Patents Represented by Attorney J. G. Carter
  • Patent number: 4521330
    Abstract: A method for gelling relatively high molecular weight polyoxyalkylene-containing materials having a block of at least about 10 weight percent of oxyethylene units by blending therewith a sufficient quantity of a relatively low molecular weight material having at least two hydroxyl groups per molecule containing urea dissolved therein.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: June 4, 1985
    Assignee: The Dow Chemical Company
    Inventors: Franciszek Olstowski, Richard D. Peffley
  • Patent number: 4519843
    Abstract: An aqueous hydraulic cement slurry is disclosed which comprises water, a hydraulic cement, a surfactant and, as a fluid loss additive, epihalohydrin derivatives of polyalkylenepolyamines.
    Type: Grant
    Filed: August 8, 1984
    Date of Patent: May 28, 1985
    Assignee: The Dow Chemical Company
    Inventors: Stephen B. Willis, Pamela J. Boyce
  • Patent number: 4515846
    Abstract: Polyurethane backed carpet prepared from a urethane-forming composition containing a catalyst composition containing at least one conventional catalyst and at least one delayed action heat activated catalyst results in a carpet having an improvement in at least one of tack-free time, edge curl and tuft lock.
    Type: Grant
    Filed: April 9, 1984
    Date of Patent: May 7, 1985
    Assignee: The Dow Chemical Company
    Inventors: Linda M. McKinney, Osborne K. McKinney
  • Patent number: 4515934
    Abstract: Vinyl ester resin compositions containing triazine groups or both triazine and oxazoline groups are prepared by reacting (a) a polyepoxide containing triazine groups, or (b) a polyepoxide containing both triazine and oxazoline groups, or (c) a mixture of (a) and (b) above with (d) about 0.75 to about 1, preferably from about 0.9 to about 1, moles of a monounsaturated monocarboxylic acid or mixture of monounsaturated monocarboxylic acids per epoxide group in the presence of (e) a suitable quantity of a suitable catalyst.
    Type: Grant
    Filed: March 19, 1984
    Date of Patent: May 7, 1985
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4507412
    Abstract: High solids coatings are prepared from (1) adducts of a polyepoxide and a polyamine and (2) a polyisocyanate blocked with a ketoxime or lactam.
    Type: Grant
    Filed: July 6, 1984
    Date of Patent: March 26, 1985
    Assignee: The Dow Chemical Company
    Inventors: Richard A. Hickner, Michael B. Cavitt
  • Patent number: 4506063
    Abstract: Advanced epoxy resins are prepared which contain triazine groups or both triazine and oxazoline groups. When cured, these resins have higher heat distortion temperatures and/or higher elongation values than advanced epoxy resins which do not contain triazine groups or triazine and oxazoline groups.
    Type: Grant
    Filed: February 22, 1984
    Date of Patent: March 19, 1985
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4500442
    Abstract: Hydroxylated lecithins are employed as mold release agents in the preparation of molded articles from polyurethane-forming compositions. Polyol compositions containing such mold release agents are also disclosed.
    Type: Grant
    Filed: February 10, 1984
    Date of Patent: February 19, 1985
    Assignee: The Dow Chemical Company
    Inventor: Louis W. Meyer
  • Patent number: 4499255
    Abstract: Epoxy resins are prepared by reacting an excess of an epihalohydrin with a phenolic hydroxyl-containing compound in the presence of the incremental addition of a basic catalyst while removing water by codistilling with a solvent and epihalohydrin.
    Type: Grant
    Filed: August 16, 1983
    Date of Patent: February 12, 1985
    Assignee: The Dow Chemical Company
    Inventors: Chun S. Wang, Ha Q. Pham, James L. Bertram
  • Patent number: 4496661
    Abstract: Compositions exhibiting high catalytic activity in the polymerization of .alpha.-olefins are prepared by reacting a mixture of a tetrahydrocarbyloxy titanium compound such as tetraisopropyl titanate and/or a titanium tetrahalide such as titanium tetrachloride and a titaniumoxydihalide such as titaniumoxydichloride, an organomagnesium component such as a hydrocarbon soluble complex of dialkyl magnesium and an organoaluminum compound such as triethyl aluminum and a halide source such as ethyl aluminum dichloride. Polymerization processes employing this catalyst composition do not require conventional catalyst removal steps in order to provide polymers having suitable color and other physical characteristics and these catalysts provide higher efficiencies and a broader molecular weight distribution than those catalysts employing either of the titanium compounds alone.
    Type: Grant
    Filed: October 24, 1983
    Date of Patent: January 29, 1985
    Assignee: The Dow Chemical Company
    Inventor: Randall S. Shipley
  • Patent number: 4496709
    Abstract: Epoxy resins having improved properties are prepared by reacting an epoxy resin with a dihydric phenol in the presence of a sufficient quantity of a phosphonium trifluoroacetate catalyst such that the product resulting from reacting a mixture of the catalyst, epoxy resin and dihydric phenol has a % epoxide difference from the theoretical percent epoxide of from about 0.5 to about 4.0.
    Type: Grant
    Filed: June 16, 1983
    Date of Patent: January 29, 1985
    Assignee: The Dow Chemical Company
    Inventors: George A. Doorakian, Marsha A. Paul, Adolphus V. Gist
  • Patent number: 4496660
    Abstract: A catalyst for polymerizing olefins is the reaction product of (A) the reaction product of (1) the reaction product of (a) an alkyl magnesium compound such as dibutylmagnesium, with (b) an oxygen-containing and/or nitrogen-containing compound such as n-propyl alcohol, or isopropylamine, with (2) a halide source such as titanium tetrachloride or silicon tetrachloride; and (B) a transition metal compound such as titanium tetrachloride and (C) a reducing agent such as triisobutylaluminum.Also disclosed is a non-transition metal containing catalyst support for use in preparing olefin polymerization catalysts.The polymers which are produced in the presence of this catalyst and a cocatalyst such as triethylaluminum have a low catalyst support to transition metal ratio and therefore, the catalyst efficiency based on quantity of polymer per quantity of total catalyst is very high resulting in a polymer having good color and very little, if any, corrosion.
    Type: Grant
    Filed: October 1, 1980
    Date of Patent: January 29, 1985
    Assignee: The Dow Chemical Company
    Inventors: Donald E. Gessell, Ronald L. Gibbs, Ricardo Fuentes, Jr.
  • Patent number: 4489202
    Abstract: Epoxy resins containing triazine groups are prepared by (I) reacting (A) a material having at least one aromatic hydroxyl group per molecule such as bisphenol A with (B) a cyanogen halide such as cyanogen bromide in the presence of (C) a base and recovering a mixture of cyanate-containing products and unreacted (A) materials; (II) trimerizing the product recovered in (I) in the presence of a trimerization catalyst such as cobalt naphthenate and (III) epoxidizing the product from step II by reaction with an epihalohydrin such as epichlorohydrin, dehydrohalogenation of the resultant product with a basic acting material such as sodium hydroxide and recovering the resultant epoxy resin containing triazine groups.
    Type: Grant
    Filed: October 31, 1983
    Date of Patent: December 18, 1984
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4487915
    Abstract: The subject oligomers are prepared by reacting a diphenol with a cyanogen halide in the presence of an alkaline agent. The resultant product is then reacted with an epoxy resin thereby producing a hydroxy aromatic oligomers containing triazine and oxazoline groups. An epoxy resin is then prepared by reacting the previously formed oligomers with an epihalohydrin followed by dehydrohalogenation of the resultant product.
    Type: Grant
    Filed: February 2, 1984
    Date of Patent: December 11, 1984
    Assignee: The Dow Chemical Company
    Inventor: Robert E. Hefner, Jr.
  • Patent number: 4485031
    Abstract: Incompatible compositions containing a relatively high molecular weight polyol containing terminal primary amine groups and a relatively low molecular weight polyol containing primary hydroxyl groups are rendered compatible by the addition thereto of a substituted urea such as dimethyl urea.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: November 27, 1984
    Assignee: The Dow Chemical Company
    Inventors: Franciszek Olstowski, Richard D. Peffley
  • Patent number: 4485032
    Abstract: Compositions containing a relatively high molecular weight polyol and ethylene glycol which compositions are incompatible, i.e. separate into two distinct phases upon storage, are compatibilized by the admixture therewith of urea or a substituted urea.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: November 27, 1984
    Assignee: The Dow Chemical Company
    Inventors: Franciszek Olstowski, Richard D. Peffley
  • Patent number: 4483894
    Abstract: Substrates having a backing of fine celled polyurethane foam are prepared by applying to the back of the substrate a frothed polyurethane forming composition containing small amounts of a silicone surfactant having an average molecular weight below about 30,000 which provides the resultant foam with a cell count value of greater than about 16 per 0.0025 square inches and wherein the unfilled, unfrothed liquid components of said polyurethane forming composition obtains a viscosity of greater than 10,000 centipoise in less than 40 minutes at 25.degree. C.
    Type: Grant
    Filed: March 30, 1983
    Date of Patent: November 20, 1984
    Assignee: The Dow Chemical Company
    Inventors: James R. Porter, Randall C. Jenkines
  • Patent number: 4482667
    Abstract: Modified polyalkylenepolyamine compositions are prepared which are useful as fluid loss additives.
    Type: Grant
    Filed: March 5, 1984
    Date of Patent: November 13, 1984
    Assignee: The Dow Chemical Company
    Inventors: Stephen B. Willis, Pamela J. Boyce
  • Patent number: 4482692
    Abstract: Epoxy resin compositions are disclosed which are the reaction products resulting from reacting (A) the reaction product of a cyanuric halide and at least one dihydric or polyhydric phenol with (B) at least one dihydric or polyhydric phenol and (C) at least one epoxy resin having an average of more than one epoxy group per molecule. These epoxy resin compositions are suitable for use as electrical laminates, structural laminates, coatings, castings, electrical encapsulation and the like.
    Type: Grant
    Filed: October 24, 1983
    Date of Patent: November 13, 1984
    Assignee: The Dow Chemical Company
    Inventors: James L. Bertram, William Davis, Louis L. Walker
  • Patent number: 4481347
    Abstract: Phosphorus-containing epoxy resins are prepared by reacting an epoxy resin with a polyhydric phenolic compound and a phosphoramide.
    Type: Grant
    Filed: October 24, 1983
    Date of Patent: November 6, 1984
    Assignee: The Dow Chemical Company
    Inventors: James L. Bertram, William Davis
  • Patent number: 4481320
    Abstract: The blocking characteristics of ethylene interpolymers containing --COOH groups are reduced by treating such polymers with a solution of an inorganic compound of a Group I-A metal such as trisodium phosphate and an organic compound of a Group I-A metal such as sodium acetate or a combination thereof.
    Type: Grant
    Filed: February 24, 1984
    Date of Patent: November 6, 1984
    Assignee: The Dow Chemical Company
    Inventors: David P. Flores, James A. Allen