Abstract: A process is disclosed of forming a reversal dye image. This is accomplished by developing an imagewise exposed photographic element with a black-and-white developer and poisoning the developed silver as a redox amplification catalyst for a peroxide oxodizing agent. The undeveloped silver is then rendered developable to form a silver catalyst image pattern. This latter silver image pattern is then used to catalyze the redox reaction of a peroxide oxidizing agent and a dye-image-generating reducing agent, such as a color-developing agent, or a redox dye-releaser.
Abstract: A method is disclosed of forming a dye image through redox amplification using a peroxide oxidizing agent. This is accomplished by forming an immobile cobalt complex image and using this image to define a reversal immobile catalytic manganese complex image. The immobile catalytic manganese complex image is employed as a catalyst in a peroxide redox amplification step to form an image dye.
Abstract: A color photographic material comprising at least one light-sensitive silver halide emulsion layer having preferably a non-diffusing color coupler associated to it and at least one non-lightsensitive binder layer containing a colloidal silver dispersion provides less contact fog and a better color reproduction if the non-lightsensitive binder layer containing the colloidal silver dispersion contains also a soluble iodide, particularly sodium, potassium or ammonium iodide. Alternatively the soluble iodide may also be contained in a non-lightsensitive binder layer adjacent that binder layer which contains the silver dispersion.
Abstract: Reversal color images are produced in silver halide photographic elements which employ a leuco dye comprising the reaction product of a color-forming coupler and an N,N-dialkyl-p-phenylenediamine stabilized against aerial oxidation by an electronegative group attached to the benzene ring. A method is disclosed which comprises developing a silver image in imagewise exposed areas of the silver halide element. The residual silver halide in unexposed areas is then fogged and developed while concurrently oxidizing the leuco dye in these unexposed areas to form a dye image which is a reversal of the imagewise exposure. Developed silver is then removed from the element to leave a dye image without oxidizing the leuco dye in the imagewise exposed areas of the element.