Abstract: There has been provided an improved reinforcing web for multicellular honeycomb converter core bodies. The reinforcing web contains at least one flat thin metal strip to which is secured at least one corrugated thin metal strip as by brazing or welding. The reinforcing web is located centrally of the core body and gives the converter bodies hereof sufficient axial strength to survive the severe durability tests imposed by the automotive manufacturers.

Abstract: A converter having electrically heatable strips connected in an electrical circuit, and intertwined with non-electricvally heated thin metal strips, having an electrical connection, or anchor, from the electrically heatable thin metal strips to the non-electrically heated thin metal strips, whereby the potential difference between the electrically heatable strips non-electrically heatable thin metal strips is reduced.

Abstract: A synthetic zeolite, designated zeolite GZS-11, is made having a molar composition expressed by the formula:[x M.sub.2/n O+(1.0.+-.0.2-x)R.sub.2/n O]:Y.sub.2 O.sub.3 :y XO.sub.2 :w H.sub.2 Owhere M is an inorganic cation of valance n, R is an organic cation of valence n, "x" has a value of less than 1.0, Y is one or more of +3 valence elements, such as aluminum, boron, gallium, iron, chromium, vanadium, molybdenum, or manganese, X is one or more of +4 valence elements, such as silicon, germanium, or titanium, "y" has a value of between 6 to 25, "w" has a value of up to 4 depending upon the degree of hydration of the zeolite, and having an X-ray diffraction pattern of the as-synthesized zeolite substantially as in Table 1. The method for making the low ratio of XO.sub.2 /Y.sub.2 O.sub.3 such as SiO.sub.2 /Al.sub.2 O.sub.3 is achieved by adjusting the synthesis mixture composition during the aging stage through the addition of one or more of the solutions containing the reactive sources of zeolitic components.

Abstract: Flexible metal foil catalyst members suitable for use in catalytic devices for combustion engine emission control are prepared by electrophoretic deposition using an aqueous slurry of catalyst support particles. The deposited support layer is of uniform thickness and stable surface area. The catalyst support may then be impregnated with catalytic species and assembled into a catalytic device. The catalyst members from the invention are especially suitable for use in automotive applications, and more especially in electrically heated catalytic devices.

Abstract: A curing agent for epoxy resins is prepared from an amine and an epoxy, as well as subsequent modification by a polyisocyanate compound, in such a manner that the curing agent is in the form of small spherical particles. The particles can be as small as 0.1 microns. This curing agent can be easily dispersed in curing agent masterbatches and curable compositions with minimal effect on their storage stability. The resulting curable compositions have a wide range of applications, including automobile and electronic adhesives.

Abstract: Flexible metal foil catalyst members suitable for use in catalytic devices for combustion engine emission control are prepared by electrophoretic deposition using an aqueous slurry of catalyst support particles. The deposited support layer is of uniform thickness and stable surface area. The catalyst support may then be impregnated with catalytic species and assembled into a catalytic device. The catalyst members from the invention are especially suitable for use in automotive applications, and more especially in electrically heated catalytic devices.

Abstract: An alumina sorbent capable of adsorbing NOx and SOx from waste gases and being regenerated by heating above 650.degree. C. is made by incorporating an alumina stabilizing agent into the sorbent. A preferred method is to add the stabilizer when the alumina is precipitated. The precipitated powder is formed subsequently into a slurry, milled and spray dried to form the stabilized spheroidal alumina particles having a particle size of less than 500 microns. These particles are impregnated with an alkali metal or alkaline earth metal to form the stabilized sorbent. Alumina stabilizers include one or more of silica, lanthana, other rare earths, titania, zirconia and alkaline earths.

Abstract: A synthetic zeolite, designated zeolite GZS-11, is made having a molar composition expressed by the formula:[x M.sub.2/n O+(1.0.+-.0.2-x)R.sub.2/n O]:Y.sub.2 O.sub.3 :y XO.sub.2 :wH.sub.2 Owhere M is an inorganic cation of valance n, R is an organic cation of valence n, "x" has a value of less than 1.0, Y is one or more of+3 valence elements, such as aluminum, boron, gallium, iron, chromium, vanadium, molybdenum, or manganese, X is one or more of+4 valence elements, such as silicon, germanium, or titanium, "y" has a value of between 6 to 25, "w" has a value of up to 4 depending upon the degree of hydration of the zeolite, and having an X-ray diffraction pattern of the assynthesized zeolite substantially as in Table 1. The method for making the low ratio of XO.sub.2 /Y.sub.2 O.sub.3 such as SiO.sub.2 /Al.sub.2 O.sub.3 is achieved by adjusting the synthesis mixture composition during the aging stage through the addition of one or more of the solutions containing the reactive sources of zeolitic components.

Abstract: There is provided a novel terminal bus and retainer for a multicellular converter, particularly a catalytic converter, which converter is characterized by an electrically heatable portion and a light-off portion. The electrically heatable portion includes flat thin metal strips as heater bands and flat thin metal bands not electrically heatable. A terminal bus and retainer is adapted to be connected to a voltage source and to the ends of the heater bands. A portion of the terminal bus and retainer may be used as a connector bus. The terminal bus and retainer also retains the thin metal foil elements in tightly spirally wound condition. These devices are especially useful in catalytic converters for automotive vehicles.

Abstract: Porous bodies are produced which are suitable for use as supports for catalysts, including living cells, such as bacteria and which are upset resistant to acids and bases. The bodies have a significantly large average pore diameter of about 0.5 to 100 microns, (i.e. 5,000 to 1,000,000 .ANG.) and a total pore volume of about 0.1 to 1.5 cc/g with the large pores contributing a pore volume of from about 0.1 to 1.0 cc/g. The bodies are made by preparing a mixture of ultimate particles containing a zeolite and one or more optional ingredients such as inorganic binders, extrusion or forming aids, burnout agents, or a forming liquid, such as water. In a preferred embodiment, the ultimate particles are formed by spray drying.

Abstract: There is provided an improved core element for use in converters, especially catalytic converters. The core is characterized by two portions one of which portions is capable of being electrically heated, and the other of which is isolated from the first portion electrically and thermally and is called a light-off portion. A plurality of core elements is wrapped about a central rigid metallic pin and the assembly tightly spirally wound about the pin to form the core, part of which is electrically heatable and the other of which is not heated electrically. The core is formed from a plurality of composite core elements, each including a corrugated strip backed up with a flat two-member strip, one band of the two-member flat strip being of generally relatively narrow width, contiguous with the leading portion of the corrugated strip, and the other band contiguous with the trailing portion of the corrugated strip and usually being of relatively greater width.

Abstract: There has been provided a process for spot welding a stack of thin metal strips or layers with a non-depositing welder gun. The process involves forming a stack of thin metal layers, compressing the layers between the jaws of a press, one of which has at least one receptacle for and adapted to receive the non-depositing welder gun tip, placing the gun in the receptacle, optionally flooding with an inert gas, and applying electrical power to the gun for a period of from 1 to 10 seconds. The process is especially useful in the formation of a stack of thin metal strips for making a multicellular honeycomb converter body for removing pollutants from the exhaust of an internal combustion engine.

Abstract: A bioremediation support for the support of microorganisms used in the biotreatment of an aqueous waste stream or contaminated vapor is made of a low-density siliceous glassy material. This material has a cellular or frothy texture, large pores of greater than 1,000 Anstrom units in diameter dispersed throughout the material, a high macropore volume in pores of greater than 1,000 .ANG. of more than 0.3 cc/cc and a BET surface area of greater than 10 m.sup.2 /g. A preferred material is pumice.

Abstract: A method and apparatus for reducing the emissions from a thermal oxidizer for volatile organic compounds (VOC) containing waste gases. The waste gas is treated in a thermal reactor and either before, in or after the thermal reactor the waste gas is contacted with a catalyzed surface device in the gas stream within the thermal oxidizer. The catalyzed surface device has a catalyzed surface which contacts the waste gas and further oxidizes the waste gas.

Abstract: There is provided an improved converter body core element having a corrugated thin metal strip having, parallel to and close to a longitudinal marginal edge thereof, a recess dimensioned and configured to receive a heater band. In specific embodiments, the heater band is desirably lightly corrugated, i.e., having an amplitude of the corrugations which is from one tenth to one third the amplitude of the corrugations in the strip containing the recess, and the heater band is dimensioned and configured to fit into the recess.

Abstract: There is provided an electrically heatable converter body including a multicellular metallic honeycomb characterized by a plurality of first thin metal strips and a plurality of second thin metal strips in layered alternating relation, and wherein the first thin metal strips have a leading edge portion and a trailing edge portion, the leading edge portion of the first thin metal strips being longer than the trailing edge of said first thin metal strips.

Abstract: There is provided an improved combined electrically heatable and light-off converter which is characterized by an integral intertwining structure wherein thin metal strips form a multicellular converter body. A first plurality of the thin metal strips extend the entire axial length of the converter body and are usually corrugated, and a second plurality of thin metal strips usually flat, alternating with the first plurality, extend less than the full axial length of the converter body.

Abstract: A method of making a novel structure for the first stage of a multiple-stage combustion, in which a metal strip is coated with a catalyst on only one side. The strip is also corrugated with a herringbone pattern. The strip is then folded back and forth upon itself to form a reactor of a desired cross-section. The reactor has rows of channels that are formed between the layers of the metal. The single coated side of the metal defines the walls of the channels in every other row. The fuel-air mixture that flows through the coated channels is combusted. The fuel-air mixture that flows through the uncoated channels is not combusted, and cools the catalyzed surfaces. The herringbone corrugations prevent the layers of metal from nesting together, and also define zigzag paths for flow of combustion gas. The one or more stages subsequent to the ignition stage can employ a catalyst capable of operating at the very high temperatures present in gas turbines. The subsequent stages can also be non-catalytic.

Abstract: An improved converter having electrically heatable strips connected in an electrical circuit, and intertwined with non-electricvally heated thin metal strips, having an electrical connection, or anchor, from the electrically heatable thin metal strips to the non-electrically heated thin metal strips, whereby the potential difference between the electrically heatable strips non-electrically heatable thin metal strips is reduced.

Abstract: A method and apparatus for reducing the emissions from a thermal oxidizer for volatile organic compounds (VOC) containing waste gases. The waste gas is treated in a thermal reactor and either before, in or after the thermal reactor the waste gas is contacted with a catalyzed surface device in the gas stream within the thermal oxidizer. The catalyzed surface device has a catalyzed surface which contacts the waste gas and further oxidizes the waste gas.