Zigzag Arrangement Of Flat Solid Sorbent Beds For Parallel Flow Patents (Class 96/129)
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Patent number: 11524257Abstract: A media design for modular use in an air cleaning or HVAC systems to removes gas phase contaminants. The design allows for a control of gas contaminant removal using variable media length, path length, and contact time to ensure a contained MTZ length and low pressure drop. In one embodiment, the design includes a filter module at an angle to an airflow and an air filter mounted within the filter frame. The filter module may include channels therethrough that are oriented at the optimum angle in relation to the airflow to provide the required dwell time and pressure drop for a given application.Type: GrantFiled: July 18, 2018Date of Patent: December 13, 2022Assignee: Environmental Management Confederation, Inc.Inventors: Forwood C. Wiser, III, Caitlin Naske
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Patent number: 11129914Abstract: An ethylene oxide adsorption recovery system includes a tower body defining a gas channel extending longitudinally therein. A sidewall of the tower body further comprises a plurality of mounting holes disposed longitudinally along the side wall and in communication with the gas channel. A bottom portion of the tower body includes a first pipe in communication with the gas channel, and a top portion of the tower body includes a second pipe in communication with the gas channel. A plurality of adsorption panels is coupled to the tower body through corresponding respective mounting holes of the plurality of mounting holes, each of the plurality of adsorption panels extends into the gas channel. A sealing door is movably coupled to the sidewall of the tower body and configured to selectively fix each of the plurality of adsorption panels to a respective mounting hole of the plurality of mounting hole.Type: GrantFiled: August 25, 2020Date of Patent: September 28, 2021Assignees: Chio Kang Medical, Inc., Qiaokang Biotech (Guangdong) Co., LTD.Inventors: Dongxin Hou, Jianlong Xue, Shengwei Hu, Weiguo Wang, Yecheng He, Qinghua Xiao, Ziping Zhu, Lixiong Feng
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Patent number: 11071939Abstract: A sorbent cartridge retention frame configured for use in an air scrubbing system comprising a first inlet side, a second outlet side, a plurality of compartments each configured to hold a solid-sorbent material, a plurality of respective walls arranged to form and separate the plurality of compartments, a first permeable membrane arranged to cover the first inlet side, a second permeable membrane arranged to cover the second outlet side. The first and/or second permeable membrane are configured for affixation to respective ends of the walls through a process of melting and solidification of the wall material such that wall material bonds with the membrane material.Type: GrantFiled: August 9, 2017Date of Patent: July 27, 2021Assignee: enVerid Systems, Inc.Inventors: Udi Meirav, Sharon Perl-Olshvang
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Patent number: 10967083Abstract: An ethylene oxide adsorption recovery system includes a tower body defining a gas channel extending longitudinally therein. A sidewall of the tower body further comprises a plurality of mounting holes disposed longitudinally along the side wall and in communication with the gas channel. A bottom portion of the tower body includes a first pipe in communication with the gas channel, and a top portion of the tower body includes a second pipe in communication with the gas channel. A plurality of adsorption panels is coupled to the tower body through corresponding respective mounting holes of the plurality of mounting holes, each of the plurality of adsorption panels extends into the gas channel. A sealing door is movably coupled to the sidewall of the tower body and configured to selectively fix each of the plurality of adsorption panels to a respective mounting hole of the plurality of mounting hole.Type: GrantFiled: August 25, 2020Date of Patent: April 6, 2021Assignees: Chio Kang Medical, Inc., Qiaokang Biotech (Guangdong) Co., LTD.Inventors: Dongxin Hou, Jianlong Xue, Shengwei Hu, Weiguo Wang, Yecheng He, Qinghua Xiao, Ziping Zhu, Lixiong Feng
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Patent number: 10767606Abstract: A tubular air cleaner for an internal combustion engine includes a tubular housing, which includes a circumferential wall including an inlet, a top wall including an outlet, and a bottom wall opposed to the top wall, and a tubular filter element, which includes a tubular filter portion and is accommodated in the housing. A frame is arranged at an inner side of the filter portion to maintain shape of the filter portion. A planar adsorbent filter, which adsorbs evaporated fuel of the internal combustion engine, extends in an axial direction of the filter portion and is fixed to the frame. The inner surface of the filter portion is spaced apart from each of opposite planes of the adsorbent filter by a gap that allows air to reach the outlet without passing through the adsorbent filter.Type: GrantFiled: November 21, 2017Date of Patent: September 8, 2020Assignee: TOYOTA BOSHOKU KABUSHIKI KAISHAInventor: Hiroaki Morikawa
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Patent number: 10753320Abstract: A tubular air cleaner for an internal combustion engine includes a tubular housing, a tubular filter element, and a planar adsorbent filter. The tubular housing includes a circumferential wall including an inlet, a top wall including an outlet, and a bottom wall opposed to the top wall. The tubular filter element is accommodated in the housing. The planar adsorbent filter is located at an inner side of the filter element to adsorb evaporated fuel of the internal combustion engine. The adsorbent filter extends in an axial direction of the filter element. The filter element includes an inner surface spaced apart from each of opposite planes of the adsorbent filter by a gap that allows air to reach the outlet without passing through the adsorbent filter.Type: GrantFiled: November 21, 2017Date of Patent: August 25, 2020Assignee: TOYOTA BOSHOKU KABUSHIKI KAISHAInventor: Hiroaki Morikawa
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Patent number: 10753319Abstract: A tubular air cleaner for an internal combustion engine includes a housing and a filter element. The housing includes a case and a cap coupled to the case in a removable manner. The cap includes a cap body and an adsorbent filter assembly. The adsorbent filter assembly includes a planar adsorbent filter, which adsorbs evaporated fuel of the internal combustion engine, and a fixing portion. The adsorbent filter is located at an inner side of the filter element and extends in an axial direction of the filter element. The inner surface of the filter element is spaced apart from each of opposite planes of the adsorbent filter by a gap that allows air to reach an outlet without passing through the adsorbent filter.Type: GrantFiled: November 21, 2017Date of Patent: August 25, 2020Assignee: TOYOTA BOSHOKU KABUSHIKI KAISHAInventor: Hiroaki Morikawa
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Patent number: 10589211Abstract: A cylindrical air cleaner for an internal combustion engine includes a cylindrical housing including a circumferential wall having an inlet, a top wall having an outlet, and a bottom wall opposed to the top wall. There is a tubular filter element accommodated in the housing. A planar adsorbent filter to adsorb evaporated fuel of the internal combustion engine is located at an inner side of the filter element and extends in an axial direction of the filter element. The adsorbent filter includes a basal end portion fixed to an inner surface of the bottom wall. An inner surface of the filter element is spaced apart from each of opposite planes of the adsorbent filter by a gap that allows air to reach the outlet without passing through the adsorbent filter.Type: GrantFiled: November 2, 2017Date of Patent: March 17, 2020Assignee: TOYOTA BOSHOKU KABUSHIKI KAISHAInventor: Hiroaki Morikawa
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Patent number: 9629938Abstract: The invention relates to an exhaust gas filter device for filtering contaminants out of exhaust gases, comprising: a filtering apparatus for filtering the exhaust gases, wherein the exhaust gases enter the filtering apparatus at a filter inlet surface, flow through the filtering apparatus and exit the filtering apparatus at a filter outlet surface; and a distribution channel for distributing the exhaust gases to be filtered along the filter inlet surface, and a collection channel for collecting the filtered exhaust gases exiting at the filter outlet surface; wherein the cross section of the collection channel increases in the direction of flow of the exhaust gases and/or the cross section of the distribution channel decreases in the direction of flow of the exhaust gases.Type: GrantFiled: July 26, 2013Date of Patent: April 25, 2017Assignee: TZ Technisches Zentrum Entwicklungs- und Handelsgesellschaft mbHInventors: Wigand Fitzner, Klaus Döge
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Patent number: 9011583Abstract: An article comprising a plurality of intersecting walls having outer surfaces that define a plurality of cells extending from one end to a second end, wherein the walls forming each cell in a first subset of cells are covered by a barrier layer to form a plurality of heat exchange flow channels, and wherein the walls forming each cell in a second subset of cells different from the first subset of cells, comprise a CO2 sorbent and form reaction flow channels. Heat exchange flow channels allow quick and uniform heating and cooling of the sorbent body. The article may be useful, for example, for removing CO2 from a gas stream.Type: GrantFiled: April 29, 2011Date of Patent: April 21, 2015Assignee: Corning IncorporatedInventors: Amit Halder, Dayue David Jiang, Weiguo Miao, Steven Bolaji Ogunwumi, Zhen Song
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Patent number: 8979985Abstract: A conformal filter is disclosed having a plurality of sorbent beds oriented perpendicular to an inner side surface of the filter which conforms to an adjacent surface, such as a wearer's face when attached to a respirator. The inner side of the filter may approximate the curved shape of an interfacing surface. Because the sorbent beds are oriented perpendicular to the inner side surface, a conformal configuration can be achieved without bending the sorbent beds and while keeping constant bed residence time throughout the entire cross-sectional area of the air flow, thus enforcing even air distribution. Reduced bed depth is also achieved through this configuration which consequently reduces the overall pressure drop through the filter. Other embodiments are described and claimed.Type: GrantFiled: July 18, 2013Date of Patent: March 17, 2015Assignee: Scott Technologies, Inc.Inventors: Frank Ding, Edward Powers Simmonds, Michael Lee Parham
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Publication number: 20130298774Abstract: A conformal filter is disclosed having a plurality of sorbent beds oriented perpendicular to an inner side surface of the filter which conforms to an adjacent surface, such as a wearer's face when attached to a respirator. The inner side of the filter may approximate the curved shape of an interfacing surface. Because the sorbent beds are oriented perpendicular to the inner side surface, a conformal configuration can be achieved without bending the sorbent beds and while keeping constant bed residence time throughout the entire cross-sectional area of the air flow, thus enforcing even air distribution. Reduced bed depth is also achieved through this configuration which consequently reduces the overall pressure drop through the filter. Other embodiments are described and claimed.Type: ApplicationFiled: July 18, 2013Publication date: November 14, 2013Inventors: Frank Ding, Edward Powers Simmonds, Michael Lee Parham
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Publication number: 20120132071Abstract: An air purification system comprises a chamber having an air inlet and an air outlet, a plurality of flexible wires hanging from a ceiling of the chamber, a spray mechanism configured to spray droplets in the chamber, and a sound wave generator configured to generate a standing sound wave in the chamber. During operation of the air purification system, the plurality of flexible wires are elastically deformed by the standing sound wave generated by the sound wave generator such that portions of the plurality of flexible wires converge at nodes of the sound wave, and also the droplets move to the nodes of the standing sound wave, while trapping particles in the air during the movement to the nodes. The droplets collide against and are adsorbed to the plurality of flexible wires at the nodes of the sound wave.Type: ApplicationFiled: November 26, 2010Publication date: May 31, 2012Applicant: Empire Technology Development LLCInventor: Takahisa Kusuura
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Patent number: 7645324Abstract: Improved adsorbent sheet based parallel passage adsorbent structures for enhancing the kinetic selectivity of certain kinetic-controlled adsorption processes, such as PSA, TSA and PPSA processes, and combinations thereof, are provided. The enhancements in kinetic selectivity made possible through the implementation of the present inventive improved adsorbent structures may unexpectedly enable significant intensification of selected kinetic adsorption processes relative to attainable performance with conventional adsorbent materials in beaded or extruded form. Such process intensification enabled by the present inventive adsorbent structures may provide for increased adsorption cycle frequencies, and increased gas flow velocities within the adsorbent beds, which may increase the productivity and/or recovery of a kinetic adsorption system incorporating the inventive adsorbent structures.Type: GrantFiled: January 6, 2006Date of Patent: January 12, 2010Assignee: Xebec Adsorption Inc.Inventors: Edward J. Rode, Andre J. J. Boulet, Aaron M. Pelman, Matthew L. Babicki, Bowie G. Keefer, James A. Sawada, Soheil Alizadeh-Khiavi, Surajit Roy, Andrea C. Gibbs, Steven M. Kuznicki
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Patent number: 7588629Abstract: A filter cassette having opposing rectangular side panels with at least one pair of filter media containers there between wherein each filter media container has a pair of opposing rectangular end plates and a pair of opposing rectangular media screens, each pair of containers are in a “V” configuration with adjacent end plates having a unitary configuration and at least one media fill aperture for each media container on a non-sealing side of the filter cassette, outermost end plates on a sealing side of the filter cassettes extend between corners of opposing side panels forming a substantially smooth sealing surface, and a fill cap is attached to each unitary pair of end plates having media fill apertures enclosing the media fill apertures.Type: GrantFiled: January 20, 2006Date of Patent: September 15, 2009Assignee: AAF-McQuay Inc.Inventors: Mike Osborne, Keiron O'Connell, Husheder P. Daruwalla, Joachim Horst Wenzek, Ng Cheah Wei
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Patent number: 7585346Abstract: A media holding module to hold various granular and pelletized gas phase filtration media for filtering air. The module is comprised of two solid side plates, and a perforated end panel and four perforated wall panels disposed between the side plates. The perforated wall panels are arranged in a generally “V”-shaped configuration. The interior wall panels are contoured at the module inlet to provide aerodynamic airflow. Additionally, the interior wall panels are perforated across their entire surface areas to allow for airflow access to all filtration media in the filtration media beds. The compartment created by the wall panels may be subdivided to form sub-compartments capable of holding discrete beds of filtration media in series. The module's support members are located outside of the air stream to avoid airflow resistance and turbulence. The module further includes a flexible, reversible sealing system for sealing the module in the module housing in various configurations while preventing air bypass.Type: GrantFiled: July 13, 2006Date of Patent: September 8, 2009Inventors: Jeffrey L. Roseberry, Robert A. Darling
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Patent number: 7470311Abstract: A dehumidification unit comprised of alternate laminations of an adsorption element which supports an adsorbent and which is provided with a first air ventilation passage and a cooling element, which is provided with a second air ventilation passage. The first air ventilation passage of the adsorption element and the second air ventilation passage of the cooling element are adjacently formed, with a single plate member lying between the first and second air ventilation passages. As a result of such arrangement, as compared with a structure formed with two plate members lying therebetween second air ventilation passages, the performance of heat transfer between the air ventilation passages is further improved, whereby the dehumidification capability of the dehumidification unit is maintained at high levels over a long period of time.Type: GrantFiled: July 22, 2002Date of Patent: December 30, 2008Assignee: Daikin Industries, Ltd.Inventors: Takahisa Sueoka, Guannan Xi, Akira Kamino
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Patent number: 7364608Abstract: The chemical filter supporting an ion-exchange resin comprising a fiber supporting body containing ion-exchange fiber and ion-exchange resin powder which is supported on the fiber supporting body is provided. The chemical filter possesses a large ion-exchange capacity per unit volume and exhibits high initial performance of eliminating ionized gaseous pollutants and excellent durability of the elimination performance.Type: GrantFiled: January 11, 2005Date of Patent: April 29, 2008Assignee: Nichias CorporationInventors: Takashi Tanahashi, Toshiro Nakano, Akihiro Imai
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Patent number: 7090474Abstract: A diaphragm pump which overcomes the problem of diaphragm failure due to overfill of the oil transfer chamber. An overfill preventive element in the form of a mechanical stop, a fully closed coil spring, or a valve system, or alternatives are provided.Type: GrantFiled: May 16, 2003Date of Patent: August 15, 2006Assignee: Wanner Engineering, Inc.Inventors: Kenneth Eugene Lehrke, Richard D. Hembree
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Publication number: 20030159586Abstract: An adsorption bed arrangement includes a plurality of adsorption elements, a housing, and a gasket member. Each of the adsorption elements has a first adsorptive media and a second adsorptive media contained within a respective element. The first and second adsorptive medias remove different contaminants from the incoming air stream. For example, the first adsorptive media removes acidic contaminants and the second adsorptive media removes basic contaminants. Each of the adsorption elements is selectively openable to provide access to the adsorptive medias. The housing defines an interior, a plurality of inlet openings, and a plurality of outlet openings. The adsorption elements are positioned within the housing interior and the housing is selectively openable to provide access to the adsorption elements. The gasket member is between the housing and the adsorption elements.Type: ApplicationFiled: March 13, 2003Publication date: August 28, 2003Applicant: Donaldson Company, Inc.Inventors: Kevin J. Seguin, Paul Peterson, Kristine M. Graham
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Patent number: 6533847Abstract: An adsorption bed arrangement includes a plurality of adsorption elements, a housing, and a gasket member. Each of the adsorption elements has a first adsorptive media and a second adsorptive media contained within a respective element. The first and second adsorptive medias remove different contaminants from the incoming air stream. For example, the first adsorptive media removes acidic contaminants and the second adsorptive media removes basic contaminants. Each of the adsorption elements is selectively openable to provide access to the adsorptive medias. The housing defines an interior, a plurality of inlet openings, and a plurality of outlet openings. The adsorption elements are positioned within the housing interior and the housing is selectively openable to provide access to the adsorption elements. The gasket member is between the housing and the adsorption elements.Type: GrantFiled: February 13, 2001Date of Patent: March 18, 2003Assignee: Donaldson Company, Inc.Inventors: Kevin J. Seguin, Paul Peterson, Kristine M. Graham
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Patent number: 6197097Abstract: A filter for cleaning air by removing noxious and/or odorous matter from the air flow by desorption is constructed so that filter sections (12) can be sequentially heated for a desorption of the noxious and odorous matter. An air discharge (13) for desorption air is provided on the air exit side (11) of the filter (2) for the discharge of the desorbed noxious and odorous matter, preferably into the combustion air of an engine. The air discharge (13, 22) for the desorption air covers at least one filter section 12 at a time when that section is being heated. A relative motion between the filter sections (12) and the air discharge (13) assures that other filter sections keep filtering while at least one filter section at a time is regenerated.Type: GrantFiled: May 27, 1999Date of Patent: March 6, 2001Assignee: DaimlerChrysler AGInventors: Harald Ertl, Johann Goebel, Sabine Kunz
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Patent number: 6156089Abstract: A system for circulating air which includes particles, bacterial organisms, and odoriferous material includes a fan coupled to ducting of the air circulation system for causing movement of air in a stream through the ducting; a filter holder configured to hold an air filtering device supported within the air stream; and an air filtering device for removing from the circulating air the particles, bacterial organisms, and odoriferous material. The air filtering device may include multiple filter elements having multiple layers of differing filtering materials, which may include activated carbon and potassium permanganate.Type: GrantFiled: August 5, 1998Date of Patent: December 5, 2000Assignee: Air Kontrol, Inc.Inventors: Michael J. Stemmer, Edward C. Sofsky
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Patent number: 6113674Abstract: An adsorption bed arrangement includes a plurality of adsorption elements, a housing, and a gasket member. Each of the adsorption elements has adsorption media contained within a respective element. Each of the adsorption elements are selectively openable to provide access to the adsorption media. The housing defines an interior, a plurality of inlet openings, and a plurality of outlet openings. The plurality of adsorption elements are positioned within the housing interior. The housing is selectively openable to provide access to the plurality of adsorption elements. The gasket member is between the housing and the adsorption elements. A method for changing filtering media in an adsorption apparatus includes steps of removing an access panel from an adsorption bed housing to expose a cover member covering an end of an adsorption element; removing the cover member from the end of the adsorption element to expose filtering media within the element; and pouring the filtering media from the element.Type: GrantFiled: January 15, 1998Date of Patent: September 5, 2000Assignee: Donaldson Company, Inc.Inventors: Kristine M. Graham, Paul Peterson, Donald R. Monson, Jarren B. Mills, Timothy H. Grafe
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Patent number: 5964927Abstract: An adsorption apparatus has a housing including an inlet and an outlet, and defining an inlet plenum extending vertically below the inlet and an outlet plenum extending vertically below the outlet. A plurality of adsorption bed assemblies in a vertically stacked configuration are retained in the housing in fluid communication with the inlet plenum. Each of the adsorption bed assemblies has a bottom opening and a top opening and layers of adsorption material with the assembly oriented in a V-type configuration. A plurality of baffles angle upward from the inlet plenum to the outlet plenum, including a baffle disposed between each pair of adjacent stacked adsorption bed assemblies, to direct flow up toward the bottom opening of the adsorption bed assembly immediately above the baffle and to direct flow passing from the top opening of the adsorption bed assembly immediately below the baffle.Type: GrantFiled: July 11, 1997Date of Patent: October 12, 1999Assignee: Donaldson Company, Inc.Inventors: Kristine M. Graham, Paul Peterson, Donald R. Monson, Jarren B. Mills, Timothy H. Grafe
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Patent number: 5772738Abstract: A multifunctional air filter module includes a filter case having an air introduction side opening and an air discharge side opening and a pleated fabric air filter element containing an activated carbon. The periphery of the pleated filter element is fixed in the filter case without clearance therebetween. At least one fabric filter element composed of a fabric including an activated carbon having a strong base, KMnO.sub.4 or ZnCl.sub.2, a fabric of a cation exchange fiber or a fabric of an anion exchange fiber, is simply placed in air introduction side grooves formed by pleats of the fixed air filter element, and is replaceable and can be regenerated. The air filter module is compact and can reduce the volume of a space occupied thereby in a semiconductor plant. Flexibility of installation thus is provided and the range of the use thereof is widened. Multifunctionality is increased easily merely by addition of replaceable filter element fabrics.Type: GrantFiled: May 30, 1996Date of Patent: June 30, 1998Assignees: Purex Co., Ltd., Kabushiki Kaisha ToshibaInventor: Hisashi Muraoka
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Patent number: 5595910Abstract: A biofilter for the removal of contaminants from gas streams disclosed. The biofilter makes use of a series of modular trays, each containing a gas-contacting medium for removing at least one contaminant from the process stream. The trays have a modular design that allows them to be sealingly stacked and to be configured to allow series, parallel or series-parallel flow through the biofilter.Type: GrantFiled: December 10, 1993Date of Patent: January 21, 1997Assignee: Rotron IncorporatedInventors: Wayne D. Kant, Bruce Singleton
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Patent number: 5464468Abstract: A rotary adsorption/desorption gas treating apparatus includes a rotary drum rotatable along a rotation axis and having a plurality of gas passage compartments arranged in a peripheral direction of the drum. The apparatus further includes an adsorbing element cassette mounted inside each of the gas passage compartments and including a gas-permeable adsorbing mat. The rotational range of the rotary drum is divided between an adsorption zone and a desorption zone. In the adsorption zone, a treatment subject gas is allowed to pass the gas passage compartments in the direction along the rotation axis of the rotary drum. In the desorption zone, a refreshing gas is allowed to pass the gas passage compartments in the direction along the rotation axis of the rotary drum. The adsorbing mat, when mounted in the compartment, includes a portion thereof oriented normal or inclined relative to a side end face of the rotary drum.Type: GrantFiled: December 6, 1993Date of Patent: November 7, 1995Assignee: Taikisha Ltd.Inventors: Shinpei Tanaka, Hirofumi Morimoto
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Patent number: 5290345Abstract: The present invention pertains to a refillable gas adsorption bed assembly having a box-like, generally rectangular frame The frame has a pair of oppositely disposed side members and a pair of oppositely disposed end members. There is a first and a second rectangular fine mesh screen mounted within the frame on opposite sides of a filler opening through one of the side members. The first and second prefilters are mounted within the frame. The first prefilter is disposed to one side of both screens and the second prefilter is disposed on the opposite side of both screens. The invention includes a housing for the gas adsorption bed assembly and a counterflow adsorber module formed by operably connecting the housings end-to-end.Type: GrantFiled: January 13, 1993Date of Patent: March 1, 1994Assignee: Donaldson Company, Inc.Inventors: Richard J. Osendorf, Paul C. Peterson, Donald R. Monson
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Patent number: 4110116Abstract: New cyanine dyes derived from di-halogen-benzoxazoles and benzothiazoles are desensitizers for silver halide negative emulsions and useful electron acceptor spectral sensitizers for direct positive silver halide emulsions.Type: GrantFiled: March 16, 1977Date of Patent: August 29, 1978Assignee: Minnesota Mining and Manufacturing CompanyInventors: Paolo Beretta, Luigi Valbusa
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Patent number: 4040825Abstract: The present invention relates to light-sensitive photographic material with a light-sensitive heavy metal compound, e.g. a silver halide, and a spectral sensitizer. The spectral sensitizer is a compound in which the radicals of a sensitizing dyestuff are covalently bonded to amino, imino, hydroxyl, mercapto, carboxylic acid or carboxylic acid amide groups of a natural hydrophilic colloid, preferably gelatin.The invention also relates to new sensitizing dyes which are dinuclear cyanine dyes or merocyanine dyes which have attached either to a heterocyclic nucleus of the dye or to its methine chain a group which is reactive with a hydrophilic colloid.Type: GrantFiled: March 11, 1976Date of Patent: August 9, 1977Assignee: Ciba-Geigy AGInventors: Rolf Steiger, Jean-Francois Reber, Aaron David Ezekiel, Geoffrey Ernest Ficken
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Patent number: 4025347Abstract: New cyanine dyes, comprising at least one of the following nuclei (or derivatives thereof):1. 2,3,3-trimethyl-5-phenyl-sulfonyl-indolenine;2. 2,3,3-trimethyl-5-benzoyl-indolenine;3. 1-aryl or alkyl-2-phenyl-5-phenyl-sulfonyl-indole;4. 1-aryl or alkyl-2-phenyl-5-benzoyl-indole,Are desensitizers for silver halide negative emulsions and useful electron acceptor spectral sensitizers for direct positive silver halide emulsions.Type: GrantFiled: June 12, 1974Date of Patent: May 24, 1977Assignee: Minnesota Mining and Manufacturing CompanyInventors: Paolo Beretta, Luigi Valbusa
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Patent number: 4025349Abstract: Novel methyne dyes comprising two auxochromic groups of the type used in a cyanine or merocyanine dye linked by a carbon atom chain wherein each of the carbon atoms have an unsaturated linkage to at least one adjacent carbon atom in the chain and at least one pair of carbon atoms in the chain being joined by a triple bond or, in an alternate resonance form, the chain including three consecutive carbon to carbon double bonds. The dyes are useful as spectral sensitizing dyes for silver halide emulsions and as intermediates for synthesizing chain-substituted methine dyes.Type: GrantFiled: March 5, 1975Date of Patent: May 24, 1977Assignee: Eastman Kodak CompanyInventor: John David Mee
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Patent number: 4006025Abstract: Colloidally stable dispersions of a spectral sensitizing dye are formed directly in water without the use of an organic solvent. The process of the invention involves mixing the dye particles with water to form a slurry and then homogenizing or milling the slurry at an elevated temperature in the presence of a surfactant to form finely divided particles uniformly dispersed in the water.Type: GrantFiled: June 6, 1975Date of Patent: February 1, 1977Assignee: Polaroid CorporationInventors: Thomas F. Swank, Richard Waack
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Patent number: 4003750Abstract: Methine dyes comprising first and second nuclei joined by a double bond or a methine linkage. The first nuclei may be eitherA. a pyrido nucleus joined at the 4- or 6-carbon atom thereof to said double bond or methine linkage or,B. a 5,6-dihydropyrido nucleus joined at the 4- or 5-carbon atom to said double bond or methine linkage.The pyrido or dihydropyrido nucleus can have fused to its 1,2-side the atoms required to complete a ring containing 5 or 6 atoms. The second nuclei may be either the same as (a) or (b) or can be of the type typically used in cyanine styryl and merocyanine dyes. Such dyes are useful filter dyes and spectral sensitizers for silver halide compositions. Also described are intermediates useful in the synthesis of said dyes.Type: GrantFiled: May 3, 1973Date of Patent: January 18, 1977Assignee: Eastman Kodak CompanyInventors: Donald W. Heseltine, Donald W. Kurtz, Derek D. Chapman, James K. Elwood
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Patent number: 3980481Abstract: Direct-positive silver halide emulsions comprising fogged silver halide grains and an electron acceptor are described wherein the emulsion is spectrally sensitized by means of 2-aryl-indolocarbocyanines. The combination of electron acceptors and these spectral sensitizers provides super-sensitizing effects that are not impaired by the presence of color couplers.Type: GrantFiled: January 11, 1974Date of Patent: September 14, 1976Assignee: AFGA-GEVAERT N.V.Inventors: Theofiel Hubert Ghys, Willy Joseph Vanassche, Herman Alberik Pattyn
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Patent number: 3974147Abstract: Dihydroheterocyclic amines having a N-hydrocarbyl substitution and a 2-(or 4-) (omega-(nuclearly substituted cyclic)) vinylenyl substitution are described. There compounds are oxidized in an acidic environment to produce styryl dyes.Type: GrantFiled: June 25, 1975Date of Patent: August 10, 1976Assignee: Minnesota Mining and Manufacturing CompanyInventors: George V. D. Tiers, Joseph A. Wiese, Jr.
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Patent number: 3955996Abstract: A method for spectrally sensitizing a photographic light-sensitive emulsion, which comprises dissolving a photographic spectrally sensitizing dye having an amidinium ion auxochrome in an organic solvent containing a substantially water-free acid having a pKa not exceeding about 5, and adding this dye-containing acid-organic solvent solution to a light-sensitive emulsion.Type: GrantFiled: November 15, 1974Date of Patent: May 11, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Masanao Hinata, Masanaga Ohki, Haruo Takei, Yuji Mihara
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Patent number: 3945832Abstract: A direct positive silver halide photographic emulsion containing1. at least one dimethine dye having the general formula (I): ##EQU1## 2. AT LEAST ONE COMPOUND HAVING THE GENERAL FORMULA (II): ##SPC1##3. at least one compound having the general formula (III) ##EQU2## or the general formula (IV) ##SPC2##wherein Y, Y.sub.o, Z, L.sub.1, L.sub.2, R.sub.o, m, n, X, Z.sub.1, R.sub.1, X.sub.1, a, p, q, Y.sub.1, Y.sub.2, m.sub.1, R.sub.3, r, X.sub.2 and X.sub.3 are as hereinafter defined.Type: GrantFiled: March 27, 1974Date of Patent: March 23, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Masanao Hinata, Reiichi Ohi, Tadao Shishido
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Patent number: 3933505Abstract: A silver halide photographic emulsion for direct positives, containing a fluorene compound having at least one nitro group as a substituent.Type: GrantFiled: December 18, 1973Date of Patent: January 20, 1976Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Masanao Hinato, Reiichi Ohi
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Patent number: 3933507Abstract: Heat developable light-sensitive photographic material having a layer which contains a light-sensitive combination of a silver compound substantially insensitive to light, a reducing agent for that silver compound and a polymethine sensitizer. The exposed material is heated so that the silver compound in the exposed areas is reduced and a visible silver image is formed.Type: GrantFiled: August 10, 1972Date of Patent: January 20, 1976Assignee: AGFA-Gevaert, A.G.Inventors: Anita VON Konig, Helmut Kampfer, Eric Maria Brinckmann, Frans Clement Heugebaert