With Rotating Gas Distributor Patents (Class 96/124)
  • Patent number: 5584322
    Abstract: A rotary slide valve (10) controls compressed air, nitrogen and oxygen streams independently from each other. The rotary slide valve (10) consists of a housing (15) with pairs of diametrically opposed radial bores and a valve body (11) with recesses (35, 37). The valve body (11) is coupled to a rotary drive R. According to its position, the valve body (11) opens and closes compressed air inlets, compressed air outlets or nitrogen outlets and controls the streams of compressed air and nitrogen. In addition, the rotary slide valve controls several streams of oxygen through several axial oxygen inlets (49, 51) and outlets (53, 55) which may be interconnected through an axial recess of the valve body (11). The rotary slide valve (10) is used in particular in air oxygen-enriching installations.
    Type: Grant
    Filed: November 29, 1995
    Date of Patent: December 17, 1996
    Assignee: PPV Verwaltungs AG
    Inventors: Gunter Poschl, Detlev Degenhardt
  • Patent number: 5578111
    Abstract: A process is described for the separation of a mixture of substances by sorption of the mixture's components on two different sorption agents, which are individually and independently adjustable in their sorption properties, and is performed in a manner by which the mixture of substances to be separated is introduced into a separation chamber between the surfaces of the sorption agents, and in which the separation chamber is occupied by a gap medium, in which the mixture's components can be dissolved and/or dispersed and/or evaporated, while the phases containing the sorption agents move in opposing directions, and the separated components of the mixture held on the sorption agents are recovered after passage through the separation path. This process is characterized in that the separation chamber is formed by at least two or several hollow, concentrically superimposed cylindrical disks Z.sub.A and Z.sub.B, which are filled with structural elements, and which contain separation media Ph.sub.A and Ph.sub.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: November 26, 1996
    Assignee: Reuter Chemischer Apparatebau GmbH
    Inventor: Karl A. Reuter
  • Patent number: 5547640
    Abstract: An extremely compact, energy efficient air purifier for incinerating volatile organic chemical contaminants, and airborne organic particulates comprises a cylindrical ceramic heat transfer/storage element having many substantially identical axially parallel flow passages with very large surface area per mass, and a rotating guide for guiding the inlet air flow to a preset radial segment of the ceramic element. The air flow exiting from the preset radial segment is directed to the remaining segment in the opposite direction. The air flow exiting from the remaining segment is exhausted from the air purifier. Included is a pre-heater for heating the ceramic element at start up, and maintaining the air flow at a stable incineration temperature.
    Type: Grant
    Filed: January 6, 1995
    Date of Patent: August 20, 1996
    Inventor: Dae S. Kim
  • Patent number: 5366541
    Abstract: Improved apparatus for fractionating fluid mixtures by pressure swing molecular adsorption employing a rotary distributor valve and an array of adsorber columns. The columns are, in one embodiment, contained within a product holding tank or, in another embodiment, attached to a product tank. The valve sequences to provide a quasi steady-state flow, allowing optimization of adsorption/desorption cycles, and eliminating most of the valves, switches and plumbing usually required.
    Type: Grant
    Filed: October 25, 1993
    Date of Patent: November 22, 1994
    Assignee: Dynotec Corporation
    Inventors: Charles C. Hill, Theodore B. Hill
  • Patent number: 5268021
    Abstract: Improved apparatus for fractionating fluid mixtures by pressure swing molecular adsorption employing a rotary distributor valve and an array of adsorber columns. The columns are, in one embodiment, contained within a product holding tank or, in another embodiment, attached to a product tank. The valve sequences to provide a quasi steady-state flow, allowing optimization of adsorption/desorption cycles, and eliminating most of the valves, switches and plumbing usually required.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: December 7, 1993
    Assignee: Dynotec Corporation
    Inventors: Charles C. Hill, Theodore B. Hill
  • Patent number: 5256174
    Abstract: A pressure-swing adsorption type gas separator system includes two adsorption vessels and a switching valve for placing each of the adsorption vessels alternately in communication with a raw gas source and an exhaust gas line so that a pressurized adsorption process and a reduced-pressure desorption process are sequentially carried out in each of the vessels. The switching valve is a four-port rotary valve having four ports connected to the adsorption vessels, a raw gas source and an exhaust gas line and is driven by a rotary drive. Preferably, the rotary drive is a drive motor for a pressurizing pump provided in a raw gas line, and the four-port rotary valve is connected to the drive motor via a speed reducer.
    Type: Grant
    Filed: August 3, 1992
    Date of Patent: October 26, 1993
    Assignee: Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Norichika Kai, Shozo Kaneko, Tsugiya Abe
  • Patent number: 5248325
    Abstract: A rotary gas recovery system includes a fixed adsorption tower (12) divided into a plurality of sections (12') arranged in the circumferential direction around a central axis and filled with adsorbent (11), a first manifold (14) on one side of the tower having opening (14a, 14b) for supplying and discharging gases to and from the fixed adsorption tower, a second manifold (15) having openings (15a-15d) for supplying and discharging gases through the first manifold, and a movable valve plate (16) slidably interposed between the first manifold (14) and second manifold (15) and having openings (16a, 16b) for sequentially connecting the openings in the first manifold with the openings in the second manifold by a continuous motion.
    Type: Grant
    Filed: May 7, 1992
    Date of Patent: September 28, 1993
    Assignee: Mitsubishi Jukogyo Kabushiki Kaisha
    Inventors: Yoshimi Kagimoto, Kunio Saki, Sadamu Takahashi, Jun Izumi, Kazuaki Ohshima
  • Patent number: 4172730
    Abstract: Silver halide radiographic sensitive materials comprising at least one silver halide photographic emulsion layer on a support, which are used according to a process which comprises exposure to radiation from a fluorescent intensifying screen which emits light having a maximum emission in the green spectral range by excitation with radiation wherein at least 1/2 of the emission energy is in the wavelength range of above about 400 nm, and carrying out development of the exposed sensitive material to form radiographic images, wherein said silver halide sensitive materials contain below about 8.6 g of silver per square meter and said at least one silver halide photographic emulsion layer contains a combination of at least one dye represented by formula (I) and at least one dye represented by formula (II): ##STR1## wherein A.sub.1 and A.sub.2 each represents a hydrogen atom or a halogen atom; A.sub.3 and A.sub.4 each represents a hydrogen atom, a halogen atom, an alkoxy group or a phenyl group; B.sub.1, B.sub.
    Type: Grant
    Filed: April 15, 1977
    Date of Patent: October 30, 1979
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Nobuaki Miyasaka, Kenji Takahashi
  • Patent number: 4152163
    Abstract: A spectrally sensitized silver halide photographic emulsion comprising a silver halide emulsion containing a combination of at least one sensitizing dye represented by the following general formula (I): ##STR1## at least one sensitizing dye represented by the following general formula (II): ##STR2## and at least one organic heterocyclic compound represented by the following general formula (III) or (IV): ##STR3## wherein Z.sup.1 and Z.sup.2, which may be the same or different, each represents a group of atoms necessary for forming a thiazole nucleus or a selenazole nucleus; Z.sup.3 has the same meaning as Z.sup.1 and Z.sup.2 ; Z.sup.4 represents a group of atoms necessary for forming an imidazole nucleus or an oxazole nucleus; Z.sup.5 represents a group of atoms necessary for forming an imidazole nucleus; R.sup.1, R.sup.2, R.sup.4, R.sup.5 and R.sup.7, which may be the same or different, each represents an alkyl group, with at least one of R.sup.1, R.sup.2, R.sup.4 and R.sup.
    Type: Grant
    Filed: March 14, 1977
    Date of Patent: May 1, 1979
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Sato, Tadashi Ikeda, Takeo Sakai, Haruo Takei, Jun Hayashi
  • Patent number: 4147553
    Abstract: A silver halide photographic emulsion containing, in supersensitizing amounts, the combination ofat least one compound represented by the following general formula (I): ##STR1## wherein Z.sub.1 represents the atoms necessary for forming a benzene ring or a naphthalene ring; W.sub.1 represents a sulfur atom or a selenium atom; Y represents an oxygen atom or a sulfur atom; R.sub.1 represents an alkyl group or an aryl group; and R.sub.2 represents a lower alkyl group having 1 to 6 carbon atoms in the alkyl moiety or an aryl group;At least one carbocyanine dye represented by the following general formula (II): ##STR2## wherein Z.sub.2 represents the atoms necessary for forming a thiazole ring, a selenazole ring, an oxazole ring, an imidazole ring or a pyrroline ring; Z.sub.3 represents the atoms necessary for forming an oxazole ring or an imidazole ring; R.sub.4 and R.sub.5, which may be the same or different, each represents an alkyl group; R.sub.
    Type: Grant
    Filed: February 7, 1978
    Date of Patent: April 3, 1979
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Sato, Tadashi Ikeda, Takeo Sakai, Haruo Takei, Jun Hayashi
  • Patent number: 4147547
    Abstract: A light-sensitive silver halide photographic material having improved anti-fogging properties is described.
    Type: Grant
    Filed: January 10, 1978
    Date of Patent: April 3, 1979
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takeo Koitabashi, Noboru Fujimori, Shigemasa Itoh
  • Patent number: 4135933
    Abstract: A supersensitized silver halide photographic emulsion containing a cyan coupler and, in combination, at least one of the sensitizing dyes represented by the following general formula (I) and at least one of the sensitizing dyes represented by the general formula (II): ##STR1## WHEREIN W.sup.1 and W.sup.2 each represents a hydrogen atom, an alkyl group, an alkoxyl group, a halogen atom, an alkoxycarbonyl group, an acyl group or an aryl group; R.sup.1 and R.sup.2 each represents a sulfoalkyl group; R.sup.3 represents an alkyl group or an allyl group; X.sub.1 represents an acid anion; and m is 1 or 2, m being 1 in the case that the dye forms an inner salt of a betaine-like structure; ##STR2## wherein Z.sup.1 and Z.sup.2 each represents an atomic group required for forming a benzothiazole nucleus, a benzoselenazole nucleus, a .beta.-naphthothiazole nucleus or a .beta.-naphthoselenazole nucleus; R.sup.4 and R.sup.5 each represents an aliphatic group and at least one of R.sup.4 and R.sup.
    Type: Grant
    Filed: December 1, 1977
    Date of Patent: January 23, 1979
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto, Jun Hayashi
  • Patent number: 4049456
    Abstract: A light-sensitive silver halide photographic material is disclosed which contains a support and a red-sensitive layer. The red-sensitive layer contains at least one sensitizing dye selected from a particular group of sensitizing dyes and at least one sensitizing dye selected from a second group of sensitizing dyes and at least one of a particular group of compounds.
    Type: Grant
    Filed: April 7, 1976
    Date of Patent: September 20, 1977
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takeo Koitabashi, Hideo Akamatsu
  • Patent number: 4045230
    Abstract: A light-sensitive silver halide color photographic material comprising at least a support and a red-sensitive, silver halide-containing layer containing at least one sensitizing dye of the following general formula I ##STR1## AND AT LEAST ONE SENSITIZING DYE OF THE FOLLOWING GENERAL FORMULA II ##STR2##
    Type: Grant
    Filed: March 16, 1976
    Date of Patent: August 30, 1977
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Takeo Koitabashi, Hideo Akamatsu, Noboru Fujimori
  • Patent number: 4042400
    Abstract: A light-sensitive silver halide photographic material spectrally sensitized with at least one compound of the formula ##STR1## and at least one compound of the formula ##STR2## wherein Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 are individually a non-metal atom grouping necessary to complete an unsubstituted or alkyl-, alkoxyl-, phenyl-, hydroxyl-, carboxyl- or halogen-substituted benzene ring, or a non-metal atom grouping necessary to complete a naphthalene ring; Z is a sulfur or selenium atom; n.sub.1, n.sub.2, n.sub.3 and n.sub.4 are individually 2, 3 or 4; M.sub.1 and M.sub.2 are individually a hydrogen atom, an alkali metal atom or H-Q where Q is an organic base.
    Type: Grant
    Filed: January 12, 1976
    Date of Patent: August 16, 1977
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shigeji Baba, Bunji Okubo, Eiichi Sakamoto
  • Patent number: 4040839
    Abstract: A silver halide photographic emulsion containing at least one sensitizing dye of the following general formula (I) and at least one sensitizing dye of general formulae (II) and/or (III), in an amount effective to achieve supersensitization: ##STR1## wherein V.sup.1 and V.sup.2, which may be the same or different, each represents a hydrogen atom, halogen atom, trifluoromethyl, cyano, carboxy, alkoxycarbonyl, aminosulfonyl or alkylsulfonyl; W.sup.1 and W.sup.2, which may be the same or different, each represents a hydrogen atom, halogen atom, alkyl, alkoxy, hydroxy, acyloxy or phenyl; R.sup.1 represents alkyl or substituted alkyl; R.sup.2 and R.sup.3, which may be the same or different, each represents alkyl or substituted alkyl, and at least one of R.sup.2 and R.sup.3 represents 1 or 0; substituted alkyl containing a carboxy or sulfo radical; R.sup.4 and R.sup.5, which may be the same or different, each has the same meanings as R.sup.1 ; X.sup.- represents an acid anion; and m represents ##STR2## wherein V.
    Type: Grant
    Filed: May 19, 1976
    Date of Patent: August 9, 1977
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junichi Matsuyama, Masanao Hinata, Akira Sato
  • Patent number: 4040825
    Abstract: The present invention relates to light-sensitive photographic material with a light-sensitive heavy metal compound, e.g. a silver halide, and a spectral sensitizer. The spectral sensitizer is a compound in which the radicals of a sensitizing dyestuff are covalently bonded to amino, imino, hydroxyl, mercapto, carboxylic acid or carboxylic acid amide groups of a natural hydrophilic colloid, preferably gelatin.The invention also relates to new sensitizing dyes which are dinuclear cyanine dyes or merocyanine dyes which have attached either to a heterocyclic nucleus of the dye or to its methine chain a group which is reactive with a hydrophilic colloid.
    Type: Grant
    Filed: March 11, 1976
    Date of Patent: August 9, 1977
    Assignee: Ciba-Geigy AG
    Inventors: Rolf Steiger, Jean-Francois Reber, Aaron David Ezekiel, Geoffrey Ernest Ficken
  • Patent number: 4039335
    Abstract: A silver halide photographic emulsion spectrally sensitized with a combination of sensitizing dyes consisting essentially of at least one sensitizing dye represented by the following general formula [I] and at least one sensitizing dye represented by the following general formula [II] in supersensitizing amounts: ##STR1## wherein R.sup.1 and R.sup.2 each is an alkyl group, R.sup.3 is an alkyl group, X.sub.1 is an acidic anion, m is 1 or 2, and m is 1 when the dye forms an intramolecular salt (betaine-like structure). ##STR2## WHEREIN Z.sup.1 is a sulfur atom or a selenium atom, Z.sup.2 is an atomic group necessary to form a benzothiazole ring, a benzoselenazole ring, a naphtho[1,2-d]thiazole ring or a naphtho[1,2-d]selenazole ring, R.sup.4 and R.sup.5 is an alkyl group, R.sup.6 is an alkyl group, a phenyl group, an aralkyl group, a furyl group or a thienyl group, X.sub.2 is an acidic anion, n is 1 or 2, and n is 1 when the dye forms an intramolecular salt (betaine-like structure).
    Type: Grant
    Filed: October 29, 1976
    Date of Patent: August 2, 1977
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto, Jun Hayashi
  • Patent number: 4028115
    Abstract: A spectrally sensitized silver halide photographic emulsion containing, in combination, four carbocyanine sensitizing dyes.
    Type: Grant
    Filed: August 26, 1976
    Date of Patent: June 7, 1977
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto, Jun Hayashi
  • Patent number: 4026707
    Abstract: Silver halide supersensitized with a mixture of naphthoxazole and benzoxazole carbocyanine dyes.
    Type: Grant
    Filed: August 12, 1976
    Date of Patent: May 31, 1977
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Tadahiko Obikawa, Shigemasa Itoh
  • Patent number: 4018610
    Abstract: A spectrally sensitized silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least one sensitizing dye represented by the following general formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 each represents an atomic group necessary for completing a benzimidazole nucleus, an oxazole nucleus, a benzoxazole nucleus, a naphthoxazole nucleus, a thiazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a selenazole nucleus, a benzoselenazole nucleus or a naphthoselenazole nucleus excepting that both of Z.sup.1 and Z.sup.2 do not simultaneously represent an atomic group necessary for completing an oxazole nucleus, a benzoxazole nucleus or a naphthoxazole nucleus; R.sup.1 and R.sup.2 each represents an aliphatic group which may be substituted and the carbon chain of which may be interrupted with an oxygen atom or a sulfur atom; R.sup.0 represents a hydrogen atom, an alkyl group or an aralkyl group; X.sub.(1).sup.
    Type: Grant
    Filed: July 28, 1975
    Date of Patent: April 19, 1977
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
  • Patent number: 4010037
    Abstract: A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least one sensitizing dye of the following general formula (I) ##STR1## wherein Z.sub.1 and Z.sub.2 each represents an atomic group required for forming a benzimidazole ring; R.sub.1 and R.sub.2 each represents an aliphatic group and at least one of R.sub.1 and R.sub.2 represents an alkyl group having a carboxy group, a hydroxyalkyl group or an alkyl group having a sulfo group; X.sub.1 represents an acid anion; and m is 1 or 2, m being 1 when the dye forms an inner salt (a betaine-like structure) and at least one sensitizing dye of the following general formula (II) ##STR2## wherein Z.sub.3 represents an atomic group required for forming a benzoxazole ring or a .beta.-naphthoxazole ring; Z.sub.4 represents an atomic group required for forming a benzothiazole ring, a benzoselenazole ring, a .beta.-naphthothiazole ring or a .beta.-naphthoselenazole ring; R.sub.3 and R.sub.
    Type: Grant
    Filed: January 28, 1976
    Date of Patent: March 1, 1977
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Tadashi Ikeda, Mitsuo Iwamoto
  • Patent number: 4005437
    Abstract: Recording media comprising a mixture of 4,4'-bis(3-diazo-3,4-dihydro-4-oxo-1-naphthalenesulfonyloxy)benzil and an alkali soluble resin are suitable for recording information with electron beams. These recording media have high sensitivity, high resolving power and can be reproducibly formulated.
    Type: Grant
    Filed: April 18, 1975
    Date of Patent: January 25, 1977
    Assignee: RCA Corporation
    Inventors: Daniel Louis Ross, Lucian Anthony Barton
  • Patent number: 3988155
    Abstract: A silver halide photographic emulsion containing, in supersensitizing amounts, at least one sensitizing dye represented by the following general formula (I) ##EQU1## wherein Z.sub.11 represents the atoms necessary to complete a pyridine nucleus or a quinoline nucleus; Z.sub.12 represents the atoms necessary to complete an oxazole nucleus, a benzoxazole nucleus, a naphthoxazole nucleus, an imidazole nucleus, a benzimidazole nucleus or a naphthoimidazole nucleus; and R.sub.11 and R.sub.12 each represents an aliphatic group with at least one of R.sub.11 and R.sub.12 having a carboxy or sulfo group; and at least one sensitizing dye represented by the following general formula (II) ##EQU2## wherein Z.sub.21 and Z.sub.22, which can be the same or different, each represents the atoms necessary to complete a thiazole nucleus, a benzothiazole nucleus, a selenazole nucleus or a benzoselenazole nucleus; and R.sub.21 and R.sub.22 each represents an aliphatic group with at least one of R.sub.21 and R.sub.
    Type: Grant
    Filed: September 4, 1975
    Date of Patent: October 26, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
  • Patent number: 3986878
    Abstract: A silver halide photographic emulsion containing, in supersensitizing amounts, at least one sensitizing dye represented by the following general formula (I) ##EQU1## wherein Z.sub.11 represents the atoms necessary to complete a thiazole nucleus, a selenazole nucleus, a benzothiazole nucleus, a benzoselenazole nucleus, a naphthothiazole nucleus or a naphthoselenazole nucleus; Z.sub.12 represents the atoms necessary to complete a naphthothiazole nucleus, or a naphthoselenazole nucleus; and R.sub.11 and R.sub.12 each represents an aliphatic group with at least one of R.sub.11 and R.sub.12 having a carboxy or sulfo group; and at least one sensitizing dye represented by the following general formula (II) ##EQU2## wherein Z.sub.21 represents the atoms necessary to complete a thiazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a selenazole nucleus, a benzoselenazole nucleus or a naphthoselenazole nucleus; Z.sub.
    Type: Grant
    Filed: September 4, 1975
    Date of Patent: October 19, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
  • Patent number: 3985563
    Abstract: A silver halide photographic emulsion containing, in supersensitizing amounts, at least one sensitizing dye represented by the following General Formula (I): ##EQU1## in which Z.sub.11 represents an atomic group necessary for completing a pyridine or quinoline nucleus; Z.sub.12 represents an atomic group necessary for completing an oxazole, benzoxazole, naphthoxazole, imidazole, benzimidazole or naphthimidazole nucleus; and R.sub.11 and R.sub.12 each represents an aliphatic group and at least one of R.sub.11 and R.sub.12 is an aliphatic group containing a carboxy group or a sulfo group; and at least one sensitizing dye represented by the following General Formula (II): ##EQU2## in which Z.sub.21 represents an atomic group necessary for completing a thiazole, benzothiazole, naphthothiazole, selenazole, benzoselenazole or naphthoselenazole nucleus; Z.sub.22 represents an atomic group necessary for completing an imidazole, benzimidazole or naphthimidazole nucleus; an R.sub.21 and R.sub.
    Type: Grant
    Filed: September 9, 1975
    Date of Patent: October 12, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
  • Patent number: 3977883
    Abstract: A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least one sensitizing dye of the following general formula (I) ##EQU1## WHEREIN Z.sub.1 and Z.sub.2 each represents an atomic group required to form a quinoline ring; R.sub.1 and R.sub.2 each represents an aliphatic group, with at least one of R.sub.1 and R.sub.2 being a hydroxyalkyl group, an alkyl group containing a carboxyl group or an alkyl group containing a sulfo group; X.sub.1 is an acid anion; and m is 1 or 2, and when m is 1 the dye forms an intramolecular salt and at least one sensitizing dye of the following general formula (II) ##EQU2## WHEREIN Z.sub.3 represents an atomic group required to form a benzimidazole ring, a benzoxazole ring or a .beta.-naphthoxazole ring; Z.sub.4 represents an atomic group required to form a benzothiazole ring, a benzoselenazole ring, a .beta.-naphthothiazole ring or a .beta.-naphthoselenazole ring; R.sub.3 and R.sub.
    Type: Grant
    Filed: December 6, 1974
    Date of Patent: August 31, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto
  • Patent number: 3977882
    Abstract: A silver halide photographic emulsion which is spectrally sensitized so that it has a maximum sensitivity wave length within the region of 580-640 nm, characterized by containing in a super sensitizing amount the combination of at least one carbocyanine dye represented by the general formula (I) and at least one of the dyes selected from the group consisting of dyes represented by the general formula (II): ##EQU1## WHEREIN Z.sub.1 represents the grouping necessary for the formation of .beta.-naphthothiazole or .beta.-naphthoselenazole ring, Z.sub.2 represents the grouping necessary for the formation of benzoxazole ring, A.sub.1 represents a hydrogen atom, an alkyl radical or an aryl radical, R.sub.1 represents an alkyl group and R.sub.2 represents a hydroxyalkyl group, a carboxyalkyl group or an alkyl group substituted with a sulfo group, X.sub.1 represents an acid anion group, an l is 1 or 2, the dye forming an intramolecular salt when l is 1: ##EQU2## WHEREIN Z.sub.3 and Z.sub.
    Type: Grant
    Filed: July 17, 1975
    Date of Patent: August 31, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Akira Sato
  • Patent number: 3976492
    Abstract: A silver halide photographic emulsion containing at least one sensitizing dye represented by the formula (I) ##EQU1## wherein Z.sub.1 represents a group of atoms necessary to complete a thiazole nucleus, a benzothiazole nucleus, a benzoselenazole nucleus, a naphthothiazole nucleus or a naphthoselenazole nucleus; Z.sub.2 represents a group of atoms necessary to complete a naphthothiazole nucleus or a naphthoselenazole nucleus; and R.sub.1 and R.sub.2, which may be the same or different, each represents an aliphatic group and at least one of R.sub.1 and R.sub.2 is an aliphatic group containing a carboxyl group or a sulfo group; and at least one sensitizing dye represented by the formula (II) ##EQU2## wherein Z.sub.3 and Z.sub.4 which may be the same or different, each represents a group of atoms necessary to complete a thiazole nucleus, a benzothiazole nucleus or a benzoselenazole nucleus; and R.sub.3 and R.sub.4, which may be the same or different, each represents an aliphatic group and at least one of R.sub.
    Type: Grant
    Filed: July 25, 1975
    Date of Patent: August 24, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Tadashi Ikeda
  • Patent number: 3975199
    Abstract: A silver halide photographic emulsion having improved sensitivity and comprising an emulsion containing photosensitive silver halide crystals and a solid basic metal oxide selected from the group consisting of magnesium oxide, calcium oxide and a compound oxide of zinc and aluminum.
    Type: Grant
    Filed: December 18, 1974
    Date of Patent: August 17, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hiroshi Yamashita, Yutaka Sakasai
  • Patent number: 3973969
    Abstract: Silver halide photographic emulsions are supersensitized by a combination of at least one sensitizing dye represent by following general formula (I): ##EQU1## And at least one sensitizing dye represented by following general formula (II): ##SPC1##Specific moieties given in the above formulae are identified in the specification.
    Type: Grant
    Filed: May 2, 1975
    Date of Patent: August 10, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Masanao Hinata, Hirotetu Kato, Akiro Sato, Akira Ogawa
  • Patent number: 3969116
    Abstract: A silver halide photographic sensitive element for flash exposure having at least a photographic silver halide emulsion layer which is characterized by containing at least a sensitizing dye having a reduction potential in a range of -0.7 volts - -1.7 volts and at least a sensitizing dye having a reduction potential in a range of -0.7 volts - -1.7 volts and an oxidation potential of larger than a value which is approximately 0.5 volts smaller than the oxidation potential of said sensitizing dye or at least a substantially colorless compound having an oxidation potential of larger than a value which is approximately 0.5 volts smaller than the oxidation potential of said sensitizing dye as the combination having a supersensitization function.
    Type: Grant
    Filed: November 18, 1974
    Date of Patent: July 13, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Seiiti Kubodera
  • Patent number: 3967967
    Abstract: A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least two carbocyanine dyes having structures hereinafter defined.
    Type: Grant
    Filed: December 6, 1974
    Date of Patent: July 6, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Atsuo Iwamoto
  • Patent number: 3966477
    Abstract: A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at last two carbocyanine sensitizing dyes as hereinafter defined.
    Type: Grant
    Filed: December 6, 1974
    Date of Patent: June 29, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Tadashi Ikeda, Akira Ogawa, Akira Sato, Atsuo Iwamoto
  • Patent number: 3955979
    Abstract: A silver halide photographic light-sensitive element suitable for exposure to light for a period of time of less than (preferably) 0.0001 second comprising a support bearing thereon at least one layer of a silver halide photographic emulsion, the silver halide photographic emulsion containing at least one sensitizing dye represented by the following General Formula (I) in combination with at least one sensitizing dye represented by the following General Formula (II): ##SPC1##wherein R.sub.1 and R.sub.2 each represents an alkyl group, at least one of R.sub.1 and R.sub.2 being an alkyl group having a sulfo substituent; ##SPC2##Wherein R.sub.B represents a methyl group or an ethyl group, R.sub.3 and R.sub.4 have the same meaning as R.sub.1 and R.sub.2, at least one of R.sub.3 and R.sub.4 being an alkyl group having a sulfo substituent.
    Type: Grant
    Filed: March 24, 1975
    Date of Patent: May 11, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Masanao Hinata, Hirotetu Kato
  • Patent number: 3953215
    Abstract: A silver halide photographic emulsion containing in a supersensitizing amount the combination of at least one sensitizing dye represented by the general formula (I) ##SPC1##wherein, A.sub.1, A.sub.2, A.sub.3 and A.sub.4 each represents a member selected from the group consisting of a hydrogen atom, a lower alkyl group, an alkoxy group, a halogen atom, a hydroxyl group, an aryl group, a carboxyl group, an alkoxycarbonyl group, a cyano group, a trifluoromethyl group, an amino group, an acylamide group, an acyloxyl group, an alkoxycarbonylamino group, and a carbalkoxy group; and A.sub.1 and A.sub.2 and A.sub.3 and A.sub.4 can combine to form a naphthoxazole nucleus; R.sub.o represents a hydrogen atom, a lower alkyl group or an aryl group; R.sub.1 and R.sub.2 each represents an alkyl group, provided that at least one of R.sub.1 or R.sub.2 represents a sulfoalkyl group; X.sub.
    Type: Grant
    Filed: July 16, 1974
    Date of Patent: April 27, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masanao Hinata, Haruo Takei, Akira Sato, Masao Takano, Nobuaki Miyasaka
  • Patent number: 3947275
    Abstract: A sensitized gelatino-silver halide emulsion comprising a supersensitizing combination of at least one sensitizing dye represented by general formula I: ##SPC1##wherein R.sub.1, R.sub.2 and R.sub.3 are each a member selected from the group consisting of an alkyl having up to 6 carbon atoms and a substituted alkyl group having up to 6 carbon atoms, at least one of R.sub.1, R.sub.2 and R.sub.3 being a substituted alkyl group having a sulfo group therein; R.sub.4 is a hydrogen atom or forms an alkylene linkage together with R.sub.2 ; Z.sub.1 is an atomic group necessary for completing a benzimidazole nucleus; A.sub.1 and A.sub.2 are each a member selected from the group consisting of a hydrogen atom, a phenyl group, a halogen atom, a carboxyl group, an alkoxy carbonyl group, an alkyl group, an alkoxyl group, a hydroxyl group, a trifluoromethyl group, and a cyano group, A.sub.2 being capable of condensing with A.sub.1 or A.sub.3 to form a benzene nucleus; and A.sub.
    Type: Grant
    Filed: November 21, 1973
    Date of Patent: March 30, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Akira Sato, Akira Ogawa
  • Patent number: 3933510
    Abstract: A silver halide photographic emulsion which contains in combination a supersensitizing amount of at least one pseudocyanine sensitizing dye and at least one oxacarbocyanine sensitizing dye.
    Type: Grant
    Filed: September 4, 1973
    Date of Patent: January 20, 1976
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keisuke Shiba, Haruo Takei, Akira Sato, Tadashi Ikeda
  • Patent number: 3932186
    Abstract: Improved green-sensitivity is imparted to a photosensitive silver halide emulsion by a benzimidazolothiacarbocyanine dye of the formula: ##SPC1##Wherein R.sup.1 and R.sup.2 are lower alkyl; R.sup.3 is sulfoalkyl or carboxyalkyl each having an alkylene chain of from 1 to 4 carbon atoms inclusive; R.sup.4 is hydrogen, halogen, lower alkyl, lower carbalkoxy, lower alkoxy or acetamido; R.sup.5 is halogen, cyano or carbalkoxy; R.sup.6 is hydrogen or halogen; Y is an anion customary in the cyanine dye art; and n is 0 or 1.
    Type: Grant
    Filed: January 2, 1974
    Date of Patent: January 13, 1976
    Assignee: Polaroid Corporation
    Inventors: Alan L. Borror, Ruth Linda Hill, Bernard Zuckerman
  • Patent number: RE35099
    Abstract: An improved apparatus for fractionating fluid mixtures by pressure swing molecular adsorption employing a rotary distributor valve and an array of adsorber columns. The columns are contained within a product holding tank. The valve sequences to provide a quasi steady-state flow, allowing optimization of adsorption/desorption cycles, and eliminating most of the valves, switches and plumbing usually required.
    Type: Grant
    Filed: October 1, 1993
    Date of Patent: November 28, 1995
    Assignee: SeQual Technologies, Inc.
    Inventor: Charles C. Hill