Water Sorbed Patents (Class 95/231)
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Patent number: 7976621Abstract: A power plant may include a combustion apparatus (11) producing an exhaust gas (12), an absorber (20) receiving the exhaust gas (12), the absorber (20) including a desiccant and producing a first stream of desiccant solution containing water and a first concentration of desiccant, and an apparatus (29, 70, 94) for dehydrating the first stream of desiccant solution while maintaining the water in a liquid phase. The apparatus (29, 70, 94) may include a heat exchanger (71, 110), a crystallizing heat exchanger (74, 96), a separator (78, 98) and a flash tank (112) for dehydrating the desiccant solution while maintaining water in a liquid phase and subsequently recovering water from the solution.Type: GrantFiled: March 1, 2010Date of Patent: July 12, 2011Assignee: Siemens Energy, Inc.Inventors: Fred W. Shoemaker, Michael S. Briesch, Philip G. Deen, Terrence B. Sullivan
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Patent number: 7942387Abstract: A system and method for managing water content in a fluid include a collection chamber for collecting water from the fluid with a desiccant, and a regeneration chamber for collecting water from the desiccant and transferring it to a second fluid. An evaporator cools the desiccant entering the collection chamber, and a condenser heats the desiccant entering the regeneration chamber. Diluted desiccant from the collection chamber is exchanged with concentrated desiccant from the regeneration chamber in such a way as to efficiently control the transfer of both mass and heat between the chambers. In one embodiment, mass is not exchanged until one or both of the desiccant levels in the chambers exceeds a predetermined level. Heat is transferred between the two desiccant flows as they are transferred between the chambers. This increases efficiency and reduces the energy input required for the evaporator and the condenser.Type: GrantFiled: August 27, 2007Date of Patent: May 17, 2011Assignee: DUCool Ltd.Inventor: Dan Forkosh
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Patent number: 7938888Abstract: A liquid desiccant regenerator system, including a desiccant/air heat exchanger having a first desiccant inlet and a desiccant reservoir. The reservoir has a first desiccant outlet, a second desiccant outlet and a second desiccant inlet. The first desiccant inlet and the first desiccant outlet are connectable to a heat source, the second desiccant inlet conducts diluted desiccant of the reservoir and the second desiccant outlet conducts concentrated desiccant from the reservoir. The second desiccant inlet and the desiccant outlet are connected to a desiccant/desiccant heat exchanger for applying heat to the diluted desiccant flowing into the reservoir. A dehumidification method is also provided.Type: GrantFiled: July 12, 2005Date of Patent: May 10, 2011Assignee: Agam Energy Systems Ltd.Inventor: Gad Assaf
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Patent number: 7883569Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas; and the helium is recovered and sold. Excess nitrogen is vented.Type: GrantFiled: February 12, 2007Date of Patent: February 8, 2011Inventor: Donald Leo Stinson
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Patent number: 7722706Abstract: A device is provided for extracting water from atmospheric air (8) having a free-flowing adsorbent or absorbent (3, 13), in particular a saline solution (3), having a hygroscopic salt for the adsorption or absorption of water, the adsorption or absorption being provided at least along an adsorption or absorption section (7), which realizes a high yield of (potable) water per unit volume of the structure or of the absorbent/adsorbent (3), a decrease in the assembly effort and a stabilization of the process. This is achieved according to the invention in having a free-flowing adsorbent (3, 13) or absorbent (3, 13) disposed at least along the adsorption or absorption section (7) essentially on a guide element (1, 16, 19, 22, 24) for guiding the adsorbent (3) or absorbent (3), in particular on a presettable track.Type: GrantFiled: May 26, 2004Date of Patent: May 25, 2010Assignee: Logos-Innovationen GmbHInventor: Frank Thielow
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Patent number: 7666251Abstract: Method of purifying a feed stream containing carbon dioxide wherein the feed stream after having been compressed and dried is partly cooled and then used to reboil a stripping column. Thereafter, the feed stream is further cooled and expanded to a lower operational temperature of the stripping column. A carbon dioxide product stream composed of the liquid column bottoms of the stripping column is expanded at one or more pressures to generate refrigeration, then fully vaporized within the main heat exchanger and compressed by a compressor to produce a compressed carbon dioxide product. Refrigeration is recovered in the main heat exchanger from a column overhead stream extracted from the stripping column within the main heat exchanger either directly or indirectly by auxiliary processing in which carbon dioxide is further separated and optionally recycled back to the main compressor used in compressing the feed stream.Type: GrantFiled: April 3, 2006Date of Patent: February 23, 2010Assignee: Praxair Technology, Inc.Inventors: Minish Mahendra Shah, Henry Edward Howard
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Patent number: 7655071Abstract: A process for cooling down a hot flue gas stream comprising water vapour and carbon dioxide, the process including: (a) heat exchange between the hot flue gas stream and a cooling water stream so that the hot flue gas stream is cooled to a cooled down gas stream at a temperature at which at least part of the water vapour therein has condensed and the cooling water stream increases in temperature; (b) combining the condensed water vapour and the cooling water stream to produce a combined water stream; (c) separation of the cooled down gas stream from the combined water stream; (d) cooling the combined water stream by contact with air from the atmosphere and by evaporation of a portion of the combined water stream; (e) using at least part of any non-evaporated and cooled water of the combined water stream as at least part of the cooling water stream for cooling the hot flue gas stream in step (a); and (f) storing any non-evaporated and cooled water of the combined water stream that is not used in step (e) and uType: GrantFiled: December 14, 2006Date of Patent: February 2, 2010Assignee: Shell Oil CompanyInventor: Wilhelmus Jozef De Vreede
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Publication number: 20090291874Abstract: The present application discloses compositions comprising ionic liquids and an amine compound, and methods for using and producing the same. In some embodiments, the compositions disclosed herein are useful in reducing the amount of impurities in a fluid medium or a solid substrate.Type: ApplicationFiled: May 21, 2009Publication date: November 26, 2009Inventors: Jason E. Bara, Dean E. Camper, Richard D. Noble, Douglas L. Gin
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Patent number: 7601208Abstract: A water production unit is provided that uses liquid desiccant and vehicle exhaust for extracting water from air.Type: GrantFiled: November 7, 2005Date of Patent: October 13, 2009Assignee: Hamilton Sundstrand CorporationInventor: Stephen Tongue
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Patent number: 7517391Abstract: An integrated ship mounted system for loading a gas stream, separating heavier hydrocarbons, compressing the gas, cooling the gas, mixing the gas with a desiccant, blending it with a liquid carrier or solvent, and then cooling the mix to processing, storage and transportation conditions. After transporting the product to its destination, a hydrocarbon processing train and liquid displacement method is provided to unload the liquid from the pipeline and storage system, separate the liquid carrier, and transfer the gas stream to a storage or transmission system.Type: GrantFiled: July 7, 2006Date of Patent: April 14, 2009Assignee: SeaOne Maritime Corp.Inventors: Bruce Hall, Micahel J. Mulvany, Tolulope O. Okikiolu
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Patent number: 7431900Abstract: A hydrogen peroxide vapor generation unit (10) receives hydrogen peroxide and water solution at an interface (20) and interconnects with an air dryer (14) by way of nipples (72, 92). In one embodiment, the dryer includes a clamping assembly (42) which is latched (74, 94) with the nipples and which receives a disposable desiccant cartridge (40). In an alternate embodiment, a reusable desiccant cartridge (40?) is connected directly to the nipples (72, 92). When the desiccant cartridge (40?) is saturated, it is removed and placed in a regenerator unit (120). A regenerated cartridge is installed in its place.Type: GrantFiled: February 28, 2003Date of Patent: October 7, 2008Assignee: Steris IncInventors: Aaron L. Hill, Arthur T. Nagare, Frank E. Dougherty, Stanley M. Voyten
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Publication number: 20080202343Abstract: An improved air humidity absorbing device to be used in a cargo container, includes: an external box made from cardboard material; the contents of the box including an external bag made from non woven spunbound; and at least two internal bags from the coated Tyvek material. The at least two internal bags are formed by subdividing the external bag into the at least two internal bags, and each of the internal bags is filled with an active mixture including Calcium Chloride (CaCl2) and Amylopectin.Type: ApplicationFiled: April 3, 2006Publication date: August 28, 2008Inventor: John Ivar Allan Lundin
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Patent number: 7377958Abstract: An apparatus is provided for removing airborne moisture from a designated area. In one embodiment, the apparatus includes a bucket, a liquid absorption medium (such as ground corn cobs) placed in the bottom of the bucket to form a media bed, a tray placed over the absorption media bed, and a moisture absorption medium (such as calcium chloride) placed in the bucket over the tray. A method is also provided for absorbing moisture from a humid environment using the apparatus. When the apparatus is exposed to humid conditions, the CaCl2 will absorb moisture and become hardened. As the CaCl2 media hardens, it will expand. However, its lateral expansion is restricted by a side wall of the tray. Over further time, the CaCl2 will begin to dissolve into a brine. The brine will gravitationally seep through the through-openings in the tray and be captured by the corn cob medium.Type: GrantFiled: February 17, 2005Date of Patent: May 27, 2008Inventor: Joaquin P. Cunanan
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Patent number: 7306650Abstract: A method, and systems for implementing such method, for purifying and conditioning air of weaponized contaminants. The method includes wetting a filter packing media with a salt-based liquid desiccant, such as water with a high concentration of lithium chloride. Air is passed through the wetted filter packing media and the contaminants in are captured with the liquid desiccant while the liquid desiccant dehumidifies the air. The captured contaminants are then deactivated in the liquid desiccant, which may include heating the liquid desiccant. The liquid desiccant is regenerated by applying heat to the liquid desiccant and then removing moisture. The method includes repeating the wetting with the regenerated liquid desiccant which provides a regenerable filtering process that captures and deactivates contaminants on an ongoing basis while also conditioning the air. The method may include filtration effectiveness enhancement by electrostatic or inertial means.Type: GrantFiled: February 28, 2003Date of Patent: December 11, 2007Assignee: Midwest Research InstituteInventors: Steven J. Slayzak, Ren S. Anderson, Ronald D. Judkoff, Daniel M. Blake, Todd B. Vinzant, Joseph P. Ryan
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Patent number: 7306654Abstract: A method of separating water from air is provided comprising the steps of (a) contacting air having water vapor with an hygroscopic liquid mixture to produce a water rich hygroscopic liquid mixture, (b) heating at least a portion of the water rich hygroscopic liquid mixture to produce a gaseous mixture including water vapor and at least one other gaseous component, (c) condensing at least a portion of the water vapor in the gaseous mixture to produce liquid water and a depleted gaseous mixture at a first pressure, and (d) removing at least a portion of the at least one other gaseous component to maintain the first pressure below a predetermined pressure, wherein the depleted gaseous mixture is in fluid communication with the water rich hygroscopic liquid mixture. An absorber vessel is also provided for effecting the method of separating water from air.Type: GrantFiled: January 30, 2004Date of Patent: December 11, 2007Inventors: Ronald King, Norman L. Arrison
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Patent number: 7204867Abstract: Contemplated plants comprise an acid gas removal unit that receives a compressed gas from an injection gas compressor, wherein acid gas is removed from the compressed gas in the acid gas removal unit at a pressure approximately above pipeline pressure.Type: GrantFiled: November 25, 2002Date of Patent: April 17, 2007Assignee: Fluor Technologies CorporationInventors: Richard B. Nielsen, John Mak
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Patent number: 7074258Abstract: A process for the removal of water from gas which comprises an absorption step of bringing a gas saturated with water vapor into gas-liquid contact with a water-lean absorbing liquid comprising a water absorbing liquid having a cloud point temperature above the freezing point of water whereby water vapor present in the gas is absorbed into the water-lean absorbing liquid at a temperature below its cloud point to produce a refined gas having a reduced water vapor content and water-loaded absorbing liquid. A regeneration step is provided in which the water-loaded absorbing liquid is heated to above the cloud point temperature of the absorbing liquid whereby the water-loaded absorbing liquid separates into a water-rich phase and an absorbing liquid-rich phase and the absorbing liquid-rich phase is cooled to a temperature below its cloud point prior to recycling the absorbing liquid-rich phase for use as water-lean absorbing liquid in the absorption step.Type: GrantFiled: March 6, 2002Date of Patent: July 11, 2006Assignee: BP Exploration Operating Company LimitedInventors: Ian Ralph Collins, Stephen Paul Goodwin
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Patent number: 6984257Abstract: An improved apparatus and method for use with a natural gas dehydrator. The apparatus and method of the invention provide for recirculation of gaseous or combustible materials so that they are not released into the atmosphere and to provide fuel for the process. Likewise, liquid hydrocarbons are collected. Various components, including separators, an absorber, wet glycol, dry glycol, an effluent condenser, heat exchangers, and a reboiler are utilized in accordance with the present invention.Type: GrantFiled: April 18, 2003Date of Patent: January 10, 2006Inventors: Rodney T. Heath, Forrest D. Heath
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Patent number: 6974542Abstract: A column of solvent containing foaming contaminants is provided. Gas is educted into the solvent in the column so as to generate foam in the column. The gas is educted into the column independently of the input flow of solvent into the solvent using a pumparound arrangement with the solvent. Foam generation continues so as to push the foam up in the column, wherein much of the solvent that is in the foam is allowed to drain back down into the column. The foam passes through concentrators which increase the residency time of the foam in the column to further dry the foam and to create larger bubbles. The drier foam is pushed out of the column and into a container. The foam is broken up into gas and the liquid foaming contaminants. The gas is recirculated for injection into the column even after foaming has stopped. The foaming contaminants are concentrated at the surface level of the solvent in the column. These contaminants are removed from the column.Type: GrantFiled: May 22, 2003Date of Patent: December 13, 2005Inventor: Stephen A. von Phul
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Patent number: 6964729Abstract: An improved method and apparatus for oxidizing undesired compounds residing within a liquid glycol based absorbent wherein the compounds are heated within a reboiler chamber to their boiling point to effectuate production of vaporized effluents. The absorbent's vaporized effluents rise upwardly exiting the reboiler chamber and enter a reflux tower wherein they are partially condensed via a condenser embodied within the interior of the tower. The residual uncondensed effluents are then transported to and first heated via a vaporizer/heat exchanger, thus effectuating the vaporization of any ambient condensed liquids contained within the effluents. The revaporized effluents then enter the invention's thermal oxidizer combustion chamber where they are second heated to a temperature necessary to effectuate destruction of undesirable compounds, such as but not limited to benzene, toluene and xylene.Type: GrantFiled: September 5, 2000Date of Patent: November 15, 2005Inventor: Parviz Khosrowyar
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Patent number: 6896718Abstract: Moisture is removed from gas by contacting the gas with a solution of potassium formate to remove moisture from the gas, regenerating the potassium formate solution by removing water from it, and returning the potassium formate solution to contact gas to dehydrate it. Regeneration of the potassium formate solution is most preferably accomplished in a cavitation regenerator. The gas is most preferably natural gas.Type: GrantFiled: August 24, 2001Date of Patent: May 24, 2005Assignee: Clearwater International LLCInventor: John H. Hallman
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Publication number: 20040206242Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.Type: ApplicationFiled: May 6, 2004Publication date: October 21, 2004Applicant: Membrane Technology and Research, Inc.Inventors: Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
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Publication number: 20040187686Abstract: A process for removing contaminants from a natural gas feed stream including water and sour species is provided, which process comprises the steps of cooling the natural gas feed stream in a first vessel (12) to a first operating temperature at which hydrates are formed and removing from the first vessel (12) a stream of dehydrated gas (34); and cooling the dehydrated gas in a second vessel (14) to a second operating temperature at which solids of the sour species are formed or at which the sour species dissolve in a liquid and removing from the second vessel (14) a stream of dehydrated sweetened gas (62).Type: ApplicationFiled: February 5, 2004Publication date: September 30, 2004Inventors: Robert Amin, Casper Krijno Groothuis
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Patent number: 6793714Abstract: In a process for dehydration/fractionation of a wet natural gas containing heavy constituents and light constituents, In the presence of methanol, aqueous liquid phases are combined and the resultant combined aqueous liquid phase contacted with the first part of the gas to be scrubbed, which carries along the major part of the methanol, which allows to collect practically pure water. Before this step, all or part of one or both of the aqueous liquid phases and/or all or part of the aqueous liquid phase from a washing zone is sent to a distillation stage where practically pure methanol is collected at the top and a methanol-depleted aqueous liquid phase is collected at the bottom prior to being sent back to the first stage or used for the washing stage.Type: GrantFiled: March 29, 2002Date of Patent: September 21, 2004Assignee: Institut Francais du PetroleInventors: Fabrice Lecomte, Béatrice Fischer, Jean-Charles Viltard
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Patent number: 6789288Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.Type: GrantFiled: October 25, 2002Date of Patent: September 14, 2004Assignee: Membrane Technology and Research, Inc.Inventors: Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
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Patent number: 6767388Abstract: Process for dehydrating/fractionating a low-pressure wet natural gas containing “heavy” constituents and “light” constituents includes a stage a) in which at least a fraction of the wet gas at temperature T0 is contacted with an aqueous liquid phase L'1 containing methanol, the gas carrying along substantially all of the methanol contained in phase L'1. In a stage b), the gas from stage (a) is cooled to a temperature T1 lower than temperature T0, producing a gas phase G1 at equilibrium with a hydrocarbon-containing liquid phase L1 containing C3+ and an aqueous liquid phase L'1 containing methanol. In stage c), phase L'1 is sent to stage (a), and in stage d), said phase G1 is fractionated by distillation carried out by continuous thermal exchange with a cooling fluid, so as to extract the “light” constituents (gas phase G2) and the “heavy” constituents (condensed phase L2).Type: GrantFiled: March 29, 2002Date of Patent: July 27, 2004Assignee: Institut Francais du PetroleInventors: Fabrice Lecomte, Béatrice Fischer, Jean-Charles Viltard
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Publication number: 20040139855Abstract: A process for the removal of water from gas which comprises an absorption step of bringing a gas (1) saturated with water vapour into gas-liquid contact with a water-lean absorbing liquid (3) comprising a water absorbing liquid having a cloud point temperature above the freezing point of water whereby water vapour present in the gas is absorbed into the water-lean absorbing liquid at a temperature below its cloud point to produce a refined gas (4) having a reduced water vapour content and water-loaded absorbing liquid (5); and a regeneration step of heating the water-loaded absorbing liquid (5) to above the cloud point temperature of the absorbing liquid whereby the water-loaded absorbing liquid separates into a water-rich phase (7) and an absorbing liquid-rich phase (8) and cooling the absorbing liquid-rich phase to a temperature below its cloud point prior to recycling the absorbing liquid-rich phase for use as water-lean absorbing liquid (3) in the absorption step.Type: ApplicationFiled: March 17, 2004Publication date: July 22, 2004Inventors: Ian Ralph Collins, Stephen Paul Goodwin
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Publication number: 20040099138Abstract: A high purity stream of methane can be obtained from crude natural gas, especially exhaust gas from waste landfills, by a process that includes first removing moisture, then feeding the dried crude gas mixture to a gas-liquid contact absorber to strip heavy hydrocarbon compounds in a primarily carbon dioxide by product stream. Methane enriched gas from the absorber is separated in a membrane separation unit which provides permeate enriched in carbon dioxide that is recycled to the absorber and a purified product stream of methane.Type: ApplicationFiled: November 13, 2003Publication date: May 27, 2004Applicant: L'Air Liquide, Societe Anonyme A Directoire et Conseil De Surveillance Pour L'Etude etInventors: Sandeep K. Karode, Charles L. Anderson
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Publication number: 20040079228Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.Type: ApplicationFiled: October 25, 2002Publication date: April 29, 2004Applicant: Membrane Technology and Research, Inc.Inventors: Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
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Patent number: 6699308Abstract: A system for removing water from natural gas which comprises: bringing the natural gas into contact with a liquid including an absorbent for the water; subjecting the natural gas and liquid to turbulent mixing conditions thereby causing the water to be absorbed by the absorbent; and separating a natural gas phase with reduced water content and a liquid phase including the absorbent and absorbed water. The mixing is conducted in a turbulent contactor (11) including a gas inlet (15), a liquid inlet (16), an outlet (104) leading to a venturi passage (105) and a tube (106) extending from the outlet (104) back upstream. The tube (106) may be perforated and/or spaced from the periphery of the outlet (104).Type: GrantFiled: January 22, 2002Date of Patent: March 2, 2004Assignee: Statoil ASAInventors: Finn Patrick Nilsen, Harald Linga
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Publication number: 20040031389Abstract: An improved apparatus and method for use with a natural gas dehydrator. The apparatus and method of the invention provide for recirculation of gaseous or combustible materials so that they are not released into the atmosphere and to provide fuel for the process. Likewise, liquid hydrocarbons are collected. Various components, including separators, an absorber, wet glycol, dry glycol, an effluent condenser, heat exchangers, and a reboiler are utilized in accordance with the present invention.Type: ApplicationFiled: April 18, 2003Publication date: February 19, 2004Inventors: Rodney T. Heath, Forrest D. Heath
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Patent number: 6666906Abstract: Potassium or other alkali metal formate solution is used to absorb moisture from gas through a membrane. The membrane may be supported on permeable tubes, and the potassium or other alkali metal formate may be regenerated for reuse, preferably by a cavitation regenerator. The potassium or other alkali metal formate should be present as a 40-80% solution, most preferably 70-76%. The process is especially useful for the dehydration of natural gas.Type: GrantFiled: November 6, 2001Date of Patent: December 23, 2003Assignee: Clearwater International, L.L.C.Inventor: John H. Hallman
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Patent number: 6602423Abstract: A column of solvent containing foaming contaminants is provided. Gas is educted into the solvent in the column so as to generate foam in the column. The gas is educted into the column independently of the input flow of solvent into the solvent using a pumparound arrangement with the solvent. Foam generation continues so as to push the foam up in the column, wherein much of the solvent that is in the foam is allowed to drain back down into the column. The foam passes through concentrators which increase the residency time of the foam in the column to further dry the foam and to create larger bubbles. The drier foam is pushed out of the column and into a container. The foam is broken up into gas and the liquid foaming contaminants. The gas is recirculated for injection into the column even after foaming has stopped. The foaming contaminants are concentrated at the surface level of the solvent in the column. These contaminants are removed from the column.Type: GrantFiled: February 27, 2001Date of Patent: August 5, 2003Inventor: Stephen A. von Phul
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Patent number: 6579343Abstract: The present invention provides a method for purifying a gas by contacting the gas with a liquid ionic compound. Natural gas may be purified, removing water and carbon dioxide, by contacting the natural gas with a liquid ionic compound.Type: GrantFiled: April 1, 2002Date of Patent: June 17, 2003Assignee: University of Notre Dame du LacInventors: Joan F. Brennecke, Edward J. Maginn
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Patent number: 6551379Abstract: Apparatus for use with a natural gas dehydrator wherein a portion of the wet glycol in an emissions separator is pumped under pressure as circulating wet glycol which may be used as a coolant for effluent removed from a reboiler and/or a power source for an eductor to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluent, comprising at least liquid water, liquid hydrocarbons and uncondensed vapors, moves into the first chamber wherein the liquid water and/or the liquid hydrocarbons are separated from the uncondensed vapors. At least, the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are compressed and combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. In some instances, the liquid hydrocarbons are transferred to a third chamber and removed therefrom.Type: GrantFiled: February 8, 2002Date of Patent: April 22, 2003Inventor: Rodney T. Heath
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Patent number: 6514321Abstract: A system and method for dehumidifying air including a multiple effect evaporator that creates a concentrated desiccant solution. The desiccant solution from the multiple effect evaporator is conveyed to a desiccant spray chamber that sprays the cooled desiccant solution into an air stream. The desiccant solution absorbs water vapor from the air stream creating a desiccant and water solution. A conduit transfers the water and desiccant solution to the multiple effect evaporator for removal of the water from the desiccant solution.Type: GrantFiled: October 18, 2000Date of Patent: February 4, 2003Assignee: PowerMax, Inc.Inventors: John M. Lehto, John Tyson
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Patent number: 6506233Abstract: Desiccant tablets including solid potassium formate are used to dry gas, especially in natural gas transmission lines. Preferred tablets comprise 1-4% potassium formate (most preferably 2-3%), up to 1% of a surfactant as a lubricant, and the balance desiccant salts, preferably calcium chloride.Type: GrantFiled: November 9, 2001Date of Patent: January 14, 2003Assignee: Clearwater, Inc.Inventor: Kevin W. Smith
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Publication number: 20020185006Abstract: Process for dehydrating/fractionating a low-pressure wet natural gas containing <<heavy >> constituents and <<light >> constituents, wherein:Type: ApplicationFiled: March 29, 2002Publication date: December 12, 2002Inventors: Fabrice Lecomte, Beatrice Fischer, Jean-Charles Viltard
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Publication number: 20020178918Abstract: In a process intended for dehydration/fractionation of a wet natural gas containing <<heavy>> constituents and <<light>> constituents, in the presence of methanol, which comprises at least the following stagesType: ApplicationFiled: March 29, 2002Publication date: December 5, 2002Inventors: Fabrice Lecomte, Beatrice Fischer, Jean-Charles Viltard
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Patent number: 6461413Abstract: In a process using a hydrophilic liquid desiccant, for dehydrating a gas containing water with regeneration of the steps of: (a) absorbing water by contact between the moist gas and regenerated liquid desiccant from step c), producing a dry gaseous effluent and a stream of liquid desiccant charged with water and absorbed gases; (b) regenerating the liquid desiccant charged with water in a regeneration zone constituting a reboiling zone and a distillation zone, the charged liquid desiccant being sent to said distillation zone, from which a vapor containing water leaves overhead and from which liquid desiccant still containing water leaves from the bottom in the reboiling zone; (c) passing the liquid desiccant from the reboiling zone of step b) and still containing water to an absorption zone, in which the water in the desiccant is vaporized and the water vapor is absorbed by a fraction of regenerated or non regenerated desiccant, passing the resultant desiccant which has absorbed water vapor to the reboiling zType: GrantFiled: November 27, 2000Date of Patent: October 8, 2002Assignee: ProsernatInventors: Benoit Landreau, Jean-Claude Amande
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Patent number: 6425942Abstract: The gas which is to be dried is fed into an absorber (1) where it is brought into contact with a glycol in countercurrent. The glycol absorbs the moisture from the gas and impurities. The glycol laden with water and impurities is removed from the absorber (1) via a line (5). It is then regenerated in a reboiler (9) where the water is eliminated by heating. The water-free glycol is passed into a storage vessel (10) from which it can then be refed to the absorber (1). The glycol which is withdrawn from the storage vessel (10) is purified by mixing it with at least half the quantity of water. The mixture is brought to a temperature above cloud point where it is maintained for a predetermined length of time so that the impurities flocculate. The flocculated impurities are removed in a filter (18) arid the purified glycol mixed with water is refed to the reboiler (9) via a line (19). The drying process is very economical as it integrates environmentally-friendly and simple purification of the glycol.Type: GrantFiled: June 13, 2000Date of Patent: July 30, 2002Assignee: Ruhrgas AktiengesellschaftInventor: Randolf Ruediger Forster
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Publication number: 20020073843Abstract: Apparatus for use with a natural gas dehydrator wherein a portion of the wet glycol in an emissions separator is pumped under pressure as circulating wet glycol which may be used as a coolant for effluent removed from a reboiler and/or a power source for an eductor to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluent, comprising at least liquid water, liquid hydrocarbons and uncondensed vapors, moves into the first chamber wherein the liquid water and/or the liquid hydrocarbons are separated from the uncondensed vapors. At least, the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are compressed and combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. In some instances, the liquid hydrocarbons are transferred to a third chamber and removed therefrom.Type: ApplicationFiled: February 8, 2002Publication date: June 20, 2002Inventor: Rodney T. Heath
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Patent number: 6368384Abstract: Desiccant tablets including solid potassium formate are used to dry gas, especially in natural gas transmission lines. The most preferred tablets comprise 5-15% potassium formate, up to 1% of a surfactant as a lubricant, and the balance desiccant salts, preferably calcium chloride.Type: GrantFiled: March 9, 2001Date of Patent: April 9, 2002Assignee: Clearwater, Inc.Inventor: Kevin W. Smith
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Patent number: 6364933Abstract: Apparatus for use with a natural gas dehydrator wherein a portion of the wet glycol in an emissions separator is pumped under pressure as circulating wet glycol which may be used as a coolant for effluent removed from a reboiler and/or a power source for an eductor to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluent, comprising at least liquid water, liquid hydrocarbons and uncondensed vapors, moves into the first chamber wherein the liquid water and/or the liquid hydrocarbons are separated from the uncondensed vapors. At least, the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are compressed and combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. In some instances, the liquid hydrocarbons are transferred to a third chamber and removed therefrom.Type: GrantFiled: May 5, 2000Date of Patent: April 2, 2002Inventor: Rodney T. Heath
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Patent number: 6355092Abstract: The invention relates to an apparatus for performing membrane gas/liquid absorption at elevated pressure, comprising a pressure vessel in which a membrane unit is provided for separate feed-through of the gas phase and the liquid phase, in such a way that exchange of components to be absorbed can take place between the gas phase and the liquid phase, the flow direction of the gas phase through the absorber being essentially perpendicular to the flow direction of the liquid phase through the absorber. The invention further relates to a method for performing gas/liquid membrane absorption employing this absorber, in particular for the absorption of CO2, H2S, mercury (vapor) and/or water (vapor) from a gas phase at elevated pressure. The invention finally relates to a method for refining natural gas using the absorber and method according to the invention.Type: GrantFiled: November 9, 1999Date of Patent: March 12, 2002Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Ondersoek TMOInventors: Albert Edward Jansen, Paul Hubert Maria Feron, Jan Hendrik Hanemaaijer, Piet Huisjes
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Patent number: 6251165Abstract: Process for recovering a solvent from a gas coming from a treating process using the solvent, the gas having a low temperature Ta and a high temperature Td, the difference Td-Ta being sufficient to carry out an adsorption step and a desorption step. The process is characterized in that/ a) a first solvent-containing gas stream is sent to an adsorption step, this gas being at a temperature Ta, at the end of this step the gas is practically solvent-free and the solvent is collected in a first adsorber, b) a second gas stream at a temperature Td, this gas being solvent-free, is sent to carry out desorption of a second adsorption means loaded with solvent during a previous step a), and c) the solvent is sent at least partly to a step of the treating process using the solvent.Type: GrantFiled: June 2, 1999Date of Patent: June 26, 2001Assignee: Institut Francais du PetroleInventors: Sophie Jullian, Etienne Lebas, Michel Thomas
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Patent number: 6251166Abstract: A glycol regenerating system wherein a pressurized reboiler is introduced to a typical prior art system, the pressurized reboiler being in the glycol stream upstream from the conventional atmospheric reboiler. The pressurized reboiler heats the rich glycol coming from the glycol contactor from about 300° F. to 400° F. and keeps the glycol under pressure from about 10-25 psig. in order to first distill and condense VOCs (volatile organic compounds) which constitute non-condensable hydrocarbons and condensable hydrocarbons such as BTEX (Benzene, Toluene, Ethylbenzene, Xylene) compounds, the components being conveniently under pressure for transporting the components to a desired location.Type: GrantFiled: August 18, 1999Date of Patent: June 26, 2001Assignee: Anderson Controls, LCInventor: R. David Anderson
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Patent number: 6238461Abstract: A natural gas dehydrator wherein a portion of the wet glycol from the absorber is pumped under pressure as circulating wet glycol which is used as a coolant for effluents removed from a reboiler and a power source for an educator to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluents, comprising liquid water, liquid hydrocarbons and uncondensed vapors, move in to the first chamber wherein the liquid water is separated therefrom. The liquid hydrocarbons and the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. Also, gases from gas emitting level control apparatus in the natural gas dehydrator are collected and fed into the first chamber.Type: GrantFiled: June 15, 1999Date of Patent: May 29, 2001Inventor: Rodney T. Heath
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Patent number: 6183540Abstract: A method is provided for the extraction of aromatic hydrocarbons, including benzene, toluene, ethylbenzene, and xylene, collectively known as “BTEX,” in a continuous process utilizing a glycol contactor to cause absorption of the BTEX upstream of an amine-based gas sweetening process. The preferred glycol for BTEX absorption is triethylene glycol. The glycol used in the glycol contactor for BTEX extraction may either be fully regenerated (dry), or wet glycol from a downstream gas dehydration system. The method may be achieved with the use of a number of separate absorber/contactor vessels, or the method may be achieved within one combination vessel.Type: GrantFiled: August 27, 1999Date of Patent: February 6, 2001Assignee: Kinder Morgan, Inc.Inventor: Jonathan E. Thonsgaard
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Patent number: RE39944Abstract: A natural gas dehydrator wherein a portion of the wet glycol from the absorber is pumped under pressure as circulating wet glycol which is used as a coolant for effluents removed from a reboiler and a power source for an educator to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluents, comprising liquid water, liquid hydrocarbons and uncondensed vapors, move in to the first chamber wherein the liquid water is separated therefrom. The liquid hydrocarbons and the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. Also, gases from gas emitting level control apparatus in the natural gas dehydrator are collected and fed into the first chamber.Type: GrantFiled: May 29, 2003Date of Patent: December 25, 2007Inventor: Rodney T. Heath