Patents Represented by Attorney, Agent or Law Firm Charles A. Cross
  • Patent number: 5792808
    Abstract: An anti-blocking agent comprising silicon dioxide or mixtures of silicon dioxide and zeolite is described, which is characterized in that it has a bimodal pore size distribution, the first maximum of the bimodal pore size distribution being in the pore size range<5 nm and the second maximum of the bimodal pore size distribution in the pore size range>6 nm. The anti-blocking agent is obtainable by micronizing a mixture comprising silicon dioxide of a certain pore size and silicon dioxide and/or zeolite having a different pore size. It can be produced together with lubricating agent as a combined anti-blocking and lubricating agent. Incorporation of the anti-blocking agent or of the combined anti-blocking agent and lubricating agent into a polymer in the form of a master batch is preferable.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 11, 1998
    Assignee: Grace GmbH
    Inventors: Richard Sobuttka, Georg Luers, Andreas Schmidt
  • Patent number: 5789467
    Abstract: Epoxy-polymerized tannin/inorganic oxide composite particles are obtained by polymerizing the tannin with a polyepoxy crosslinking agent in situ on inorganic oxide particles. The compositions of the invention are capable of achieving the performance of tannin in beverage treatment applications without tannin's associated filtration disadvantages.
    Type: Grant
    Filed: June 28, 1996
    Date of Patent: August 4, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Demetrius Michos
  • Patent number: 5773380
    Abstract: High potassium zeolite A particles are used to overcome problems of zeolite degassing (and/or undesired gas adsorption/desorption), especially when loaded into organic matrices. The zeolite A particles preferably have a potassium content (measured as K.sub.2 O) of at least about 14 wt. %, more preferably 15-25 wt. %. Compositions containing the high potassium zeolite A in an organic matrix may be especially suitable for use in insulating glass window spacer applications. The high potassium zeolite A may also be used in other conventional desiccant forms.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: June 30, 1998
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: James Neil Pryor
  • Patent number: 5728207
    Abstract: The present invention is directed to an imidized polycarboxylic acid polymer useful as a cement admixture, to improved cement compositions containing said polymer and to a process of forming the same.
    Type: Grant
    Filed: July 3, 1996
    Date of Patent: March 17, 1998
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Ahmad Arfaei, David Charles Darwin, Ellis Martin Gartner, Byong-Wa Chun, Hideo Koyata, Lawrence Lu Kuo
  • Patent number: 5091455
    Abstract: Interpenetrating network polymers (IPN's) are made by admixing polyols, polyisocyanate, and a poly(vinylchloride) plastisol, followed by heating to complete the cure. The resulting polyurethane/poly(vinylchloride) IPN has superior properties as sealant, especially for automotive parts.
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: February 25, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Norman E. Blank, RIchard C. Hartwig, Cung Vu
  • Patent number: 5079094
    Abstract: Reactive hot melt structural adhesives comprising urethane oligomer and epoxy mixture in specified ratios. The compositions offer very high shear, peel, and impact strengths, properties of particular value in bonding adherends in an auto body assembly line.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: January 7, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Michael E. Kimball
  • Patent number: 5041517
    Abstract: A polyol is reacted with a polyisocyanate prepolymer to make a polyurethane. The polyol is the reaction product of trimethylol propane with ethylene oxide (1:3 molar). The polyisocyanate prepolymer is the reaction product of poly(ethylene adipate) with MDI. The novel polyurethane is stable in both aliphatic and aromatic hydrocarbons and is especially useful in bonding together laminates of nylon-supported permeable membranes. The laminates are used in modules for separation of hydrocarbon-containing gases.
    Type: Grant
    Filed: June 12, 1989
    Date of Patent: August 20, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Cung Vu, Jalandar Y. Jadhay
  • Patent number: 5039458
    Abstract: A method of preparing a hydrophilic, biocompatible contact lens characterized by a surface which resists nonspecific protein adsorption. The method involves forming a prepolymer, at least 75% of which are oxyethylene-based diols and polyols having molecular weights of about 7000 to about 30,000. The prepolymer is subsequently gelled and hydrated to produce a hydrated polyurea-polyurethane polymer gel. The hydrated polymer gel is used to obtain a contact lens which resists nonspecific protein adsorption. Preferably, the contact lens are prepared by molding the prepolymer into a contact lens mold, prior to polymerization, to achieve the desired lens shape.
    Type: Grant
    Filed: November 7, 1989
    Date of Patent: August 13, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: James A. Braatz, Clifton L. Kehr
  • Patent number: 5032432
    Abstract: Poly(vinyl chloride) plastisol compositions modified with epoxy and acid anhydrides can be painted wet-on-wet with acid catalyzed, high solids enamel paints, followed by curing at 120.degree. C. or lower, to give strongly adherent products on electrodeposition coatings and dry, tack-free painted surface. The compositions are also stabilized by the addition of an imide, which provides storage stability at 40.degree. C. for more than three days.
    Type: Grant
    Filed: July 12, 1990
    Date of Patent: July 16, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Truc-Chi Huynh-Tran
  • Patent number: 5021535
    Abstract: The component polyol/polyisocyanate composition useful in forming an abrasion resistant polyurethane automotive undercoating. The polyol component is unmodified castor oil or castor oil modified with cyclohexanone-formaldehyde condensate. The modified castor oil may be further modified by adding the reaction product of neopentyl glycol and adipic acid. The polyisocyanate component comprises an MDI-based mixture containing polyisocyanate prepolymers based on alkylene oxides.
    Type: Grant
    Filed: August 31, 1990
    Date of Patent: June 4, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Cung Vu, Norman E. Blank
  • Patent number: 4962138
    Abstract: Novel reactive hot melt structural adhesives comprising urethane oligomer and epoxy mixture in specified ratios. The compositions offer very high shear, peel, and impact strengths, properties of particular value in bonding adherends in an auto body assembly line.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: October 9, 1990
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Michael E. Kimball
  • Patent number: 4959399
    Abstract: Poly(vinyl chloride) plastisol compositions modified with epoxy and acid anhydrides can be painted wet-on-wet with acid catalyzed, high solids enamel paints, followed by curing at 120.degree. C. or lower, to give strongly adherent products on electrodeposition coatings and dry, tack-free painted surface. The compositions are also stabilized by the addition of an imide, which provides storage stability at 40.degree. C. for more than three days.
    Type: Grant
    Filed: May 20, 1988
    Date of Patent: September 25, 1990
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Truc-Chi Huynh-Tran
  • Patent number: 4929706
    Abstract: Modified hydrophilic prepolymers and polymers are disclosed wherein the prepolymers and polymers are characterized by cell growth enhancement, and, in some instances, antibody production stimulation. Isocyanate-capped oxyethylene-based prepolymers are modified by reaction with a compound having at least one isocyanate (NCO) reactive group. Preferably, the NCO reactive group is a sulfhydryl group, an amino group or a carboxyl group, in quantities sufficient to modify at least a portion of the isocyanate groups of the prepolymer. The prepolymer and polymer also express a free functional group, preferably an amino, sulfonic acid or a sulfhydryl. When the free functional group is sulfhydryl or sulfonic acid, antibody production stimulation, as well as cell growth enhancement, is observed.
    Type: Grant
    Filed: March 3, 1989
    Date of Patent: May 29, 1990
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Aaron H. Heifetz, Richard A. Wolfe, James A. Braatz, Narender P. Luthra
  • Patent number: 4888200
    Abstract: A process and apparatus for an electrostatic spray coating operation wherein liquid overspray in the spray coating operation is collected and drained onto a workpiece support. The overspray is then removed from the workpiece support by a squeegee blade wherein the collected overspray is drained into a sump. From the sump, the spray, and optionally with makeup liquid, is recycled to the spray head.
    Type: Grant
    Filed: April 21, 1988
    Date of Patent: December 19, 1989
    Assignee: W. R. Grace & Co.,-Conn.
    Inventor: Robert D. Milliken
  • Patent number: 4886866
    Abstract: Hydrophilic polymeric soft contact lenses which are characterized by their biocompatibility and resistance to nonspecific protein adsorption. At least 75%, preferably at least 80%, of the prepolymers from which the lenses are prepared are isocyanate-capped oxyethylene-based diols or polyols having molecular weight of about 7000-30,000. Essentially all of the hydroxyl groups of the diols or polyols are capped with polyisocyanate prior to formation of the hydrated polymer of which the contact lenses are made.
    Type: Grant
    Filed: February 16, 1989
    Date of Patent: December 12, 1989
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: James A. Braatz, Clifton L. Kehr
  • Patent number: 4877829
    Abstract: Novel polyurethane formulations especially useful as membranes for the protection of bridge deckings. The polyurethane is prepared by mixing two components, A and B. Component A comprises castor oil, a low molecular weight polyol having a molecular wieght between 92 and about 200, preferably with an elastomer. Component B is a modified MDI, being either (i) a mix of 4,4'- and 2,4'-isomers of diphenylmethane diisocyanate or (ii) a diphenylmethane diisocyanate and its reaction product with a low molecular weight poly(oxyalkylene).
    Type: Grant
    Filed: May 19, 1988
    Date of Patent: October 31, 1989
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Cung Vu, Timothy J. Martin, Andrew M. Gillanders, Bassam Sbaiti
  • Patent number: 4859735
    Abstract: Novel polyurethane formulations especially useful as membranes of the protection of bridge deckings. The polyurethane is prepared by mixing two components, A and B. Component A comprises castor oil modified with a ketone-formaldehyde condensate and also preferably contains an elastomer. Component B is a modified MDI, being a mixture of diphenylmethane diisocyanate and its reaction product with a low molecular weight poly(oxyalkylene).
    Type: Grant
    Filed: September 16, 1988
    Date of Patent: August 22, 1989
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Cung Vu
  • Patent number: 4855185
    Abstract: Novel polyurethane formulations especially useful as membranes for the protection of bridge deckings. The polurethane is prepared by mixing two components, A and B. Component A consists essentially of a low-molecular weight polyol, e.g., glycerol; a poly(oxypropylene) triol; and an elastomer. Component B is a special MDI, either a mix of 4,4'- and 2,4'-isomers of diphenylmethane diisocyanate or a mix of 4,4'-diphenylmethane diisocyanate and its reaction product with a low molecular weight poly(oxypropylene).
    Type: Grant
    Filed: June 15, 1988
    Date of Patent: August 8, 1989
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Cung Vu, Susan P. Buxbaum, Norman E. Blank, Richard C. Hartwig
  • Patent number: 4816589
    Abstract: 1-Cyanoethylimidazoles are hydrogenated to provide the correspondng 1-aminopropylimidazoles, e.g., an ethanol solution of 1-cyanoethyl-2-ethyl-4-methylimidazole is hydrogenated at 1000 psi using Raney nickel catalyst to prepare 1-aminpropyl-2-ethyl-4-methylimidazole, useful as an intermediate in the preparation of epoxy accelerators.
    Type: Grant
    Filed: August 6, 1987
    Date of Patent: March 28, 1989
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Shiow-Ching Lin, Jennifer M. Quirk
  • Patent number: 4804734
    Abstract: Two-component polyol/polyisocyanate composition especially useful as an abrasion-, heat-, and corrosion-resistant automotive undercoating. The polyol component comprises glycerol, a polypropylene oxide glycol, and a polypropylene oxide triol. The polyisocyanate component comprises MDI (diphenylmethane-4,4'-diisocyanate), plus a poly(oxypropylene) glycol capped with MDI.
    Type: Grant
    Filed: September 25, 1987
    Date of Patent: February 14, 1989
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Cung Vu, Richard C. Hartwig