Water Sorbed Patents (Class 95/231)
  • Patent number: 7976621
    Abstract: A power plant may include a combustion apparatus (11) producing an exhaust gas (12), an absorber (20) receiving the exhaust gas (12), the absorber (20) including a desiccant and producing a first stream of desiccant solution containing water and a first concentration of desiccant, and an apparatus (29, 70, 94) for dehydrating the first stream of desiccant solution while maintaining the water in a liquid phase. The apparatus (29, 70, 94) may include a heat exchanger (71, 110), a crystallizing heat exchanger (74, 96), a separator (78, 98) and a flash tank (112) for dehydrating the desiccant solution while maintaining water in a liquid phase and subsequently recovering water from the solution.
    Type: Grant
    Filed: March 1, 2010
    Date of Patent: July 12, 2011
    Assignee: Siemens Energy, Inc.
    Inventors: Fred W. Shoemaker, Michael S. Briesch, Philip G. Deen, Terrence B. Sullivan
  • Patent number: 7942387
    Abstract: A system and method for managing water content in a fluid include a collection chamber for collecting water from the fluid with a desiccant, and a regeneration chamber for collecting water from the desiccant and transferring it to a second fluid. An evaporator cools the desiccant entering the collection chamber, and a condenser heats the desiccant entering the regeneration chamber. Diluted desiccant from the collection chamber is exchanged with concentrated desiccant from the regeneration chamber in such a way as to efficiently control the transfer of both mass and heat between the chambers. In one embodiment, mass is not exchanged until one or both of the desiccant levels in the chambers exceeds a predetermined level. Heat is transferred between the two desiccant flows as they are transferred between the chambers. This increases efficiency and reduces the energy input required for the evaporator and the condenser.
    Type: Grant
    Filed: August 27, 2007
    Date of Patent: May 17, 2011
    Assignee: DUCool Ltd.
    Inventor: Dan Forkosh
  • Patent number: 7938888
    Abstract: A liquid desiccant regenerator system, including a desiccant/air heat exchanger having a first desiccant inlet and a desiccant reservoir. The reservoir has a first desiccant outlet, a second desiccant outlet and a second desiccant inlet. The first desiccant inlet and the first desiccant outlet are connectable to a heat source, the second desiccant inlet conducts diluted desiccant of the reservoir and the second desiccant outlet conducts concentrated desiccant from the reservoir. The second desiccant inlet and the desiccant outlet are connected to a desiccant/desiccant heat exchanger for applying heat to the diluted desiccant flowing into the reservoir. A dehumidification method is also provided.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: May 10, 2011
    Assignee: Agam Energy Systems Ltd.
    Inventor: Gad Assaf
  • Patent number: 7883569
    Abstract: Produced natural gas containing carbon dioxide is dehydrated and chilled to liquefy the carbon dioxide and then fractionated to produce a waste stream of liquid carbon dioxide and hydrogen sulfide. Natural gas liquids may be first separated and removed before fractionation. After fractionation, the waste stream is pressurized and transmitted to a remote injection well for injection either for disposal of the waste stream and preferably to urge hydrocarbons toward the producing well. A hydrocarbon stream proceeds from fractionation to a methanol absorber system which removes carbon dioxide gas. The hydrocarbon stream is thereafter separated into at least hydrocarbon gas, nitrogen and helium. Some of the nitrogen is reintroduced into a fractionation tower to enhance the recovery of hydrocarbons. A methanol recovery system is provided to recover and reuse the methanol. The hydrocarbons are sold as natural gas; and the helium is recovered and sold. Excess nitrogen is vented.
    Type: Grant
    Filed: February 12, 2007
    Date of Patent: February 8, 2011
    Inventor: Donald Leo Stinson
  • Patent number: 7722706
    Abstract: A device is provided for extracting water from atmospheric air (8) having a free-flowing adsorbent or absorbent (3, 13), in particular a saline solution (3), having a hygroscopic salt for the adsorption or absorption of water, the adsorption or absorption being provided at least along an adsorption or absorption section (7), which realizes a high yield of (potable) water per unit volume of the structure or of the absorbent/adsorbent (3), a decrease in the assembly effort and a stabilization of the process. This is achieved according to the invention in having a free-flowing adsorbent (3, 13) or absorbent (3, 13) disposed at least along the adsorption or absorption section (7) essentially on a guide element (1, 16, 19, 22, 24) for guiding the adsorbent (3) or absorbent (3), in particular on a presettable track.
    Type: Grant
    Filed: May 26, 2004
    Date of Patent: May 25, 2010
    Assignee: Logos-Innovationen GmbH
    Inventor: Frank Thielow
  • Patent number: 7666251
    Abstract: Method of purifying a feed stream containing carbon dioxide wherein the feed stream after having been compressed and dried is partly cooled and then used to reboil a stripping column. Thereafter, the feed stream is further cooled and expanded to a lower operational temperature of the stripping column. A carbon dioxide product stream composed of the liquid column bottoms of the stripping column is expanded at one or more pressures to generate refrigeration, then fully vaporized within the main heat exchanger and compressed by a compressor to produce a compressed carbon dioxide product. Refrigeration is recovered in the main heat exchanger from a column overhead stream extracted from the stripping column within the main heat exchanger either directly or indirectly by auxiliary processing in which carbon dioxide is further separated and optionally recycled back to the main compressor used in compressing the feed stream.
    Type: Grant
    Filed: April 3, 2006
    Date of Patent: February 23, 2010
    Assignee: Praxair Technology, Inc.
    Inventors: Minish Mahendra Shah, Henry Edward Howard
  • Patent number: 7655071
    Abstract: A process for cooling down a hot flue gas stream comprising water vapour and carbon dioxide, the process including: (a) heat exchange between the hot flue gas stream and a cooling water stream so that the hot flue gas stream is cooled to a cooled down gas stream at a temperature at which at least part of the water vapour therein has condensed and the cooling water stream increases in temperature; (b) combining the condensed water vapour and the cooling water stream to produce a combined water stream; (c) separation of the cooled down gas stream from the combined water stream; (d) cooling the combined water stream by contact with air from the atmosphere and by evaporation of a portion of the combined water stream; (e) using at least part of any non-evaporated and cooled water of the combined water stream as at least part of the cooling water stream for cooling the hot flue gas stream in step (a); and (f) storing any non-evaporated and cooled water of the combined water stream that is not used in step (e) and u
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: February 2, 2010
    Assignee: Shell Oil Company
    Inventor: Wilhelmus Jozef De Vreede
  • Publication number: 20090291874
    Abstract: The present application discloses compositions comprising ionic liquids and an amine compound, and methods for using and producing the same. In some embodiments, the compositions disclosed herein are useful in reducing the amount of impurities in a fluid medium or a solid substrate.
    Type: Application
    Filed: May 21, 2009
    Publication date: November 26, 2009
    Inventors: Jason E. Bara, Dean E. Camper, Richard D. Noble, Douglas L. Gin
  • Patent number: 7601208
    Abstract: A water production unit is provided that uses liquid desiccant and vehicle exhaust for extracting water from air.
    Type: Grant
    Filed: November 7, 2005
    Date of Patent: October 13, 2009
    Assignee: Hamilton Sundstrand Corporation
    Inventor: Stephen Tongue
  • Patent number: 7517391
    Abstract: An integrated ship mounted system for loading a gas stream, separating heavier hydrocarbons, compressing the gas, cooling the gas, mixing the gas with a desiccant, blending it with a liquid carrier or solvent, and then cooling the mix to processing, storage and transportation conditions. After transporting the product to its destination, a hydrocarbon processing train and liquid displacement method is provided to unload the liquid from the pipeline and storage system, separate the liquid carrier, and transfer the gas stream to a storage or transmission system.
    Type: Grant
    Filed: July 7, 2006
    Date of Patent: April 14, 2009
    Assignee: SeaOne Maritime Corp.
    Inventors: Bruce Hall, Micahel J. Mulvany, Tolulope O. Okikiolu
  • Patent number: 7431900
    Abstract: A hydrogen peroxide vapor generation unit (10) receives hydrogen peroxide and water solution at an interface (20) and interconnects with an air dryer (14) by way of nipples (72, 92). In one embodiment, the dryer includes a clamping assembly (42) which is latched (74, 94) with the nipples and which receives a disposable desiccant cartridge (40). In an alternate embodiment, a reusable desiccant cartridge (40?) is connected directly to the nipples (72, 92). When the desiccant cartridge (40?) is saturated, it is removed and placed in a regenerator unit (120). A regenerated cartridge is installed in its place.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: October 7, 2008
    Assignee: Steris Inc
    Inventors: Aaron L. Hill, Arthur T. Nagare, Frank E. Dougherty, Stanley M. Voyten
  • Publication number: 20080202343
    Abstract: An improved air humidity absorbing device to be used in a cargo container, includes: an external box made from cardboard material; the contents of the box including an external bag made from non woven spunbound; and at least two internal bags from the coated Tyvek material. The at least two internal bags are formed by subdividing the external bag into the at least two internal bags, and each of the internal bags is filled with an active mixture including Calcium Chloride (CaCl2) and Amylopectin.
    Type: Application
    Filed: April 3, 2006
    Publication date: August 28, 2008
    Inventor: John Ivar Allan Lundin
  • Patent number: 7377958
    Abstract: An apparatus is provided for removing airborne moisture from a designated area. In one embodiment, the apparatus includes a bucket, a liquid absorption medium (such as ground corn cobs) placed in the bottom of the bucket to form a media bed, a tray placed over the absorption media bed, and a moisture absorption medium (such as calcium chloride) placed in the bucket over the tray. A method is also provided for absorbing moisture from a humid environment using the apparatus. When the apparatus is exposed to humid conditions, the CaCl2 will absorb moisture and become hardened. As the CaCl2 media hardens, it will expand. However, its lateral expansion is restricted by a side wall of the tray. Over further time, the CaCl2 will begin to dissolve into a brine. The brine will gravitationally seep through the through-openings in the tray and be captured by the corn cob medium.
    Type: Grant
    Filed: February 17, 2005
    Date of Patent: May 27, 2008
    Inventor: Joaquin P. Cunanan
  • Patent number: 7306650
    Abstract: A method, and systems for implementing such method, for purifying and conditioning air of weaponized contaminants. The method includes wetting a filter packing media with a salt-based liquid desiccant, such as water with a high concentration of lithium chloride. Air is passed through the wetted filter packing media and the contaminants in are captured with the liquid desiccant while the liquid desiccant dehumidifies the air. The captured contaminants are then deactivated in the liquid desiccant, which may include heating the liquid desiccant. The liquid desiccant is regenerated by applying heat to the liquid desiccant and then removing moisture. The method includes repeating the wetting with the regenerated liquid desiccant which provides a regenerable filtering process that captures and deactivates contaminants on an ongoing basis while also conditioning the air. The method may include filtration effectiveness enhancement by electrostatic or inertial means.
    Type: Grant
    Filed: February 28, 2003
    Date of Patent: December 11, 2007
    Assignee: Midwest Research Institute
    Inventors: Steven J. Slayzak, Ren S. Anderson, Ronald D. Judkoff, Daniel M. Blake, Todd B. Vinzant, Joseph P. Ryan
  • Patent number: 7306654
    Abstract: A method of separating water from air is provided comprising the steps of (a) contacting air having water vapor with an hygroscopic liquid mixture to produce a water rich hygroscopic liquid mixture, (b) heating at least a portion of the water rich hygroscopic liquid mixture to produce a gaseous mixture including water vapor and at least one other gaseous component, (c) condensing at least a portion of the water vapor in the gaseous mixture to produce liquid water and a depleted gaseous mixture at a first pressure, and (d) removing at least a portion of the at least one other gaseous component to maintain the first pressure below a predetermined pressure, wherein the depleted gaseous mixture is in fluid communication with the water rich hygroscopic liquid mixture. An absorber vessel is also provided for effecting the method of separating water from air.
    Type: Grant
    Filed: January 30, 2004
    Date of Patent: December 11, 2007
    Inventors: Ronald King, Norman L. Arrison
  • Patent number: 7204867
    Abstract: Contemplated plants comprise an acid gas removal unit that receives a compressed gas from an injection gas compressor, wherein acid gas is removed from the compressed gas in the acid gas removal unit at a pressure approximately above pipeline pressure.
    Type: Grant
    Filed: November 25, 2002
    Date of Patent: April 17, 2007
    Assignee: Fluor Technologies Corporation
    Inventors: Richard B. Nielsen, John Mak
  • Patent number: 7074258
    Abstract: A process for the removal of water from gas which comprises an absorption step of bringing a gas saturated with water vapor into gas-liquid contact with a water-lean absorbing liquid comprising a water absorbing liquid having a cloud point temperature above the freezing point of water whereby water vapor present in the gas is absorbed into the water-lean absorbing liquid at a temperature below its cloud point to produce a refined gas having a reduced water vapor content and water-loaded absorbing liquid. A regeneration step is provided in which the water-loaded absorbing liquid is heated to above the cloud point temperature of the absorbing liquid whereby the water-loaded absorbing liquid separates into a water-rich phase and an absorbing liquid-rich phase and the absorbing liquid-rich phase is cooled to a temperature below its cloud point prior to recycling the absorbing liquid-rich phase for use as water-lean absorbing liquid in the absorption step.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: July 11, 2006
    Assignee: BP Exploration Operating Company Limited
    Inventors: Ian Ralph Collins, Stephen Paul Goodwin
  • Patent number: 6984257
    Abstract: An improved apparatus and method for use with a natural gas dehydrator. The apparatus and method of the invention provide for recirculation of gaseous or combustible materials so that they are not released into the atmosphere and to provide fuel for the process. Likewise, liquid hydrocarbons are collected. Various components, including separators, an absorber, wet glycol, dry glycol, an effluent condenser, heat exchangers, and a reboiler are utilized in accordance with the present invention.
    Type: Grant
    Filed: April 18, 2003
    Date of Patent: January 10, 2006
    Inventors: Rodney T. Heath, Forrest D. Heath
  • Patent number: 6974542
    Abstract: A column of solvent containing foaming contaminants is provided. Gas is educted into the solvent in the column so as to generate foam in the column. The gas is educted into the column independently of the input flow of solvent into the solvent using a pumparound arrangement with the solvent. Foam generation continues so as to push the foam up in the column, wherein much of the solvent that is in the foam is allowed to drain back down into the column. The foam passes through concentrators which increase the residency time of the foam in the column to further dry the foam and to create larger bubbles. The drier foam is pushed out of the column and into a container. The foam is broken up into gas and the liquid foaming contaminants. The gas is recirculated for injection into the column even after foaming has stopped. The foaming contaminants are concentrated at the surface level of the solvent in the column. These contaminants are removed from the column.
    Type: Grant
    Filed: May 22, 2003
    Date of Patent: December 13, 2005
    Inventor: Stephen A. von Phul
  • Patent number: 6964729
    Abstract: An improved method and apparatus for oxidizing undesired compounds residing within a liquid glycol based absorbent wherein the compounds are heated within a reboiler chamber to their boiling point to effectuate production of vaporized effluents. The absorbent's vaporized effluents rise upwardly exiting the reboiler chamber and enter a reflux tower wherein they are partially condensed via a condenser embodied within the interior of the tower. The residual uncondensed effluents are then transported to and first heated via a vaporizer/heat exchanger, thus effectuating the vaporization of any ambient condensed liquids contained within the effluents. The revaporized effluents then enter the invention's thermal oxidizer combustion chamber where they are second heated to a temperature necessary to effectuate destruction of undesirable compounds, such as but not limited to benzene, toluene and xylene.
    Type: Grant
    Filed: September 5, 2000
    Date of Patent: November 15, 2005
    Inventor: Parviz Khosrowyar
  • Patent number: 6896718
    Abstract: Moisture is removed from gas by contacting the gas with a solution of potassium formate to remove moisture from the gas, regenerating the potassium formate solution by removing water from it, and returning the potassium formate solution to contact gas to dehydrate it. Regeneration of the potassium formate solution is most preferably accomplished in a cavitation regenerator. The gas is most preferably natural gas.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: May 24, 2005
    Assignee: Clearwater International LLC
    Inventor: John H. Hallman
  • Publication number: 20040206242
    Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.
    Type: Application
    Filed: May 6, 2004
    Publication date: October 21, 2004
    Applicant: Membrane Technology and Research, Inc.
    Inventors: Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
  • Publication number: 20040187686
    Abstract: A process for removing contaminants from a natural gas feed stream including water and sour species is provided, which process comprises the steps of cooling the natural gas feed stream in a first vessel (12) to a first operating temperature at which hydrates are formed and removing from the first vessel (12) a stream of dehydrated gas (34); and cooling the dehydrated gas in a second vessel (14) to a second operating temperature at which solids of the sour species are formed or at which the sour species dissolve in a liquid and removing from the second vessel (14) a stream of dehydrated sweetened gas (62).
    Type: Application
    Filed: February 5, 2004
    Publication date: September 30, 2004
    Inventors: Robert Amin, Casper Krijno Groothuis
  • Patent number: 6793714
    Abstract: In a process for dehydration/fractionation of a wet natural gas containing heavy constituents and light constituents, In the presence of methanol, aqueous liquid phases are combined and the resultant combined aqueous liquid phase contacted with the first part of the gas to be scrubbed, which carries along the major part of the methanol, which allows to collect practically pure water. Before this step, all or part of one or both of the aqueous liquid phases and/or all or part of the aqueous liquid phase from a washing zone is sent to a distillation stage where practically pure methanol is collected at the top and a methanol-depleted aqueous liquid phase is collected at the bottom prior to being sent back to the first stage or used for the washing stage.
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: September 21, 2004
    Assignee: Institut Francais du Petrole
    Inventors: Fabrice Lecomte, Béatrice Fischer, Jean-Charles Viltard
  • Patent number: 6789288
    Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.
    Type: Grant
    Filed: October 25, 2002
    Date of Patent: September 14, 2004
    Assignee: Membrane Technology and Research, Inc.
    Inventors: Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
  • Patent number: 6767388
    Abstract: Process for dehydrating/fractionating a low-pressure wet natural gas containing “heavy” constituents and “light” constituents includes a stage a) in which at least a fraction of the wet gas at temperature T0 is contacted with an aqueous liquid phase L'1 containing methanol, the gas carrying along substantially all of the methanol contained in phase L'1. In a stage b), the gas from stage (a) is cooled to a temperature T1 lower than temperature T0, producing a gas phase G1 at equilibrium with a hydrocarbon-containing liquid phase L1 containing C3+ and an aqueous liquid phase L'1 containing methanol. In stage c), phase L'1 is sent to stage (a), and in stage d), said phase G1 is fractionated by distillation carried out by continuous thermal exchange with a cooling fluid, so as to extract the “light” constituents (gas phase G2) and the “heavy” constituents (condensed phase L2).
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: July 27, 2004
    Assignee: Institut Francais du Petrole
    Inventors: Fabrice Lecomte, Béatrice Fischer, Jean-Charles Viltard
  • Publication number: 20040139855
    Abstract: A process for the removal of water from gas which comprises an absorption step of bringing a gas (1) saturated with water vapour into gas-liquid contact with a water-lean absorbing liquid (3) comprising a water absorbing liquid having a cloud point temperature above the freezing point of water whereby water vapour present in the gas is absorbed into the water-lean absorbing liquid at a temperature below its cloud point to produce a refined gas (4) having a reduced water vapour content and water-loaded absorbing liquid (5); and a regeneration step of heating the water-loaded absorbing liquid (5) to above the cloud point temperature of the absorbing liquid whereby the water-loaded absorbing liquid separates into a water-rich phase (7) and an absorbing liquid-rich phase (8) and cooling the absorbing liquid-rich phase to a temperature below its cloud point prior to recycling the absorbing liquid-rich phase for use as water-lean absorbing liquid (3) in the absorption step.
    Type: Application
    Filed: March 17, 2004
    Publication date: July 22, 2004
    Inventors: Ian Ralph Collins, Stephen Paul Goodwin
  • Publication number: 20040099138
    Abstract: A high purity stream of methane can be obtained from crude natural gas, especially exhaust gas from waste landfills, by a process that includes first removing moisture, then feeding the dried crude gas mixture to a gas-liquid contact absorber to strip heavy hydrocarbon compounds in a primarily carbon dioxide by product stream. Methane enriched gas from the absorber is separated in a membrane separation unit which provides permeate enriched in carbon dioxide that is recycled to the absorber and a purified product stream of methane.
    Type: Application
    Filed: November 13, 2003
    Publication date: May 27, 2004
    Applicant: L'Air Liquide, Societe Anonyme A Directoire et Conseil De Surveillance Pour L'Etude et
    Inventors: Sandeep K. Karode, Charles L. Anderson
  • Publication number: 20040079228
    Abstract: A process and corresponding apparatus for dehydrating gas, especially natural gas. The process includes an absorption step and a membrane pervaporation step to regenerate the liquid sorbent.
    Type: Application
    Filed: October 25, 2002
    Publication date: April 29, 2004
    Applicant: Membrane Technology and Research, Inc.
    Inventors: Johannes G. Wijmans, Alvin Ng, Anurag P. Mairal
  • Patent number: 6699308
    Abstract: A system for removing water from natural gas which comprises: bringing the natural gas into contact with a liquid including an absorbent for the water; subjecting the natural gas and liquid to turbulent mixing conditions thereby causing the water to be absorbed by the absorbent; and separating a natural gas phase with reduced water content and a liquid phase including the absorbent and absorbed water. The mixing is conducted in a turbulent contactor (11) including a gas inlet (15), a liquid inlet (16), an outlet (104) leading to a venturi passage (105) and a tube (106) extending from the outlet (104) back upstream. The tube (106) may be perforated and/or spaced from the periphery of the outlet (104).
    Type: Grant
    Filed: January 22, 2002
    Date of Patent: March 2, 2004
    Assignee: Statoil ASA
    Inventors: Finn Patrick Nilsen, Harald Linga
  • Publication number: 20040031389
    Abstract: An improved apparatus and method for use with a natural gas dehydrator. The apparatus and method of the invention provide for recirculation of gaseous or combustible materials so that they are not released into the atmosphere and to provide fuel for the process. Likewise, liquid hydrocarbons are collected. Various components, including separators, an absorber, wet glycol, dry glycol, an effluent condenser, heat exchangers, and a reboiler are utilized in accordance with the present invention.
    Type: Application
    Filed: April 18, 2003
    Publication date: February 19, 2004
    Inventors: Rodney T. Heath, Forrest D. Heath
  • Patent number: 6666906
    Abstract: Potassium or other alkali metal formate solution is used to absorb moisture from gas through a membrane. The membrane may be supported on permeable tubes, and the potassium or other alkali metal formate may be regenerated for reuse, preferably by a cavitation regenerator. The potassium or other alkali metal formate should be present as a 40-80% solution, most preferably 70-76%. The process is especially useful for the dehydration of natural gas.
    Type: Grant
    Filed: November 6, 2001
    Date of Patent: December 23, 2003
    Assignee: Clearwater International, L.L.C.
    Inventor: John H. Hallman
  • Patent number: 6602423
    Abstract: A column of solvent containing foaming contaminants is provided. Gas is educted into the solvent in the column so as to generate foam in the column. The gas is educted into the column independently of the input flow of solvent into the solvent using a pumparound arrangement with the solvent. Foam generation continues so as to push the foam up in the column, wherein much of the solvent that is in the foam is allowed to drain back down into the column. The foam passes through concentrators which increase the residency time of the foam in the column to further dry the foam and to create larger bubbles. The drier foam is pushed out of the column and into a container. The foam is broken up into gas and the liquid foaming contaminants. The gas is recirculated for injection into the column even after foaming has stopped. The foaming contaminants are concentrated at the surface level of the solvent in the column. These contaminants are removed from the column.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: August 5, 2003
    Inventor: Stephen A. von Phul
  • Patent number: 6579343
    Abstract: The present invention provides a method for purifying a gas by contacting the gas with a liquid ionic compound. Natural gas may be purified, removing water and carbon dioxide, by contacting the natural gas with a liquid ionic compound.
    Type: Grant
    Filed: April 1, 2002
    Date of Patent: June 17, 2003
    Assignee: University of Notre Dame du Lac
    Inventors: Joan F. Brennecke, Edward J. Maginn
  • Patent number: 6551379
    Abstract: Apparatus for use with a natural gas dehydrator wherein a portion of the wet glycol in an emissions separator is pumped under pressure as circulating wet glycol which may be used as a coolant for effluent removed from a reboiler and/or a power source for an eductor to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluent, comprising at least liquid water, liquid hydrocarbons and uncondensed vapors, moves into the first chamber wherein the liquid water and/or the liquid hydrocarbons are separated from the uncondensed vapors. At least, the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are compressed and combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. In some instances, the liquid hydrocarbons are transferred to a third chamber and removed therefrom.
    Type: Grant
    Filed: February 8, 2002
    Date of Patent: April 22, 2003
    Inventor: Rodney T. Heath
  • Patent number: 6514321
    Abstract: A system and method for dehumidifying air including a multiple effect evaporator that creates a concentrated desiccant solution. The desiccant solution from the multiple effect evaporator is conveyed to a desiccant spray chamber that sprays the cooled desiccant solution into an air stream. The desiccant solution absorbs water vapor from the air stream creating a desiccant and water solution. A conduit transfers the water and desiccant solution to the multiple effect evaporator for removal of the water from the desiccant solution.
    Type: Grant
    Filed: October 18, 2000
    Date of Patent: February 4, 2003
    Assignee: PowerMax, Inc.
    Inventors: John M. Lehto, John Tyson
  • Patent number: 6506233
    Abstract: Desiccant tablets including solid potassium formate are used to dry gas, especially in natural gas transmission lines. Preferred tablets comprise 1-4% potassium formate (most preferably 2-3%), up to 1% of a surfactant as a lubricant, and the balance desiccant salts, preferably calcium chloride.
    Type: Grant
    Filed: November 9, 2001
    Date of Patent: January 14, 2003
    Assignee: Clearwater, Inc.
    Inventor: Kevin W. Smith
  • Publication number: 20020185006
    Abstract: Process for dehydrating/fractionating a low-pressure wet natural gas containing <<heavy >> constituents and <<light >> constituents, wherein:
    Type: Application
    Filed: March 29, 2002
    Publication date: December 12, 2002
    Inventors: Fabrice Lecomte, Beatrice Fischer, Jean-Charles Viltard
  • Publication number: 20020178918
    Abstract: In a process intended for dehydration/fractionation of a wet natural gas containing <<heavy>> constituents and <<light>> constituents, in the presence of methanol, which comprises at least the following stages
    Type: Application
    Filed: March 29, 2002
    Publication date: December 5, 2002
    Inventors: Fabrice Lecomte, Beatrice Fischer, Jean-Charles Viltard
  • Patent number: 6461413
    Abstract: In a process using a hydrophilic liquid desiccant, for dehydrating a gas containing water with regeneration of the steps of: (a) absorbing water by contact between the moist gas and regenerated liquid desiccant from step c), producing a dry gaseous effluent and a stream of liquid desiccant charged with water and absorbed gases; (b) regenerating the liquid desiccant charged with water in a regeneration zone constituting a reboiling zone and a distillation zone, the charged liquid desiccant being sent to said distillation zone, from which a vapor containing water leaves overhead and from which liquid desiccant still containing water leaves from the bottom in the reboiling zone; (c) passing the liquid desiccant from the reboiling zone of step b) and still containing water to an absorption zone, in which the water in the desiccant is vaporized and the water vapor is absorbed by a fraction of regenerated or non regenerated desiccant, passing the resultant desiccant which has absorbed water vapor to the reboiling z
    Type: Grant
    Filed: November 27, 2000
    Date of Patent: October 8, 2002
    Assignee: Prosernat
    Inventors: Benoit Landreau, Jean-Claude Amande
  • Patent number: 6425942
    Abstract: The gas which is to be dried is fed into an absorber (1) where it is brought into contact with a glycol in countercurrent. The glycol absorbs the moisture from the gas and impurities. The glycol laden with water and impurities is removed from the absorber (1) via a line (5). It is then regenerated in a reboiler (9) where the water is eliminated by heating. The water-free glycol is passed into a storage vessel (10) from which it can then be refed to the absorber (1). The glycol which is withdrawn from the storage vessel (10) is purified by mixing it with at least half the quantity of water. The mixture is brought to a temperature above cloud point where it is maintained for a predetermined length of time so that the impurities flocculate. The flocculated impurities are removed in a filter (18) arid the purified glycol mixed with water is refed to the reboiler (9) via a line (19). The drying process is very economical as it integrates environmentally-friendly and simple purification of the glycol.
    Type: Grant
    Filed: June 13, 2000
    Date of Patent: July 30, 2002
    Assignee: Ruhrgas Aktiengesellschaft
    Inventor: Randolf Ruediger Forster
  • Publication number: 20020073843
    Abstract: Apparatus for use with a natural gas dehydrator wherein a portion of the wet glycol in an emissions separator is pumped under pressure as circulating wet glycol which may be used as a coolant for effluent removed from a reboiler and/or a power source for an eductor to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluent, comprising at least liquid water, liquid hydrocarbons and uncondensed vapors, moves into the first chamber wherein the liquid water and/or the liquid hydrocarbons are separated from the uncondensed vapors. At least, the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are compressed and combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. In some instances, the liquid hydrocarbons are transferred to a third chamber and removed therefrom.
    Type: Application
    Filed: February 8, 2002
    Publication date: June 20, 2002
    Inventor: Rodney T. Heath
  • Patent number: 6368384
    Abstract: Desiccant tablets including solid potassium formate are used to dry gas, especially in natural gas transmission lines. The most preferred tablets comprise 5-15% potassium formate, up to 1% of a surfactant as a lubricant, and the balance desiccant salts, preferably calcium chloride.
    Type: Grant
    Filed: March 9, 2001
    Date of Patent: April 9, 2002
    Assignee: Clearwater, Inc.
    Inventor: Kevin W. Smith
  • Patent number: 6364933
    Abstract: Apparatus for use with a natural gas dehydrator wherein a portion of the wet glycol in an emissions separator is pumped under pressure as circulating wet glycol which may be used as a coolant for effluent removed from a reboiler and/or a power source for an eductor to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluent, comprising at least liquid water, liquid hydrocarbons and uncondensed vapors, moves into the first chamber wherein the liquid water and/or the liquid hydrocarbons are separated from the uncondensed vapors. At least, the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are compressed and combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. In some instances, the liquid hydrocarbons are transferred to a third chamber and removed therefrom.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: April 2, 2002
    Inventor: Rodney T. Heath
  • Patent number: 6355092
    Abstract: The invention relates to an apparatus for performing membrane gas/liquid absorption at elevated pressure, comprising a pressure vessel in which a membrane unit is provided for separate feed-through of the gas phase and the liquid phase, in such a way that exchange of components to be absorbed can take place between the gas phase and the liquid phase, the flow direction of the gas phase through the absorber being essentially perpendicular to the flow direction of the liquid phase through the absorber. The invention further relates to a method for performing gas/liquid membrane absorption employing this absorber, in particular for the absorption of CO2, H2S, mercury (vapor) and/or water (vapor) from a gas phase at elevated pressure. The invention finally relates to a method for refining natural gas using the absorber and method according to the invention.
    Type: Grant
    Filed: November 9, 1999
    Date of Patent: March 12, 2002
    Assignee: Nederlandse Organisatie voor Toegepast-Natuurwetenschappelijk Ondersoek TMO
    Inventors: Albert Edward Jansen, Paul Hubert Maria Feron, Jan Hendrik Hanemaaijer, Piet Huisjes
  • Patent number: 6251165
    Abstract: Process for recovering a solvent from a gas coming from a treating process using the solvent, the gas having a low temperature Ta and a high temperature Td, the difference Td-Ta being sufficient to carry out an adsorption step and a desorption step. The process is characterized in that/ a) a first solvent-containing gas stream is sent to an adsorption step, this gas being at a temperature Ta, at the end of this step the gas is practically solvent-free and the solvent is collected in a first adsorber, b) a second gas stream at a temperature Td, this gas being solvent-free, is sent to carry out desorption of a second adsorption means loaded with solvent during a previous step a), and c) the solvent is sent at least partly to a step of the treating process using the solvent.
    Type: Grant
    Filed: June 2, 1999
    Date of Patent: June 26, 2001
    Assignee: Institut Francais du Petrole
    Inventors: Sophie Jullian, Etienne Lebas, Michel Thomas
  • Patent number: 6251166
    Abstract: A glycol regenerating system wherein a pressurized reboiler is introduced to a typical prior art system, the pressurized reboiler being in the glycol stream upstream from the conventional atmospheric reboiler. The pressurized reboiler heats the rich glycol coming from the glycol contactor from about 300° F. to 400° F. and keeps the glycol under pressure from about 10-25 psig. in order to first distill and condense VOCs (volatile organic compounds) which constitute non-condensable hydrocarbons and condensable hydrocarbons such as BTEX (Benzene, Toluene, Ethylbenzene, Xylene) compounds, the components being conveniently under pressure for transporting the components to a desired location.
    Type: Grant
    Filed: August 18, 1999
    Date of Patent: June 26, 2001
    Assignee: Anderson Controls, LC
    Inventor: R. David Anderson
  • Patent number: 6238461
    Abstract: A natural gas dehydrator wherein a portion of the wet glycol from the absorber is pumped under pressure as circulating wet glycol which is used as a coolant for effluents removed from a reboiler and a power source for an educator to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluents, comprising liquid water, liquid hydrocarbons and uncondensed vapors, move in to the first chamber wherein the liquid water is separated therefrom. The liquid hydrocarbons and the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. Also, gases from gas emitting level control apparatus in the natural gas dehydrator are collected and fed into the first chamber.
    Type: Grant
    Filed: June 15, 1999
    Date of Patent: May 29, 2001
    Inventor: Rodney T. Heath
  • Patent number: 6183540
    Abstract: A method is provided for the extraction of aromatic hydrocarbons, including benzene, toluene, ethylbenzene, and xylene, collectively known as “BTEX,” in a continuous process utilizing a glycol contactor to cause absorption of the BTEX upstream of an amine-based gas sweetening process. The preferred glycol for BTEX absorption is triethylene glycol. The glycol used in the glycol contactor for BTEX extraction may either be fully regenerated (dry), or wet glycol from a downstream gas dehydration system. The method may be achieved with the use of a number of separate absorber/contactor vessels, or the method may be achieved within one combination vessel.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: February 6, 2001
    Assignee: Kinder Morgan, Inc.
    Inventor: Jonathan E. Thonsgaard
  • Patent number: RE39944
    Abstract: A natural gas dehydrator wherein a portion of the wet glycol from the absorber is pumped under pressure as circulating wet glycol which is used as a coolant for effluents removed from a reboiler and a power source for an educator to form a vacuum in a first chamber of a liquid water removal separator apparatus. The cooled effluents, comprising liquid water, liquid hydrocarbons and uncondensed vapors, move in to the first chamber wherein the liquid water is separated therefrom. The liquid hydrocarbons and the uncondensed vapors are removed from the first chamber and move into the eductor wherein they are combined into the circulating wet glycol. The separated liquid water is transferred to a second chamber of the liquid water removal separator apparatus and then removed therefrom. Also, gases from gas emitting level control apparatus in the natural gas dehydrator are collected and fed into the first chamber.
    Type: Grant
    Filed: May 29, 2003
    Date of Patent: December 25, 2007
    Inventor: Rodney T. Heath