Abstract: The present invention provides steam reforming catalyst compositions containing Pd and Zn, and methods of steam reforming alcohols over a catalyst. Surprisingly superior results and properties of the present invention, including low temperature activity and/or low carbon monoxide output, are also described. Methods of making a steam reforming catalyst are also provided.
Type:
Grant
Filed:
May 16, 2003
Date of Patent:
April 24, 2007
Assignee:
Battelle Memorial Institute
Inventors:
Jamelyn D. Holladay, Yong Wang, Jianli Hu, Ya-Huei Chin, Robert A. Dagle, Guanguang Xia, Eddie G. Baker, Daniel R. Palo, Max R. Phelps, Heon Jung
Abstract: Various aspects and applications of microsystem process networks are described. The design of many types of microsystems can be improved by ortho-cascading mass, heat, or other unit process operations. Microsystems having exergetically efficient microchannel heat exchangers are also described. Detailed descriptions of numerous design features in microcomponent systems are also provided.
Type:
Grant
Filed:
June 6, 2000
Date of Patent:
October 24, 2006
Assignee:
Battelle Memorial Institute
Inventors:
Robert S. Wegeng, Ward E. TeGrotenhuis, Greg A. Whyatt
Abstract: The present invention provides microcombustors, microreformers, and methods of steam reforming alcohols over a catalyst. The microcombustors can be manufactured with a very small size and can operate at very low temperature. Surprisingly superior results and properties obtained in methods of the present invention are also described.
Type:
Grant
Filed:
November 7, 2001
Date of Patent:
July 18, 2006
Assignee:
Battelle Memorial Institute
Inventors:
Jamelyn D. Holladay, Max R. Phelps, Yong Wang, Ya-Huei Chin
Abstract: The present invention includes a catalyst structure and method of making the catalyst structure for Fischer-Tropsch synthesis that both rely upon the catalyst structure having a first porous structure with a first pore surface area and a first pore size of at least about 0.1 ?m, preferably from about 10 ?m to about 300 ?m. A porous interfacial layer with a second pore surface area and a second pore size less than the first pore size is placed upon the first pore surface area. Finally, a Fischer-Tropsch catalyst selected from the group consisting of cobalt, ruthenium, iron and combinations thereof is placed upon the second pore surface area. Further improvement is achieved by using a microchannel reactor wherein the reaction chamber walls define a microchannel with the catalyst structure is placed therein through which pass reactants. The walls may separate the reaction chamber from at least one cooling chamber. The present invention also includes a method of Fischer-Tropsch synthesis.
Type:
Grant
Filed:
September 19, 2003
Date of Patent:
May 16, 2006
Assignee:
Battelle Memorial Institute
Inventors:
Yong Wang, David P. Vanderwiel, Anna Lee Y. Tonkovich, Yufei Gao, Eddie G. Baker
Abstract: Reactors and processes are disclosed that can utilize high heat fluxes to obtain fast, steady-state reaction rates. Porous catalysts used in conjunction with microchannel reactors to obtain high rates of heat transfer are also disclosed. Reactors and processes that utilize short contact times, high heat flux and low pressure drop are described. Improved methods of steam reforming are also provided.
Type:
Grant
Filed:
July 1, 2003
Date of Patent:
May 16, 2006
Assignee:
Battelle Memorial Institute
Inventors:
Anna Lee Y. Tonkovich, Yong Wang, Robert S. Wegeng, Yufei Gao
Abstract: Carbon nanotube structures are disclosed in which nanotubes are disposed over a porous support such as a foam, felt, mesh, or membrane. Techniques of making these structures are also disclosed. In some of these techniques, a support is pretreated with a templated surfactant composition to assist with the formation of a nanotube layer.
Type:
Grant
Filed:
September 30, 2004
Date of Patent:
March 14, 2006
Assignee:
Battelle Memorial Institute
Inventors:
Yong Wang, Ya-Huei Chin, Yufei Gao, Christopher L. Aardahl, Terri L. Stewart
Abstract: Methods have been developed to form catalysts having active metals disposed on a carbon nanotube coated porous substrate. Catalysts and reactions over nanotube-containing catalysts are also disclosed. Results are presented showing enhanced performance resulting from use of the inventive catalyst. Mesoporous oxide layers can be utilized to improve catalyst properties.
Abstract: A CPAP device and a method for treating sleep apnea use a head appliance with an oral adaptor comprising a tube partially inserted in a person's mouth and a diaphragm applied over the tube against the mouth, such that the lips are formed into a tight seal with the tube. A nasal seal is described comprising two rollers to which a strap is attached, so that the nasal seal is easily put in place, adjusted and maintained by rolling the rollers on the nose sides or pulling the straps.
Abstract: Novel methods of making laminated, microchannel devices are described. Examples include: assembly from thin strips rather than sheets; and hot isostatic pressing (HIPing) to form devices with a hermetically sealed wall. Laminated microchannel articles having novel features are also described. The invention includes processes conducted using any of the articles described.
Type:
Grant
Filed:
November 27, 2002
Date of Patent:
January 24, 2006
Assignee:
Velocys Inc.
Inventors:
Anna Lee Tonkovich, Gary Roberts, Sean P. Fitzgerald, Timothy M. Werner, Matthew B. Schmidt, Robert J. Luzenski, G. Bradley Chadwell, James A. Mathias, Abhishek Gupta, David J. Kuhlmann, Thomas D. Yuschak
Abstract: The present invention is a chemical reactor for catalytic chemical reactions having gas phase reactants. The chemical reactor has reactor microchannels for flow of at least one reactant and at least one product, and a catalyst material wherein the at least one reactant contacts the catalyst material and reacts to form the at least one product. The improvement, according to the present invention is: the catalyst material is on a porous material having a porosity that resists bulk flow therethrough and permits molecular diffusion therein. The porous material further has a length, a width and a thickness, the porous material defining at least a portion of one wall of a bulk flow path through which the at least one reactant passes.
Type:
Grant
Filed:
October 4, 2002
Date of Patent:
January 10, 2006
Assignee:
Battelle Memorial Institute
Inventors:
Anna Lee Y. Tonkovich, Yong Wang, Sean P. Fitzgerald, Jennifer L. Marco, Gary L. Roberts, David P. Vanderwiel, Robert S. Wegeng
Abstract: The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.
Type:
Grant
Filed:
March 18, 2003
Date of Patent:
January 3, 2006
Assignee:
Battelle Memorial Institute
Inventors:
Yong Wang, David P. Vanderwiel, Anna Lee Y. Tonkovich, Yufei Gao, Eddie G. Baker
Abstract: The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.
Type:
Grant
Filed:
June 30, 2003
Date of Patent:
December 13, 2005
Assignee:
Battelle Memorial Institute
Inventors:
Robert S. Wegeng, Scot D. Rassat, Victoria S. Stenkamp, Ward E. TeGrotenhuis, Dean W. Matson, M. Kevin Drost, Vilayanur V. Viswanathan
Abstract: Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Superior results were achieved for combustion chambers which contained a gap for free flow through the chamber. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results.
Type:
Grant
Filed:
February 14, 2002
Date of Patent:
November 29, 2005
Assignee:
Battelle Memorial Institute
Inventors:
Anna Lee Tonkovich, Gary L. Roberts, Steven T. Perry, Sean P. Fitzgerald
Abstract: A method of steam reforming a hydrocarbon over a spinel-containing catalyst at short residence times or short contact times. The present invention also provides spinel-containing catalysts. Surprisingly superior results and properties obtained in methods and catalysts of the present invention are also described.
Type:
Grant
Filed:
March 24, 2003
Date of Patent:
October 25, 2005
Assignee:
Battelle Memorial Institute
Inventors:
Yong Wang, Anna Lee Y. Tonkovich, David P. Vanderwiel
Abstract: Apparatus for changing a baby including a disposable changing pad component, a changing platform component and a combination of a changing pad component and platform component. The disposable changing pad component includes a water impermeable layer and a fabric layer and at least one movement resistance aid to anchor the pad in place. The changing platform component includes a generally smooth region for receiving a baby and at least one changing pad retainer for holding the changing pad.
Abstract: A microchannel contactor and methods of contacting substances in microchannel apparatus are described. Some preferred embodiments are combined with microchannel heat exchange.
Type:
Grant
Filed:
March 7, 2003
Date of Patent:
March 22, 2005
Assignee:
Battelle Memorial Institute
Inventors:
Ward E. TeGrotenhuis, Scot D. Rassat, Victoria S. Stenkamp
Abstract: The present invention provides apparatus and methods for separating hydrogen. In preferred embodiments, the apparatus and methods utilize microchannel devices with small distances for heat and mass transfer to achieve rapid cycle times and surprisingly large volumes of hydrogen separated in short times using relatively compact hardware.
Type:
Grant
Filed:
November 15, 2002
Date of Patent:
November 30, 2004
Assignee:
Battelle Memorial Institute
Inventors:
Bruce F. Monzyk, Anna Lee Y. Tonkovich, Yong Wang, David P. VanderWiel, Steven T. Perry, Sean P. Fitzgerald, Wayne W. Simmons, Jeffrey S. McDaniel, Albert E. Weller, Jr., Chad M. Cucksey
Abstract: The present invention includes a catalyst having a layered structure with, (1) a porous support, (2) a buffer layer, (3) an interfacial layer, and optionally (4) a catalyst layer. The invention also provides a process in which a reactant is converted to a product by passing through a reaction chamber containing the catalyst.
Type:
Grant
Filed:
June 6, 2002
Date of Patent:
July 13, 2004
Assignee:
Battelle Memorial Institute
Inventors:
Anna Lee Y. Tonkovich, Yong Wang, Yufei Gao
Abstract: The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.
Type:
Grant
Filed:
October 28, 2002
Date of Patent:
June 15, 2004
Assignee:
Battelle Memorial Institute
Inventors:
Yong Wang, David P. Vanderwiel, Anna Lee Y. Tonkovich, Yufei Gao, Eddie G. Baker