Abstract: A storable, substantially water-free flowable surfactant mixture containing 40% by weight to 70% by weight of a nonionic surfactant of the formula R.sup.1 --(OC.sub.2 H.sub.4).sub.n --OH wherein R.sup.1 is an alkyl or alkenyl group containing 10 to 20 carbon atoms and an average degree of ethoxylation n of from 1 to 8; 20% by weight to 50% by weight of a nonionic surfactant, liquid at room temperature, of the formula: R.sup.2 --(OC.sub.2 H.sub.4).sub.r --(OC.sub.3 H.sub.6).sub.p --OH wherein R.sup.2 is an alkyl or alkenyl group containing 10 to 20 carbon atoms, an average degree of ethoxylation r of from 2 to 8 and an average degree of propoxylation p of from 1 to 6; and 1% by weight to 10% by weight of a C.sub.10 to C.sub.22 carboxylic acid and/or alkali metal salts thereof. The flowable surfactant mixture provides a base for forming a pseudo-plastic detergent formulation.
Type:
Grant
Filed:
April 18, 1996
Date of Patent:
July 27, 1999
Assignee:
Henkel-Ecolab GmbH & Co. OHG
Inventors:
Hans-Josef Beaujean, Thomas Merz, Erich Holz, Thomas Holderbaum, Guenther Amberg, Khalil Shamayeli, Michael Marschner, Hubert Harth
Abstract: An alkaline cleaning composition containing: (a) from about 0.01 to about 50% by weight of an alkyl polyglycoside of formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is a divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6; (b) from about 0.05 to about 20% by weight of a silicate component; (c) from about 0.01 to about 5% by weight of a chelating agent consisting of hydroxyethylidene diphosphonic acid; and (d) remainder, water, all weights being based on the weight of the composition.
Abstract: An adjuvant containing: (a) a sulfated alkyl oleate; (b) an alkyl polyglycoside corresponding to formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is a divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6; and (c) an alkyl ester.
Abstract: A pearlescent concentrate containing: (a) a pearlescent agent; (b) a cocamide monoethanolamine having a specific carbon chain distribution; and (c) water.
Type:
Grant
Filed:
July 15, 1997
Date of Patent:
July 20, 1999
Assignee:
Henkel Corporation
Inventors:
Arturo Valdes, Anil Shah, Marc Blumstein
Abstract: Pumpable water-containing surfactant concentrates with a solids content of 30 to 60% by weight containing(a) alkyl and/or alkenyl oligoglycosides and(b) amphoteric or zwitterionic surfactantsin a ratio by weight of 10:90 to 90:10, based on the solids content; processes for their preparation and their use in the production of surface-active formulations.
Type:
Grant
Filed:
April 4, 1997
Date of Patent:
July 20, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Guenter Uphues, Joerg Kahre, Ansgar Behler, Peter Neumann, Hermann Hensen, Werner Seipel, Holger Tesmann
Abstract: A process for suppressing the foaming properties of a cleaning product by adding to the cleaning product a foam-suppressing additive consisting of polyethylene glycol ethers corresponding to formula IR.sub.1 O--(CH.sub.2 CH.sub.2 O).sub.n --R.sub.2 (I)wherein R.sub.1 is a long-chain branched alkyl or alkenyl radical, R.sub.2 is an alkyl radical containing 4 to 8 carbon atoms and n is a number from 4 to 9, and wherein the radical R.sub.1 O is derived from an alcohol mixture consisting of at least 45 mol percent of an equimolar isomer mixture of 2-hexyl-1-dodecanol and 2-octyl-1-decanol and 0 to 55 mol percent of 2-hexyl-1-decanol.
Abstract: A polyamide resin comprising the reaction product obtained by the reaction of an acid component comprised of a major concentration of a dimer acid and minor concentration of a monobasic acid and an amine component comprised of a major concentration of a short-chain alkylenediamine, a first minor concentration of a medium-chain alkylenediamine and second minor concentration of a polyoxyalkylene diamine having a molecular weight greater than about 500 is provided. The polyamide resin is used to form a blend of containing the polyamide in a major amount by weight and a first minor amount by weight of a polar wax and a second minor amount by weight of a polyolefin elastomer. The composition is used to reinforce a footwear upper, e.g. as a print on box toe material.
Type:
Grant
Filed:
June 23, 1998
Date of Patent:
July 13, 1999
Inventors:
Dwight D. Heinrich, Reimar Heucher, Sandra Drahos
Abstract: Dimer alcohol bis-sulfates, trimer alcohol tris-sulfates and ether sulfates thereof are prepared by reacting dimer alcohols, trimer alcohols, or alkylene oxide adducts thereof with a sulfating agent, and then neutralizing the reaction product with an aqueous base material.
Type:
Grant
Filed:
October 1, 1997
Date of Patent:
July 13, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Georg Knuebel, Alfred Westfechtel, Gerhard Hermanns, Rainer Hoffmann, Hans-Christian Raths
Abstract: A process for fixing dyes impregnated in fine-dimensional synthetic textile substrates in an environmentally safe manner. The process comprises contacting the dyed synthetic substrates with a phenol- and formaldehyde-free dye-fixative composition comprising:(a) polymethacrylic acid,(b) copolymers of methacrylic acid consisting essentially of methacrylic acid and an ethylenically unsaturated comonomer selected from the group consisting of 2-acrylamido-2-methyl-propanesulfonic acid, sodium vinyl sulfonate, sodium styrene sulfonate, alkyl acrylate,(c) sulfamic acid, and(d) combinations of (a), (b) and (c).
Type:
Grant
Filed:
November 19, 1997
Date of Patent:
July 13, 1999
Assignee:
Henkel Corporation
Inventors:
Howard Cole, Brian Francois, David I. Devore
Abstract: A transparent/translucent dishwashing composition in bar/paste form containing: (a) an alkyl polyglycoside of the formula IR.sub.1 (R.sub.2 O).sub.b (Z).sub.a (I)wherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6; (b) a short-chain alcohol; (c) a fatty acid; (d) an amide; and (e) a polyol.
Abstract: Described are a concentrate, a working solution and a process for iron phosphating of metals, in which the solution contains nitrobenzene sulfonic acid and substituted short-chain monocarboxylic acids of the amino acid and/or hydroxycarboxylic acid type as the accelerators.
Abstract: A plastisol composition based on styrene copolymers, plasticizers and inorganic fillers contains, as styrene copolymers, copolymers which can be produced by emulsion polymerization and contain a) styrene and/or .alpha.-methyl styrene and/or p-methyl styrene and b) 3 to 20 wt.-% (relative to the copolymer) methacrylic acid and/or acrylic acid and/or itaconic acid. To increase the abrasion resistance, further crosslinkers or strengtheners can be added. The plastisols are suitable for use in motor vehicle construction as underseal material, as an adhesive for hood lining, as a compound for grille protection or as a spot-welding paste, and in the packaging products industry as a sealing compound for container closures or as a seam seal or as a flange-joint adhesive for tin cans.
Abstract: A process for producing unsaturated fatty compounds having improved low-temperature properties bya) splitting lauric oils into fatty acids and glycerol,b) subjecting the fatty acids to fractional crystallization to obtain a fraction of unsaturated fatty acids, andc) hydrogenating the unsaturated fatty acids, optionally after converting the unsaturated fatty acids into their lower alkyl esters, to form unsaturated fatty alcohols having an iodine value of from about 85 to about 100.
Type:
Grant
Filed:
June 10, 1997
Date of Patent:
June 29, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Michael Koehler, Alfred Westfechtel, Guenter Demmering, Horst-Dieter Komp, Christiane Boehr, Achim Ansmann, Udo Steinberner
Abstract: A cleaning vehicle which is suitable for holding and transporting containers and devices for the commercial cleaning and disinfection of floors and other surfaces, consists of a main vehicle with wheels and a trailer with wheels and a coupling for connecting the trailer to the main vehicle. The coupling consists of at least one tow-hook and corresponding eyes in which the hook can engage. The shape of the hook and eyes is such that the coupling allows the trailer to rotate about the connecting line of the eyes of the main vehicle and/or the vertical movement of the trailer in relation to the main vehicle, but no movement of the trailer in the plane of travel in relation to the main vehicle. The wheels of the main vehicle do not lock when taking curves and are stable even on uneven surfaces. At the same time the trailer can be properly steered by the main vehicle without any undesired movements of the trailer. The improvement is also simple and economical.
Type:
Grant
Filed:
September 3, 1996
Date of Patent:
June 22, 1999
Assignee:
Henkel-Ecolab GmbH & Co. OHG
Inventors:
Franz Kresse, Rainer Osberghaus, Roland Schunter, Hans-Leo Fernschild
Abstract: A process for producing detergent agglomerates useful in the production of detergent granules, comprising: (a) providing at least one solid, powder-form detergent component; (b) providing an alkyl polyglycoside of formula I:R.sub.1 O(R.sub.2 O).sub.b (Z).sub.a Iwherein R.sub.1 is a monovalent organic radical having from about 6 to about 30 carbon atoms; R.sub.2 is divalent alkylene radical having from 2 to 4 carbon atoms; Z is a saccharide residue having 5 or 6 carbon atoms; b is a number having a value from 0 to about 12; a is a number having a value from 1 to about 6; and (c) applying the alkyl polyglycoside onto the detergent component to form a detergent agglomerate product.
Abstract: A process for controlling the deposition of stickies from paper stock suspensions during papermaking by adding to the paper stock suspensions from 0.001% to 5.0% by weight based on the weight of fibrous paper stock, of alkoxylation products obtained by reaction of alkylene oxides with C.sub.10-22 carboxylic acid derivatives or C.sub.10-22 carboxylic acids containing functional groups with at least one OH group in the 9, 10, 13 or 14 position.
Type:
Grant
Filed:
October 24, 1997
Date of Patent:
June 22, 1999
Assignee:
Henkel Kommanditgesellschaft auf Aktien
Inventors:
Bernhard Nellessen, Rita Koester, Klaus Hornfeck, Berthold Schreck, Peter Daute
Abstract: A process for producing detergent tablets by exposing a detergent composition to microwave radiation in the frequency range from 3 to 300,000 MHz while treating the detergent composition with hot air having a temperature of 50.degree. C. to 300.degree. C.
Type:
Grant
Filed:
May 7, 1997
Date of Patent:
June 22, 1999
Assignee:
Henkel-Ecolab GmbH & Co. OHG
Inventors:
Mario Ulbl, Andreas Potthoff, Sandra Witt, Manfred Klemm
Abstract: A compound having the formula:((CH.sub.2 .dbd.CR.sup.1 --C(O)O--) .sub.x R.sup.2 --(O--C(O)R.sup.3).sub.y --O--C(O)).sub.n --R.sup.4 --(C(O)OM) .sub.mwherein:R.sup.1 is hydrogen or methyl,R.sup.2 is an alkylene group or substituted alkylene group (typically having less than six carbon atoms, more typically two or three carbon atoms),R.sup.3 is an alkylene group or substituted alkylene group (typically having less than ten carbon atoms, more typically from four to six carbon atoms),R.sup.4 is an aromatic radical (e.g. the residue of an aromatic polycarboxylic polyanhydride having a functionality of one half the sum of n and m),n and m are integers from two to four (typically two or three),x is an integer from one to three, andy is an integer from one to five.Among the compounds which fall within the above formula are those in which R.sup.1 is hydrogen, R.sup.2 is an ethylene group, R.sup.3 is a pentamethylene group, and R.sup.
Type:
Grant
Filed:
October 17, 1996
Date of Patent:
June 15, 1999
Assignee:
Henkel Corporation
Inventors:
Ramesh Narayan, Miguel A. Dones, Michael McDermott
Abstract: Improved autodeposited coatings on metallic surfaces are formed by contacting the metallic surfaces with an autodepositing composition comprising an acidic aqueous coating solution containing dispersed solid resin particles of either an internally stablilized or externally stabilized vinylidene chloride polymer, an exemplary internally stabilized polymer being prepared from vinylidene chloride and a monomeric surfactant which includes an inorganic ionizable group, and an exemplary externally stabilized polymer being prepared from vinylidene chloride and a reactive comonomer, the resulting resin particles having surfactant adsorbed thereon, said autodeposited coatings having extremely good corrosion resistant properties without treatment with a reaction rinse such as a chromium rinse.
Type:
Grant
Filed:
June 6, 1995
Date of Patent:
June 15, 1999
Assignee:
Henkel Corporation
Inventors:
Wilbur S. Hall, Herbert Fischer, Roland Morlock
Abstract: An improvement in the process of recovery of copper from aqueous ammoniacal solutions containing copper values in which the copper values are extracted from the aqueous ammoniacal solution by an organic phase comprised of a diketone copper extractant dissolved in a water-immiscible organic hydrocarbon solvent, by improving the stripping of the copper from the organic extractant phase, in which the improved stripping results from the incorporation into, or addition to the diketone extractant phase of a catalytic amount of an hydroxy aryl oxime. Also an improved extractant composition is provided comprised of the mixture of a diketone copper extractant and a catalytic amount (preferably about 0.5 to about 5 mole % in relation to the diketone) of an hydroxy aryl oxime, such as nonyl or dodecyl salicylaldoxime.
Type:
Grant
Filed:
September 3, 1996
Date of Patent:
June 1, 1999
Assignee:
Henkel Corporation
Inventors:
Michael J. Virnig, R. Brantley Sudderth