Abstract: The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. In another aspect, the apparatus or methods utilize heat exchange channels of varying lengths that have volumes controlled to provide equal heat fluxes. Methods of fuel cell startup are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.
Type:
Grant
Filed:
April 29, 2002
Date of Patent:
June 8, 2004
Assignee:
Battelle Memorial Institute
Inventors:
Robert S. Wegeng, Scot D. Rassat, Ward E. TeGrotenhuis, Kevin Drost, Vilayanur V. Vishwanathan
Abstract: Laminated, multiphase separators and contactors having wicking structures and gas flow channels are described. Some preferred embodiments are combined with microchannel heat exchange. Integrated systems containing these components are also part of the present invention.
Type:
Grant
Filed:
June 6, 2000
Date of Patent:
December 23, 2003
Assignee:
Battelle Memorial Institute
Inventors:
Ward E. TeGrotenhuis, Robert S. Wegeng, Greg A. Whyatt, Victoria S. Stenkamp, Phillip A. Gauglitz
Abstract: The present invention provides compact adsorption systems that are capable of rapid temperature swings and rapid cycling. Novel methods of thermal swing adsorption and thermally-enhanced pressure swing adsorption are also described. In some aspects of the invention, a gas is passed through the adsorbent thus allowing heat exchangers to be very close to all portions of the adsorbent and utilize less space. In another aspect, the adsorption media is selectively heated, thus reducing energy costs. Methods and systems for gas adsorption/desorption having improved energy efficiency with capability of short cycle times are also described. Advantages of the invention include the ability to use (typically) 30-100 times less adsorbent compared to conventional systems.
Type:
Grant
Filed:
April 30, 2001
Date of Patent:
October 7, 2003
Assignee:
Battelle Memorial Institute
Inventors:
Robert S. Wegeng, Scot D. Rassat, Victoria S. Stenkamp, Ward E. TeGrotenhuis, Dean W. Matson, M. Kevin Drost, Vilayanur V. Viswanathan
Abstract: Reactors and processes are disclosed that can utilize high heat fluxes to obtain fast, steady-state reaction rates. Porous catalysts used in conjunction with microchannel reactors to obtain high rates of heat transfer are also disclosed. Reactors and processes that utilize short contact times, high heat flux and low pressure drop are described. Improved methods of steam reforming are also provided.
Type:
Grant
Filed:
January 27, 2000
Date of Patent:
September 9, 2003
Assignee:
Battelle Memorial Institute
Inventors:
Anna Lee Y. Tonkovich, Yong Wang, Robert S. Wegeng, Yufei Gao
Abstract: The present invention includes Fischer-Tropsch catalysts, reactions using Fischer-Tropsch catalysts, methods of making Fischer-Tropsch catalysts, processes of hydrogenating carbon monoxide, and fuels made using these processes. The invention provides the ability to hydrogenate carbon monoxide with low contact times, good conversion rates and low methane selectivities. In a preferred method, the catalyst is made using a metal foam support.
Type:
Grant
Filed:
January 27, 2000
Date of Patent:
May 6, 2003
Assignee:
Battelle Memorial Institute
Inventors:
Yong Wang, David P. Vanderwiel, Anna Lee Y. Tonkovich, Yufei Gao, Eddie G. Baker
Abstract: The present invention is a method and apparatus (vessel) for providing a heat transfer rate from a reaction chamber through a wall to a heat transfer chamber substantially matching a local heat transfer rate of a catalytic thermal chemical reaction. The key to the invention is a thermal distance defined on a cross sectional plane through the vessel inclusive of a heat transfer chamber, reaction chamber and a wall between the chambers. The cross sectional plane is perpendicular to a bulk flow direction of the reactant stream, and the thermal distance is a distance between a coolest position and a hottest position on the cross sectional plane. The thermal distance is of a length wherein the heat transfer rate from the reaction chamber to the heat transfer chamber substantially matches the local heat transfer rate.
Type:
Grant
Filed:
July 27, 1998
Date of Patent:
April 1, 2003
Assignee:
Battelle Memorial Institute
Inventors:
Anna Lee Y. Tonkovich, Yong Wang, Robert S. Wegeng, Yufei Gao
Abstract: The present invention provides apparatus and methods for separating fluid components. In preferred embodiments, the apparatus and methods utilize microchannel devices with small distances for heat and mass transfer to achieve rapid cycle times and surprisingly large volumes of fluid components separated in short times using relatively compact hardware.
Type:
Grant
Filed:
April 30, 2001
Date of Patent:
January 21, 2003
Assignee:
Battelle Memorial Institute
Inventors:
Anna Lee Y. Tonkovich, Bruce F. Monzyk, Yong Wang, David P. VanderWiel, Steven T. Perry, Sean P. Fitzgerald, Wayne W. Simmons, Jeffrey S. McDaniel, Albert E. Weller, Jr.
Abstract: The present invention provides apparatus and methods for separating hydrogen. In preferred embodiments, the apparatus and methods utilize microchannel devices with small distances for heat and mass transfer to achieve rapid cycle times and surprisingly large volumes of hydrogen separated in short times using relatively compact hardware.
Type:
Grant
Filed:
April 30, 2001
Date of Patent:
January 7, 2003
Assignee:
Battelle Memorial Institute
Inventors:
Bruce F. Monzyk, Anna Lee Y. Tonkovich, Yong Wang, David P. VanderWiel, Steven T. Perry, Sean P. Fitzgerald, Wayne W. Simmons, Jeffrey S. McDaniel, Albert E. Weller, Jr., Chad M. Cucksey
Abstract: The present invention includes a catalyst having a layered structure with, (1) a porous support, (2) a buffer layer, (3) an interfacial layer, and optionally (4) a catalyst layer. The invention also provides a process in which a reactant is converted to a product by passing through a reaction chamber containing the catalyst.
Type:
Grant
Filed:
January 27, 2000
Date of Patent:
August 27, 2002
Assignee:
Battelle Memorial Institute
Inventors:
Anna Lee Y. Tonkovich, Yong Wang, Yufei Gao
Abstract: An electret article can be made by quenching a molten blend containing a polymer and a performance-enhancing additive. The resulting low crystallinity material can be annealed and charged to produce a material for making electret filters having superior oily mist loading performance properties.
Type:
Grant
Filed:
October 1, 1997
Date of Patent:
May 30, 2000
Assignee:
3M Innovative Properties Company
Inventors:
Alan D. Rousseau, Marvin E. Jones, Betty Z. Mei
Abstract: A retroreflective article (100, 200, 300) that has a retroreflective layer (120, 220, 320) that includes optical elements (121, 221, 321) and a specularly reflective layer (122, 222, 322), and a binder layer (110, 210, 310), that is the reaction product of an epoxy resin and polymer that has a silicon-containing, crosslinkable, terminal, functional groups. Retroreflective articles of this construction can demonstrate good abrasion resistance and laundering durability.