Abstract: Oxidizing agents are added to slurries of inorganic oxides which have been heated, e.g., autoclaved, to produce abrasive slurries which impart relatively equal polishing rates for conductive metal and insulating layers used to make semiconductor chips. A relatively flexible abrasive slurry in terms of its abrasivity is also provided by this slurry, thereby permitting the modification of a copper polishing slurry's abrasivity when a new insulating material is used to make a chip. When using this method, an increase in particle abrasivity of this slurry can be correlated with a decrease in particle surface area as determined by N2 adsorption (BET method) and abrasivity can be increased (or decreased) by heating the slurry to produce particles with a surface area determined to have the abrasivity desired.

Abstract: Silica compositions for abrasive systems in dentifrice formulations are disclosed. The silica abrasive system comprises (a) silica gels having a median particle size below 7 microns, a pH of from about 6 to about 11 and powder RDA's of from 100 to about 200 and (b) silica gels or precipitates having a median particle size of 7 microns or greater and powder RDA's of from 50 to about 180. Silica (a) is preferably prepared by contacting a hydrous silica gel with an alkaline medium. Dentifrice compositions comprising the abrasive system has an RDA of 150 or less and PCR's of at least 80 and up to about 150, and an REA of less than about 30 (as measured on the IU scale).

Abstract: A dispersion comprising fine porous inorganic oxide particles, e.g., silica gel particles, wherein the particles have a median particle size below three microns. The dispersed particles have a porosity after drying in which at least about 0.50 cc/g of pore volume is from pores having a pore size of 600 Å or less as determined by nitrogen porosimetry. Embodiments prepared from silica gel have porosity after drying in which at least about 0.7 cc/g of pore volume is from pores having a diameter of 600 Å or smaller. The particles of the dispersion also can be described as having viscosity derived pore volume of at least about 0.5 g/cc. The dispersion is prepared by forming a dispersion from inorganic oxides having sufficient rigid structure to maintain porosity after milling and drying. After the inorganic oxide is selected, it is milled to have a median particle size of 0.05 to about 3 microns.

Abstract: Autoclaving slurries of porous, inorganic oxide particles results in an increased abrasiveness of the particles as reflected in increased removal rates of a polished substrate at standard polishing conditions in chemical mechanical polishing operations. Slurries having novel abrasion properties, especially for silica-based slurries, are created. The increase in particle abrasivity strongly correlates with a decrease in particle surface area as determined by N2 adsorption (BET method). As a result, methods for obtaining a desired abrasivity for a slurry can be practiced by heating a slurry of inorganic oxide particles to a BET surface area previously identified as associated with the abrasivity desired. The resulting slurries can be used in conventional polishing machinery. The method is particularly suitable for preparing silica-based abrasive slurries.

Abstract: Adsorbent particles comprising superparamagnetic and/or low Curie Temperature transition metal-containing cores surrounded by a hydrous siliceous oxide coating can be formed by an aqueous process wherein the core is precipitated from an aqueous solution and a siliceous oxide coating is deposited thereon while complete drying of the core is avoided until after the siliceous oxide is deposited. The resulting siliceous adsorbents exhibit strong superparamagnetic and/or low Curie temperature magnetic properties with low transition metal leachability.

Abstract: The present invention relates to an integrated additive composition which contains anti-blocking agents and at least one organic component and is characterized in that the organic component(s) is (are) localized in a concentration of 5 to 65 wt.-%, relative to the total weight of the composition, in the pores of the anti-blocking agent, the volume of the organic component(s) not being greater, however, than the pore volume of the anti-blocking agent. The invention also describes processes for the preparation of this integrated additive composition and its use in polyolefin films and in injection molding.

Abstract: Silica compositions for abrasive systems in dentifrice formulations are disclosed. The silica abrasive system comprises (a) silica gels having a median particle size below 7 microns, a pH of from about 6 to about 11 and powder RDA's of from 100 to about 200 and (b) silica gels or precipitates having a median particle size of 7 microns or greater and powder RDA's of from 50 to about 180. Silica (a) is preferably prepared by contacting a hydrous silica gel with an alkaline medium. Dentifrice compositions comprising the abrasive system has an RDA of 150 or less and PCR's of at least 80 and up to about 150, and an REA of less than about 30 (as measured on the IU scale).

Abstract: Autoclaving slurries of porous, inorganic oxide particles results in an increased abrasiveness of the particles as reflected in increased removal rates of a polished substrate at standard polishing conditions in chemical mechanical polishing operations. Slurries having novel abrasion properties, especially for silica-based slurries, are created. The increase in particle abrasivity strongly correlates with a decrease in particle surface area as determined by N2 adsorption (BET method). As a result, methods for obtaining a desired abrasivity for a slurry can be practiced by heating a slurry of inorganic oxide particles to a BET surface area previously identified as associated with the abrasivity desired. The resulting slurries can be used in conventional polishing machinery. The method is particularly suitable for preparing silica-based abrasive slurries.

Abstract: The incorporation of waxes into thermoplastic adsorbent compositions enables the formation of high adsorbent loading compositions which have suitable flowability properties. The wax-containing thermoplastic adsorbent compositions are especially useful as thermoplastic adsorbent adhesives for use in desiccating interior compartments of insulating glass units.

Abstract: A substantially solvent-free molten or fluid desiccant/organic matrix composition is adhered to a package whereby the desiccant is in communication with a compartment of the resulting package such that the compartment is desiccated by the desiccant composition. The desiccant composition preferably contains a thermoplastic organic matrix, is heated before it is adhered to the package, and cools after application. In some instances, the desiccant matrix may be adhered to a component of the package contents. The package is preferably non-reclosable and suitable for holding an article such as a drug, medical device or electronic device.

Abstract: The invention relates to an aggregated silica gel which has been produced from silica gel particles having a particle size of 1 to 20.mu., a surface of 200 to 1000 m.sup.2 /g and a specific pore volume of 0.4 to 2.5 ml/g and a binding agent selected from synthetic or natural phyllosilicate, pyrogenic silicon dioxide and organic polymers soluble in water or dispersible in water. Aggregation takes place by spray-drying a suspension having 1 to 25% solids. The product is suitable as a matting agent for coatings, as an antiblocking agent for polymer films and as a beer clarifying agent.

Abstract: Effective anti-corrosive pigments are obtained using basic or neutral to basic polyvalent metal organophosphonates. The anti-corrosive organophosphonate pigments may optionally contain a co-acidic substance such as silica. The organophosphonate pigments provide ant-corrosive protection comparable to traditional pigments while enabling the avoidance of heavy metals.

Abstract: An anti-blocking agent comprising silicon dioxide or mixtures of silicon dioxide and zeolite is described, which is characterized in that it has a bimodal pore size distribution, the first maximum of the bimodal pore size distribution being in the pore size range <5 nm and the second maximum of the bimodal pore size distribution in the pore size range >6 nm. The anti-blocking agent is obtainable by micronizing a mixture comprising silicon dioxide of a certain pore size and silicon dioxide and/or zeolite having a different pore size. It can be produced together with lubricating agent as a combined anti-blocking and lubricating agent. Incorporation of the anti-blocking agent or of the combined anti-blocking agent and lubricating agent into a polymer in the form of a master batch is preferable.

Abstract: High potassium zeolite A particles are used to overcome problems of zeolite degassing (and/or undesired gas adsorption/desorption), especially when loaded into organic matrices. The zeolite A particles preferably have a potassium content (measured as K.sub.2 O) of at least about 14 wt. %, more preferably 15-25 wt. %. Compositions containing the high potassium zeolite A in an organic matrix may be especially suitable for use in insulating glass window spacer applications. The high potassium zeolite A may also be used in other conventional desiccant forms.

Abstract: Compositions which contain a titania component have been found which provide reduction of sulfar levels in the gasoline resulting from FCC processes (and other cracking processes conducted in the absence of added hydrogen) without the need for feedstock pretreatments nor added hydrogen. The compositions preferably also contain an alumina supported Lewis acid component. These compositions are preferably used as particles in admixture with catalytic cracking catalyst particles in the circulating catalyst inventory.

Abstract: Crystalline molecular sieves which comprise mostly single and/or twinned crystal particles can be loaded into organic matrices in comparatively high amounts with less viscosity buildup than molecular sieves conventionally used for such desiccant applications. Desiccant/organic matrix compositions made with the single and/or twinned crystal zeolites exhibit improved physical integrity and/or improved rheological and adsorption characteristics in comparison to conventional systems. The compositions are especially useful in insulated glass window spacer applications.

Abstract: Crystalline molecular sieves which comprise mostly single and/or twinned crystal particles can be loaded into organic matrices in comparatively high amounts with less viscosity buildup than molecular sieves conventionally used for such desiccant applications. Desiccant/organic matrix compositions made with the single and/or twinned crystal zeolites exhibit improved rheological and adsorption characteristics in comparison to conventional systems. The compositions are especially useful in insulated glass window spacer applications.

Abstract: Polymer-bound adsorbent beads are usable as a direct replacement for conventional clay-bound beads in insulating glass unit manufacture to eliminate the problem of dusting associated with conventional beads. Polymer-bound beads provide good adsorption and superior crush strength compared to clay-bound adsorbent beads previously used in insulating glass units to desiccate the space between the glass panes. The polymer-bound adsorbent beads may also be used as a substitute for conventional desiccant beads in water adsorption applications such as in bottle stoppers, sachets, blister packaging, etc.

Abstract: Siliceous oxides having a combination of low total volatiles content and basic pH are useful as odor control agents in organic resin systems, especially polyolefin-based systems. These modified siliceous oxides advantageously reduce odor and off-trade while minimizing discoloration of the resin. The adsorbents are especially useful for resin systems containing fatty acid amide slip aids.

Abstract: Amide-containing polymers characterized by the presence of piperazine amide and/or substituted piperazine amide in the polymer chain are used as adsorbents to remove polyphenolic compounds from liquids. The compositions are especially useful in combination with protein removal agents such as silica gel or tannin. The amide-containing polymer compositions (alone or in combination with protein removal agents) are especially useful in the stabilization and/or chillproofing of plant derived liquids or beverages such as beer, wine, fruit juice and vegetable juice.