Patents Represented by Attorney Beverly J. Artale
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Patent number: 6334949Abstract: A method for the removal of carbonyl sulfide from liquefied petroleum is disclosed. Removal of carbonyl sulfide is accomplished by contacting a liquid petroleum gas stream containing a carbonyl sulfide as an impurity with a calixarene complexing agent as the principal agent for the removal of the carbonyl sulfide.Type: GrantFiled: January 31, 2001Date of Patent: January 1, 2002Assignee: The United States of America as represented by the Secretary of CommerceInventors: Thomas J. Bruno, Anthony F. Lagalante
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Patent number: 6280607Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NOx control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.Type: GrantFiled: July 20, 2000Date of Patent: August 28, 2001Assignee: W R Grace & Co.-Conn.Inventors: Alan W. Peters, John A. Rudesill, Gordon Dean Weatherbee, Edward F. Rakiewicz, Mary Jane A. Barbato-Grauso, Xinjin Zhao
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Patent number: 6204219Abstract: A process for the preparation of mixed oxide compositions of cerium oxide and at least one non-noble metal oxide is disclosed. The process involves contacting a salt solution containing a cerium (IV) salt with hydrogen peroxide and thereafter, treating the resulting solution with excess base to precipitate a mixed oxides. Mixed oxide compositions produced by the process maintain a high specific surface area after prolonged exposure to high temperatures.Type: GrantFiled: July 29, 1999Date of Patent: March 20, 2001Assignee: W. R. Grace & Co.-Conn.Inventors: Rasto Brezny, Manoj M. Koranne
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Patent number: 6165933Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) palladium promote CO combustion in FCC processes while minimizing the formation of NO.sub.x. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide.Type: GrantFiled: April 10, 1997Date of Patent: December 26, 2000Assignee: W. R. Grace & Co.-Conn.Inventors: Alan W. Peters, Edward F. Rakiewicz, Gordon Dean Weatherbee, Xinjin Zhao
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Patent number: 6152150Abstract: A dry zeolite containing composition is used in a method for removing grease and/or oil stains from the human body is disclosed. In accordance with the method, zeolites having an average particle size of about 0.5 mm or less provide superior performance to remove grease and oil stains from the skin. Stain removing activities of the zeolite compositions may be enhanced by the addition of an imide.Type: GrantFiled: August 3, 1999Date of Patent: November 28, 2000Assignee: OdorPro, Inc.Inventors: John B. Cook, Gary J. Calton
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Patent number: 6143167Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NO.sub.x control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.Type: GrantFiled: April 28, 1997Date of Patent: November 7, 2000Assignee: W. R. Grace & Co.-Conn.Inventors: Alan W. Peters, John A. Rudesill, Gordon Dean Weatherbee, Edward F. Rakiewicz, Mary Jane A. Barbato-Grauso
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Patent number: 6129834Abstract: Compositions comprising a component containing (i) an acidic oxide support, (ii) an alkali metal and/or alkaline earth metal or mixtures thereof, (iii) a transition metal oxide having oxygen storage capability, and (iv) a transition metal selected from Groups Ib and/or IIb of the Periodic Table provide NO.sub.x control performance in FCC processes. The acidic oxide support preferably contains silica alumina. Ceria is the preferred oxygen storage oxide. Cu and Ag are preferred Group I/IIb transition metals. The compositions are especially useful in the cracking of hydrocarbon feedstocks having above average nitrogen content.Type: GrantFiled: April 9, 1997Date of Patent: October 10, 2000Assignee: W. R. Grace & Co. -Conn.Inventors: Alan W. Peters, John A. Rudesill, Gordon Dean Weatherbee, Edward F. Rakiewicz, Mary Jane A. Barbato-Grauso, Xinjin Zhao
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Patent number: 6107067Abstract: A porous inorganic oxide carrier body for immobilizing living cells is prepared from inorganic oxide particles such as clay particles. The particles have an average particle size of from 0.01 to 20 microns, and the carrier body has a total pore volume of 0.05 to 1.0 cc/g and an average pore diameter of 50 to 700 .ANG., and has substantially no pore volume in the range of 800 .ANG. or greater. The carrier is prepared by forming a mixture containing the particles, a liquid medium and optional ingredients including zeolite and activated carbon, and forming the mixture into a shaped carrier body which may be optionally dried and calcined. Typical shapes of the carrier include spheres, cylinders, rings, honeycombs and shaped monoliths. Bacteria and other microorganisms immobilized on the carrier are useful for treatment of contaminated waste streams or contaminated vapors, or for other uses for which microorganisms are used such as the synthesis of chemicals.Type: GrantFiled: July 6, 1998Date of Patent: August 22, 2000Assignee: W.R. Grace & Co.-Conn.Inventors: James George Miller, Robert Haywood Bates, deceased, Timothy Allen Boyer, Donald Richard Durham
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Patent number: 6068665Abstract: An improved method for the removal of stains from textiles is disclosed. The method involves the use of novel mixtures of zeolites and imides. The method of the invention provides superior performance in the removal of stains, especially those from animal wastes or fluids. The zeolite/imide mixtures are useful to remove stains from various textile fabrics and fibers, e.g. carpets, clothing, and upholstered goods.Type: GrantFiled: May 24, 1999Date of Patent: May 30, 2000Assignee: OdorPro, Inc.Inventors: Gary J. Calton, John B. Cook
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Patent number: 6066228Abstract: A method for making a honeycomb carrier body and product formed thereby in which a corrugated foil strip is provided having opposite side edges and corrugations oriented at an oblique angle to the side edges. The corrugated foil strip is folded on lines perpendicular to the side edges to provide a core body having fluid passages between opposite ends and a shaped periphery defined by parallel outside folds in the corrugated strip. The core body thus formed is inserted into a jacket tube so that folds at the core body periphery are in compressive contact with the jacket tube, and the periphery of the core body is joined to the jacket tube. Preferably, the corrugated foil strip is coated before the folding step, such as with an oxide layer, a catalytic coating or both, prior to the folding step.Type: GrantFiled: March 26, 1998Date of Patent: May 23, 2000Assignee: Engelhard CorporationInventors: Gordon Wayne Brunson, Bryce Zoccola
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Patent number: 6051529Abstract: A powder composition of ceric oxide and a stabilizing non-noble metal oxide, such as zirconium oxide, mixed at the atomic level in complete solid solution. The powder is used to form washcoats for catalytic converters. The composition has high oxygen storage capacity and maintains an ultrafine crystallite size at high temperatures. The powder is formed by a spray pyrolysis process that includes atomizing a clear solution of cerium ions and ions of the non-noble metal into a fine mist that is passed rapidly through a furnace to form powder particles.Type: GrantFiled: December 10, 1998Date of Patent: April 18, 2000Assignee: W. R. Grace & Co.-Conn.Inventor: Rasto Brezny
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Patent number: 6017531Abstract: Hydrophillic compositions and methods of use are provided for debriding and wound healing applications. The compositions contain certain proteases produced by microorganisms of the genus Vibrio.Type: GrantFiled: June 2, 1997Date of Patent: January 25, 2000Assignees: W. R. Grace & Co., Conn. / Teva Pharmaceuticals USA, Inc.Inventors: Donald Zane Fortney, Donald Richard Durham, Kang Yang
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Patent number: 5985220Abstract: A metal foil has improved resistance to permanent thermal expansion. This metal foil includes a metal foil substrate and a thin barrier layer on at least one surface of the metal foil substrate. The metal foil can be used in a catalyst assembly to provide a catalyst support having improved resistance to permanent thermal expansion. The catalyst assembly includes a metal foil substrate and a thin barrier layer on at least one surface of the metal foil substrate. A catalyst material is provided on at least a portion of the barrier layer. This invention further relates to a method for reducing permanent thermal expansion of a metal foil. This method includes applying a barrier layer coating to at least one surface of a metal foil substrate. The method further can include the step of applying a catalyst material to at least a portion of the barrier layer.Type: GrantFiled: October 2, 1996Date of Patent: November 16, 1999Assignee: Engelhard CorporationInventor: Ernest Wilson Hughes
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Patent number: 5919727Abstract: A powder composition of ceric oxide and a stabilizing non-noble metal oxide, such as zirconium oxide, mixed at the atomic level in complete solid solution. The powder is used to form washcoats for catalytic converters. The composition has high oxygen storage capacity and maintains an ultrafine crystallite size at high temperatures. The powder is formed by a spray pyrolysis process that includes atomizing a clear solution of cerium ions and ions of the non-noble metal into a fine mist that is passed rapidly through a furnace to form powder particles.Type: GrantFiled: November 14, 1996Date of Patent: July 6, 1999Assignee: W. R. Grace & Co.-Conn.Inventor: Rasto Brezny
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Patent number: 5789339Abstract: The present invention generally relates to supported perovskites and their use for low temperature oxidation of volatile oxygen-containing organic compounds, particularly alcohols. The present invention further relates to the use of supported perovskites to reduce the amount of oxygen-containing organic compounds present in waste gases produced by processes such as baking or brewing.Type: GrantFiled: June 7, 1995Date of Patent: August 4, 1998Assignee: W. R. Grace & Co.-Conn.Inventors: Michael S. Ziebarth, Cristian Libanati, Mohit Uberoi
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Patent number: 5780384Abstract: The present invention generally relates to supported mono charged cation delta manganese dioxide hydrate having a noble metal on the surface thereof, and to the use thereof for low temperature oxidation of volatile organic compounds (VOCs), particularly oxygen-containing VOCs. The present invention further relates to the use of the supported catalysts to reduce the amount of VOCs present in waste gases produced by processes such as baking, brewing, and flexographic printing. Catalysts prepared from the supported manganese-containing catalysts have increased resistance to poisoning in the presence of catalyst contaminants, e.g., sulfur containing compounds.Type: GrantFiled: January 3, 1997Date of Patent: July 14, 1998Assignee: Megtec Systems, Inc.Inventors: Douglas Charles Tomczak, Cristian Libanati, Jean Willem Beeckman
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Patent number: 5720796Abstract: A grinding aid and an enhanced roll press method of grinding granulated blast-furnace slag by treating the slag feed of the roll press with from about 0.002 to 0.2 weight percent of polyacrylic acid or its alkali metal salt in combination with up to about 4 weight percent water.Type: GrantFiled: August 8, 1995Date of Patent: February 24, 1998Assignee: W. R. Grace & Co.-Conn.Inventors: Josephine Ho-wah Cheung, James Michael Gaidis
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Patent number: 5657923Abstract: There is provided a process for brazing a first coated part to a second metal part which includes the steps of cleaning or masking, the surfaces of at least the first metal part, interposing a brazing metal foil between the metal parts, and induction heating the assembly to fuse the brazing metal foil, whereby the parts are adhered together, and then cooling. A controlled heating profile is disclosed.Type: GrantFiled: February 1, 1995Date of Patent: August 19, 1997Assignee: W. R. Grace & Co.-Conn.Inventor: David Thomas Sheller
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Patent number: 5651906Abstract: An electrically heatable converter body formed of thin metal core elements and a housing. The thin metal core elements have a distal end and a proximal end. The distal ends are secured to the housing, and at least some, preferably all, of the proximal ends are free of attachment to any rigid member.Type: GrantFiled: July 12, 1995Date of Patent: July 29, 1997Assignee: W. R. Grace & Co.-Conn.Inventors: William A. Whittenberger, David Thomas Sheller
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Patent number: D399036Type: GrantFiled: December 20, 1996Date of Patent: October 6, 1998Inventor: Gayle P. Washington