Patents Represented by Attorney David M. Weisberg
  • Patent number: 7241713
    Abstract: This invention provides methods of making molecular sieve catalyst particles, molecular sieve slurries that can be used in such methods, molecular sieve catalyst compositions and their use in catalytic hydrocarbon conversion processes. In one of its aspects, the invention provides a method of making molecular sieve catalyst particles, the method comprising the steps of: a) providing a solution or suspension of an aluminum-containing inorganic oxide precursor in a liquid medium; b) combining the solution or suspension of aluminum-containing inorganic oxide precursor with a molecular sieve, and optionally other formulating agents, to form a catalyst formulation slurry; c) aging the catalyst formulation slurry to generate in said slurry a percentage, or increase in said slurry the existing percentage, of aluminum atoms of the aluminum-containing precursor in the form of oligomers having a sharp 27Al NMR peak at 62-63 ppm; and d) forming molecular sieve catalyst particles from the catalyst formulation slurry.
    Type: Grant
    Filed: October 2, 2003
    Date of Patent: July 10, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Yun-Feng Chang, Stephen N. Vaughn, Kenneth R. Clem, Luc R. Martens, Weiguo Hu
  • Patent number: 7232787
    Abstract: The invention is directed to a method of synthesizing a molecular sieve. In particular, the invention is directed to a method for synthesizing a molecular sieve, especially a silicoaluminophosphate molecular sieve, in the presence of a templating agent and a polymeric base. The invention is also directed to formulating the molecular sieve into a catalyst useful in a process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
    Type: Grant
    Filed: October 22, 2003
    Date of Patent: June 19, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Guang Cao, Matu J. Shah
  • Patent number: 7230151
    Abstract: This invention is to a process of making olefin, particularly ethylene and propylene, from an oxygenate feed. The invention uses two or more zeolite catalysts. Examples of zeolite catalysts include a first catalyst containing of ZSM-5, and a second catalyst containing a 10-ring molecular sieve, including but not limited to, ZSM-22, ZSM-23, ZSM35, ZSM-48, and mixtures thereof. The ZSM-5 can be unmodified, phosphorous modified, steam modified having a micropore volume reduced to not less than 50% of that of the unsteamed ZSM-5, or various mixtures thereof.
    Type: Grant
    Filed: July 15, 2004
    Date of Patent: June 12, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Luc R. M. Martens, Keith H. Kuechler, James R. Lattner
  • Patent number: 7223896
    Abstract: This invention provides processes for maintaining a desired particle size distribution in an oxygenate to olefin reaction system. In one embodiment, the invention comprises replacing lost catalyst fines with less active co-catalyst particles. By adding less active co-catalyst particles to the reaction system, desirable fluidization characteristics and hydrodynamics can be maintained without affecting the overall (or primary catalyst) performance and product selectivities. The invention is also directed to a population of catalyst particles having a desirable particle size distribution well-suited for realizing ideal fluidization and hydrodynamic characteristics.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: May 29, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Luc R. M. Martens, James R. Lattner, Rutton D. Patel, David C. Skouby, Stephen Neil Vaughn, Yun-feng Chang, Jesse F. Goellner, Mareel J. Janssen, Richard C. Senior
  • Patent number: 7214844
    Abstract: The invention relates to a molecular sieve catalyst composition, to a method of making or forming the molecular sieve catalyst composition, and to a conversion process using the catalyst composition. In particular, the invention is directed to a making a molecular sieve catalyst composition by forming a slurry by combining a molecular sieve, a binder and a matrix material, wherein the slurry has a pH, above or below the isoelectric point of the molecular sieve. The catalyst composition has improved attrition resistance, particularly useful in a conversion process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
    Type: Grant
    Filed: January 20, 2005
    Date of Patent: May 8, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Yun-feng Chang, Stephen N. Vaughn, Luc R. M. Martens, Joseph E. Baumgartner, Stuart L. Soled, Kenneth R. Clem