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  • Publication number: 20120031827
    Abstract: The subject invention relates generally to friable metal oxide agglomerates and specifically to agglomerates containing high surface area rare earth-containing materials and a polymeric binder.
    Type: Application
    Filed: August 8, 2011
    Publication date: February 9, 2012
    Applicant: MOLYCORP MINERALS, LLC
    Inventors: John L. Burba, Carl R. Hassler, Charles F. Whitehead, Joseph A. Lupo, John Lahlouh, Chris Vogdes, Brandt Wright
  • Patent number: 4540509
    Abstract: Ion exchange resins in the base form, e.g., DOWEX MWA--1--OH ion exchange resin, which contain crystalline Al(OH).sub.3, e.g., gibbsite, and/or bayerite, and/or norstrandite, are treated with hot, concentrated LiX solutions (where X is anion) to prepare 3-layer crystalline LiX.2Al(OH).sub.3.nH.sub.2 O in the resin.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: September 10, 1985
    Assignee: The Dow Chemical Company
    Inventor: John L. Burba, III
  • Publication number: 20090111689
    Abstract: An aggregate composition and process for making the aggregate composition. The aggregate composition includes an insoluble rare earth-containing compound and a polymer binder. The insoluble rare earth-containing compound can include one or more of cerium, lanthanum, or praseodymium. A suitable insoluble cerium-containing compound can be derived from cerium carbonate or a cerium salt. In a specific embodiment, the aggregate composition consists essentially of one or more cerium oxides, the polymer binder and optionally a flow aid. A process for making the composition includes mixing the insoluble rare earth-containing compound with a polymer binder to form a mixture, and subjecting the mixture to mechanical, chemical and/or thermal treatment to adhere the rare earth compound to the polymer binder. The aggregate composition can be used in a variety of fluid treatment applications to remove one or more chemical and biological contaminants in a fluid.
    Type: Application
    Filed: October 31, 2007
    Publication date: April 30, 2009
    Applicant: CHEVRON U.S.A. INC.
    Inventor: John L. Burba, III
  • Patent number: 8809229
    Abstract: An aggregate composition and process for making the aggregate composition. The aggregate composition includes an insoluble rare earth-containing compound and a polymer binder. The insoluble rare earth-containing compound can include one or more of cerium, lanthanum, or praseodymium. A suitable insoluble cerium-containing compound can be derived from cerium carbonate or a cerium salt. In a specific embodiment, the aggregate composition consists essentially of one or more cerium oxides, the polymer binder and optionally a flow aid. A process for making the composition includes mixing the insoluble rare earth-containing compound with a polymer binder to form a mixture, and subjecting the mixture to mechanical, chemical and/or thermal treatment to adhere the rare earth compound to the polymer binder. The aggregate composition can be used in a variety of fluid treatment applications to remove one or more chemical and biological contaminants in a fluid.
    Type: Grant
    Filed: September 9, 2013
    Date of Patent: August 19, 2014
    Assignee: Molycorp Minerals, LLC
    Inventor: John L. Burba
  • Patent number: 4477367
    Abstract: Crystalline 2-layer LiOH.2Al(OH).sub.3.nH.sub.2 O, preferably supported by a porous substrate, is prepared by treating crystalline 2-layer LiX.2Al(OH).sub.3.nH.sub.2 O, where X is anion, with a LiOH solution or other hydroxide ion source. The so-formed crystalline 2-layer LiOH.2Al(OH).sub.3.nH.sub.2 O is particularly suitable for exchange of the OH ion with larger X' ions to produce other crystalline 2-layer LiX'.2Al(OH).sub.3.nH.sub.2 O.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: October 16, 1984
    Assignee: The Dow Chemical Company
    Inventor: John L. Burba, III
  • Patent number: 8349764
    Abstract: An aggregate composition and process for making the aggregate composition. The aggregate composition includes an insoluble rare earth-containing compound and a polymer binder. The insoluble rare earth-containing compound can include one or more of cerium, lanthanum, or praseodymium. A suitable insoluble cerium-containing compound can be derived from cerium carbonate or a cerium salt. In a specific embodiment, the aggregate composition consists essentially of one or more cerium oxides, the polymer binder and optionally a flow aid. A process for making the composition includes mixing the insoluble rare earth-containing compound with a polymer binder to form a mixture, and subjecting the mixture to mechanical, chemical and/or thermal treatment to adhere the rare earth compound to the polymer binder. The aggregate composition can be used in a variety of fluid treatment applications to remove one or more chemical and biological contaminants in a fluid.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: January 8, 2013
    Assignee: Molycorp Minerals, LLC
    Inventor: John L. Burba, III
  • Patent number: 4461714
    Abstract: The bayerite form of crystalline alumina, Al(OH).sub.3, contained within a macroporous ion exchange resin is converted to the gibbsite form of Al(OH).sub.3 by reaction with hot MgX.sub.2, where X is halide, followed by water-washing the MgX.sub.2 portion from the product, thereby causing the conversion of bayerite to the gibbsite form of crystalline Al(OH).sub.3. The gibbsite form may then be reacted with hot LiX solution, where X is anion, to form crystalline 2-layer LiX.2Al(OH).sub.3.nH.sub.2 O.
    Type: Grant
    Filed: August 30, 1982
    Date of Patent: July 24, 1984
    Assignee: The Dow Chemical Company
    Inventor: John L. Burba, III