Abstract: A method for manufacturing positive a electrode active material for a lithium battery represented by general formula Li.sub.x Mn.sub.2-y M.sub.y O.sub.4 (M: a 2-valency metal, 0.45.ltoreq.y.ltoreq.0.60, 1.ltoreq.x.ltoreq.2.1) having cubic spinel structure of and a lattice constant within 8.190 angstroms by employing a solid phase reaction, comprising the steps of firing a lithium compound, a manganese compound and a metal M compound and refiring the fired material after pressurizing it at least once to remove a metal M oxide.

Abstract: A nickel-hydrogen secondary battery is disclosed wherein a long life is assured, an improved self-discharging property in a high temperature storage and the inhibition of increase in inner pressure of the battery in the occasion of over-charging can be realized. The nickel-hydrogen secondary battery comprises, a case, a paste-type positive electrode accommodated in the case and containing nickel hydroxide and a polymeric binder, a paste-type negative electrode accommodated in the case and containing a hydrogen-absorbing alloy and a polymeric binder, a separator accommodated in the case in so as to be interposed between the positive and negative electrodes, and an alkali electrolyte accommodated in the case.

Abstract: A lithium-ion battery including an electrodeposited anode material having a micron-scale, three-dimensional porous foam structure separated from interpenetrating cathode material that fills the void space of the porous foam structure by a thin solid-state electrolyte which has been reductively polymerized onto the anode material in a uniform and pinhole free manner, which will significantly reduce the distance which the Li-ions are required to traverse upon the charge/discharge of the battery cell over other types of Li-ion cell designs, and a procedure for fabricating the battery are described. The interpenetrating three-dimensional structure of the cell will also provide larger energy densities than conventional solid-state Li-ion cells based on thin-film technologies. The electrodeposited anode may include an intermetallic composition effective for reversibly intercalating Li-ions.

Abstract: Disclosed is a method of manufacturing an alkaline secondary battery improved in the positive electrode utilization, the large-current discharge characteristic, the discharge capacity, and the capacity recovery ratio after storage. This method of manufacturing an alkaline secondary battery comprising a positive electrode containing a nickel compound and a cobalt compound, a negative electrode and an alkaline electrolyte, the method comprising the step of performing initial charging which comprises a charging process of supplying a current I (mA) satisfying the following Inequality (1):50<(T.times.C.sup.2)/(I.times.S)<2000 (1)where C is a electrochemical capacity (mAh) of the cobalt compound contained in the positive electrode, which is calculated on the basis of a electrochemical equivalent of the cobalt compound, T is a temperature (.degree.C.) at which the charging process is performed, and S is an area (cm.sup.2) of the positive electrode.

Abstract: The non-aqueous electrolyte secondary battery comprising a positive electrode comprising a positive active material capable of absorbing/releasing lithium ion and a negative electrode comprising as a negative active material a graphite comprising boron having a S1/S2 ratio of about 1.0 or less wherein S1 is the area of the peak having its top at a range of from 188 to 192 eV and S2 is the area of the peak having its top at a range of from 185 to 187 eV as measured by X-ray photoelectron spectroscopy (XPS). The content of boron in the graphite is from about 0.008% to about 3% by weight. The boron-containing graphite incorporated as a negative active material contains little boron compound having an extremely low electronic conductivity, and the discharge capacity of the non-aqueous electrolyte secondary battery can be enhanced.

Abstract: This invention is to provide a nickel-cadmium alkaline storage battery in which the content of nickel hydroxide and/or nickel oxide in a negative active material is from 2 to 60 wt% based on the total amount of cadmium, and the content of cadmium hydroxide in the negative active material is 0.95 or lower in terms of a weight ratio to nickel hydroxide in a positive active material; a manganese dioxide-cadmium alkaline storage battery in which the content of cadmium hydroxide in a negative active material in the discharged state is 0.84 or lower in terms of a weight ratio to manganese dioxide in a positive active material; and a silver oxide-cadmium alkaline storage battery in which the content of cadmium hydroxide in a negative active material in the discharged state is 1.36 or lower in terms of a weight ratio to silver in a positive active material.

Abstract: An alkaline secondary battery which is characterized in that it comprises, a positive electrode containing nickel hydroxide having a value of 0.8° or more in the half-width of a peak in the (101) plane thereof as measured by X-ray powder diffraction (2?) using Cu—K? ray, and 4.0 to 15% by weight of at least one material selected from the group consisting of zinc and zinc compounds, and an alkali electrolyte, the ratio of which to theoretical capacity of the positive electrode being 0.7 to 2.0 cm3/Ah, the weight of the at least one material being one calculated as zinc element and based on the weight of the nickel hydroxide.

Abstract: Nickel-metal hydride batteries and electrodes capable of increased power output and recharge rates. The positive and negative electrodes may be formed by pressing powdered metal-hydride active materials into porous metal substrates. The porous metal substrates are formed from copper, copper-plated nickel, or a copper-nickel alloy. The electrode tab are directly attached to the porous metal substrate via a low electrical-resistance connection which includes welding, brazing, or soldering.

Abstract: The present invention relates to rechargeable nickel metal hydride batteries and methods for making the same. More particularly, the present invention relates to rechargeable nickel metal hydride batteries having a precharge in the negative electrode sufficient for oxidation prevention in the negative electrode. The present invention discloses a nickel metal hydride battery, wherein the precharge of the negative electrode may be supplied by a variety of sources. The positive active material of the positive electrode may have positive active particles, such as nickel hydroxide, having a precursor coating that incorporates cobalt material capable of forming a conductive network. Sources other than cobalt-containing materials in the positive electrode include hydrogen gas provided directly to the negative active material, nickel aluminum mixed with the negative active material, the etching of the negative active material with an alkaline solution and borohydride chemically charging the negative active material.

Abstract: This invention discloses an alkali secondary battery which includes a cadmium-free positive electrode whose swelling ratio is decreased, and in which the cycle characteristic is improved and the charge efficiency in use at high temperatures is also improved. This alkali secondary battery includes a positive electrode accommodated in a case and having a structure in which a paste containing nickel hydroxide grains, a conductor, and a binder is filled in a metal porous body, a negative electrode accommodated in the case and so arranged as to oppose the positive electrode with a separator sandwiched between them, and an alkali electrolyte contained in the case. The nickel hydroxide grains contained in the positive electrode have a structure in which cobalt and at least one transition metal selected from the group consisting of copper, bismuth, chromium, gallium, indium, lanthanum, scandium, and yttrium are coprecipitated with metal nickel at a ratio of 1.5 to 11.0 wt % with respect to nickel hydroxide.

Abstract: There is provided a method of producing an active material of a positive electrode used for an alkaline secondary battery which is difficult to be oxidized, and high in its reactivity with an alkaline electrolyte to form a cobalt electric conductive matrix improved in electric conductivity. The method of producing thereof is characterized in that nickel hydroxide powder is dispersed in an aqueous solution of a strongly acidic cobalt salt and the dispersed solution thereof is, while being stirred, added gradually with an aqueous alkali solution to made to react one with another to precipitate a cobalt hydroxide while maintaining the reaction solution in the region of acidity to neutrality, and a solid part in which the cobalt hydroxide is mixed in the nickel hydroxide is separated from the reaction solution which is in the region of acidity to neutrality after the completion of the reaction, and is then washed with water.

Abstract: An object of the present invention is to provide a cathode active material which contains small-particle sized and low-crystalline lithium transition metal silicate and which undergoes charge-discharge reaction at room temperature. The cathode active material for a non-aqueous electrolyte secondary battery is characterized by containing a lithium transition metal silicate and exhibits diffraction peaks having half widths of 0.175 to 0.6°, the peaks observed through powder X-ray diffractometry within a 2? range of 5 to 50°.

Abstract: This invention discloses an alkali secondary battery which includes a cadmium-free positive electrode whose swelling ratio is decreased, and in which the cycle characteristic is improved and the charge efficiency in use at high temperatures is also improved. This alkali secondary battery includes a positive electrode accommodated in a case and having a structure in which a paste containing nickel hydroxide grains, a conductor, and a binder is filled in a metal porous body, a negative electrode accommodated in the case and so arranged as to oppose the positive electrode with a separator sandwiched between them, and an alkali electrolyte contained in the case. The nickel hydroxide grains contained in the positive electrode have a structure in which cobalt and at least one transition metal selected from the group consisting of copper, bismuth, chromium, gallium, indium, lanthanum, scandium, and yttrium are coprecipitated with metal nickel at a ratio of 1.5 to 11.0 wt % with respect to nickel hydroxide.

Abstract: A positive active material for the non-aqueous electrolyte secondary battery comprising a lithium-nickel composite oxide represented by the compositional formula LiaNi1-b-cCObMnCO2 (a≦1.09, 0.05≦b≦0.35, 0.15≦c≦0.35, and 0.25≦b+c≦0.55). BY the X-ray diffractometry with the CuK&agr; ray, the lithium-nickel composite oxide exhibits an intensity ratio R ((I012+I006)/I101) of not greater 0.50, wherein R is the ratio of the sum of the diffraction peak intensity I012 on the 012 plane and the diffraction peak intensity I006 on the 006 plane to the diffraction peak intensity I101 on the 101 plane. The crystallinity of the positive active material of the compositional formula LiaNi1-b-cCobMnCO2 can be kept high and it is possible to secure the good capacity density and cycle life performance.

Abstract: A positive active material for a non-aqueous electrolyte secondary battery includes a lithium-nickel composite oxide represented by the compositional formula LiaNi1?b?cCObMncO2 (a?1.09, 0.05?b?0.35, 0.15?c?0.35, and 0.25?b+c?0.55). By X-ray diffractometry with a CuK? ray, the lithium-nickel composite oxide exhibits an intensity ratio R ((I012+I006)/I101) of not greater than 0.50, wherein R is the ratio of the sum of the diffraction peak intensity I012 on the 012 plane and the diffraction peak intensity I006 on the 006 plane to the diffraction peak intensity I101 on the 101 plane. The crystallinity of the positive active material of the compositional formula LiaNi1?b?cCobMncO2 can be kept high and it is possible to secure good capacity density and cycle life performance.

Abstract: A nonaqueous polymer battery includes a lithium ion conductive polymer having pores, a positive active material, and a carbonaceous negative active material. In the nonaqueous polymer battery, the positive active material is represented by Li.sub.1-x CoO.sub.2 (0.ltoreq.x.ltoreq.1) wherein the molar ratio of the carbon atoms in the negative active material to the cobalt atoms in the positive active material is 7.5 or lower; the positive active material is represented by Li.sub.1-x NiO.sub.2 (0.ltoreq.x.ltoreq.1) wherein the molar ratio of the carbon atoms in the negative active material to the nickel atoms in the positive active material is less than 10; or the positive active material is represented by Li.sub.1-x Ni(Co)O.sub.2 (Li.sub.1-x NiO.sub.2 having not more than 20% of the nickel atoms thereof displaced with cobalt ions; 0.ltoreq.x.ltoreq.

Abstract: A positive electrode active material for lithium battery which is represented by general formula Li.sub.x Mn.sub.2-y M.sub.y O.sub.4 (M: a 2-valency metal selected from Ni, Co, Fe and Zn with 0.45.ltoreq.y.ltoreq.0.60, 1.ltoreq.x.ltoreq.2.1) having cubic spinel structure of lattice constant within 8.190 angstrom. Such an active material is manufactured by employing sol-gel process wherein one of inorganic salt, hydroxide and organic acid salt of lithium or a mixture of these for Li, one of inorganic salt and organic acid salt of manganese or a mixture of these for Mn, and one of inorganic salt and organic acid salt of the selected metal or a mixture of these for M are used as the starting materials for synthesis, ammonia water is added to the solutions of these starting materials in alcohol or water to obtain gelatinous material and the gelatinous material thus obtained is fired.

Abstract: A method of making a battery includes selecting selecting a sample of nickel oxyhydroxide, incorporating the sample of nickel oxyhydroxide into a battery, and determining the voltage peak capacity of the battery.

Abstract: A mixture of rare earth elements, in which La is comprised from 75 to 90 wt % of rare earth elements, with the balance being Ce, Nd, Pr and other rare earth elements (the mixture being referred to as a highly lanthanum-rich misch metal, and is hereinafter designated Lm), is used to produce a hydrogen absorbing alloy having a composition represented by LmNi.sub.x-A-B Co.sub.A Al.sub.B, Lm.sub.1-x Zr.sub.x Ni.sub.Y-A-B Co.sub.A Al.sub.B, or Lm.sub.1-x Zr.sub.x Ni.sub.Y-A-B-C Co.sub.A Mn.sub.B Al.sub.C. By using these hydrogen absorbing alloys as negative electrode materials, nickel metal hydride secondary batteries can be fabricated that have a large discharge capacity and that also have excellent cycle life and high rate discharge characteristics. Such electrode characteristics that are balanced between the aspects of discharge capacity and cycle life have heretofore been unattainable by either La alone or a misch metal having a relatively low La content or a conventional lanthanum-rich misch metal.

Abstract: Disclosed is a secondary battery comprising an electrode assembly including a cathode, an anode and a separator interposed between the cathode and the anode, the secondary battery comprising a HF scavenger.