Abstract: Light-sensitive compositions containing a quinone diazide which are useful in positive-working photoresists and positive-working lithographic printing plates are developed with a developing composition comprising methyltriethanol ammonium hydroxide. The developing composition provides the advantage that it is free of metal ions and, accordingly, does not contaminate the surface of the image. It is additionally advantageous in that it provides extended development latitude, increased exposure latitude, improved resist contrast, improved prebake latitude, a low depletion rate and minimal loss of image layer thickness.

Abstract: A photosensitive lithographic printing plate comprising a support having thereon a photosensitive layer composed of a photosensitive diazo-oxide resin containing a hydroxystyrene unit and a hydroxystyrene unit having an o-quinoediazide group bonded through the oxygen of the hydroxystyrene. The photosensitive layer can contain an alkali-soluble resin. The photosensitive lithographic printing plate is stable mechanically, provides a large difference in solubility between the exposed areas and the unexposed areas of the layer, and has improved printability and sensitivity.

Abstract: A photopolymerizable coating over a diazo resin provides a high-speed lithographic plate or photoresist while improving the printing life of the plate while making its development simpler than that of most other photopolymer plates. The photopolymer is a cinnamoylated polyvinyl alcohol resin which is placed over a diazo based material.

Abstract: Light sensitive, high molecular weight diazo polymers useful for the manufacture of color proofing guides are herein provided. The novel diazo polymers of the instant invention have the generic formula: ##STR1## Where R is methyl or hydrogen X is methoxy, ethoxy or hydrogenY is oxygen or sulfurZ is an anion of a sulfonic, carboxylic or phosphonic acidN is an integer from 8 to 970.

Abstract: Modifying the surface of a diazotype material by incorporating an acrylic or methacrylic polymer into the diazotype sensitizing coating composition or coating the assembly with it so as to roughen the surface of the material thereby enabling nitrogen, which is liberated when the material is exposed to light, to escape from between the master and the diazotype material to prevent nitrogen accumulating between the two and hence avoiding slippage of one relative to the other.

Abstract: A lithographic photographic material has a photosensitive layer comprising gelatin having an isoelectric point of at least 7 and a condensation product formed between a diazonium salt of a para-aminodipheynylamine derivative and an aldehyde. The photosensitive layer can be photoinsolubilized and will form a photo-relief.A method for using the lithographic photographic material comprises partially photoinsolubilizing the photosensitive layer and then immersing it in a bath of an acid or direct dye to form level dying, washing the dye material with water to remove unexposed areas, thereby forming an image composed of the dye photoinsolubilized resin layer corresponding to the exposed areas.

Abstract: A heat developable light-sensitive material comprising at least one layer containing a diazonium salt and a metal-.beta.-diketonate. If desired, these two essential components can be incorporated into different layers of the light-sensitive materials. The heat developable light-sensitive materials forms stable positive images upon exposure and heating.

Abstract: Diazotype material which after imagewise exposure can be developed by applying onto its sensitized surface between 1.5 and 4.5 cm.sup.3 per square meter of developing solution, consists of a paper support, the same side of which is coated successively with a sealing layer containing as a filmforming binder polyvinylacetate or a copolymer of styrene with butadiene and a light-sensitive layer having a dry weight of at most 8 g per square meter and comprising a diazonium compound, polyvinyl alcohol with a degree of hydrolysis over 75% and starch particles, whereby the weight ratio polyvinyl alcohol to starch particles is 1 : 5 to 20. The light-sensitive layer may also comprise an azo-coupling component.

Abstract: A heat developable light-sensitive material comprising a support with at least one layer thereon and containing at least (a) an organic silver salt, (b) light-sensitive silver halide or a silver halide-forming component and (c) a reducing agent with (d) an iron family compound in at least one layer on the support.

Abstract: An imaging system is provided wherein a blocked dye precursor is activated by an amine to an unblocked form which, in the presence of an inert cobalt (III) complex containing amine releasing ligands, undergoes a redox reaction to form a dye. The amine generated during the redox reaction causes further dye formation, giving increased speed.

Abstract: A photographic element which comprises a resin film or resin coated paper support having superimposed thereon a layer of a composition comprising a copolymer containing therein the moiety of the general formula (I) ##STR1## wherein R.sub.1 and R.sub.2 each is a hydrogen atom or an alkyl group having 1 to 12 carbon atoms.

Abstract: A method for increasing the ink-receptivity of a light-sensitive planographic printing plate comprising a support having thereon a light-sensitive layer comprising an o-quinonediazide based light-sensitive material which is rendered alkali solution-soluble by irradiation of active light and a condensate of an aldehyde and a substituted phenol represented by the formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each is a hydrogen atom, an alkyl group, or a halogen atom, and R.sub.3 is an alkyl group or a cycloalkyl group.

Abstract: A process for thermal development, which comprises irradiating with microwaves an imagewise exposed thermally developable recording material in thermal contact with a conductive layer or material having a surface electric resistance ranging from about 1 ohm/.quadrature. to about 10.sup.5 ohm/.quadrature., whereby the heat generated in the conductive layer or material develops the thermally developable recording material.

Abstract: A method of manufacturing a diazo copying material for use in preparing a secondary original, which comprises coating a water-dispersible precoating liquid comprising a porous powder, a binding agent and an anionic surface active agent having the following general formula on a transparent or translucent support and drying thereafter, and subsequently coating a photosensitive liquid consisting essentially of a photosensitive diazonium salt on the precoated surface of said support and drying thereafter.

Abstract: A method of producing a support for a printing plate comprising treating an aluminum plate, which has been oxidized by anodizing and then etched, with hot water or with water vapor.

Abstract: A structure for producing images, such as microform, comprises a layer of a water soluble high molecular weight condensation product of a nitrogen compound, which is capable of giving off nitrogen upon subjecting it to energy, to form an insoluble resinous product, and thereunder a layer of an image forming material which is not soluble in water.The imaging structure may also comprise as the image forming material a layer of a composition which contains from about 50 to 100 atomic percent, and preferably from about 80 to 100 atomic percent tellurium and extended thereover a layer of an energy sensitive material, which is capable of changing, upon subjecting it to energy, its solubility such that a latent image of soluble and insoluble areas is formed upon imagewise exposure.

Abstract: An improved light-sensitive negative-working diazo type film is described. The film includes a diazo-oxide sensitizer and an additive therefore which improves the actinic opacity of the image formed during the diazo process. The additive operates by reacting with the azo dye formed in the image areas. An example of such an additive is a sulfonic acid halide.

Abstract: A light-sensitive vesicular imaging composition is disclosed comprising a vesiculating agent which liberates gas upon exposure to activating radiation, a binder and a diol speed-increasing agent. The composition is coated as a thin film. Imagewise irradiation of the element causes gas to be released in the exposed areas. The composition, comprising gas entrapped in a thermoplastic matrix, can be heated to produce a visible record.

Abstract: An organic solvent- or water-developable photosensitive composition consisting essentially of a ring-opened polymer or copolymer of at least one norbornene derivative having at least one substituent selected from the group consisting of ester groups, nitrile groups, carboxyl groups, amide groups, imide groups, hydroxyl groups, halogens and carboxylic acid anhydride groups, or a ring-opened copolymer of at least one said norbornene derivative and at least one cycloolefin other than cyclohexene, or a hydrolysis product of said ring-opened polymer or copolymer and a photosensitive crosslinking agent or photosensitizer soluble in organic solvents or water. The above photosensitive composition is excellent in sensitivity, adhesion and stability.

Abstract: A positive light-sensitive composition containing: (a) a quinonediazide type, positive light-sensitive substance and (1) (b) at least one compound selected from the group consisting of those compounds represented by the following general formulae (I) ##STR1## wherein X.sub.1 and X.sub.2 each represents an oxygen atom or a sulfur atom; R.sub.1 and R.sub.2 each represents a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a cycloalkyl group; (2) those compounds represented by the general formula (II) ##STR2## wherein R.sub.3 represents a hydrogen atom, an alkyl group, an aralkyl group, an aryl group or a cycloalkyl group; and R.sub.4 represents a hydrogen atom, an alkyl group or a cycloalkyl group; and (3) o-benzoic acid sulfimide.

Abstract: A method for producing a water developable lithographic printing plate which comprises treating at least one surface of a metal sheet substrate with a layer of a lithographically suitable, light sensitive, water soluble substance and subsequently coating the thus treated base sheet with an upper layer of a water insoluble, ink receptive, lithographically suitable photosensitive composition. Said photosensitive layers must be either both positive working or both negative working. Upon imagewise exposure through a mask by standard methods the exposed areas of said upper photosensitive composition are alternatively characterized as either water permeable or water impermeable and the unexposed areas are alternatively water impermeable or water permeable as opposed to the exposed areas. Upon said imagewise exposure, the exposed lower level areas in a negative system are rendered water insoluble whereas the exposed lower level areas in a positive system are rendered more water soluble than the unexposed areas.

Abstract: There is disclosed a method of producing diazotype photoprinting material in which a base paper is withdrawn from a supply roll and transported through a precoating station in which a solution containing a silicon filler is applied to one side of the base paper; the paper is then transported from the precoating station past a plurality of heaters to a sensitizing station in which a solution containing a diazotype sensitizing compound is applied to one side of the base paper; the base paper is then transported past a second set of heaters to a transparentizing station in which a solution containing a water emulsion of a water clear synthetic organic resin is applied to the other side of the base paper simultaneously to render the base paper translucent and to decurl the paper; the paper is then transported past a third set of heaters to dry the paper to a moisture content of about 4% and finally is wound into a roll. A method of transparentizing any water absorbent natural fiber material is also disclosed.

Abstract: When a water-soluble alcohol having 4 to 6 hydroxyl groups is added to a photosensitive composition comprising a water-soluble polymer substance and a bisazide crosslinking agent, the polymer crosslinking reaction by said bisazide crosslinking agent is promoted and a polymer crosslinkage enough to form an image is produced even at a low exposure dose of ultraviolet ray. Thus, the photosensitive composition is highly sensitized as compared with prior art photosensitive compositions. The alcohol is exemplified by erythritol, pentitol, etc. and is preferably added in an amount of 1 - 100 parts by weight per 100 parts by weight of the water-soluble polymer substance.

Abstract: Copolymers of glycidyl acrylate and allyl glycidyl ether and terpolymers derived from addition of glycidyl methacrylate to the polymerizable mixture, having an inherent viscosity within the range of about 0.09 to 0.28 and an epoxy equivalent of at least about 0.64 per 100 g. of polymer are provided which upon admixture with a catalyst which is a radiation-sensitive aryldiazonium salt of a complex halogenide, provides compositions suitable for use in a dry photopolymer positive imaging process. In the process, the polymer which is non-tacky at room temperature, together with the catalyst is applied to a substrate and exposed to an energy source for example, electromagnetic radiation through a transparency or mask. Following exposure, the coating is heated to the softening point of the unexposed portion of the coating and a powder or toner is applied thereto, the toner being adhered to only the tacky, non-exposed area of the coating, resulting in a pigmented image.

Abstract: Film base material is provided which comprises a film of biaxially oriented synthetic linear polyester of highly hydrophobic character having superimposed thereon adherent to said film a subbing layer which contains a copolymer of vinylidene chloride, an alkyl acrylate or methacrylate, an allyl or methallyl component containing an active methylene group the monomer of which has the general formula ##STR1## wherein T is --CN or --COCH.sub.3, X is O, NH or S, and R is a hydrogen atom or methyl group and optionally at least one copolymerizable acid.The subbing layer improves the adhesion between the film support and the photographic emulsion layers and prevents the separation of the layers or frilling when the final photographic film is processed.

Abstract: A method for the amplification or intensification of dye images formed in a negative-working diazo system which comprises the steps of: (1) initially image-wise exposing a negative-working diazo layer to actinic radiation sufficient to convert a portion of the diazo compound contained therein to an active coupling constituent in the light-struck areas to form a first latent image, (2) developing the exposed diazo layer to effect coupling so as to form colored incipient images in the light-struck areas, (3) exposing the entire diazo layer from the same side as the initial image-wise exposure to actinic radiation of a greater amount than that used in the initial exposure, said amount of actinic radiation being sufficient to substantially photolyze the non-image areas while simultaneously creating second latent images beneath the already-developed areas, and (4) developing the exposed diazo layer again to effect coupling in said second latent image areas to form color therein and to amplify the initial colored i

Abstract: A light-sensitive layer transfer material and such layer disposed on a carrier, for use in screen-printing stencils, printed circuit boards, integrated circuits, intaglio printing plates, relief printing plates, proof prints and the like, which comprises an alkali-soluble phenolic resin, such as phenol-formaldehyde novolacs, an ester or an amide of an o-naphthoquinone-diazide sulphonic acid, such as the p-cumyl phenyl ester of 1,2-naphthoquinone-2-diazide-4-sulphonic acid, etc., and an acrylic resin, such as a polymer of an alkyl ester of acrylic acid or methacrylic acid.

Abstract: A light-sensitive vesicular imaging element and a method of manufacture are provided, comprising a vesiculating layer which includes a binder and vesiculating agent which liberates gas upon exposure to activating radiation, and an overcoat which contains a polymer soluble in a solvent in which the binder of the vesiculating layer is substantially insoluble. Upon imagewise irradiation of the element, gas bubbles are generated in the exposed areas. The bubbles may be developed to a visible record by overall heating.

Abstract: A positive working, thermally stable photoresist, comprising a light-sensitive orthoquinone diazide or naphthoquinone diazide and a polyamic acid condensation product of an aromatic dianhydride and an aromatic di-primary amine, and a support carrying a layer of said photoresist. After exposure, the image is developed in the layer with an alkaline aqueous developer and is unaffected by heating to 500.degree. C, thus allowing the use of the photoresist layer for plasma and sputter-etching as well as ion implantation.

Abstract: A photocopying material is provided having a light-sensitive layer comprising an oleophilic resin and a resinous diazonium compound, which both are soluble in an organic solvent but substantially insoluble in water, in admixture with a surface active agent which, after imagewise exposure, renders the layer developable with plain water such as ordinary tap water so as to yield an excellent photocopy and in particular a printing form from which many thousands of fine prints can be made on an offset machine.

Abstract: A new and improved developing solution for two-component light-sensitive diazo-type copying materials is described. The solution is a substituted organic diamine formulation which produces dry, high quality diazo prints rapidly, replacing conventional dry ammonia gas systems. The preferred diamine is N-(2-hydroxyethyl)-ethylenediamine alone or with diethylaminopropylamine.

Abstract: Modifying the surface of a diazotype material by incorporating hydroxyalkyl cellulose ether into the diazotype sensitizing coating composition or coating the assembly with it so as to roughen the surface of the material thereby enabling nitrogen, which is liberated when the material is exposed to light, to escape from between the master and the diazotype material to prevent nitrogen accumulating between the two and hence avoiding slippage of one relative to the other.

Abstract: A translucent sheet bearing opaque graphic intelligence thereon coated with a film which absorbs ultraviolet light, whereby the passage of visible light therethrough projects a legible image while light in the ultraviolet range is not transmitted so that diazotype copies cannot be produced of the graphic intelligence.

Abstract: Polymerization of polymerizable compositions comprising mixtures of lactones with monomeric or prepolymeric epoxides is effected by mixing such compositions with radiation-sensitive aromatic diazonium salts which decompose upon application of energy such as electromagnetic radiation to release Lewis Acid to initiate polymerization of said monomers.

Abstract: Copolymers of glycidyl acrylate and allyl glycidyl ether and terpolymers derived from addition of glycidyl methacrylate to the polymerizable mixture, having an inherent viscosity within the range of about 0.09 to 0.28 and an epoxy equivalent of at least about 0.64 per 100 g. of polymer are provided which upon admixture with a catalyst which is a radiation-sensitive aryldiazonium salt of a complex halogenide, provides compositions suitable for use in a dry photopolymer positive imaging process. In the process, the polymer which is non-tacky at room temperature, together with the catalyst is applied to a substrate and exposed to an energy source for example, electromagnetic radiation through a transparency or mask. Following exposure, the coating is heated to the softening point of the unexposed portion of the coating and a powder or toner is applied thereto, the toner being adhered to only the tacky, nonexposed area of the coating, resulting in a pigmented image.

Abstract: A light-sensitive material comprising a layer containing:(a) at least one organic compound containing tellurium and/or selenium; and(b) at least one sensitizing compound selected from the oxides, basic halides, halides, sulfates, nitrates, perchlorates, or organic acid salts of In (III), Sb (III), Ti (IV), Zn (II), Bi (III), Ge (IV), and Sn (IV).

Abstract: An erasable diazotype intermediate assembly comprising a translucent paper base, a rubber-like polymeric intervening barrier layer and a sensitizing layer consisting of a water soluble cellulose derivative, a cross linking resin and the diazo sensitizing chemicals.

Abstract: Compositions comprising the reaction product of a novel, highly branched polyalkylenimine-urea-aldehyde resin and a polyacrylic resin provide useful intermediate coatings when applied to preconditioned metal surfaces which may be subsequently coated with light sensitive materials to make photolithographic plates. The intermediate coating, particularly when applied to a grained or ungrained aluminum support member which has been anodized and finally coated with light sensitive materials produces a highly durable plate that possesses good storage characteristics and is capable of unusually extended press runs.

Abstract: An image-forming element is disclosed comprised of a support and a coating thereon containing a cobalt(III)complex and a compound containing a conjugated .pi. bonding system capable of forming at least a bidentate chelate with cobalt(III). The coating is predominantly free of anions which will form conjugate acids by deprotonation of a cobalt(II)complex containing the chelating compound. In one preferred form the image-forming element is radiation-sensitive. In this form the image-forming element can contain a photoactivator capable of initiating reduction of the cobalt(III)complex. An imaging process is disclosed in which the coating is exposed to actinic radiation to produce an image. Images can be recorded directly within the image-forming coating or in a separate image-recording element or layer by use of the residual cobalt(III)complex or by use of one or more of the reaction products produced by exposure.

Abstract: Diazotype copies are produced from one-component diazotype material in a practically dry state without adversely affecting their feel or the speed of development. The diazotype material comprises a support and a light-sensitive surface layer having an average maximum thickness of not more than 8 micrometers and comprising 0.2-2 milligram molecules of one or more diazo compounds, which, in vitro, couple more actively than 4-diazo-2-chloro-N.N.-diethylaniline. After imagewise exposure the copy is developed by applying to the light-sensitive surface of the diazotype material a quantity amounting to 1.5 to 4.5 cm.sup.3 /m.sup.2 of an aqueous, buffered solution, which is at a pH of between 5.5 and 7 and which comprises per liter 0.1-0.6 g.mol of azocoupling component, consisting for at least 50% by weight of phloroglucinol and 1-3 g. equivalents of buffer salt. The diazo layer advantageously is formed by spreading 2-8 cm.sup.3 of sensitizing solution of adapted concentration onto the support.

Abstract: A process for the formation of formazan dye images employing nuclei of metals from Groups VIIIB and/or IB of the periodic table to catalyze the reduction of tetrazolium salts to the corresponding formazan dye by a reducing agent.

Abstract: Carboxylic acids are included in resists to increase their speed and adhesion.

Abstract: A light-sensitive vesicular imaging composition comprising a vesiculating agent which liberates gas upon exposure to activating radiation, and a binder which is a sulfonamide polymer having the sulfur-nitrogen linkage either in the polymer chain or as a pendant moiety. The composition is coated as a thin film. Imagewise irradiation of the element causes gas bubbles to be released in the exposed areas, which bubbles may be developed by overall heating to a visible record.

Abstract: A light-sensitive lithographic printing plate comprising a support with a hydrophilic surface having thereon a light-sensitive layer comprising a light-sensitive polyester containing o-quinonediazido groups as terminal groups.

Abstract: This invention relates to a light-sensitive copying composition for the preparation of screen printing stencils comprising a condensation product of an aromatic diazonium compound in admixture with a hydrophilic hardenable binder, the condensation product containing at least one unit each of the general types A(-D).sub.

Abstract: A photosensitive color-forming element comprises a support and a photosensitive color-forming layer formed on said support and containing therein at least one photosensitive color-forming azido compound of the formula ##STR1## wherein [A] is a benzene ring or naphthalene ring, R.sub.1 and R.sub.2 each is a hydrogen or halogen atom or alkyl, alkoxyl, dialkylamino, acyl, acylamino, nitro or hydroxyl radical, and R.sub.3 is a hydrogen or halogen atom, or alkyl, alkoxyl, nitro, carboxyl, alkylcarboxyl, dialkylcarbamoyl, sulfonic acid, dialkylaminosulfonyl, alkylsulfonyl or acyl radical or a group of the formula (II), (III), (IV) or (V): ##STR2## in which formula X is an --O-- bonding or --NH-- bonding.[B] is a benzene ring or naphthalene ring, and R.sub.4 and R.sub.

Abstract: Process of producing diazo-sensitized film products which comprises pretreating the film surface with a halogen containing phenolic substance, coating with a plastics anchor layer and then coating with another plastics layer which includes or is impregnated with a light-sensitive diazonium compound.

Abstract: A positive photoresist having increased sensitivity to light and formed by the addition of an acidic compound to a 1,2-quinone-diazide sulphonic acid ester sensitizer.

Abstract: light-sensitive vesicular imaging materials, suitable for the production of labels, etc., comprise a light-sensitive vesicular imaging layer applied to one surface of a self-supporting plastics sheet or film preferably a polyester film, e.g., an oriented and heat-set film of polyethylene terephthalate, said light-sensitive vesicular imaging layer comprising a polymeric vehicle having uniformly dispersed therein a sensitizing agent which releases a vesicle-forming gas upon exposure to light and may comprise a nitrogent-liberating diazonium salt, said polymeric vehicle comprising a thermoplastic polymer having a nitrogent permeability constant (as defined in the specification) in the range 1 .times. 10.sup.-15 to 1 .times. 10.sup.-10 and being softenable upon heating above ambient temperature to permit the gas released by the sensitizing agent in the light-struck areas to form light-scattering or reflecting vesicles therein, e.g.

Abstract: light-sensitive vesicular imaging materials, suitable for the production of labels, etc., comprise a light-sensitive vesicular imaging layer applied to one surface of an opaque self-supporting plastics sheet or film, preferably a polyester film, e.g., an oriented and heat-set film of polyethylene terephthalate, said light-sensitive vesicular imaging layer comprising a polymeric vehicle having uniformly dispersed therein a sensitizing agent which releases a vesicle-forming gas upon exposure to light and may comprise a nitrogen-liberating diazonium salt, said polymeric vehicle comprising a thermoplastic polymer having a nitrogent permeability constant (as defined in the specification) in the range of 1 .times. 10.sup.-15 to 1 .times. 10.sup.-10 and being softenable upon heading above ambient temperature to permit the gas released by the sensitizing agent in the light-struck areas to form light scattering or reflecting vesicles therein, and an adhesive layer applied to the other surface of the sheet or film.