Search Patents
  • Publication number: 20010031400
    Abstract: A nickel hydroxide positive active material for an alkaline battery contains nickel hydroxide powder having a nickel valence of greater than 2; and a cobalt compound having a cobalt valence of greater than 2, which is formed on the surface of said nickel hydroxide powder. For example, the surface of nickel oxyhydroxide powder is covered by cobalt oxyhydroxide layer. This positive active material is used as a starting material to produce an electrode by retaining it in a three-dimensional porous material.
    Type: Application
    Filed: May 10, 2001
    Publication date: October 18, 2001
    Applicant: JAPAN STORAGE BATTERY CO., LTD.
    Inventors: Yukitaka Seyama, Hideki Sasaki, Toshio Murata
  • Patent number: 4844999
    Abstract: A nickel electrode for an alkaline battery includes a porous alkali-proof metal fiber substrate as a current collector and an active material principally formed of a nickel hydroxide powder is precluded from formation of the higher oxide, .gamma.-NiOOH, is improved in the ratio of utilization of the active material, and is provided with a high energy density and a long service life when the nickel hydroxide powder employed therein possesses a pore radius in the range of 15 to 30 .ANG., a total pore volume of not more than 0.05 ml/g, and a specific surface area in the range of 15 to 30 m.sup.2 /g. An alkaline battery is also provided by the invention which uses the nickel electrode described above.
    Type: Grant
    Filed: May 26, 1988
    Date of Patent: July 4, 1989
    Assignee: Yuasa Battery Company Limited
    Inventors: Masahiko Oshitani, Hiroshi Yufu
  • Patent number: 4985318
    Abstract: A nickel electrode for an alkaline battery comprises a porous alkaline-proof metal fiber substrate used as a current collector, and active material for the electrode. The active material includes nickel hydroxide powder active material, to which zinc or magnesium is added at a rate in a range of 3-10 wt % or 1-3 wt %, respectively. The zinc and magnesium is in a solid solution in crystal of the nickel hydroxide, and the active material forms principle compound of paste, which is loaded in the electrode.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: January 15, 1991
    Assignee: Yuasa Battery Co., Ltd.
    Inventors: Masahiko Oshitani, Keiichi Hasegawa, Hiroshi Yufu
  • Patent number: 6924064
    Abstract: A positive active material for non-aqueous electrolyte secondary battery is provided comprising lithium manganese oxide having such a spinel structure that the half-width (2?) of the reflection peak corresponding to 440 plane as determined by X-ray diffractometry using CuK? ray is not greater than 0.145°. The use of this positive active material makes it possible to obtain a secondary battery which exhibits a good cycle life performance at room temperature and high temperatures and a reduced capacity drop when stored at high temperatures.
    Type: Grant
    Filed: November 5, 2001
    Date of Patent: August 2, 2005
    Assignee: Japan Storage Battery Co., Ltd.
    Inventors: Atsuro Kondo, Junichi Toriyama, Masanao Terasaki
  • Patent number: 5795558
    Abstract: A positive electrode active material for a lithium secondary battery is made of LiNi.sub.1-x-y-z Co.sub.x Mn.sub.y Al.sub.z O.sub.2, in which x, y and z satisfy relations of 0.ltoreq.y.ltoreq.0.3, 0.ltoreq.x.ltoreq.0.25, 0.ltoreq.z.ltoreq.0.15.
    Type: Grant
    Filed: October 9, 1997
    Date of Patent: August 18, 1998
    Assignee: Japan Storage Battery Co., Ltd.
    Inventors: Takashi Aoki, Mikito Nagata, Hisashi Tsukamoto
  • Patent number: 6221529
    Abstract: A positive electrode for a lithium battery wherein nickel oxyhydroxide is held in an electro-conductive three-dimensional porous material or a sintered nickel substrate and a lithium battery using it. When the three-dimensional porous material is used, the electric contact of the active material and the current collector is good, also the contact state of nickel oxyhydroxide particles, which are active materials, each other is good, further, the contact resistance among the particles is low, and also the diffusion of the lithium ion, which is the rate-determining step of the reaction, becomes easy among the particles.
    Type: Grant
    Filed: November 18, 1997
    Date of Patent: April 24, 2001
    Assignee: Japan Storage Battery Co., Ltd.
    Inventor: Hideo Yasuda
  • Patent number: 5718989
    Abstract: A positive electrode active material for a lithium secondary battery is made of LiNi.sub.1-x-y-z Co.sub.x Mn.sub.y Al.sub.z O.sub.2, in which x, y and z satisfy relations of 0.ltoreq.y.ltoreq.0.3, 0.ltoreq.x.ltoreq.0.25, 0<z.ltoreq.0.15.
    Type: Grant
    Filed: December 27, 1996
    Date of Patent: February 17, 1998
    Assignee: Japan Storage Battery Co., Ltd.
    Inventors: Takashi Aoki, Mikito Nagata, Hisashi Tsukamoto
  • Patent number: 6399246
    Abstract: A water-soluble binder useful for preparing an electrode for either primary or secondary batteries, having either aqueous or non-aqueous electrolyte, contains polyacrylamide and at least one copolymer selected from carboxylated styrene-butadiene copolymer and styrene-acrylate copolymer. The water-dispersible binder eliminates or reduces the need for organic solvents during preparation of an electrode made of a particulate active electrode material. The binder exhibits good chemical resistance, adhesive properties, flexibility and resilience, making it well suited for use in preparing batteries having a spirally wound electrode assembly.
    Type: Grant
    Filed: May 5, 2000
    Date of Patent: June 4, 2002
    Assignee: Eveready Battery Company, Inc.
    Inventors: Mark D. Vandayburg, George E. Blomgren
  • Patent number: 7238447
    Abstract: A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.
    Type: Grant
    Filed: November 16, 2001
    Date of Patent: July 3, 2007
    Assignee: Toshiba Battery Co., Ltd.
    Inventors: Kunihiko Miyamoto, Shuichiro Irie, Shinichi Miyamoto, Naomi Hadano, Teiji Okayama
  • Patent number: 6399247
    Abstract: A nickel-metal hydride secondary battery comprising electrode group comprising positive electrode comprised mainly of nickel hydroxide, negative electrode comprised mainly of a hydrogen storage alloy, and separator being disposed between the positive electrode and the negative electrode, wherein the electrode group is sealed in battery casing, together with an alkali electrolyte liquid, wherein, in the battery, a W element and an Na element are present simultaneously. The nickel-metal hydride secondary battery of the present invention is advantageous not only in that it exhibits high utilization of the active material and excellent self-discharge characteristics in a high temperature storage as well as high charging efficiency in a high temperature environment, but also in that it has excellent large current discharge characteristics.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: June 4, 2002
    Assignees: Toshiba Battery Co., Ltd., Kabushiki Kaisha Toshiba
    Inventors: Hiroshi Kitayama, Hirotaka Hayashida, Masaaki Yamamoto, Naomi Bando, Kunihiko Miyamoto, Hideharu Suzuki
  • Publication number: 20140329145
    Abstract: An alkaline, rechargeable electrochemical cell includes a pasted electrode structure in which a composition comprising a paste matrix component includes cobalt in an amount greater than 6 weight percent ranging up to 14 weight percent. The matrix may also include a rare earth such as yttrium. The composition further includes particles of nickel hydroxide dispersed in the matrix, and these particles include cobalt levels ranging from greater than 8 atomic percent up to 15 atomic percent. Cells incorporating these materials have good charging efficiency at elevated temperatures.
    Type: Application
    Filed: February 6, 2013
    Publication date: November 6, 2014
    Applicant: Ovonic Battery Company, Inc.
    Inventor: Ovonic Battery Company, Inc.
  • Publication number: 20020018935
    Abstract: In accordance with the non-aqueous electrolyte secondary battery of the invention and the process for the preparation thereof, charging is carried out with a combination of a positive electrode provided with excess lithium and a negative electrode in order to cause lithium to be deposited on the negative electrode. Accordingly, no oxidized surface film is interposed between lithium and the current collector of negative electrode or the negative active material layer as in the case where a metallic lithium foil is laminated on the negative electrode. In this arrangement, a battery having a small internal resistance can be provided. Since the deposition of lithium is conducted in the assembled battery, lithium does not come in contact with air, preventing the formation of a thick ununiform oxidized film on the surface thereof. Thus, the deposition of dendrite can be inhibited, making it possible to inhibit the drop of battery capacity and hence provide a battery having an excellent cycle life performance.
    Type: Application
    Filed: July 6, 2001
    Publication date: February 14, 2002
    Applicant: JAPAN STORAGE BATTERY CO., LTD.
    Inventor: Mikio Okada
  • Patent number: 7851087
    Abstract: A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.
    Type: Grant
    Filed: May 5, 2009
    Date of Patent: December 14, 2010
    Assignee: Toshiba Battery Co., Ltd.
    Inventors: Kunihiko Miyamoto, Shuichiro Irie, Shinichi Miyamoto, Naomi Hadano, Teiji Okayama
  • Publication number: 20120015250
    Abstract: Provided are a positive electrode material for lithium ion batteries and a process for preparing the same. The positive electrode material for lithium ion batteries comprises a composite positive electrode material consists of LiCoO2 and an auxiliary positive electrode material, the general formula of the auxiliary positive electrode material is LiCo1?x?yNixMnyO2, wherein 0<x<0.9, 0<y<0.9, 0<x+y<0.9, and the LiCoO2 is a modified LiCoO2 coated with an Al2O3 film. The overcharge performance of the batteries can be significantly increased and the use amount of the overcharge additive can be reduced by using the positive electrode material so as to its improve the cycle performance of the batteries and improve the anti-overcharge safety in the special applications and the charging conditions.
    Type: Application
    Filed: December 22, 2009
    Publication date: January 19, 2012
    Applicant: SHENZHEN BAK BATTERY CO., LTD.
    Inventors: Xin Teng, Wei He, Ming He, Ruyu Rao, Bin Xiao, Qiming Pan
  • Patent number: 7594938
    Abstract: A high-capacity enclosed nickel-zinc primary battery excellent in characteristics such as capacity maintenance factor, energy density, and high-efficient discharge characteristics, an anode using it, and a production method for them. An enclosed nickel-zinc primary battery which uses as an anode an anode active material of nickel hydroxide compound, such as nickel oxyhydroxide, particles and uses zinc alloy gel as a cathode material, wherein a ratio of anode theoretical capacity to cathode theoretical capacity is 1.0-1.6, and a ratio of alkali electrolyte to anode theoretical capacity is 1.0-1.6 ml/Ah.
    Type: Grant
    Filed: May 25, 2007
    Date of Patent: September 29, 2009
    Assignee: Toshiba Battery Co., Ltd.
    Inventors: Kunihiko Miyamoto, Shuichiro Irie, Shinichi Miyamoto, Naomi Hadano, Teiji Okayama
  • Patent number: 6558842
    Abstract: A nickel hydroxide positive active material for an alkaline battery contains nickel hydroxide powder having a nickel valence of greater than 2; and a cobalt compound having a cobalt valence of greater than 2, which is formed on the surface of said nickel hydroxide powder. For example, the surface of nickel oxyhydroxide powder is covered by cobalt oxyhydroxide layer. This positive active material is used as a starting material to produce an electrode by retaining it in a three-dimensional porous material.
    Type: Grant
    Filed: May 10, 2001
    Date of Patent: May 6, 2003
    Assignees: Japan Storage Battery Co., Ltd., GS-Melcotec Co., Ltd.
    Inventors: Yukitaka Seyama, Hideki Sasaki, Toshio Murata
  • Patent number: 6251538
    Abstract: A nickel hydroxide positive active material for an alkaline battery contains nickel hydroxide powder having a nickel valence of greater than 2; and a cobalt compound having a cobalt valence of greater than 2, which is formed on the surface of said nickel hydroxide powder. For example, the surface of nickel oxyhydroxide powder is covered by cobalt oxyhydroxide layer. This positive active material is used as a starting material to produce an electrode by retaining it in a three-dimensional porous material.
    Type: Grant
    Filed: April 28, 1999
    Date of Patent: June 26, 2001
    Assignees: Japan Storage Battery Co., Ltd., GS-Melcotec Co., Ltd.
    Inventors: Yukitaka Seyama, Hideki Sasaki, Toshio Murata
  • Patent number: 6800397
    Abstract: In accordance with the non-aqueous electrolyte secondary battery of the invention and the process for the preparation thereof, charging is carried out with a combination of a positive electrode provided with excess lithium and a negative electrode in order to cause lithium to be deposited on the negative electrode. Accordingly, no oxidized surface film is interposed between lithium and the current collector of negative electrode or the negative active material layer as in the case where a metallic lithium foil is laminated on the negative electrode. In this arrangement, a battery having a small internal resistance can be provided. Since the deposition of lithium is conducted in the assembled battery, lithium does not come in contact with air, preventing the formation of a thick ununiform oxidized film on the surface thereof. Thus, the deposition of dendrite can be inhibited, making it possible to inhibit the drop of battery capacity and hence provide a battery having an excellent cycle life performance.
    Type: Grant
    Filed: July 6, 2001
    Date of Patent: October 5, 2004
    Assignee: Japan Storage Battery Co., Ltd.
    Inventor: Mikio Okada
  • Patent number: 6268082
    Abstract: The present invention is to provide a production method of an active material for an alkaline secondary battery comprising: a step of mixing particles comprising particles mainly containing nickel hydroxide and particles of a metal cobalt or a cobalt compound in a mixer with a sealed structure comprising a heating means in the presence of oxygen and an alkaline aqueous solution while heating. An active material produced by the method allows a high utilization. And a battery assembled with a positive electrode using the active material has an excellent high ratio discharge characteristic, and hardly causes the capacity decline even at the time of recharging after leaving in the over discharge state for a long time.
    Type: Grant
    Filed: March 12, 1999
    Date of Patent: July 31, 2001
    Assignee: Toshiba Battery Co., Ltd.
    Inventors: Masayoshi Hiruma, Naomi Bando, Kunihiko Miyamoto, Makoto Wakabayashi
  • Publication number: 20030140483
    Abstract: An alkaline secondary battery which is characterized in that it comprises, a positive electrode containing nickel hydroxide having a value of 0.8° or more in the half-width of a peak in the (101) plane thereof as measured by X-ray powder diffraction (2&thgr;) using Cu—K&agr; ray, and 4.0 to 15% by weight of at least one material selected from the group consisting of zinc and zinc compounds, and an alkali electrolyte, the ratio of which to theoretical capacity of the positive electrode being 0.7 to 2.0 cm3/Ah, the weight of the at least one material being one calculated as zinc element and based on the weight of the nickel hydroxide.
    Type: Application
    Filed: January 3, 2003
    Publication date: July 31, 2003
    Applicant: TOSHIBA BATTERY CO., LTD.
    Inventors: Makoto Wakabayashi, Kunihiko Miyamoto, Tetsuya Yamane, Naomi Bando, Kiyoshi Ishitsuka, Ken-Ichi Kanno, Hidekazu Oppata