Search Patents
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Publication number: 20090035662Abstract: A rechargeable lithium-ion battery includes a positive electrode that includes a first current collector and a first active material. The battery also includes an electrolyte and a negative electrode that includes a second current collector and a second active material, where the second active material includes a lithium titanate material. The positive electrode has a first capacity and the negative electrode has a second capacity, the second capacity being less than the first capacity such that the rechargeable lithium-ion battery is negative-limited.Type: ApplicationFiled: September 29, 2008Publication date: February 5, 2009Inventors: Erik R. Scott, Gaurav Jain, Kevin W. Eberman, Craig L. Schmidt
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Patent number: 7635541Abstract: A method for charging an implantable medical device includes charging a lithium-ion battery provided in a medical device, the lithium-ion battery having a negative electrode with a lithium titanate active material. For at least a portion of the charging, the potential of the negative electrode is more than approximately 70 millivolts below the equilibrium potential of the negative electrode.Type: GrantFiled: October 27, 2005Date of Patent: December 22, 2009Assignee: Medtronic, Inc.Inventors: Erik R. Scott, William G. Howard, Craig L. Schmidt
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Patent number: 10903491Abstract: A rechargeable lithium-ion battery disclosed herein comprises a positive electrode with a positive electroactive material that in a charged state comprises lithium iron (II) orthosilicate (Li2FeSiO4) and in a discharged state comprises FeSiO4 or LiFeSiO4. A negative electrode comprises phosphorene. A separator is disposed between the positive electrode and the negative electrode. An electrolyte has an organic solvent especially containing ether-based organic solvents and a lithium salt that provides a conductive medium for lithium ions to transfer between the positive electrode and the negative electrode. Such a rechargeable lithium-ion battery provides advantageous power delivery, long driving ranges, and fast charge to enhance widespread use of batteries, especially in vehicles. Furthermore, lithium plating can be minimized or avoided, even at low temperature charging. Methods of recharging a rechargeable lithium-ion battery at low temperatures are also disclosed.Type: GrantFiled: January 9, 2019Date of Patent: January 26, 2021Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLCInventors: Xingcheng Xiao, Li Yang, Gayatri V. Dadheech, Gongshin Qi, Mark W. Verbrugge, Sherman H. Zeng
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Patent number: 9123953Abstract: A method for modifying a positive electrode material for a lithium-ion battery. The method includes: a) stirring a liquid polyacrylonitrile (LPAN) solution at the temperature of between 80 and 300° C. for between 8 and 72 h to yield a cyclized LPAN solution; b) adding positive electrode material for a lithium-ion battery, in a powder form, to the cyclized LPAN solution, and evenly mixing a resulting mixture; c) grinding the mixture, and drying the mixture at room temperature; and d) calcining the mixture at the temperature of between 500 and 1800° C. for between 6 and 24 h in the presence of an inert gas to form a graphene-like structure by the cyclized LPAN. The graphene-like structure is evenly distributed in the positive electrode material of the lithium-ion battery to yield a graphene-like structure modified positive electrode material of the lithium-ion battery.Type: GrantFiled: June 24, 2013Date of Patent: September 1, 2015Assignee: Shen Zhen UniversityInventors: Jianhong Liu, Dayong Gui, Qianling Zhang, Chuanxin He, Caizhen Zhu
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Publication number: 20090286158Abstract: A lithium-ion battery includes a positive electrode that includes a positive current collector, a first active material, and a second active material. The lithium-ion battery also includes a negative electrode comprising a negative current collector, a third active material, and a quantity of lithium in electrical contact with the negative current collector. The first active material, second active material, and third active materials are configured to allow doping and undoping of lithium ions, and the second active material exhibits charging and discharging capacity below a corrosion potential of the negative current collector and above a decomposition potential of the first active material.Type: ApplicationFiled: July 28, 2009Publication date: November 19, 2009Inventors: William G. Howard, Craig L. Schmidt, Erik R. Scott
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Patent number: 11552286Abstract: The present disclosure provides a lithium-ion battery, the lithium-ion battery comprises a positive electrode plate, a negative electrode plate, a separator and an electrolyte. The positive active material comprises a material having a chemical formula of LiaNixCoyMzO2, the negative active material comprises a graphite-type carbon material, the lithium-ion battery satisfies a relationship 58%?KYa/(KYa+KYc)×100%?72%. In the present disclosure, by reasonably matching the relationship between the anti-compression capability of the positive active material and the anti-compression capability of the negative active material, it can make the positive electrode plate and the negative electrode plate both have good surface integrity, and in turn make the lithium-ion battery have excellent dynamics performance and excellent cycle performance at the same time.Type: GrantFiled: June 21, 2019Date of Patent: January 10, 2023Assignee: CONTEMPORARY AMPEREX TECHNOLOGY CO., LIMITEDInventors: Manfang Zhang, Shengwei Wang, Fuping Luo, Xinxin Du, Qiaoge Wang
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Patent number: 7871727Abstract: Alloy compositions, lithium ion batteries, and methods of making lithium ion batteries are described. The lithium ion batteries have anodes that contain an alloy composition that includes a) silicon, b) aluminum, c) transition metal, d) tin, e) indium, and f) a sixth element that contains yttrium, a lanthanide element, an actinide element, or a combination thereof. The alloy composition is a mixture of an amorphous phase that includes silicon and a crystalline phase that includes an intermetallic compound of 1) tin, 2) indium, and 3) the sixth element.Type: GrantFiled: March 23, 2006Date of Patent: January 18, 2011Assignee: 3M Innovative Properties CompanyInventors: Mark N. Obrovac, Leif Christensen
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Patent number: 7235334Abstract: The present invention is an electrolyte for a lithium ion rechargeable battery and a lithium ion rechargeable battery that includes the same. More particularly, the present invention discloses an electrolyte for a lithium ion rechargeable battery that provides excellent cycle life characteristics and high-temperatures storage stability and prevents a drop in discharge capacity of a battery at low temperature, and a lithium ion rechargeable battery including the same. The lithium ion rechargeable battery including the electrolyte provides improved cycle life characteristics and prevents the problems of a drop in discharge capacity at low temperature and high-temperature swelling through the formation of a stable SEI film at the initial charge cycle.Type: GrantFiled: June 20, 2005Date of Patent: June 26, 2007Assignee: Samsung SDI Co., Ltd.Inventors: Jin Hee Kim, Jin Sung Kim, Yong Shik Kim
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Publication number: 20030031931Abstract: Improved lithium-ion batteries in which the cathode comprises particles that include (i) transition metal grains having a grain size no greater than about 50 nanometers; and (ii) lithium-containing grains selected from the group consisting of lithium oxides, lithium sulfides, lithium halides (e.g., chloride, bromides, iodides, or fluorides), and combinations thereof.Type: ApplicationFiled: August 7, 2001Publication date: February 13, 2003Applicant: 3M Innovative Properties CompanyInventors: Mark N. Obrovac, Jeffrey R. Dahn
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Patent number: 7858236Abstract: A lithium-ion battery includes a positive electrode that includes a positive current collector, a first active material, and a second active material. The lithium-ion battery also includes a negative electrode comprising a negative current collector, a third active material, and a quantity of lithium in electrical contact with the negative current collector. The first active material, second active material, and third active materials are configured to allow doping and undoping of lithium ions, and the second active material exhibits charging and discharging capacity below a corrosion potential of the negative current collector and above a decomposition potential of the first active material.Type: GrantFiled: July 28, 2009Date of Patent: December 28, 2010Assignee: Medtronic, Inc.Inventors: William G. Howard, Craig L. Schmidt, Erik R. Scott
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Publication number: 20130302684Abstract: A lithium-ion battery cathode material includes a composite of sulfur and porous carbon, and glass particles and/or glass ceramic particles that satisfy a composition represented by the following formula (1), LiaMbPcSd??(1) wherein M is B, Zn, Si, Cu, Ga, or Ge, and a to d are the compositional ratio of each element, and satisfy a:b:c:d=1 to 12:0 to 0.2:1:2 to 9.Type: ApplicationFiled: December 21, 2011Publication date: November 14, 2013Applicant: IDEMITSU KOSAN CO., LTD.Inventors: Hiromichi Koshika, Hiroyuki Higuchi, Atsushi Sato
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Publication number: 20120028124Abstract: An anode material for lithium-ion batteries is provided that comprises an elongated core structure capable of forming an alloy with lithium; and a plurality of nanostructures placed on a surface of the core structure, with each nanostructure being capable of forming an alloy with lithium and spaced at a predetermined distance from adjacent nanostructures.Type: ApplicationFiled: December 30, 2009Publication date: February 2, 2012Applicant: UNIVERSITY OF LOUISVILLE RESEARCH FOUNDATION, INC.Inventors: Mahendra Kumar Sunkara, Praveen Meduri, Gamini Sumanasekera
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Patent number: 7582387Abstract: A lithium-ion battery includes a positive electrode that includes a positive current collector, a first active material, and a second active material. The lithium-ion battery also includes a negative electrode comprising a negative current collector, a third active material, and a quantity of lithium in electrical contact with the negative current collector. The first active material, second active material, and third active materials are configured to allow doping and undoping of lithium ions, and the second active material exhibits charging and discharging capacity below a corrosion potential of the negative current collector and above a decomposition potential of the first active material.Type: GrantFiled: October 29, 2004Date of Patent: September 1, 2009Assignee: Medtronic, Inc.Inventors: William G. Howard, Craig L. Schmidt, Erik R. Scott
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Patent number: 9216907Abstract: A method of manufacturing a positive electrode active material for lithium ion batteries, comprising: preparing a mixture containing (A) Li3PO4, or a Li source and a phosphoric acid source, (B) at least one selected from a group of an Fe source, a Mn source, a Co source and a Ni source, water and an aqueous organic solvent having a boiling point of 150° C. or more, wherein the amounts of (A) and (B) in the mixture are adjusted to amounts necessary to manufacture therefrom LiMPO4, wherein M represents at least one selected from the group of Fe, Mn, Co and Ni, at a concentration of 0.5 to 1.5 mol/L; and generating fine particles of LiMPO4 having an average primary particle diameter of 30 to 80 nm by reacting (A) and (B) at a high temperature and high pressure.Type: GrantFiled: March 25, 2010Date of Patent: December 22, 2015Assignee: SUMITOMO OSAKA CEMENT CO., LTD.Inventors: Masatsugu Nakano, Akinori Yamazaki
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Publication number: 20100285368Abstract: A lithium ion battery includes: a positive electrode; a negative electrode that includes a negative electrode active material layer that contains an alloy-formable active material; an ion permeable insulating layer that is interposed between the positive electrode and the negative electrode; and an ion conductive polymer layer that is interposed between the negative electrode and the ion permeable insulating layer, in which the ion conductive polymer layer is configured to include a negative electrode-side portion and an ion permeable insulating layer-side portion that have different compositions, and the ion permeable insulating layer-side portion is configured to have higher ion conductivity than the negative electrode-side portion. With such a lithium ion battery, charge/discharge cycle characteristics and rate characteristics can be improved.Type: ApplicationFiled: April 27, 2010Publication date: November 11, 2010Inventors: Taisuke Yamamoto, Masaya Ugaji, Masahiro Kinoshita
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Patent number: 11949108Abstract: A negative electrode including a negative electrode active material layer and an additive. The additive includes a metal sulfide. The additive is distributed in the negative electrode active material layer, and/or distributed on the surface of the negative electrode active material layer. The negative electrode effectively improves the performance of the lithium ion battery, and greatly improves the capacity and cycle performance of the lithium ion battery.Type: GrantFiled: July 27, 2020Date of Patent: April 2, 2024Assignee: NINGDE AMPEREX TECHNOLOGY LIMITEDInventors: Jing Jiang, Qiao Zeng, Kefei Wang
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Patent number: 8003260Abstract: A lithium-ion battery comprising a first electrode made of cathodic material, a second electrode made of anodic material and an electrolyte, said lithium-ion battery containing an overcharge protection material consisting of redox molecules, characterized by the fact that said redox molecules have a reduction potential which is lower than said anodic material.Type: GrantFiled: September 5, 2007Date of Patent: August 23, 2011Assignee: Dow Global Technologies Inc.Inventors: Ivan Exnar, Qing Wang
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Patent number: 8470476Abstract: A lithium ion battery includes: a positive electrode; a negative electrode that includes a negative electrode active material layer that contains an alloy-formable active material; an ion permeable insulating layer that is interposed between the positive electrode and the negative electrode; and an ion conductive polymer layer that is interposed between the negative electrode and the ion permeable insulating layer, in which the ion conductive polymer layer is configured to include a negative electrode-side portion and an ion permeable insulating layer-side portion that have different compositions, and the ion permeable insulating layer-side portion is configured to have higher ion conductivity than the negative electrode-side portion. With such a lithium ion battery, charge/discharge cycle characteristics and rate characteristics can be improved.Type: GrantFiled: April 27, 2010Date of Patent: June 25, 2013Assignee: Panasonic CorporationInventors: Taisuke Yamamoto, Masaya Ugaji, Masahiro Kinoshita
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Publication number: 20110311882Abstract: Hybrid solid-liquid electrolyte lithium-ion battery devices are disclosed. Certain devices comprise anodes and cathodes conformally coated with an electron insulating and lithium ion conductive solid electrolyte layer.Type: ApplicationFiled: June 16, 2011Publication date: December 22, 2011Applicant: Alliance for Sustainable Energy, LLCInventors: Gi-Heon Kim, Yoon Seok Jung
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Publication number: 20030152828Abstract: The present application discloses a lithium-ion battery using heat-activatable microporous membrane which comprises a hot-melt adhesive, an engineering plastics, a tackifier and a filler. It also discloses methods of preparing such microporous membrane and the lithium-ion batteries. The battery built with the use of the microporous membrane of the present invention shows high rate capability, long cycle life, and low as well as stable impedance during charge-discharge cycling. The microporous membrane of the present invention also shows thermal shutdown behavior.Type: ApplicationFiled: December 17, 2002Publication date: August 14, 2003Inventor: Luying Sun