Abstract: A high calcium containing drilling fluid having a 0.1-10 pounds per barrel of a deflocculant which is a water-soluble acrylic polymer which contains from 5-50 mole percent of one or more of the following:Sulfoethyl acrylamide; orAcrylamide and Sulfoethyl acrylamide; orEthyl acrylate and Sulfoethyl acrylamide; orAcrylamide and Sulfophenyl acrylamide; orAcrylamide and Sulfomethyl acrylamide.
Abstract: A stable aqueous slurry of particles which comprises:______________________________________ Ingredient % by weight ______________________________________ water 40-60 oil-in-water emulsion 10-30 acrylic acid polymer having a .1-1 MW greater than 1,000,000 suspended particles 2-50 ______________________________________ .
Abstract: A process for reducing turbidity in turbid waters which comprises adding to said waters a composition consisting essentially of an aqueous solution of:(a) calcium chloride and(b) a water soluble organic positively charged polymeric coagulant having an average molecular weight of at least 2000 selected from the group consisting of polydiallyl dimethylammonium chloride polymer and dimethylamine epichlorohydrin ethylenediaminethe weight of (a) to (b) being within the range of 0.75:1 to 4:1.
Abstract: A concentrate of the type useful for preparing an oil-in-water emulsion lubricant used in the drawing and ironing of ferrous and non-ferrous metals comprising:______________________________________ Ingredient % by Weight ______________________________________ A carboxylic acid ester from the 60-90 group consisting of: (a) Dibasic acid having at least 70% by weight of its carboxylic acid groups esterified with a C.sub.4 -C.sub.30 mohydric alcohol (b) A C.sub.8 -C.sub.22 mono carboxylic acid ester of a polyhydric alcohol. Water-in-oil emulsifying agent, .5-30 Polyglycol co-emulsifier 2-4 Phosphate corrosion inhibitor 0.5-2 Copper corrosion inhibitor 0.2-1 Thickener 0-10 ______________________________________the improvement which comprises said composition having an Iodine number not greater than 5.
Type:
Grant
Filed:
September 18, 1987
Date of Patent:
August 30, 1988
Assignee:
Nalco Chemical Company
Inventors:
John T. Malito, Richard D. Wintermute, Scott F. Ross, John M. Ferrara
Abstract: A method for reducing the residual acrylic acid present in water-insoluble polyacrylic acid water absorbent gel polymers which comprises treating these polymers with at least 0.5 mole of either amino acid cysteine or lysine per mole of acrylic acid present in said waters for at least 15 minutes at a temperature of at least 80.degree. C.
Abstract: A paint spray booth detackifying composition which includes mixtures of styrene-acrylate polymer and a melamine-formaldehyde polymer and the method of using same.
Abstract: Polyacrylamide is reacted with formaldehyde and bisulfite at a temperature of at least about 100.degree. C. and at an initial reaction mixture pH of less than about 12, preferably about 3 to about 8, to produce sulfomethylpolyacrylamide.
Abstract: The decomposition of phosphonates by chlorine-bromine solutions present in industrial process waters can be diminished or prevented by treating such waters with sulfamic acid.
Abstract: Heavy metals are removed from effluent waters using the sequential steps comprising:A. Adding a surfactant;B. pH adjustment;C. Adding a cationic coagulant;D. Adding a flocculant; and,E. Recovering the floc formed by the flocculant.
Type:
Grant
Filed:
June 19, 1987
Date of Patent:
July 19, 1988
Assignee:
Nalco Chemical Company
Inventors:
Michael D. Spence, John M. Kozaruk, Mark Melvin, Stephen M. Gardocki
Abstract: The invention comprises a method for determining the corrosion rate of metals in contact with a liquid system which is capable of causing corrosion of such metals which comprises adding to the liquid system an electrochemically active compound having a reduction potential more positive than the metal in contact with the liquid system and then monitoring the system thus treated with the electrochemically active compound to determine its rate of reduction which is proportional to the corrosion rate of the metal.
Type:
Grant
Filed:
May 5, 1987
Date of Patent:
July 19, 1988
Assignee:
Nalco Chemical Company
Inventors:
Barry E. Hunt, Harvey M. Herro, Kyu-Hwa Lee, Morris Mindick
Abstract: 1,2-imidazolines are prepared by reacting gas oils containing naphthenic acid with polyamines. This reaction, in addition to forming imidazolines, reduces the acidity of the starting gas oils.
Abstract: A composition and method for inhibiting corrosion in industrial cooling waters which contain hardness and have a pH of at least 8, which composition comprises a water-soluble organic phosphonate capable of inhibiting corrosion in an aqueous alkaliine environment and a hydrocarbon polymer containing an N-substituted acrylamide polymer with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, and combinations thereof.
Type:
Grant
Filed:
May 9, 1986
Date of Patent:
July 12, 1988
Assignee:
Nalco Chemical Company
Inventors:
John E. Hoots, Donald A. Johnson, Dodd W. Fong
Abstract: Metalworking applications are provided with a lubricant comprised of at least one substantially saturated ester formed of a polyhydric alcohol and at least one carboxylic acid, from 5 to 15 weight percent of a partially-esterified vegetable oil, an air-oxidized vegetable oil, a high molecular weight alkali metal sulfonate salt, a high carbon amide, a high molecular weight ethoxylated organic alcohol, or mixtures thereof and from 0.5 to 3.0 weight percent of an ethylene homopolymer, a polymer derived from ethylene and ethylenically unsaturated carboxylic acid monomers, oxidized derivatives of ethylene polymers, or mixtures thereof. The lubricant is applied to metal in molten form.
Abstract: A method of conditioning sludge formed in paint spray booths, where the detackifier is a melamine-formaldehyde, polyvinyl alcohol and styrene-acrylate paint detackier by adding a water conditioner that includes acrylamide/dimethylaminoethylmethacrylate methylsulfate quat.
Abstract: A method for inhibiting corrosion in industrial cooling waters which contain hardness and a pH of at least 6.5, by dosing the water with a composition which comprises a water-soluble inorganic phosphate capable of inhibiting corrosion in an aqueous alkaline environment and a hydrocarbon polymer containing an N-substituted acrylamide polymers with an amide structure as follows: ##STR1## where R.sub.2 is hydrogen or methyl, R.sub.1 is a hydrogen or an alkyl and R is alkylene or phenylene, and X is sulfonate, (poly)hydroxyl, (poly)carboxyl or carbonyl, and combinations thereof; or containing derivatized maleic anhydride homo-, co- and terpolymers having N-substituted maleamic acid units, N-substituted maleimide units and maleic acid (and salts) units having a structure as follows: ##STR2## where R.sub.1, R.sub.2 and R.sub.
Type:
Grant
Filed:
May 9, 1986
Date of Patent:
June 21, 1988
Assignee:
Nalco Chemical Company
Inventors:
John E. Hoots, Donald A. Johnson, Dodd W. Fong, James F. Kneller
Abstract: A method of neutralizing the organic acidity in petroleum and petroleum fractions to produce a neutralization number less than 1.0 whereby they are rendered suitable as lube oil feed stocks which comprises treating said heavy gas oils with a neutralizing amount of monoethanolamine to form an amine salt with the organic acids and then heating the thus-neutralized petroleum or petroleum fraction at a temperature and for a time sufficient to convert the amine salts to amides.
Abstract: A method for the removal of over-sprayed paint solids which comprises contacting the over-sprayed paint solids with an oil-in-water emulsion until the emulsion is loaded with at least 5 parts by weight of paint solids per 100 parts by weight of the hydrocarbon liquid of the emulsion.
Type:
Grant
Filed:
October 23, 1987
Date of Patent:
June 14, 1988
Assignee:
Nalco Chemical Company
Inventors:
Robert R. Patzelt, Edwin C. Zuerner, Michael L. Dwyer