Abstract: An anti-blocking agent comprising silicon dioxide or mixtures of silicon dioxide and zeolite is described, which is characterized in that it has a bimodal pore size distribution, the first maximum of the bimodal pore size distribution being in the pore size range<5 nm and the second maximum of the bimodal pore size distribution in the pore size range>6 nm. The anti-blocking agent is obtainable by micronizing a mixture comprising silicon dioxide of a certain pore size and silicon dioxide and/or zeolite having a different pore size. It can be produced together with lubricating agent as a combined anti-blocking and lubricating agent. Incorporation of the anti-blocking agent or of the combined anti-blocking agent and lubricating agent into a polymer in the form of a master batch is preferable.
Type:
Grant
Filed:
June 6, 1995
Date of Patent:
August 11, 1998
Assignee:
Grace GmbH
Inventors:
Richard Sobuttka, Georg Luers, Andreas Schmidt
Abstract: Epoxy-polymerized tannin/inorganic oxide composite particles are obtained by polymerizing the tannin with a polyepoxy crosslinking agent in situ on inorganic oxide particles. The compositions of the invention are capable of achieving the performance of tannin in beverage treatment applications without tannin's associated filtration disadvantages.
Abstract: High potassium zeolite A particles are used to overcome problems of zeolite degassing (and/or undesired gas adsorption/desorption), especially when loaded into organic matrices. The zeolite A particles preferably have a potassium content (measured as K.sub.2 O) of at least about 14 wt. %, more preferably 15-25 wt. %. Compositions containing the high potassium zeolite A in an organic matrix may be especially suitable for use in insulating glass window spacer applications. The high potassium zeolite A may also be used in other conventional desiccant forms.
Abstract: The present invention is directed to an imidized polycarboxylic acid polymer useful as a cement admixture, to improved cement compositions containing said polymer and to a process of forming the same.
Type:
Grant
Filed:
July 3, 1996
Date of Patent:
March 17, 1998
Assignee:
W.R. Grace & Co.-Conn.
Inventors:
Ahmad Arfaei, David Charles Darwin, Ellis Martin Gartner, Byong-Wa Chun, Hideo Koyata, Lawrence Lu Kuo
Abstract: Interpenetrating network polymers (IPN's) are made by admixing polyols, polyisocyanate, and a poly(vinylchloride) plastisol, followed by heating to complete the cure. The resulting polyurethane/poly(vinylchloride) IPN has superior properties as sealant, especially for automotive parts.
Type:
Grant
Filed:
July 10, 1990
Date of Patent:
February 25, 1992
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Norman E. Blank, RIchard C. Hartwig, Cung Vu
Abstract: Reactive hot melt structural adhesives comprising urethane oligomer and epoxy mixture in specified ratios. The compositions offer very high shear, peel, and impact strengths, properties of particular value in bonding adherends in an auto body assembly line.
Abstract: A polyol is reacted with a polyisocyanate prepolymer to make a polyurethane. The polyol is the reaction product of trimethylol propane with ethylene oxide (1:3 molar). The polyisocyanate prepolymer is the reaction product of poly(ethylene adipate) with MDI. The novel polyurethane is stable in both aliphatic and aromatic hydrocarbons and is especially useful in bonding together laminates of nylon-supported permeable membranes. The laminates are used in modules for separation of hydrocarbon-containing gases.
Abstract: A method of preparing a hydrophilic, biocompatible contact lens characterized by a surface which resists nonspecific protein adsorption. The method involves forming a prepolymer, at least 75% of which are oxyethylene-based diols and polyols having molecular weights of about 7000 to about 30,000. The prepolymer is subsequently gelled and hydrated to produce a hydrated polyurea-polyurethane polymer gel. The hydrated polymer gel is used to obtain a contact lens which resists nonspecific protein adsorption. Preferably, the contact lens are prepared by molding the prepolymer into a contact lens mold, prior to polymerization, to achieve the desired lens shape.
Abstract: Poly(vinyl chloride) plastisol compositions modified with epoxy and acid anhydrides can be painted wet-on-wet with acid catalyzed, high solids enamel paints, followed by curing at 120.degree. C. or lower, to give strongly adherent products on electrodeposition coatings and dry, tack-free painted surface. The compositions are also stabilized by the addition of an imide, which provides storage stability at 40.degree. C. for more than three days.
Abstract: The component polyol/polyisocyanate composition useful in forming an abrasion resistant polyurethane automotive undercoating. The polyol component is unmodified castor oil or castor oil modified with cyclohexanone-formaldehyde condensate. The modified castor oil may be further modified by adding the reaction product of neopentyl glycol and adipic acid. The polyisocyanate component comprises an MDI-based mixture containing polyisocyanate prepolymers based on alkylene oxides.
Abstract: Novel reactive hot melt structural adhesives comprising urethane oligomer and epoxy mixture in specified ratios. The compositions offer very high shear, peel, and impact strengths, properties of particular value in bonding adherends in an auto body assembly line.
Abstract: Poly(vinyl chloride) plastisol compositions modified with epoxy and acid anhydrides can be painted wet-on-wet with acid catalyzed, high solids enamel paints, followed by curing at 120.degree. C. or lower, to give strongly adherent products on electrodeposition coatings and dry, tack-free painted surface. The compositions are also stabilized by the addition of an imide, which provides storage stability at 40.degree. C. for more than three days.
Abstract: Modified hydrophilic prepolymers and polymers are disclosed wherein the prepolymers and polymers are characterized by cell growth enhancement, and, in some instances, antibody production stimulation. Isocyanate-capped oxyethylene-based prepolymers are modified by reaction with a compound having at least one isocyanate (NCO) reactive group. Preferably, the NCO reactive group is a sulfhydryl group, an amino group or a carboxyl group, in quantities sufficient to modify at least a portion of the isocyanate groups of the prepolymer. The prepolymer and polymer also express a free functional group, preferably an amino, sulfonic acid or a sulfhydryl. When the free functional group is sulfhydryl or sulfonic acid, antibody production stimulation, as well as cell growth enhancement, is observed.
Type:
Grant
Filed:
March 3, 1989
Date of Patent:
May 29, 1990
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Aaron H. Heifetz, Richard A. Wolfe, James A. Braatz, Narender P. Luthra
Abstract: A process and apparatus for an electrostatic spray coating operation wherein liquid overspray in the spray coating operation is collected and drained onto a workpiece support. The overspray is then removed from the workpiece support by a squeegee blade wherein the collected overspray is drained into a sump. From the sump, the spray, and optionally with makeup liquid, is recycled to the spray head.
Abstract: Hydrophilic polymeric soft contact lenses which are characterized by their biocompatibility and resistance to nonspecific protein adsorption. At least 75%, preferably at least 80%, of the prepolymers from which the lenses are prepared are isocyanate-capped oxyethylene-based diols or polyols having molecular weight of about 7000-30,000. Essentially all of the hydroxyl groups of the diols or polyols are capped with polyisocyanate prior to formation of the hydrated polymer of which the contact lenses are made.
Abstract: Novel polyurethane formulations especially useful as membranes for the protection of bridge deckings. The polyurethane is prepared by mixing two components, A and B. Component A comprises castor oil, a low molecular weight polyol having a molecular wieght between 92 and about 200, preferably with an elastomer. Component B is a modified MDI, being either (i) a mix of 4,4'- and 2,4'-isomers of diphenylmethane diisocyanate or (ii) a diphenylmethane diisocyanate and its reaction product with a low molecular weight poly(oxyalkylene).
Type:
Grant
Filed:
May 19, 1988
Date of Patent:
October 31, 1989
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Cung Vu, Timothy J. Martin, Andrew M. Gillanders, Bassam Sbaiti
Abstract: Novel polyurethane formulations especially useful as membranes of the protection of bridge deckings. The polyurethane is prepared by mixing two components, A and B. Component A comprises castor oil modified with a ketone-formaldehyde condensate and also preferably contains an elastomer. Component B is a modified MDI, being a mixture of diphenylmethane diisocyanate and its reaction product with a low molecular weight poly(oxyalkylene).
Abstract: Novel polyurethane formulations especially useful as membranes for the protection of bridge deckings. The polurethane is prepared by mixing two components, A and B. Component A consists essentially of a low-molecular weight polyol, e.g., glycerol; a poly(oxypropylene) triol; and an elastomer. Component B is a special MDI, either a mix of 4,4'- and 2,4'-isomers of diphenylmethane diisocyanate or a mix of 4,4'-diphenylmethane diisocyanate and its reaction product with a low molecular weight poly(oxypropylene).
Type:
Grant
Filed:
June 15, 1988
Date of Patent:
August 8, 1989
Assignee:
W. R. Grace & Co.-Conn.
Inventors:
Cung Vu, Susan P. Buxbaum, Norman E. Blank, Richard C. Hartwig
Abstract: 1-Cyanoethylimidazoles are hydrogenated to provide the correspondng 1-aminopropylimidazoles, e.g., an ethanol solution of 1-cyanoethyl-2-ethyl-4-methylimidazole is hydrogenated at 1000 psi using Raney nickel catalyst to prepare 1-aminpropyl-2-ethyl-4-methylimidazole, useful as an intermediate in the preparation of epoxy accelerators.
Abstract: Two-component polyol/polyisocyanate composition especially useful as an abrasion-, heat-, and corrosion-resistant automotive undercoating. The polyol component comprises glycerol, a polypropylene oxide glycol, and a polypropylene oxide triol. The polyisocyanate component comprises MDI (diphenylmethane-4,4'-diisocyanate), plus a poly(oxypropylene) glycol capped with MDI.