Alkene Sorbed Patents (Class 95/240)
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Publication number: 20130255496Abstract: An ionic liquid solvent and gas purification method using the same are provided. The ionic liquid solvent consists of a main absorbent, a regulator for the main absorbent, an auxiliary absorbent, an activator, an antioxidant and water. The ionic liquid involves a low synthetic cost, low viscosity and high absorption capacity, and can be easily regenerated and recycled. The method, compared with traditional processes, has advantages such as a greater absorption capability and lower operation cost.Type: ApplicationFiled: September 26, 2010Publication date: October 3, 2013Applicant: INSTITUTE OF PROCESS ENGINEERING, CHINESE ACADEMYInventors: Xiangping Zhang, Yansong Zhao, Shaojuan Zeng, Suojiang Zhang, Haifeng Dong, Yingpeng Zhen, Lei Huang
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Patent number: 8410329Abstract: A polyethylene production process, comprising contacting ethylene and a polymerization catalyst under suitable reaction conditions to yield a polymerization product stream, separating a light gas stream from the polymerization product stream, wherein the light gas stream comprises ethane and unreacted ethylene, contacting the light gas stream with an absorption solvent system, wherein at least a portion of the ethylene from the light gas stream is absorbed by the absorption solvent system, removing unabsorbed gases of the light gas stream from contact with the absorption solvent system to form a waste gas stream, and recovering ethylene from the absorption solvent system.Type: GrantFiled: October 15, 2010Date of Patent: April 2, 2013Assignee: Chevron Phillips Chemical Company LPInventors: John D. Hottovy, Ted Cymbaluk
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Publication number: 20120134905Abstract: A method of use of an ionic liquid for sorption of a gas having an electric multipole moment is provided, wherein the ionic liquid comprises an anion and a non-aromatic cation. In particular, the electric multipole moment may be an electric dipole moment and/or an electric quadrupole moment. The sorption may be an adsorption or an absorption. The ionic liquid may be a pure ionic liquid, i.e. a liquid substantially only containing anions and cations, while not containing other components, e.g. water. Alternatively a solution containing the ionic liquid and a solvent or further compound, e.g. water, may be used.Type: ApplicationFiled: June 22, 2010Publication date: May 31, 2012Applicant: VTU HOLDING GMBHInventor: Roland Kalb
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Patent number: 7786323Abstract: (Meth)acrolein or (meth)acrylic acid is collected by bringing a reaction gas (1) containing (meth)acrolein or (meth)acrylic acid obtained through a vapor-phase catalytic oxidation reaction into contact with an aqueous solution as a collecting solvent in a collecting tower main body (2). The reaction gas (1) is supplied to the collecting tower main body (2) from two nozzles (2c) facing each other, and is caused to collide in the collecting tower main body (2). According to the present invention, (meth)acrolein or (meth)acrylic acid can be efficiently collected from a gas containing (meth)acrolein or (meth)acrylic acid while preventing polymerization.Type: GrantFiled: May 16, 2006Date of Patent: August 31, 2010Assignee: Mitsubishi Chemical CorporationInventors: Shuhei Yada, Yasushi Ogawa, Kenji Takasaki, Yoshiro Suzuki, Kimikatsu Jinno
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Patent number: 6749668Abstract: A process for the recovery of combustible components of a gas stream containing the combustible components and oxygen by selective absorption of the combustible components in a solvent, whereby during the absorption the gas phase is dispersed in a continuous liquid phase of the solvent. In a preferred embodiment the process is applied to give a process for the epoxidation of propene with hydrogen peroxide in the alcoholic solvent in presence of a catalyst, wherein a gas stream including unreacted propene, propene oxide and oxygen from the decomposition of the hydrogen peroxide is separated from the epoxidation reaction mixture and the combustible components in said gas stream are recovered using the process as described above.Type: GrantFiled: June 18, 2002Date of Patent: June 15, 2004Assignees: Degussa AG, Uhde GmbHInventors: Willi Hofen, Georg Thiele, Wolfgang Wöll
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Patent number: 6419727Abstract: A process for the removal of contaminants from a gas, using a gas cleaning agent, which contamination is selected from the group comprising aromatic hydrocarbons and (poly)halogenated aromatic hydrocarbons. For the removal of the contaminant a detergent is added as gas cleaning agent. The detergent is selected from a group formed by an anionic detergent, non-ionic detergent and a mixture thereof.Type: GrantFiled: October 28, 1999Date of Patent: July 16, 2002Assignee: Gemeente Amsterdam, GemeentelijkeInventor: Cornelis De Vries
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Patent number: 6358399Abstract: A process and a device for separating ethane and ethylene from a hydrocarbon steam-cracking effluent is described. Effluent (1) is absorbed in an absorption column (7) by a cooled solvent (9). At the bottom of the column, liquid phase (12) that contains the solvent and the C2+ hydrocarbons is recovered and hydrogenated (15). The hydrogenation effluent that contains the solvent is introduced into a first distillation column (70) where the solvent is regenerated. The solvent is cooled and recycled at the top of absorption column (7). The C2+ hydrocarbons are collected at the top, and a condensed liquid phase is distilled in a second distillation column (77) to recover a C2 fraction that consists of ethane and ethylene.Type: GrantFiled: August 16, 2000Date of Patent: March 19, 2002Assignee: Institute Francais du PetroleInventors: Ari Minkkinen, Jean-Hervé Le Gal, Pierre Marache
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Patent number: 6340429Abstract: A process for separating ethane and ethylene from a hydrocarbon steam-cracking effluent is described. Effluent (1) is absorbed in an absorption column by a cooled solvent (9). At the bottom of the column, the liquid phase that contains the solvent and the C2+ hydrocarbons is recovered and hydrogenated (15). The hydrogenation effluent that contains the solvent is introduced into a first distillation column (16). Ethane-ethylene mixture (17) is drawn off laterally from the column, and a phase (19) that contains the solvent and hydrocarbons with at least 3 carbon atoms is drawn off at the bottom of the column. This phase (19) is separated in a second distillation column (22), and C3+ hydrocarbons and, at the bottom of the column, regenerated solvent (26) that is cooled and that is recycled (9, 52) in the absorption column are collected.Type: GrantFiled: August 16, 2000Date of Patent: January 22, 2002Assignee: Institut Francais du PetroleInventors: Ari Minkkinen, Jean-Hervé Le Gal, Pierre Marache
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Patent number: 6161386Abstract: A method for generating electric power, such as at, or close to, natural gas fields. The method includes conditioning natural gas containing C.sub.3+ hydrocarbons and/or acid gas by means of a membrane separation step. This step creates a leaner, sweeter, drier gas, which is then used as combustion fuel to run a turbine, which is in turn used for power generation.Type: GrantFiled: December 23, 1998Date of Patent: December 19, 2000Assignee: Membrane Technology and Research, Inc.Inventor: Kaaeid A. Lokhandwala
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Patent number: 6035641Abstract: A method for generating electric power from natural gas or the like that has a low Btu value and a high nitrogen content. The method involves a membrane separation step to remove a portion of the nitrogen from the gas. The upgraded gas is used as fuel for a turbine or other driver, which provides mechanical power to drive an electric power generator.Type: GrantFiled: September 19, 1997Date of Patent: March 14, 2000Assignee: Membane Technology and Research, Inc.Inventor: Kaaeid A. Lokhandwala
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Patent number: 5681369Abstract: An apparatus is provided for recovering volatile liquid vapor from an air-volatile liquid vapor mixture. The apparatus includes first and second reaction vessels. Each of these reaction vessel includes a bed of adsorbent having an affinity for the volatile liquid vapor. The apparatus also includes a pump and an absorber for regenerating either bed of adsorbent. Further, the apparatus includes a polisher including a polisher bed of adsorbent having an affinity for the volatile liquid vapor. This polisher bed adsorbs volatile liquid vapor and substantially clean air is exhausted when initially regenerating one of the two beds of adsorbent in the first and second reaction vessels. Still further, the apparatus also includes a cooperating valve and conduit system for interconnecting the other components. Further, the invention relates to a related process for recovering volatile liquid vapor and a method of reducing backpressure in a volatile liquid vapor recovery system or unit.Type: GrantFiled: May 10, 1996Date of Patent: October 28, 1997Assignee: Jordan Holding CompanyInventor: John B. Osborne
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Patent number: 5681908Abstract: A process for rejecting reactor byproduct from the polymerization reactor in an olefins polymerization process wherein reactor waste gas stream(s) comprising unreacted monomers, reactor byproduct and light components are treated in an absorption process to additionally recover the monomers. The absorption process comprises contacting the reactor waste gas stream(s) with an absorption solvent in an absorption zone to produce a gas stream comprising the light components, and a liquid stream comprising the absorption solvent, absorbed reactor byproduct and absorbed monomers. The liquid stream is fractionated in a distillation column to produce a distillation column bottoms stream that is the absorption solvent which is conveyed to the absorption zone, and an overhead stream comprising the monomers and reactor byproduct which is further fractionated in a splitter column to reject the reactor byproduct as a bottoms stream. The recovered monomers from the splitter overhead can be conveyed to the reactor.Type: GrantFiled: January 25, 1996Date of Patent: October 28, 1997Assignee: Advanced Extraction Technologies, Inc.Inventors: Yuv R. Mehra, Robert H. Stodghill
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Patent number: 5669958Abstract: A membrane separation process for treating a gas stream containing methane and nitrogen, for example, natural gas. The separation process works by preferentially permeating methane and rejecting nitrogen. We have found that the process is able to meet natural gas pipeline specifications for nitrogen, with acceptably small methane loss, so long as the membrane can exhibit a methane/nitrogen selectivity of about 4, 5 or more. This selectivity can be achieved with some rubbery and super-glassy membranes at low temperatures. The process can also be used for separating ethylene from nitrogen.Type: GrantFiled: February 29, 1996Date of Patent: September 23, 1997Assignee: Membrane Technology and Research, Inc.Inventors: Richard W. Baker, Kaaeid A. Lokhandwala, Ingo Pinnau, Scott Segelke
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Patent number: 5634962Abstract: A method for removing hazardous gases having water solubility from storage tanks by scrubbing steps is described. Additionally, a method for removing ethylene dichloride contamination from soil is disclosed.Type: GrantFiled: January 11, 1996Date of Patent: June 3, 1997Assignee: Serv-Tech, In.Inventors: Timothy W. Trahan, Robert R. Cradeur, Nishanath K. Mehta
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Patent number: 5533437Abstract: Hydrocarbons are recovered from the product purge gas in an alkene polymerization process by absorption of heavier hydrocarbons from the purge gas by an intermediate hydrocarbon stream to yield a vapor rich in inert gas and alkene monomer. Alkene monomer is condensed at low temperatures from the inert gas, flashed and vaporized to provide refrigeration for the condensation step, and recycled to the polymerization process. The intermediate hydrocarbon from the absorption step is recycled to the polymerization process. Optionally a portion of the inert gas is reused for purge gas.Type: GrantFiled: January 20, 1995Date of Patent: July 9, 1996Assignee: Air Products and Chemicals, Inc.Inventors: Lee J. Howard, Howard C. Rowles
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Patent number: 5521264Abstract: A process for gas phase polymerization of olefins wherein reactor vent gas stream(s) comprising unreacted monomers and light components are treated in an absorption process to recover the monomers. The absorption process comprises contacting the reactor vent gas stream(s) with an absorption solvent in an absorption zone to produce a gas stream comprising the light components, and a liquid stream comprising the absorption solvent and absorbed monomers. The liquid stream is fractionated in a distillation column to produce a distillation column bottoms stream that is the absorption solvent which is conveyed to the absorption zone, and an overhead stream comprising the monomers which can be conveyed to the reactor. In a preferred embodiment, the absorption solvent consists essentially of components derived from the reactor vent gas stream(s) so that no external solvent is required.Type: GrantFiled: August 3, 1995Date of Patent: May 28, 1996Assignee: Advanced Extraction Technologies, Inc.Inventors: Yuv R. Mehra, Robert H. Stodghill
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Patent number: 5520724Abstract: The invention relates to a process for the recovery of low molecular weight C.sub.2+ hydrocarbons, in particular ethylene and ethane from a cracking gas, in particular from a fluid catalytic cracking waste gas. In accordance with the invention the light C.sub.2+ hydrocarbons are scrubbed out of the cracking gas by absorption, using an organic, preferably paraffinic, physically acting scrubbing agent, the scrubbing agent having a molecular weight of between 50 and 75 g/mol, preferably between 60 and 75 g/mol. Particularly suitable as scrubbing agents are pentane, isopentane or mixtures thereof. Prior to the generation of the loaded scrubbing agent, co-extracted methane is advantageously stripped off.Type: GrantFiled: February 3, 1995Date of Patent: May 28, 1996Assignee: Linde AktiengesellschaftInventors: Heinz Bauer, Hans Becker
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Patent number: 5423901Abstract: A method for conditioning a gas containing entrained asphaltene-containing hydrocarbons for pipeline transportation, having the steps of providing a stream of gas containing entrained asphaltene-containing hydrocarbons; and applying a surface active compound to the stream of gas, the surface active compound being a mixture of demulsifying agent, antifoaming agent, dispersant, aromatic solvent and alcohol solvent, whereby formation of emulsion from asphaltene containing hydrocarbons is prevented. The surface active compound has the following composition by volume: 5-15% demulsifying agent; 1-3% antifoaming agent; 10-40% dispersant; 10-60% aromatic solvent; and 20-60% alcohol solvent.Type: GrantFiled: May 16, 1994Date of Patent: June 13, 1995Assignee: Corpoven, S.A.Inventor: Alberto L. Mendoza
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Patent number: 5356460Abstract: Methacrolein is removed from a gaseous mixture by absorption by means of an aqueous solution which contains from 60 to 90% by weight of methacrylic acid.Type: GrantFiled: July 23, 1993Date of Patent: October 18, 1994Assignee: BASF AktiengesellschaftInventors: Herbert Vogel, Herbert Exner, Gerd Bohner