Abstract: The present invention relates to a separator membrane having a hierarchical structure, a production method therefor and a xylene separation method using same, and to: a separator membrane having a hierarchical structure comprising mesopores, the separator membrane having mesopores introduced inside a microporous zeolite separator membrane, thereby being thin, having less defects and exhibiting high xylene permeation and separation performance; a production method therefor; and a xylene separation method using same.

Abstract: A poly(amide-imide) is provided. The poly(amide-imide) is represented by formula (1), wherein R is a C6 aryl group, a C7-C8 aralkyl group, a C2-C6 alkoxyalkyl group, or a C3-C18 alkyl group; and 0.02?X?0.5.

Abstract: A filler for resinous composition is contained and used in resinous composition, and includes: a crystalline siliceous particulate material with a crystal structure made of at least one member selected from the group consisting of type FAU, type FER, type LTA and type MFI, and/or type MWW; and a surface treatment agent including an organic silica compound reacted with or adhered to a surface of the crystalline siliceous particulate material; the filler including the surface treatment agent in an amount falling in a range allowing the filler to exhibit a negative thermal expansion coefficient.

Abstract: Provided is a gas separation membrane that can be used continuously. The gas separation membrane comprises: a porous support membrane that contains an aromatic polyamide in which an aromatic ring has been replaced with a chloro group; and a separation functional layer that is disposed on the surface of the porous support membrane and contains a cross-linked polyamide obtained by polycondensation of a polyfunctional amine and a polyfunctional acid halide.

Abstract: The invention relates to an apparatus having a pressure chamber and a micropump in fluid connection with the pressure chamber. The pressure chamber includes a gas-carrying region and a liquid-carrying region. The micropump is configured to generate a pneumatic pressure within the gas-carrying region that is lower than a fluid pressure of a liquid flowing through the liquid-carrying region. According to the invention, a gas-permeable and liquid-impermeable separating element separates, at least in sections, the gas-carrying region and the liquid-carrying region. According to the present invention, the micropump is disposed on the pressure chamber.

Abstract: Hydrophobic poly(4-methyl-1-pentene) hollow fiber membrane for retention of anesthetic agents with an inner and an outer surface and between inner and outer surface an essentially isotropic support layer with a sponge-like, open-pored, microporous structure free of macrovoids and adjacent to this support layer on the outer surface a dense separation layer with a thickness between 1.0 and 3.5 ?m. The membrane has a porosity in the range of greater than 35% to less than 50% by volume and a permeance for CO2 of 20-60 mol/(h·m2·bar), a gas separation factor ?(CO2/N2) of at least 5 and a selectivity CO2/anesthetic agents of at least 150. The process for producing this membrane is based on a thermally induced phase separation process in which process a homogeneous solution of a poly(4-methyl-1-pentene) in a solvent system containing components A and B is formed, wherein component A is a strong solvent and component B a weak non-solvent for the polymer component.

Abstract: A method for drying a fluid film, which is applied to a surface of a substrate and includes a vaporizable liquid, includes following steps: transporting the substrate on a transport surface of a transport device along a transport direction through a drying device; vaporizing the liquid by way of a heat source having a heating surface, wherein the heating surface is disposed at a distance of 0.1 mm to 5.0 mm opposite to a surface of the substrate; and removing a vaporized liquid in a direction of the heat source.

Abstract: A polymeric compound including a cross-linked backbone which is a product of a reaction between a multifunctional acrylate compound and a metal porphyrin derivative, wherein the metal porphyrin derivative has a first axial position and a second axial position, and further includes a basic coordination ligand coordinated at the first axial position of the metal porphyrin derivative.

Abstract: A polyimide polymer having hydroxyl and acetoxy function groups is provided together with a membrane made from the polymer. Also provided is a process for separating at least one gas from a mixture of gases using a polyimide membrane comprising a polyimide polymer with hydroxyl and acetoxy functional the process comprising: (a) providing the polyimide membrane comprising the polyimide polymer with hydroxyl and acetoxy functional groups which is permeable to the at least one gas; (b) contacting the mixture on one side of the polyimide membrane to cause said at least one gas to permeate the membrane; and (c) removing from the opposite side of the membrane a permeate gas composition comprising a portion of said at least one gas which permeated the polyimide membrane.

Abstract: Several embodiments of the invention relate to devices for the removal of dimethyl sulfoxide (DMSO) or related compounds, or odors associated with DMSO or DMSO-related compounds. Several embodiments relate to methods of using the same. In several embodiments the devices include adsorbents, odor adsorbing fabrics, masks, clean air members and clean air supply assemblies.

Abstract: [Problem] Diamine and carboxylic dianhydride for polymerizing a hexafluoroisopropylidene group-containing polyimide are limited in chemical structure when developed into a polyimide membrane, so that it is difficult to design a chemical structure with consideration paid to the strength and separation performance of a gas separation membrane. A gas separation membrane easily soluble in an organic solvent, excellent in formability so as to be readily usable for a gas separation membrane, and excellent in gas separation performance is obtained. [Solution] A gas separation membrane, including: a polyimide that contains a repeating unit represented by general formula (1). [In the formula (1), R1 is a divalent organic group and R2 is a tetravalent organic group, R1 containing a 2-hydroxy-1,1,1,3,3,3-hexafluoroisopropyl group (—C(CF3)2OH)].

Abstract: A gas separation membrane having a polyimide structure.

Abstract: A gas separation membrane having a polyimide structure. The polyimide structure is provided to contain a repeating unit represented by general formula (1): (In the formula, R1 is a divalent organic group and R2 is a tetravalent organic group), wherein R1 is a divalent organic group represented by general formula (2): (In the formula, Raa is a single bond, an oxygen atom, a sulfur atom, —SO2— group, —CH2— group, —C(?O)— group, —C(CH3)2— group, —C(CH3)(CH2CH3)— group, —C(CF3)2— group or a divalent organic group formed by removing any two hydrogen atoms from a C3-C12 alicyclic hydrocarbon or C6-C25 aromatic hydrocarbon. Rab is a C1-C6 alkyl group. “ac” and “ad” mutually independently represent an integer of 0 to 2 such that 1?ac+ad?4. HFIP represents a —C(CF3)2OH group. A straight line that intersects with a wiggly line represents a bonding moiety).

Abstract: Gas separation membrane compositions including at least one crosslinked polymer, gas separation membranes made of such compositions, methods for making such gas separation membranes, and methods of using such membranes to separate gases are described. In one embodiment, the crosslinked polymer includes polyarylene ethers (PAE).

Abstract: Disclosed are mixed matrix polymeric membranes comprising a plurality of metal-organic frameworks (MOFs), or in some aspects a zeolitic imidazolate frameworks (ZIFs), and a polymeric matrix, wherein the plurality of MOFs are attached to the polymeric matrix through covalent or hydrogen bonds or Van der Waals interaction.

Abstract: An air filter assembly includes a felt of hollow specialty polymer fibers having nonporous walls.

Abstract: The invention relates to a specific apparatus, more particularly a chain of gas separation membrane modules, for separation of gas mixtures into two fractions each of elevated purity.

Abstract: This invention relates to self-cross-linkable and self-cross-linked aromatic polyimide polymers, their membranes and methods for making and using these polymers and membranes. The self-cross-linkable aromatic polyimide polymer described in the present invention comprises both hydroxyl functional groups and carboxylic acid functional groups. The self-cross-linked aromatic polyimide was formed via heating the self-cross-linkable aromatic polyimide polymer at ?300° C. The self-cross-linked aromatic polyimide membranes exhibit high selectivity in separation of mixtures of gases and liquids.

Abstract: The present disclosure relates to a gas separation membrane for filtration of carbon dioxide and a preparation method thereof. The gas separation membrane for filtration of carbon dioxide according to the present disclosure exhibits superior performance in rejecting carbon dioxide selectively from mixture gas. It is a separation membrane system leaving carbon dioxide and passing nitrogen, unlike the conventional systems which leave nitrogen and pass carbon dioxide. In addition, since compressed, highly-concentrated carbon dioxide can be obtained, the consumption of energy required for carbon dioxide storage following separation can be reduced. Furthermore, the separation membrane of the present disclosure, which is environment-friendly and consumes less energy, allows highly efficient separation and is easily applicable to the separation of carbon dioxide not only from the mixture of carbon dioxide with nitrogen but also from other mixtures of carbon dioxide with, for example, CO2/CH4, CO2/H2, etc.

Abstract: A novel gas separation membrane having excellent gas permeability and gas separation performance, particularly carbon dioxide (CO2) permeability and excellent separation performance of carbon dioxide to methane (CH4) is provided. Moreover, a novel gas separation membrane having excellent heat resistance, chemical resistance and strength etc. is preferably provided. A gas separation membrane comprising a resin comprising a branched polybenzoxazole has excellent gas permeability and gas separation performance, particularly excellent carbon dioxide (CO2) permeability and excellent separation performance of carbon dioxide to methane (CH4). The resin comprising a branched polybenzoxazole preferably has a cross-linked structure. Furthermore, the resin comprising a branched polybenzoxazole is preferably a hybrid with silica.

Abstract: Provided is a crosslinked thermally rearranged poly(benzoxazole-co-imide) obtained through the transesterification crosslinking of an ortho-hydroxy polyimide copolymer and a diol compound, followed by thermal rearrangement, a gas separation membrane (excluding a membrane for flue gas separation), and a method for preparing the same. The crosslinked thermally rearranged poly(benzoxazole-co-imide) according to the present invention allows less packing of polymer chains and has a structure with a larger space, and thus shows increased possibility of permeation and diffusion of small molecules therethrough.

Abstract: Provided is a method for preparing a membrane for flue gas separation including a crosslinked thermally rearranged poly(benzoxazole-co-imide) through the transesterification crosslinking of an ortho-hydroxy polyimide copolymer and a diol compound, followed by thermal rearrangement. The membrane for flue gas separation including the crosslinked thermally rearranged poly(benzoxazole-co-imide) has excellent gas permeability and selectivity, and particularly provides gas separation quality corresponding to a level exceeding the so-called 2008 upper bound in terms of carbon dioxide/methane separation.

Abstract: The present invention generally relates to high permeability, UV cross-linkable copolyimide polymers and membranes for gas, vapor, and liquid separations, as well as methods for making and using these membranes. The invention provides a process for separating at least one gas from a mixture of gases using the high permeability copolyimide membrane or the UV cross-linked copolyimide membrane, the process comprising: (a) providing a high permeability copolyimide membrane or a UV cross-linked copolyimide membrane which is permeable to said at least one gas; (b) contacting the mixture on one side of the high permeability copolyimide membrane or the UV cross-linked copolyimide membrane to cause said at least one gas to permeate the membrane; and (c) removing from the opposite side of the membrane a permeate gas composition comprising a portion of said at least one gas which permeated said membrane.

Abstract: Disclosed herein are a polyimide-polybenzoxazole copolymer, a method for preparing thereof and a gas separation membrane comprising the same. More specifically, provided are a polyimide-polybenzoxazole copolymer simply prepared through thermal-rearrangement performed by thermally treating a polyimide-poly (hydroxyimide) copolymer as a precursor, a method for preparing the same, and a gas separation membrane comprising the same. The copolymer shows superior gas permeability and gas selectivity, thus being suitable for use in gas separation membranes in various forms such as films, fibers or hollow fibers. The gas separation membrane thus prepared can advantageously endure even harsh conditions such as long operation time acidic conditions and high humidity due to the rigid polymer backbone present in the copolymer.

Abstract: A polymer of formula (I): where: n is an integer from 10 to 5,000; m is an integer from 10 to 5,000; Ar1 and Ar3 are the same or different and are residues derived from a tetra-hydroxy aromatic monomer, the tetra-hydroxy aromatic monomer being wherein R is the same or different and is H or a C1-C8 alkyl, C2-C8 alkenyl or C3-C8 cycloalkyl group; and, Ar2 and Ar4 are the same or different and are residues derived from a tetra-halogenated aromatic monomer, the tetra-halogenated aromatic monomer being wherein X is F, Cl or Br, and R1 and R2 are the same or different and are wherein y is an integer from 1 to 8; with the proviso that when Ar1 is the same as Ar3 and Ar2 is the same as Ar4, R1 and R2 are not both —CN is useful as a material for gas separation, vapor separation, adsorbents or catalysis.

Abstract: The present invention discloses a new type of high selectivity UV-cross-linked tetrazole group functionalized polymer nanosieve (TZPIM) membranes, their preparation, as well as their use for gas and liquid separations. The UV-cross-linked TZPIM membrane showed more than 50% improvement in CO2/CH4 selectivity and more than 30% improvement in CO2/N2 selectivity compared to the uncross-linked TZPIM membrane for CO2/CH4 and CO2/N2 separations, respectively.

Abstract: The present invention relates to a gas separation membrane comprising as a main component a polyacetal, wherein the polyacetal contains 1.5 to 10 mol of an oxyalkylene unit based on 100 mol of an oxymethylene unit. The gas separation membrane of the present invention has high carbon dioxide gas separating ability and high permeability rate to carbon dioxide gas and is advantageously used as a separation membrane for carbon dioxide gas contained in exhaust gas.

Abstract: Provided are cardo copolybenzimidazoles, a gas separation membrane using the same and a method for preparing the same. More particularly, provided are cardo copolybenzimidazoles obtained by introducing cardo groups and aromatic ether groups to a polybenzimidazole backbone, a gas separation membrane having significantly improved oxygen permeability by using the same, and a method for preparing the same. The cardo copolybenzimidazoles have improved solubility as compared to the polybenzimidazole polymers according to the related art, show excellent mechanical properties while maintaining thermal stability so as to be formed into a film shape, and provide a gas separation membrane having significantly improved gas permeability, particularly, oxygen permeability.

Abstract: A gas separation membrane, containing: a support; and a separating layer formed on the support, the separating layer containing a resin; the separating layer containing, at the side thereof opposite to the support, a hydrophilic modification treatment surface, the hydrophilic modification treatment surface involved in a layer having a film thickness of 0.1 ?m or less, and the hydrophilic modification treatment surface provided with a surface contact angle measured by using water thereon in the range of 60 degrees or less.

Abstract: [Problem] Diamine and carboxylic dianhydride for polymerizing a hexafluoroisopropylidene group-containing polyimide are limited in chemical structure when developed into a polyimide membrane, so that it is difficult to design a chemical structure with consideration paid to the strength and separation performance of a gas separation membrane. A gas separation membrane easily soluble in an organic solvent, excellent in formability so as to be readily usable for a gas separation membrane, and excellent in gas separation performance is obtained. [Solution] A gas separation membrane, including: a polyimide that contains a repeating unit represented by general formula (1). [In the formula (1), R1 is a divalent organic group and R2 is a tetravalent organic group, R1 containing a 2-hydroxy-1,1,1,3,3,3-hexafluoroisopropyl group (—C(CF3)2OH).

Abstract: A gas separation membrane comprises aromatic polyimide polymers that comprise a plurality of repeating units of formula (I) wherein X1 and Ar are herein defined.

Abstract: The invention describes a polymeric material comprising repeating units of Formulae I-III and methods of preparation. Novel polymeric materials, gas separation membranes and fluid component separation methods are also described.

Abstract: An apparatus for removing water vapor from a feed gas is provided that comprises a membrane housing, a membrane that divides a first pressure side and a second pressure side of the membrane housing, a feed gas inlet and outlet on the first pressure side, a sweep gas inlet and outlet on the second pressure side, a sweep gas flow regulator, and a pump. In some embodiments the feed gas can be at ambient pressure and a pressure drop across the membrane can be less than about 1 atm. In some embodiments the sweep gas can be a portion of the feed gas exiting the first pressure side. Some embodiments are part of air conditioning, drying, or water recovery systems. Additionally, some embodiments achieve dew points of less than 0° C. and dehumidification efficiencies of 200% to 600%.

Abstract: A gas separation membrane having a polyimide structure.

Abstract: A gas separation membrane having a polyimide structure. The polyimide structure is provided to contain a repeating unit represented by general formula (1): (In the formula, R1 is a divalent organic group and R2 is a tetravalent organic group), wherein R1 is a divalent organic group represented by general formula (2): (In the formula, Raa is a single bond, an oxygen atom, a sulfur atom, —SO2— group, —CH2— group, —C(?O)— group, —C(CH3)2— group, —C(CH3)(CH2CH3)— group, —C(CF3)2— group or a divalent organic group formed by removing any two hydrogen atoms from a C3-C12 alicyclic hydrocarbon or C6-C25 aromatic hydrocarbon. Rab is a C1-C6 alkyl group. “ac” and “ad” mutually independently represent an integer of 0 to 2 such that 1?ac+ad?4. HFIP represents a —C(CF3)2OH group. A straight line that intersects with a wiggly line represents a bonding moiety).

Abstract: Disclosed herein is a method for preparing a crosslinked hollow fiber membrane. The method involves spinning a one phase solution comprising a monoesterified polyimide polymer, acetone as a volatile solvent, a spinning solvent, a spinning non-solvent, and optionally an organic and/or inorganic additive, wherein the volatile solvent is present in an amount of greater than 25 wt. % to about 50 wt. %, based on the total weight of the solution.

Abstract: A gas separation membrane is provided which has both excellent gas permeability and gas separation characteristics, particularly permeability of carbon dioxide (CO2) and separation characteristics of carbon dioxide and methane (CH4), at such a high level that has not hitherto been achieved. The gas separation membrane was obtained by heat treating a membrane composed of a hyperbranched polyimide-based material in a non-oxidizing atmosphere.

Abstract: The invention describes a polymeric material comprising repeating units of Formulae I-III and methods of preparation. Novel polymeric materials, gas separation membranes and fluid component separation methods are also described.

Abstract: A gas separation membrane comprises aromatic polyimide polymers that comprise a plurality of repeating units of formula (I) wherein X1 and Ar are herein defined.

Abstract: A composition includes a first polymer having monomers each containing an imidazole group, and a second polymer, the first and second polymers being a polymer blend. The first polymer, the second polymer, or both may be cross-linked. The carbonized composition, polymeric and carbon membranes (either in the form of a flat sheet or a hollow fiber) made from the composition are also described. The polymeric and carbon membranes can be used to separate and purify gases or liquids.

Abstract: Nanocomposite adsorbent materials and methods for their preparation and use are described. As an example, a polyaniline-graphite nanoplatelet nanocomposite may be used to adsorb carbon dioxide.

Abstract: Disclosed are methods of obtaining carbon dioxide from a CO2-containing gas mixture. The methods combine the benefits of gas membrane separation with cryogenic temperatures.

Abstract: The present invention relates to a method for treating molecular sieve particles for use in a mixed matrix membrane useful in, for example, gas separations. Membranes employing treated molecular sieve particles may exhibit enhanced permeabilities and selectivities in regard to, for example, the separation of carbon dioxide and methane.

Abstract: The invention provides a porous nanoscale membrane. In one embodiment, the membrane can be used as a filtration device to screen agents that disrupt or prevent molecular interactions. In one embodiment, the membrane allows for screening agents that disrupt or prevent molecular interactions using a small sample volume with efficient high-throughput screening applications.

Abstract: A membrane for a method for filtration of gas effluents from an industrial installation including a wall having an internal surface and an external surface, the wall having pores of variable dimensions in the radial direction and in the longitudinal direction of the wall.

Abstract: The present invention is for high permeance and high selectivity blend polymeric membranes comprising poly(ethylene glycol) (PEG) and a highly permeable polymer selected from the group consisting of polymers of intrinsic microporosity (PIMs), tetrazole-functionalized polymers of intrinsic microporosity (TZPIMs), or mixtures thereof. The present invention also involves the use of such membranes for separations of liquids and gases.

Abstract: The present invention discloses a new type of high selectivity UV-cross-linked tetrazole group functionalized polymer nanosieve (TZPIM) membranes, their preparation, as well as their use for gas and liquid separations. The UV-cross-linked TZPIM membrane showed more than 50% improvement in CO2/CH4 selectivity and more than 30% improvement in CO2/N2 selectivity compared to the uncross-linked TZPIM membrane for CO2/CH4 and CO2/N2 separations, respectively.

Abstract: The present invention relates to a radiation-resistant microporous membrane having a hydrophobicity gradient, to a method for the preparation thereof, and to the use of the membrane in the sterilizing filtration of gaseous fluids or as a liquid barrier in liquid-containing systems to be vented.

Abstract: Disclosed herein is a method for preparing a crosslinked hollow fiber membrane. The method involves spinning a one phase solution comprising a monoesterified polyimide polymer, acetone as a volatile solvent, a spinning solvent, a spinning non-solvent, and optionally an organic and/or inorganic additive, wherein the volatile solvent is present in an amount of greater than 25 wt. % to about 50 wt. %, based on the total weight of the solution.

Abstract: Switchable gas permeation membranes in which a photo-switchable low-molecular-weight liquid crystalline (LC) material acts as the active element, and a method of making such membranes. Different LC eutectic mixtures were doped with mesogenic azo dyes and infused into track-etched porous membranes with regular cylindrical pores. Photo-induced isothermal phase changes in the imbibed mesogenic material afforded large, reversible changes in the permeability of the photo-switchable membrane to nitrogen. For example, membranes imbibed with a photo-switchable cyanobiphenyl LC material demonstrated low permeability in the nematic state, while the photo-generated isotropic state demonstrated a 16×-greater sorption coefficient. Both states obey a high linear sorption behavior in accordance with Henry's Law. In contrast, membranes imbibed with a photo-switchable phenyl benzoate LC material showed the opposite permeability behavior to the biphenyl-imbibed membrane, along with nonlinear sorption behavior.