Patents Represented by Attorney, Agent or Law Firm Gregory N. Clements
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Patent number: 5874496Abstract: The invention relates to a biaxially oriented polyester film having a roughness, on at least one film surface, of R.sub.z greater than 1.0 .mu.m (Ra is greater than 0.1 .mu.m), a dielectric strength (AC) greater than 220 kV/mm (the DC dielectric strength is greater than 500 kV/mm) and a migrating fraction in the film of less than 18 .mu.S/cm based on a mass of added particles in a polyester volume of 100 cm.sup.3. The film is particularly suitable for oil-impregnated capacitors.Type: GrantFiled: February 25, 1997Date of Patent: February 23, 1999Assignee: Hoechst Diafoil GmbHInventors: Rainer Kurz, Herbert Peiffer, Annegrete Bursch
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Patent number: 5874515Abstract: There is disclosed a process for reducing the number of gels generated in polyethylene terephthalate (PET) resin. Gels are crosslinked polymers created by thermal and thermo-oxidative degradation induced during polymer production. The instant process comprises the addition of primary and secondary antioxidants prior to the PET polycondensation reaction in order to reduce the amount of thermal degradation which occurs. The polyethylene terephthalate produced by this process formed approximately 25 to 90% fewer gels while maintaining physical properties suitable for use in fiber, film, and molding applications.Type: GrantFiled: December 23, 1997Date of Patent: February 23, 1999Assignee: Hoechst Celanese CorporationInventors: Xiaoyan Huang, Ligia Dominguez
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Patent number: 5814282Abstract: A polycondensation reactor for polyesters, polyamides or polyarylates, for example, in which a low viscosity material is introduced into the reactor and a relative high viscosity polymer exits the reactor. The reactor has at least two longitudinally intersecting cylindrical interior chambers, each with a rotating shaft through its length. Each shaft has a plurality of stirrers and spacers designed to wipe all interior surfaces of the reactor. The stirrers can be shaped as a cycloid or involute profile, for example. Generally the stirrers on each shaft are indexed from one another preferably by 90.degree. and intermesh with stirrers on the adjacent shaft. Stirring the low viscosity material by rotating the stirrers (on the shafts) spreads the material into a plurality of thin films. At the temperature and vacuum conditions of the reactor, a volatile component is removed, thus causing the material to polymerize, by condensation, forming a relatively high viscosity polymer.Type: GrantFiled: January 15, 1997Date of Patent: September 29, 1998Inventors: Hans Lohe, Hartmut Hey, Gordon Shaw, W. Jeffrey Stikeleather
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Patent number: 5744503Abstract: A process for recovering glycols produced during recycling of polyester comprising the step of extracting aromatic contaminants from the glycols. Extracting the aromatic contaminants is accomplished by: providing a glycol rich stream from a process to recycle polyester. The glycol rich stream comprised glycols, water, and aromatic contaminants. A solvent is added to the glycol rich stream to form a mixture. The mixture is resolved to form a glycol rich component and an aromatic contaminant rich component. The glycols are recovered from the glycol rich component.Type: GrantFiled: February 1, 1996Date of Patent: April 28, 1998Assignee: Hoechst Celanese CorporationInventors: Brad L. Smith, Gary E. Wilkins
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Patent number: 5744237Abstract: In an improved power transmission belt, the circumferentially disposed reinforcing cords are made from multi-filament yarns of heterofilaments. These cords, when fused, have good inter-filament bonding without the solvent of the solvent/adhesive systems.Type: GrantFiled: June 10, 1996Date of Patent: April 28, 1998Assignee: Hoechst Celanese CorporationInventor: Harry W. Stanhope
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Patent number: 5732531Abstract: A method for wrapping a bale of compressed, resilient fibers comprises the steps of: providing a reusable bale wrap kit. The kit includes at least two pieces. Each piece, when joined with the other piece, is adapted for substantially enclosing and containing the bale of compressed, resilient fibers. Mushroom and loop fasteners are located along an edge portion of each piece and are adapted for joining the pieces to one another. Uncompressed, resilient fibers are provided. A portion of the uncompressed, resilient fibers are surrounded with the kit. Those fibers are compressed, and the mushroom and loop fasteners are engaged.Type: GrantFiled: October 30, 1995Date of Patent: March 31, 1998Assignee: Hoechst Celanese CorporationInventors: San de Silva, William S. Sanderson
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Patent number: 5728339Abstract: A silicone release film including an oriented polyester film having a coating thereon in an amount sufficient to act as a silicone release film. The aqueous coating comprises glycidoxy silane and an aqueous based thermosetting silicone release composition. The minimum amount of glycidoxy silane present in the coating is at least 1.0% by weight of the silicone solids. Typical glycidoxy silanes are glycidoxypropyltrimethoxysilane or glycidoxypropyltriethoxysilane. A process for coating a polyester film with a silicone coating is also disclosed, where the coating occurs in-line, during the manufacturing process for the film before it is heat-set.Type: GrantFiled: February 14, 1996Date of Patent: March 17, 1998Assignee: Hoechst Celanese CorporationInventor: Grover L. Farrar
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Patent number: 5719328Abstract: A device is provided for testing a pressure drop across a cigarette filter rod. The device includes an expansible sleeve for encapsulating a filter rod and a two stage vacuum pump connected thereto. A first controllable valve connects the outer surface of the sleeve to the vacuum pump to expand the sleeve so that a filter rod can be inserted. The first controllable valve also connects the end of the sleeve to the vacuum pump so that a measurable pressure drop is created across the filter rod. A second controllable valve is connected between an exhaust port of the vacuum pump and the end of the sleeve so that, after the testing has been completed, the filter rod will be ejected from the sleeve. The pressure testing device is thus self contained and does not require an external source of vacuum or compressed air.Type: GrantFiled: June 25, 1996Date of Patent: February 17, 1998Assignee: Hoechst Celanese CorporationInventor: Joseph D. Gombash, Jr.
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Patent number: 5714258Abstract: An improved polyester fiber, polymer composition for producing such fibers by spinning and drawing, and a process for improving the production of fibers from polyester is disclosed wherein an aliphatic diester such as ethylene glycol distearate is incorporated into the polyester resin prior to spinning fibers from the resin in trace amounts of from about 0.01 to about 0.4 percent by weight of the polyester. The composition improves the process of spinning and drawing fibers from the resin and produces superior fibers.Type: GrantFiled: December 28, 1995Date of Patent: February 3, 1998Assignee: Hoechest Celanese CorporationInventor: F. Holmes Simons
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Patent number: 5709926Abstract: Reclaimable overhead transparencies for plain paper copiers are obtained by strongly adhering particulates having a large mean particle size to a transparent base sheet. A transparent, polymeric antistatic binder composition which does not substantially gel or yellow upon heating to reclamation temperatures and a glycidoxy silane are used to strongly adhere the large particulates to the base sheet. The polymeric antistatic binder composition is a mixture of an acrylic polymer or copolymer with an antistatic copolymer. The use of large particulates and the use of the mixture of an acrylic polymer or copolymer and an antistatic copolymer improves antistatic properties without the need for yellowing, foul-odor producing amounts of nitrogenous antistatic agents or gel-forming amounts of cross-linking agents which would adversely affect reclaimability. An emulsified wax is included in the coating composition to reduce the static coefficient of friction of the overhead transparency.Type: GrantFiled: July 18, 1996Date of Patent: January 20, 1998Assignee: Hoechst Diafoil CompanyInventor: Stephen J. Gust
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Patent number: 5672428Abstract: A silicone release polyester film coated with an aqueous silicone coating composition on one surface. The aqueous silicone release coating composition is made up of an alkylvinylpolysiloxane containing vinyl groups, a tin or platinum catalyst, a glycidoxysilane and an alkylhydrogenpolysiloxane. A process for coating a polyester film with the aqueous silicone coating composition is also disclosed, where the coating occurs in-line, disclosing the manufacturing process for the film before it is heat-set. The silicone release coated polyester film has an acceptable release value when subjected to solvents or heat.Type: GrantFiled: October 17, 1995Date of Patent: September 30, 1997Assignee: Hoechst Celanese CorporationInventors: Kenneth J. Muschelweicz, Robert G. Posey
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Patent number: 5672421Abstract: In an improved power transmission belt, the circumferentially disposed reinforcing cords are made from multi-filament yarns of heterofilaments. These cords, when fused, have good inter-filament bonding without the solvent of the solvent/adhesive systems.Type: GrantFiled: August 19, 1996Date of Patent: September 30, 1997Assignee: Hoechst Celanese CorporationInventor: Harry W. Stanhope
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Patent number: 5658655Abstract: In an improved power transmission belt, the circumferentially disposed reinforcing cords are made from multi-filament yarns of heterofilaments. These cords, when fused, have good inter-filament bonding without the solvent of the solvent/adhesive systems.Type: GrantFiled: June 10, 1996Date of Patent: August 19, 1997Assignee: Hoechst Celanese CorporationInventor: Harry W. Stanhope
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Patent number: 5607777Abstract: The present invention discloses a subbing coating composition for polyester films comprising:I polymer A having attached to its backbonecarboxyl groups and/orgroups which form carboxyl groups upon hydrolysis anda polymer B having attached to its backbone --SO.sub.3 X and/or --PO.sub.3 XY groups, whereinX and Y are identical or different and denote an alkali metal, ammonium or hydrogenorII a polymer A' having attached to its backbonecarboxyl groups and/or groups which form carboxyl groups upon hydrolysis, and--SO.sub.3 X and/or --PO.sub.3 XY groups, wherein X and Y are identical or different and denote an alkali metal, ammonium or hydrogenandIII an organic compound C having at least two free hydroxy groups, wherein the coating composition does not comprise addition polymerizable compounds.Type: GrantFiled: June 7, 1995Date of Patent: March 4, 1997Assignee: Hoechst Celanese CorporationInventors: James J. Krejci, John M. Heberger, Cathy R. Moore, Robin M. Donald
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Patent number: 5562997Abstract: The present invention discloses a subbing coating composition for polyester films comprising:I - a polymer A having attached to its backbone- carboxyl groups and/or- groups which form carboxyl groups upon hydrolysis and- a polymer B having attached to its backbone --SO.sub.3 X and/or --PO.sub.3 XY groups, whereinX and Y are identical or different and denote an alkali metal, ammonium or hydrogenorII - a polymer A' having attached to its backbone- carboxyl groups and/or groups which form carboxyl groups upon hydrolysis, and- --SO.sub.3 X and/or --PO.sub.3 XY groups, whereinX and Y are identical or different and denote an alkali metal, ammonium or hydrogenandIII - an organic compound C having at least two free hydroxy groups, wherein the coating composition does not comprise addition polymerizable compounds.Type: GrantFiled: July 21, 1995Date of Patent: October 8, 1996Assignee: Hoechst Celanese CorporationInventors: James J. Krejci, John M. Heberger, Cathy R. Moore, Robin M. Donald
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Patent number: 5424120Abstract: The present invention describes a polymeric support film coated with a primer coating composition and overcoated with a silicone release coating, thereby forming a silicone release film. Silicone release films are well known and serve as temporary supports for an adhesive or tacky surface such as for labels, pressure sensitive tape, etc. The primer coating composition, before dilution with water, comprises from about 25 to 75% by weight of a glycidoxy silane and from about 75 to 25% by weight of a copolyester. The copolyester comprises from about 40 to 98 mol percent isophthalic acid; from about 0 to about 50 mol percent of at least one aliphatic dicarboxylic acid; from about 2 to about 20 mol percent of at least one sulfonate group attached to a dicarboxylic nucleus; and about 100 mol percent of glycol having from about 2 to 11 carbon atoms. Typical glycidoxy silanes that can be employed in the primer coating composition include glycidoxypropyltrimethoxysilane.Type: GrantFiled: February 10, 1993Date of Patent: June 13, 1995Assignee: Hoechst Celanese CorporationInventor: Edwin C. Culbertson
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Patent number: 5350601Abstract: The present invention describes a process for priming a polymeric film with a primer coating composition and overcoating with a silicone release coating. Silicone release films are well known and serve as temporary supports for an adhesive or tacky surface such as for labels, pressure sensitive tape, etc. The primer coating composition, before dilution with water, comprises from about 25 to 75% by weight of a glycidoxy silane and from about 75 to 25% by weight of a copolyester. The copolyester comprises from about 40 to 98 mol percent isophthalic acid; from about 0 to about 50 mol percent of at least one aliphatic dicarboxylic acid; from about 2 to about 20 mol percent of at least one sulfonate group attached to a dicarboxylic nucleus; and about 100 mol percent of glycol having from about 2 to 11 carbon atoms. Typical glycidoxy silanes that can be employed in the primer coating composition include glycidoxypropyltrimethoxysilane.Type: GrantFiled: November 6, 1991Date of Patent: September 27, 1994Assignee: Hoechst Celanese CorporationInventors: Edwin C. Culbertson, Grover L. Farrar
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Patent number: 5331929Abstract: A cylinder head for an internal combustion engine of either a two-cycle operation or a four-cycle operation is disclosed. The cylinder head includes an intake port, an exhaust port, a dual-function chamber, a poppet valve positioned within the dual-function chamber, and a flapper valve also positioned within the dual-function chamber, capable of sealing the intake port from the dual-function chamber, capable of sealing the exhaust port from the dual-function chamber. If the cylinder head is for a two-cycle engine, an injector may be positioned within the cylinder head so that fuel is injected either within the dual-function chamber, or directly injected within the combustion chamber. A process of operating the cylinder head in conjunction with an internal combustion engine is also disclosed.Type: GrantFiled: October 16, 1991Date of Patent: July 26, 1994Assignees: Ronald S. Plantan, Gregory N. Clements, Dewayne DemusInventor: Ronald S. Plantan
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Patent number: 5298325Abstract: The present invention describes a polymeric support film coated with a primer coating composition and overcoated with a silicone release coating, thereby forming a silicone release film. Silicone release films are well known and serve as temporary supports for an adhesive or tacky surface such as for labels, pressure sensitive tape etc. The primer coating composition, before dilution with water, comprises from about 25 to 75% by weight of a glycidoxy silane and from about 75 to 25% by weight of a copolyester. The copolyester comprises from about 65 to 98 mol percent isophthalic acid; from about 0 to about 30 mol percent of at least one aliphatic dicarboxylic acid; from about 2 to about 20 mol percent of at least one sulfonate group attached to a dicarboxylic nucleus; and about 100 mol percent of glycol having from about 2 to 11 carbon atoms. Typical glycidoxy silanes that can be employed in the primer coating composition include glycidoxypropyltrimethoxysilane.Type: GrantFiled: February 10, 1993Date of Patent: March 29, 1994Assignee: Hoechst Celanese CorporationInventor: Edwin C. Culbertson
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Patent number: 5288437Abstract: A process is described to produce ultra thin biaxially stretched film made of thermoplastic where at least two film webs are superimposed and stretched together in both the longitudinal and transverse directions. The film webs are subjected to a heat treatment before the first draw step. After stretching, the film webs are separated again from each other.Type: GrantFiled: May 4, 1992Date of Patent: February 22, 1994Assignee: Hoechst AktiengesellschaftInventors: Guenther Crass, Siegfried Janocha, Gisbert Bammert