Abstract: A method and apparatus for perforating and stimulating a subterranean formation which is penetrated by a well bore having casing positioned therein so as to establish fluid communication between the formation and the well bore. A shell, sheath or sleeve of propellant material is positioned so as to substantially encircling at least one shaped charge in a subterranean well bore and is ignited due to the shock, heat and/or pressure generated from the detonated charge. Upon burning, the propellant material generates gases which clean perforations formed in the formation by detonation of the shaped charge(s) and which extend fluid communication between the formation and the well bore.

Abstract: Recovery of an insoluble polymeric sulfur species from the reaction solution of a hydrogen sulfide conversion process is enhanced by adding a sulfur debonding agent to the hydrogen sulfide conversion reaction solution either at the outset of the process or after conversion of the hydrogen sulfide. Conversion of the hydrogen sulfide initially produces a soluble complex having the polymeric sulfur bound therein. The sulfur debonding agent breaks the soluble complex to produce a free insoluble polymeric species readily separable from the reaction solution by conventional physical means to obtain the desired sulfur product.

Abstract: A system and process are provided for converting a light hydrocarbon gas to a synthetic heavier hydrocarbon liquid. The system includes an autothermal reformer, a Fischer-Tropsch reactor and a Brayton cycle that are structurally and functionally integrated. In the practice of the process, a mixture of a hydrocarbon feed gas, a compressed air feed and process steam is fed to the autothermal reformer to produce a synthesis gas. The synthesis gas is fed to the Fischer-Tropsch reactor where it is catalytically reacted to produce heavy hydrocarbons. The outlet from the Fischer-Tropsch reactor is separated into water, a low heating value tail gas, and the desired hydrocarbon liquid product. The water is pressurized and heated to generate process steam. The tail gas is heated and fed with compressed air and steam to the Brayton cycle having a combustor and a series of power turbines and compressors.

Abstract: A process for fracturing a subterranean formation below an earthen surface in fluid communication with a wellbore. A foamed fracturing fluid comprising an aqueous solvent, a water-soluble synthetic polymer, a surfactant, and a gas is premixed at the surface. The aqueous solvent may be a fresh water or a brine. The fracturing fluid may additionally comprise a proppant, fluid loss additive, and/or a foam breaker. After the fluid is mixed and foamed, it is injected into the formation via the wellbore at a pressure sufficient to induce at least one hydraulic fracture in the formation.

Abstract: Polymer enhanced foam fluid is utilized for completion, workover, and kill operations in wells penetrating subterranean formations. The foam is formed by appropriately adding a gas to an aqueous solution of a substantially noncrosslinked water soluble polymer and a surfactant. The solution and the foam are substantially free of crosslinking agents. The foam may be generated at the surface or in a wellbore.

Abstract: A method and apparatus for studying the conditions under which multiple condensed phases form during production, transportation, and processing of crude oil and other organic liquids. The sample temperature and pressure are controlled, and changes in fluorescence and/or electrical conductance or conductivity occurring within the sample due to formation of multiple condensed phases are detected. The measurements are made using a cell containing the liquid sample at elevated temperature and pressure. The cell has a generally cylindrical housing and separate means for visually inspecting a liquid sample which is present within the cell, controlling the temperature of the liquid sample, controlling the pressure of the liquid sample, detecting fluorescence changes occurring within the sample, and determining the electrical conductivity of the sample.

Abstract: An apparatus and process are provided for drilling and completing multiple subterranean wells from a template which is secured within a cased well bore extending to the surface. An orienting cam having a bore therethrough is positioned above the template such that the bore through the orienting cam is automatically aligned with one of at least two bores through the template. Fluid tight seals are provided between the orienting cam and the casing and between the orienting cam and one of the at least two bores through the template. Thereafter, a drill string including a drill bit is lowered from the surface of the earth through the casing, the bore through the orienting cam and the one bore through said template to drill a first subterranean well bore.

Abstract: A process employing a foamed gel in a wellbore as a completion, workover, or kill fluid. The foamed gel is formed from an aqueous solvent, a water-soluble carboxylate-containing polymer crosslinked by a crosslinking agent containing a reactive transition metal cation, a surfactant, and an added gas. The foamed gel is placed in the wellbore, where it substantially prevents the flow of formation fluid into or out of the wellbore. The completion, workover, or kill operation is then performed. Alternatively, the foamed gel may be combined with another completion, workover, or kill fluid after commencing a wellbore operation.

Abstract: A subterranean well system and a process for drilling and completing such a system from a first subterranean well bore which extends to the surface of the earth. A second well bore may be drilled from the first well bore and a first tubular of a multiple well drilling template can be positioned within the first well bore while a second tubular of the template can be positioned within both the first and second well bores. Additionally, a third well bore can be drilled from the first well bore and the first tubular can be further positioned therein. The first and second well bores can penetrate subterranean formation(s) or additional well bore(s) can be drilled from the first, second and/or third well bores so as to penetrate subterranean formations. A second multiple well drilling template may be utilized to drill such additional well bore(s) from the second or third well bores.

Abstract: An asphaltic roadway base or sub base which includes a by-product of petroleum refining units utilizing a Residuum Oil Supercritical Extraction (ROSE) process. The base course is a designed mixture of a resin-asphaltene residuum and aggregate, wherein the resin-asphaltene residuum has a penetration less than 10 at 77.degree. F. and a softening point above 150.degree. F., the resin-asphaltene residuum is present in the range of 3% to 12%, by weight of the composition, and the aggregate is present in the range of 88% to 97%, by weight of the composition.

Abstract: A process and composition are provided for permeability reduction in a hydrocarbon-bearing formation to improve hydrocarbon recovery therefrom. The process includes placement of a crosslinked polymer gel in the treatment region preceded by surface preparation of a gelation solution which is the gel precursor. The gelation solution contains a crosslinkable polymer, a chromium(III)/carboxylate complex crosslinking agent, a carboxylate salt delaying agent and an aqueous solvent. The gel is placed in the treatment region by injecting the gelation solution into a well bore in fluid communication with the formation, displacing it into the desired treatment region and gelling the solution to completion forming the permeability-reducing gel in situ. The gelation rate is retarded in a controlled manner by adjusting the composition or concentration of the delaying agent in the gelation solution.

Abstract: A process and composition are provided for permeability reduction in a treatment region to improve hydrocarbon recovery from a hydrocarbon-bearing formation. The process includes placement of a crosslinked polymer gel in the treatment region preceded by surface preparation of a gelation solution which is the gel precursor. The gelation solution contains a crosslinkable polymer, a chromium(III)/carboxylate complex crosslinking agent, a carboxylate salt delaying agent and an aqueous solvent. The gel is placed in the treatment region by injecting the gelation solution into a well bore in fluid communication with the treatment region, displacing it into the desired treatment region and gelling the solution to completion forming the permeability-reducing gel in situ. The gelation rate is retarded in a controlled manner by adjusting the composition or concentration, and correspondingly the pH, of the delaying agent in the gelation solution.

Abstract: An apparatus and method for perforating and fracturing subterranean formations to enhance fluid production. At least one unlined punch charge is loaded into at least one punch charge carrier, and the void spaces in the punch charge carrier are filled with sand. The punch charge carrier is assembled with at least one perforating charge carrier, loaded with at least one perforating charge, and a means for detonation. The assembly is positioned in a well containing a pressurized fluid adjacent the interval to be perforated and/or fractured, and the charges are detonated. The one or more punch charges create one or more apertures in the punch charge carrier, allowing sand to enter the well and be carried by the fluid in the well into the perforations and/or fractures created by the perforating charges and the pressurized fluid. The sand scours and/or props the perforations and/or fractures.

Abstract: A method and apparatus of activating electric wireline firing systems in which a firing pin is restrained against movement toward a detonator until application of sufficient voltage to the apparatus. The firing pin is not permitted to move immediately upon application of voltage to the apparatus thereby providing a period during which voltage may be interrupted to prevent detonation of the system. The requisite voltage which must be applied to the apparatus is relatively high thereby ensuring against premature detonation of the system due to high radio frequencies, stray voltages or other electrical influences.

Abstract: A composition of matter for matrix conformance formed from an aqueous solution of an alginate polysaccharide and a method of forming an alginate polysaccharide gel. A Group IIA cation, Fe.sup.2+, Fe.sup.3+, Al.sup.3+, Mn.sup.2 +, Zn.sup.2+, a dialdehyde, or a diamine may be used to crosslink the resulting alginate gel. The gel may also comprise a modifier, such as a polyvinyl alcohol, a polycarboxylic acid, or a polyacrylamide. The rate and extent of crosslinking are controlled by varying the alginate molecular weight, the alginate concentration, or the type and concentration of crosslinker, or by adding a sequestering agent such as EDTA or citrate.

Abstract: An apparatus and process for observing fluid replacement in core samples while simulating subsurface reservoir conditions, including oil composition, temperature, fluid pressure, and overburden pressure. Overburden pressure is applied to a core sample placed in the apparatus, and the core sample is saturated with a core saturating fluid at a pressure greater than the bubble point pressure of the core saturating fluid. One or more replacement fluids are provided in fluid communication with the core sample and at the same pressure as the core saturating fluid pressure. The apparatus is placed in a centrifuge and spun, and the extent and rate of replacement of the core saturating fluid in the core by a replacement fluid can be observed.

Abstract: A system and method is provided for storing a continuous length of an assembled jointed tubular conduit on an offshore vessel and for conveying the tubular conduit between the deck of the vessel and a subsurface wellhead on the floor of the body of water. The system includes a carousel positioned around the perimeter of the vessel defining a continuous close-curved carousel pathway in parallel or coplanar alignment with the horizontal deck. The assembled tubular conduit is maintained in coiled storage along the carousel pathway until it is desired to convey the tubular conduit into or out of the carousel. Horizontal and vertical directing means are provided that, in cooperation with rotation of the carousel, enable uncoiling of the tubular conduit from the carousel into the water or recoiling of the tubular conduit into the carousel from the water.

Abstract: A process for recovering entrained liquid from natural gas. The gas containing entrained liquid flows from a subterranean formation via a well into a gas/liquid separation chamber where the liquid and gas are separated by centrifugal force. One or more vanes mounted in one or more slits in the separator wall extend into the separation chamber and aid in transposing liquid through the slit or slits. Outside the chamber, the liquid drains into a storage tank. The gas is vented to the atmosphere or to a gas collection system. The separator chamber may be mounted inside a storage tank and may have an external shell around the chamber wall.

Abstract: A process employing a polymer enhanced foam in a wellbore as a drilling fluid during a wellbore drilling operation. The polymer enhanced foam is formed from an uncrosslinked acrylamide polymer, a surfactant, an aqueous solvent, and an added gas.

Abstract: An apparatus and method for controlling the pressure at which a fluid is introduced into a well penetrating a subterranean formation. The apparatus comprises a blow out sub having a sealed chamber between two plugs. The chamber is filled with a fluid at a known pressure. Thus, the pressure required to release the first plug is independent of the pressure in the well below the sub. The sub is attached to a tubular and positioned within the well. The first plug is then released upon application of a predetermined pressure fluid pressure, and the second plug is released upon application of a lesser pressure. The blow out sub may additionally comprise a tube forming a channel through the first plug, the chamber, and the second plug, with a means for controlling fluid flow through the channel. A first fluid may be introduced into the well via the channel prior to releasing the first plug.