionally further processed to produce clean fuel gas in a hydrotreater for olefinic saturation and sulfur conversion using a lean oil recycle for reactor temperature control.Type: GrantFiled: July 30, 2007Date of Patent: February 19, 2013Assignee: Fluor Technologies CorporationInventor: John Mak
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Patent number: 8353979Abstract: A heat recovery apparatus, for an absorption apparatus for removing CO2 in combustion exhaust gas emitted from a thermal power plant 112 and for regeneration apparatuses 104 to 107 for regenerating CO2 in an absorbing liquid from the absorption apparatus, includes a regeneration-apparatus-exit-CO2-gas cooling apparatus 100 for cooling CO2 gas from an exhaust port of the regeneration apparatus, and may further include a circulation line 102 for circulating reflux water among boiler feedwater heaters 114 and 116 in the thermal power plant 112 and the regeneration-apparatus-exit-CO2-gas cooling apparatus 100.Type: GrantFiled: April 6, 2010Date of Patent: January 15, 2013Assignees: Mitsubishi Heavy Industries, Ltd., The Kansai Electric Power Co., Inc.Inventors: Tsuyoshi Oishi, Hiroshi Tanaka, Takahiko Endo, Masahiko Tatsumi, Yasuyuki Yagi
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Patent number: 8303685Abstract: An improved acid gas regeneration and injection process wherein the separated acid gas stream emerging from a regenerator is compressed and injected into subsurface reservoir, the improvement comprising conducting the acid gas separation in the regenerator under pressure that exceeds 50 psia and does not exceed 300 psia.Type: GrantFiled: June 21, 2004Date of Patent: November 6, 2012Assignee: Dow Global Technologies LLCInventors: Craig N. Schubert, Timothy C. Frank
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Patent number: 8287626Abstract: A method for treating a gas mixture containing acid gases, including: contacting the gas mixture with an absorbing solution, to obtain a de-acidified gas mixture and an absorbing solution with acid gases. To regenerate the absorbing solution with acid gases, the absorbing solution is passed into a first regenerator at a first pressure, then the solution is passed into a second regenerator at a second pressure, and finally to a third regenerator at a third pressure, the third pressure being less than the second pressure which is less than the first pressure. The gases from the second and third regenerator are compressed and recycled to the first and second regenerator, respectively. Gases from the second and/or the third regenerator are drawn off to provide a gas mixture rich in hydrogen sulfide. Gases from the first regenerator are drawn off to provide a gas mixture rich in carbon dioxide.Type: GrantFiled: January 18, 2008Date of Patent: October 16, 2012Assignee: Total S.A.Inventors: Viep Hoang-Dinh, Damien Roquet, Kenza Habchi-Tounsi, Olivier Chazelas, Claire Weiss
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Patent number: 8257476Abstract: A first contaminant selected from oxygen and carbon monoxide is removed from impure liquid carbon dioxide using a mass transfer separation column system which is reboiled by indirect heat exchange against crude carbon dioxide fluid, the impure liquid carbon dioxide having a greater concentration of carbon dioxide than the crude carbon dioxide fluid. The invention has particular application in the recovery of carbon dioxide from flue gas generated in an oxyfuel combustion process or waste gas from a hydrogen PSA process. Advantages include reducing the level of the first contaminant to not more than 1000 ppm.Type: GrantFiled: September 17, 2010Date of Patent: September 4, 2012Assignee: Air Products and Chemicals, Inc.Inventors: Vincent White, Rodney John Allam
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Patent number: 8241399Abstract: A method of generating heat from a gas stream includes providing a first gas stream having a first temperature and a moisture content approximately saturating the gas stream, removing the moisture content from the first gas stream to form a second gas stream having a second temperature greater than the first temperature of the first gas stream, and heat exchanging the second gas stream having the second temperature greater than the first temperature of the first gas stream.Type: GrantFiled: May 16, 2009Date of Patent: August 14, 2012Inventor: Walter Albers
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Patent number: 8206489Abstract: The present invention relates to a method of deacidizing a gaseous effluent, wherein the following stages are carried out: a) contacting the gaseous effluent with an absorbent solution so as to obtain a gaseous effluent depleted in acid compounds and an absorbent solution laden with acid compounds, the absorbent solution being selected for its property to form two separable phases when it absorbs an amount of acid compounds, b) separating the absorbent solution laden with acid compounds into two fractions: a first absorbent solution fraction depleted in acid compounds and a second absorbent solution fraction enriched in acid compounds, c) regenerating the second fraction so as to release part of the acid compounds, d) mixing a predetermined amount of water with the first absorbent solution fraction obtained in stage b) or with the regenerated absorbent solution fraction obtained in stage c), then e) recycling the first absorbent solution fraction and the regenerated absorbent solution as the absorbent soluType: GrantFiled: December 19, 2006Date of Patent: June 26, 2012Assignee: Institut Francais du PetroleInventors: Renaud Cadours, Pierre-Louis Carrette, Pierre Boucot
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Patent number: 8192530Abstract: A system (10) for regenerating a rich absorbent solution (26), the system including: an absorber (20) facilitating interaction between a process stream (22) and an absorbent solution, wherein the process stream comprises an acidic component, and interaction of the process stream with the absorbent solution produces a reduced acidic component stream (28) and a rich absorbent solution; at least one heat exchanger accepting at least one of said reduced acidic component stream and the process stream to transfer heat to a heat transfer fluid (60); and at least one mechanism (60a) to transfer the heat transfer fluid from said at least one heat exchanger to a regenerator (34) regenerating the rich absorbent solution, wherein each of the at least one mechanisms is fluidly coupled to each of the at least one heat exchangers.Type: GrantFiled: November 12, 2008Date of Patent: June 5, 2012Assignee: ALSTOM Technology LtdInventors: Nareshkumar B. Handagama, Rasesh R. Kotdawala