Abstract: The combination of an oil-soluble polyol ester reaction product having a number average molecular weight (M.sub.n) of from about 1,300 to 8,000, e.g., the reaction product of polybutenyl succinic anhydride with pentaerythritol which reaction product can be borated, if desired, and an oil-soluble acylated nitrogen compound having a (M.sub.n) of from about 1,300 to 8,000, e.g. polybutenyl succinic anhydride reacted with an alkylene polyamine such as tetraethylene pentamine, which nitrogen compound can be borated, if desired, are surprisingly useful as combined additives for lubricating oils to increase the dispersancy and varnish inhibition properties of said oil when one part per weight of said polyol ester reaction product is combined with from 0.2 to 4, preferably 1 to 3, parts by weight of said acylated nitrogen compound.
Type:
Grant
Filed:
October 3, 1977
Date of Patent:
November 6, 1979
Assignee:
Exxon Research & Engineering Co.
Inventors:
Thor F. Lonstrup, Darrell W. Brownawell, Barry J. Howlett
Abstract: The development of color of a concentrate of alkarylsulphonic acids is reduced by adding to and dissolving in the freshly prepared concentrate up to 5% of its weight of an organic compound having at least one ether group therein, the partial vapor pressure of the compound thus dissolved in the concentrate being negligible at the temperatures at which the concentrate is stored or transported. Examples of suitable organic compounds are aliphatic or phenolic monoethers, e.g. diethylene glycol.
Type:
Grant
Filed:
March 11, 1975
Date of Patent:
October 30, 1979
Assignee:
Exxon Research & Engineering Co.
Inventors:
Marcel Prillieux, Marcel Robert, Robert Tirtiaux
Abstract: Surface active agents for oil in water emulsions and oil recovery comprising salts of alkaryl sulphonic acids and organic bases containing at least one --(C.sub.2 H.sub.4 O).sub.n H where n is greater than 1.
Type:
Grant
Filed:
October 26, 1977
Date of Patent:
October 16, 1979
Assignee:
Exxon Research & Engineering Co.
Inventors:
Pierre D. Marin, Marcel Prillieux, Robert Tirtiaux
Abstract: Lactone oxazoline reaction products of hydrocarbon sustituted lactone carboxylic acids, for example, polybutyl lactone carboxylic acid, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-(hydroxymethyl)aminomethane (THAM), and their derivatives are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.
Abstract: Oxazoline reaction products of hydrocarbon substituted dicarboxylic acid, ester, or anhydride, for example octadecenylsuccinic anhydride, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-hydroxymethylaminomethane (THAM), and their derivatives are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.
Type:
Grant
Filed:
June 19, 1978
Date of Patent:
June 5, 1979
Assignee:
Exxon Research & Engineering Co.
Inventors:
Jack Ryer, Harold N. Miller, James Zielinski, Stanley J. Brois
Abstract: Terpolymers of ethylene, a C.sub.3 to C.sub.8 alpha-olefin and a non-conjugated acyclic or alicyclic diolefin are epoxidized at sites of unsaturation which are extraneous to the main backbone chain of carbon atoms. Either the epoxidized terpolymer or the reaction products of the epoxidized terpolymer with reagents having replaceable hydrogen, i.e., water, organic acids, alcohols, amines, phenols, mercaptans and the like, are useful as multifunctional additives for synthetic and mineral oil lubricants and fuels.
Type:
Grant
Filed:
November 11, 1976
Date of Patent:
May 22, 1979
Assignee:
Exxon Research & Engineering Co.
Inventors:
James J. Pappas, Norman Jacobson, Edward N. Kresge
Abstract: Oxazoline reaction products of hydrocarbon substituted dicarboxylic acid, ester, or anhydride, for example octadecenylsuccinic anhydride, with 2,2-disubstituted-2-amino-1-alkanols, such as tris-hydroxymethylaminomethane (THAM), and their derivatives are useful additives in oleaginous compositions, such as sludge dispersants for lubricating oil, or anti-rust agents for gasoline.
Type:
Grant
Filed:
July 30, 1976
Date of Patent:
May 8, 1979
Assignee:
Exxon Research & Engineering Co.
Inventors:
Jack Ryer, Harold N. Miller, James Zielinski, Stanley J. Brois
Abstract: Highly effective antioxidants that are particularly useful in crankcase lubricating oil formulations of relatively low ash content are prepared by the condensation of phosphorodithioates of alkyl phenol sulfides with compounds having activated double bonds, particularly with styrene, alkyl styrenes, highly reactive olefins, vinyl esters and acrylate esters.
Abstract: Oil soluble ethylene polymers or copolymers having a M.sub.n greater than about 4000 in combination with an oil soluble polyester material such as a homopolymer or copolymer, comprising at least 10% by weight C.sub.4 to C.sub.16 substantially straight-chain alkyl esters of acrylic or methacrylic acid, are useful in improving the cold flow properties of distillate hydrocarbon oils.
Abstract: Oil soluble ethylene-vinyl ester copolymers having a M.sub.n less than about 4000 in combination with an oil soluble polyester material, such as a homopolymer or copolymer, comprising at least 10% by weight C.sub.14 to C.sub.16 substantially straight-chain alkyl esters of acrylic or methacrylic acid, are useful in improving the cold flow properties of distillate hydrocarbon oils.
Abstract: Oil soluble ethylene polymers or copolymers having a M.sub.n less than about 4000 in combination with an oil soluble polyester material such as a homopolymer or copolymer comprising, at least 10% by weight C.sub.4 to C.sub.16 substantially straight-chain alkyl esters of acrylic or methacrylic acid, are useful in improving the cold flow properties of distillate hydrocarbon oils.
Abstract: Sulphonic acids and sulphonates containing olefines and optionally water which improve color and thermal stability and also simplify purification of the acid.
Abstract: Olefin-dicarboxylic anhydride copolymers and their ester derivatives, having C.sub.18 to C.sub.50 linear alkyl side chains are filtration aids in solvent dewaxing of waxy lubricating oils.
Abstract: Emulsifier compositions, suitable for mixing with mineral oil to form metal working lubricants, comprise a mixture of salts of alkylaryl sulfonic acids, said acids having a molecular weight distribution with two distinct peaks, one peak being preferably in the range of 270 to 400, while the other peak is in the range of 350 to 600; which peaks differ at least 80. Mixtures of 5 to 95 wt. % sodium salts of branched chain C.sub.12 to C.sub.16 alkyl orthoxylenesulfonic acids with 95 to 5 wt. % sodium salts of branched chain C.sub.20 to C.sub.28 alkyl benzenesulfonic acids are especially preferred compositions, particularly when blended with naphthenic mineral oil, to thereby form stable emulsifiable metal working lubricants.
Abstract: Multipurpose lubricating oil additives having utility as viscosity index improvers, antiwear agents, sludge dispersants and pour point depressants comprise reaction products of (1) nitrogen compounds having one or more amino groups and/or (2) oxygen compounds having one or more hydroxyl, epoxide or ether groups and/or (3) sulfur compounds and/or (4) hydrogen with alternating interpolymers of monomers comprising (A) one or more polar monomers; (B) one or more olefinic monomers; and (C) a monomer similar to (A) or (B) but containing in addition a reactive group that reacts with (1), (2), (3) or (4).
Abstract: Multipurpose lubricating oil additives having utility as viscosity index improvers, antiwear agents, sludge dispersants and pour point depressants comprise oil-soluble reaction products of (1) nitrogen compounds having one or more amino groups and/or (2) oxygen compounds having one or more hydroxyl, epoxide or ether groups and/or (3) sulfurizing agent and/or boron compound and/or phosphorous compound with an electrophilically terminated anion of an oxidized copolymer of ethylene and at least one C.sub.3 -C.sub.50 alpha monoolefin.
Abstract: Oil-soluble, derivatized ethylene copolymers derived from about 2 to 98 wt. % ethylene, and one or more C.sub.3 to C.sub.28 alpha-olefins, e.g. propylene, which are grafted, preferably solution-grafted under an inert atmosphere and at elevated temperatures and in the presence of a high-temperature decomposable free-radical initiator, with an ethylenically-unsaturated dicarboxylic acid material and thereafter reacted with a polyamine having at least two primary amine groups, e.g. an alkylene polyamine such as diethylene triamine, to form carboxyl-grafted polymeric imide, usually maleimide, derivatives are reacted with an anhydride of a C.sub.1 -C.sub.30 hydrocarbyl substituted acid, preferably acetic anhydride, to yield an oil-soluble stable amide of said polyamine whereby oil solutions of said amide derivative are characterized by minimal viscosity change over an extended period of time. Useful number average molecular weight (M.sub.
Type:
Grant
Filed:
July 28, 1977
Date of Patent:
January 30, 1979
Assignee:
Exxon Research & Engineering Co.
Inventors:
John B. Gardiner, James Zielinski, Robert L. Elliott, Stanley J. Brois
Abstract: Copolymers of a 1,2 epoxy alkane and a cyclic carboxylate compound of the class consisting of dicarboxylic acid anhydrides, preferably maleic anhydride or a hydrocarbyl substituted succinic anhydride and a beta lactone, said copolymers having C.sub.10 to C.sub.50, preferably C.sub.20 to C.sub.40, linear, pendant hydrocarbon chains are flow improvers in residual and crude oils.
Abstract: Compounds of the formula: ##STR1## wherein Y is phenoxy, alkylphenoxy, alkoxy, phenylthio, alkylphenylthio, thioalkyl, alkyl or arylamino, and x is 1 or 2, and compounds of the above formula wherein one or both of said aromatic rings are substituted, e.g. with an alkyl group, and their use as antiwear and antioxidant additives in lubricants.
Abstract: Lactone polyol ester reaction products of hydrocarbon substituted lactone carboxylic acid, with polyols such as pentaerythritol and their derivatives are useful additives in oleaginous compositions, such as varnish-inhibiting dispersants for lubricating oils, and fuels.