Patents Represented by Attorney J. G. Carter
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Patent number: 4668745Abstract: Novel compositions are prepared by reacting sulfur dioxide with the reaction product of a material having an average of more than one 1,2-epoxide group per molecule such as a diglycidyl ether of bisphenol A with a monoethylenically unsaturated monocarboxylic acid such as methacrylic acid in the presence of an oxidizing agent such as cumene hydroperoxide.Type: GrantFiled: June 4, 1986Date of Patent: May 26, 1987Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 4662228Abstract: For use in inspecting composite materials made of fibers in a supportive polymer matrix, a test instrument and method are set forth. The apparatus uses an optical microscope to provide a view of a cut specimen having small fibers therein. The optical axis through the microscope defines an arbitrary location. In x and y dimensions, at an offset of m and n from the optical axis, a stylus having a tip is located. Through the use of stepping motors connected through appropriate gear boxes, the stage supporting the specimen is moved. This locates a particular fiber previously positioned coincident with the optical axis so that it can be tested. Testing is accomplished by moving through the offset distances of m and n to position the stylus tip over the particular fiber. On movement in the z axis, the tip is embedded in the fiber to test bonding.Type: GrantFiled: December 27, 1985Date of Patent: May 5, 1987Assignee: The Dow Chemical CompanyInventor: Ming K. Tse
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Patent number: 4654273Abstract: An electromagnetic shielded body comprising laminating or adhering to the surface of the body or incorporating as an internal lamina of a multiple laminar body a layer of film or powder of an electroconductive material which consists of a dehydrohalogenated haloorganic polymer or copolymeric material prepared by dehydrohalogenating said haloorganic polymeric material in the presence of at least one-half mole of a liquid or solution of an amine per mole of halogen moiety in said polymeric material at from 15.degree. C. to about 250.degree. C. for from about 2 minutes to about 14 days.Type: GrantFiled: March 31, 1986Date of Patent: March 31, 1987Assignee: The Dow Chemical CompanyInventors: Arthur E. Gurgiolo, Marvin E. Winquist, Thomas M. Knobel, Dale C. Teeters
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Patent number: 4654414Abstract: Thermosettable prepolymers or polymers are prepared by reacting (A) the reaction product of (1) a heterocyclic material having one or more rings, at least one nitrogen atom and at least two substituent groups which have at least one reactive hydrogen atom attached to a carbon atom which is attached to a heterocyclic ring such as 2,3,5,6-tetramethylpyrazine; (2) a cycloaliphatic or aromatic carboxylic acid mono- or dianhydride such as pyromellitic dianhydride; and (3) a material containing a polymerizable ethylenically unsaturated group and at least one group selected from (a) a heterocyclic material having one or more rings; at least one nitrogen atom and at least one substituent group which has at least one reactive hydrogen atom attached to a carbon atom which is attached to a heterocyclic ring such as 2-methyl-5-vinyl pyridine or (b) a cycloaliphatic or aromatic carboxylic acid mono- or dianhydride group such as cis-5-norbornene-endo-2,3-dicarboxylic anhydride; with (B) an aqueous or alcoholic solution ofType: GrantFiled: February 28, 1986Date of Patent: March 31, 1987Assignee: The Dow Chemical CompanyInventor: Duane S. Treybig
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Patent number: 4649188Abstract: The 2-functional content of phenol-aldehyde novolac resins is reduced by water extraction. Epoxy novolac resins prepared from the novolac resin containing less 2-functional product exhibit increased Tg values when cured.Type: GrantFiled: January 13, 1986Date of Patent: March 10, 1987Assignee: The Dow Chemical CompanyInventors: James L. Bertram, Louis L. Walker, Avis L. McCrary, Fermin M. Cortez
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Patent number: 4634506Abstract: An olefin oxide is produced from an olefin in an electrolytic cell by mixing an aqueous electrolyte and liquid olefin under pressure, flowing the liquid mixture through a restricting device into the electrolytic bath of the cell to reduce the pressure of the mixture and to vaporize the olefin, and applying an electric current to the electrolyte/olefin mixture. The electrolyte includes a metal halide, a carbonate salt and a bicarbonate salt.Type: GrantFiled: August 12, 1985Date of Patent: January 6, 1987Assignee: The Dow Chemical CompanyInventors: Leo R. Novak, Dennis J. Milligan
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Patent number: 4629762Abstract: A composition comprising (A) a polyphenol such as bisphenol A, (B) a polymer resulting from polymerizing (1) an alkenyl phenol such as p-isopropenylphenol and (2) a polymerizable ethylenically unsaturated monomer such as 2-ethylhexyl acrylate can be converted to a copolymer modified polycyanate by reaction with a cyanogen halide such as cyanogen chloride in the presence of a base such as triethylamine. These polycyanates can be cured by trimerization in the presence of a suitable catalyst or by copolymerization with an epoxy resin. Epoxy resins can also be prepared from the composition comprising components (A) and (B) by reaction with an epihalohydrin such as epichlorohydrin and subsequent dehydrohalogenation with a basic acting compound such as sodium hydroxide.Type: GrantFiled: March 24, 1986Date of Patent: December 16, 1986Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 4629764Abstract: A composition comprising (A) a polyphenol such as bisphenol A, (B) a polymer resulting from polymerizing (1) an alkenyl phenol such as p-isopropenylphenol and (2) a polymerizable ethylenically unsaturated monomer such as 2-ethylhexyl acrylate can be converted to a copolymer modified polycyanate by reaction with a cyanogen halide such as cyanogen chloride in the presence of a base such as triethylamine. These polycyanates can be cured by trimerization in the presence of a suitable catalyst or by copolymerization with an epoxy resin. Epoxy resins can also be prepared from the composition comprising components (A) and (B) by reaction with an epihalohydrin such as epichlorohydrin and subsequent dehydrohalogenation with a basic acting compound such as a sodium hydroxide.Type: GrantFiled: March 24, 1986Date of Patent: December 16, 1986Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 4629770Abstract: Thermosettable prepolymers or resins are prepared by reacting (1) a pyrazine compound containing at least two substituent groups which have a hydrogen atom attached to a carbon atom which is attached to the ring such as tetramethylpyrazine, (2) a material containing at least two aromatic aldehyde groups, and (3) at least one of (a) a nitrogen containing aromatic heterocyclic compound containing at least one hydrogen atom attached to a carbon atom attached to the ring and a polymerizable unsaturated group such as 2-methyl-5-vinylpyridine or (b) an aldehyde containing at least one polymerizable unsaturated group such as 4-isopropenyl-1-cyclohexene-1-carboxaldehyde. These prepolymers or resins are curable to thermoset products having good mechanical and thermal properties by heat and pressure or by homopolymerization or copolymerization with N,N'-bis-imides such as 1,1'-(methylenedi-4,1-phenylene)-bismaleimide. The prepolymers are suitable for preparing composites.Type: GrantFiled: April 23, 1985Date of Patent: December 16, 1986Assignee: The Dow Chemical CompanyInventor: Duane S. Treybig
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Patent number: 4629763Abstract: A composition comprising (A) a polyphenol such as bisphenol A, (B) a polymer resulting from polymerizing (1) an alkenyl phenol such as p-isopropenylphenol and (2) a polymerizable ethylenically unsaturated monomer such as 2-ethylhexyl acrylate can be converted to a copolymer modified polycyanate by reaction with a cyanogen halide such as cyanogen chloride in the presence of a base such as triethylamine. These polycyanates can be cured by trimerization in the presence of a suitable catalyst or by copolymerization with an epoxy resin. Epoxy resins can also be prepared from the composition comprising components (A) and (B) by reaction with an epihalohydrin such as epichlorohydrin and subsequent dehydrohalogenation with a basic acting compound such as sodium hydroxide.Type: GrantFiled: March 24, 1986Date of Patent: December 16, 1986Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 4624975Abstract: The hydrolyzable halide content of glycidyl ethers prepared by dehydrohalogenating a halohydrin ether intermediate product in the presence of an organic solvent, washing the resultant product with water and distilling the solvent from the organic phase from the water wash step is stabilized when the distillation step is conducted in the presence of a sulfonic acid, sulfonic acid ester, organic sulfate or any combination thereof such as p-toluene sulfonate.Type: GrantFiled: September 20, 1985Date of Patent: November 25, 1986Assignee: The Dow Chemical CompanyInventor: Ha Q. Pham
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Patent number: 4623701Abstract: Multifunctional epoxy resins are prepared by reacting (1) a polyglycidyl ether of a polyhydroxyl-containing material said glycidyl ether having an average of at least 0.Type: GrantFiled: July 10, 1985Date of Patent: November 18, 1986Assignee: The Dow Chemical CompanyInventor: John L. Massingill
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Patent number: 4623707Abstract: .alpha.-Olefins are polymerized in the presence of Ziegler-Natta catalysts which are polymer supported compounds or complexes of elements of the d-block transition metals, lanthanide or actinide series. An example of the polymer support is chloromethylated polystyrene-divinyl benzene copolymer covalently bonded to catechol. An example of the compound or complex of an element of the transition metal, lanthanide or actinide series is that which results when catechol which is covalently bonded to the polymer is contacted with titanium tetraisopropoxide.Type: GrantFiled: December 10, 1985Date of Patent: November 18, 1986Assignee: The Dow Chemical CompanyInventors: Stephen A. Bedell, William M. Coleman, III, William R. Howell, Jr.
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Patent number: 4622309Abstract: Novel titanium compounds or complexes are prepared by reacting a titanium compound such as titanium tetraisopropoxide with a compound containing at least one aliphatic hydroxyl group. These compounds and/or complexes are useful as the transition metal component in supported Ziegler-Natta catalysts.Type: GrantFiled: October 28, 1985Date of Patent: November 11, 1986Assignee: The Dow Chemical CompanyInventors: William M. Coleman, III, Morris S. Edmondson
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Patent number: 4618658Abstract: Polymer modified epoxy resin compositions are disclosed which comprise (A) an epoxy resin wherein a portion of the epoxide groups have been reacted to provide groups containing polymerizable ethylenic unsaturation; (B) at least one vinyl terminated urethane oligomer and optionally (C) at least one polymerizable ethylenically unsaturated compound. These compositions are useful as intermediates to novel polymer modified vinyl esters and thermoset (cured) products.Type: GrantFiled: May 16, 1985Date of Patent: October 21, 1986Assignee: The Dow Chemical CompanyInventors: Robert E. Hefner, Jr., Virginia B. Messick
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Patent number: 4618526Abstract: Curable compositions are disclosed which comprise a multiglycidyl ether such as the triglycidylether of tris(hydroxyphenyl)methane and an amine substituted sulfonic acid amide such as sulfanilamide. These compositions can be cured by heating in the presence or absence of an accelerator such as 2-methyl imidazole. These compositions are particularly useful in the preparation of electrical laminates.Type: GrantFiled: July 22, 1985Date of Patent: October 21, 1986Assignee: The Dow Chemical CompanyInventors: Jody R. Berman, Dennis L. Steele, Michael P. Kubisiak
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Patent number: 4614788Abstract: Disclosed are thermosettable compositions comprising (A) an epoxy resin such as the diglycidyl ether of bisphenol A; (B) boron trifluoride complexed with a primary, secondary or tertiary amine such as monoethanolamine and (C) at least one cyclic or acyclic phosphazene having at least one pendant ##STR1## group wherein Z is an alkyl or an aryl group such as hexa(n-propylamino)cyclotriphosphazene.When cured, these compositions have an increased glass transition temperature (Tg) value as compared to a similar composition without the phosphazene compound.These compositions are useful in potting compositions, wet lay-up and pre-impregnated laminate, adhesive, molding, coating, casting, encapsulation, filament winding and transfer molding applications.Type: GrantFiled: August 28, 1985Date of Patent: September 30, 1986Assignee: The Dow Chemical CompanyInventors: Marvin L. Dettloff, Dennis L. Steele, Ross C. Whiteside, Jr.
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Patent number: 4613663Abstract: Thermoplastic or thermosettable products are prepared by reacting a heterocyclic compound containing at least one nitrogen atom and at least two pendant groups containing a reactive hydrogen atom attached to a carbon atom which is attached to the aromatic heterocyclic ring such as 2,4,6-trimethylpyridine or 2,3,5,6-tetramethylpyrazine with an aldehyde having a hydrogen atom attached to a carbon atom adjacent to the carbonyl group such as phenylacetaldehyde. Also, heat resistant thermoplastic or thermosettable products are prepared by reacting the above product with either a hydroxy aromatic monoaldehyde such as 4-hydroxybenzaldehyde, aromatic dialdehyde such as terephthaldicarboxaldehyde or mixture thereof. Many of these products exhibit bulk conductive properties when doped with a dopant (doping agent) such as antimony pentafluoride.Type: GrantFiled: September 19, 1985Date of Patent: September 23, 1986Assignee: The Dow Chemical CompanyInventor: Duane S. Treybig
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Patent number: 4612359Abstract: Thermosettable compositions are prepared which contain (A) from about 0.1 to 100 percent by weight of an esterified aromatic cyanate; (B) from zero to about 99.9 percent by weight of an aromatic polycyanate, an aromatic polycyanamide or mixture thereof and (C) from zero to about 99.9 percent by weight of an epoxy resin.Type: GrantFiled: October 16, 1985Date of Patent: September 16, 1986Assignee: The Dow Chemical CompanyInventor: Robert E. Hefner, Jr.
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Patent number: 4612156Abstract: Resinous materials are produced in the substantial absence of a solvent by feeding to an extruder operated at a temperature sufficient to cause a reaction between the reactants (A) at least one material having an average of more than one vicinal epoxy group per molecule, (B) at least one material having an average of more than one group reactive with component (A) such as hydroxyl, thiol, carboxyl, isocyanate, thioisocyanate or secondary amine groups or a combination of such groups per molecule or a material having only one primary amine group per molecule, (C) at least one catalyst for promoting a reaction between components (A) and (B) if a catalyst is required to effect the reaction between components (A) and (B), and (D) optionally one or more chain terminators and thereafter recovering a resinous material resulting from the reaction between components (A) and (B) from said extruder.This process is useful in preparing advanced epoxy resins and phenoxy thermoplastic resins.Type: GrantFiled: November 19, 1985Date of Patent: September 16, 1986Assignee: The Dow Chemical CompanyInventors: Ben W. Heinemeyer, Sammy D. Tatum