Patents Represented by Attorney, Agent or Law Firm James L. De Cesare
  • Patent number: 6416817
    Abstract: A process of preparing an oxygen barrier coating using a compound of the general formula RaX3−aSi—Z—SiX3−aRa wherein Z is R′NH(R′NH)pR′, each R is selected from the group consisting of a hydrogen atom and a hydrocarbon group, each X is selected from the group consisting of an alkoxy group with 1 to 4 carbon atoms, a halogen atom, an oxime group or an acyloxy group, each R′ is a divalent hydrocarbon group having 1 to 12 carbon atoms; a is from 0 to 3 and p is 0 or 1. The invention further comprises compositions incorporating the above compound. Coatings prepared may be used in packaging applications as a top coat, or a primer for further coatings.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: July 9, 2002
    Assignees: Dow Corning SA, E.G. Technology Partners, L.P.
    Inventors: Imtiaz J. Rangwalla, John E. Wyman, Patrick Jacques Jean Merlin, Shrenik Mahesh Nanavati, Laurence Gallez
  • Patent number: 6409934
    Abstract: A polyester fiber treatment composition is capable of imparting good handle to polyester fiber, particularly polyester fiber wadding, padding, or fill, and consists of a water-based emulsion containing (A) an aminofunctional organopolysiloxane endblocked by alkoxy groups at its molecular chain terminals, (B) an aminofunctional organopolysiloxane endblocked by silanol groups at its molecular chain terminals, (C) a nonionic surfactant, and (D) water.
    Type: Grant
    Filed: October 23, 2000
    Date of Patent: June 25, 2002
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Tsutomu Naganawa, Isao Ona, Tadashi Takimoto
  • Patent number: 6410038
    Abstract: Water-in-oil-in-non-aqueous polar solvent W/O/PS type multiple emulsion contains a water phase W dispersed in an oil O as the first continuous phase of a primary emulsions W/O by an emulsifier. Primary emulsion W/O is dispersed in a second continuous non-aqueous polar solvent phase PS to form multiple emulsion W/O/PS. The emulsifier is a silicone elastomer containing polyether groups which is a network of polymeric molecules crosslinked with an &agr;,&ohgr;-unsaturated hydrocarbon.
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: June 25, 2002
    Assignee: Dow Corning Corporation
    Inventors: Zuchen Lin, William James Schulz, Jr.
  • Patent number: 6406684
    Abstract: Roll-on, soft solid paste, aerosol, and stick underarm compositions contain (i) an antiperspirant or deodorant active ingredient, (ii) a vehicle, (iii) an emollient, and (iv) a blend of a silicone rubber powder and an &agr;,&ohgr;-diene crosslinked silicone elastomer. When the silicone rubber powder and the &agr;,&ohgr;-diene crosslinked silicone elastomer are present in the blend in a weight ratio of 1:2 to 1:6, respectively, roll-on underarm compositions possess low separation of less than one percent, and syneresis is minimized in soft solid paste underarm compositions.
    Type: Grant
    Filed: September 10, 2001
    Date of Patent: June 18, 2002
    Assignee: Dow Corning Corporation
    Inventors: Cassandre Michelle Fecht, Michael Stephen Starch
  • Patent number: 6407159
    Abstract: A silicone rubber composition useful for keypads comprising a silicone rubber base produced by mixing under heat (A) a cross-linkable diorganopolysiloxane and (B) 20 to about 250 parts by weight calcium carbonate powder per 100 parts by weight of component (A), and (C) a curing agent consisting of (i) an organic peroxide or (ii) an organohydrogenpolysiloxane and a platinum catalyst in an amount sufficient to effect cure of the composition.
    Type: Grant
    Filed: December 6, 2000
    Date of Patent: June 18, 2002
    Assignee: Dow Corning Toray Silicone Co., Ltd.
    Inventors: Seiichi Sugimoto, Takahiro Sato
  • Patent number: 6387451
    Abstract: A curable coating composition which exhibits improved cure and adhesion to various substrates comprises a composition curable by a hydrosilylation reaction and includes a silicone resin, a hydrosilylation reaction inhibitor and an adhesion promoting additive which comprises an organosilicon compound having epoxy and alkoxy functionalities, an alkenylsilanol, an organotitanium compound and a metal chelate compound.
    Type: Grant
    Filed: July 11, 1996
    Date of Patent: May 14, 2002
    Assignee: Dow Corning Limited
    Inventors: Alan Collins, Antoon Peeters
  • Patent number: 6365640
    Abstract: A silicone rubber sponge composition, a silicone rubber sponge, and a process for making a silicone rubber sponge. The silicone rubber sponge composition comprises (A) 100 parts by weight of an organopolysiloxane gum described by average structural unit RaSiO(4−a)/2, where R is a monovalent hydrocarbon radical or haloalkyl and a is 1.95 to 2.05, (B) 1 to 400 parts by weight of an inorganic filler, (C) 0.01 to 50 parts by weight hollow thermoplastic resin particles (D) a mixture of (a) water-soluble silicone and (b) water in an amount such that the water in the mixture is equivalent to 0.01 to 10 parts by weight per 100 parts by weight of component (A), and (E) a curing agent in an amount sufficient to cure the composition.
    Type: Grant
    Filed: May 23, 2001
    Date of Patent: April 2, 2002
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Katsuya Baba, Manabu Suto, Hiroshi Honma, Akito Nakamura
  • Patent number: 6354620
    Abstract: A curable silicone-based coating composition, curable to a flexible coating at a coat weight of up to 15 g/m2 when cured, comprises an organopolysiloxane polymer having at least two silicon-bonded olefinically unsaturated hydrocarbon substituents, alkoxy groups or hydroxyl groups and having a degree of polymerization of no more than 150, a cross-linking organosilicon material having at least 3 silicon-bonded reactive groups and a catalyst. The coating composition optionally contains non-reinforcing filler but contains no more than 3% by weight of reinforcing filler. The coating is preferably used on a textile fabric that has an elastomeric coating on it, and reduces friction. It is particularly useful for airbags.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: March 12, 2002
    Assignees: Dow Corning Corporation, Dow Corning Ltd.
    Inventors: Graham D. Budden, Diane Marie Kosal, Patricia Ann Rolley
  • Patent number: 6346556
    Abstract: A silicone rubber sponge composition, a silicone rubber sponge, and a process for production thereof. The silicone rubber sponge composition comprises (A) 100 parts by weight organopolysiloxane gum described by average structural unit RaSiO(4−a)/2, where R is a monovalent hydrocarbon group or haloalkyl and a is 1.8 to 2.3 and having a viscosity at 25° C. of 1,000,000 mPa·s or above, (B) 1 to 400 parts by weight inorganic filler, (C) 0.01 to 50 parts by weight hollow thermoplastic resin particles, (D) 0.01 to 10 parts by weight a water-in-oil emulsion with silicone oil an oil phase, and (E) a curing agent in an amount sufficient to cure the composition.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: February 12, 2002
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Katsuya Baba, Manabu Suto, Akito Nakamura
  • Patent number: 6323268
    Abstract: A composition for rendering surfaces water repellent is formed by combining water or a solvent; a methylhydrogensiloxane polymer or copolymer; an alkoxysilane having the formula RaSi(OR′)4-a in which R represents an alkyl group containing 1-10 carbon atoms, an alkenyl group containing 2-8 carbon atoms, an aryl group, or an haloalkyl group, a has a value of 1 or 2, and R′ represents an alkyl group containing 1-6 carbon atoms; and a silicone resin. The composition can also contain other components such as a volatile methyl siloxane, a cationic oil-in-water emulsion of an aminofunctional polydimethylsiloxane, a surfactant, a catalyst, a beading agent, an organic wax, a preservative, an antifoam, a mildewcide, an UV absorber/UV light stabilizer, or a freeze-thaw additive.
    Type: Grant
    Filed: June 27, 2000
    Date of Patent: November 27, 2001
    Assignee: Dow Corning Corporation
    Inventors: Paul David Fisher, Feifei Lin, Lori Ann Stark-Kasley
  • Patent number: 6319980
    Abstract: An organic silicon compound emulsion for quickly imparting excellent water-repellent properties to the surfaces of porous inorganic base materials such as concrete, mortar, and masonry. The emulsion is prepared by the steps of emulsifying a mixture consisting of (A) an organoalkoxysilane, (B) an organopolysiloxane having in its molecule at least 2 alkoxy groups or hydroxyl groups bonded to a silicon atom, (C) an anionic emulsifying agent, and (D) water, and heat aging the emulsion at a temperature below 100° C. In another embodiment, the method comprises the steps emulsifying a mixture of the components (A) to (D) and adding an acidic or alkaline substance to the emulsion. In a third embodiment, the method comprises the steps of forming a mixture consisting of the components (A) to (D), adding an acidic or alkaline substance thereto, and performing the emulsification thereafter.
    Type: Grant
    Filed: October 19, 1999
    Date of Patent: November 20, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Hiroki Ishikawa, Atsushi Sakuma, Tsutomu Naganawa, Naohiro Muramoto, Isao Ona
  • Patent number: 6303675
    Abstract: A silicone rubber composition comprising 0.01 to 50 weight percent of a perfluoroalkyl group-containing polydiorganosiloxane having on a side chain (F1) an organic group selected from the group consisting of polyoxyalkylene group-containing organic groups, C12 or higher alkyl group, and polydialkylsiloxane chain-containing organic groups, and having of a side chain or at a molecular chain terminal (F2) a perfluoroalkyl group-containing organic group described by the general formula F(CF2)a—R1—, where R1 is selected from the group consisting of an alkylene group, an alkyleneoxyalkylene group, and a group in which ═CO or —COO— is present in an alkylelne chain, and a is an integer of at least 3, and having a weight average molecular weight of at least 1000.
    Type: Grant
    Filed: February 21, 2000
    Date of Patent: October 16, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Hideki Kobayashi, Hiroshi Honma, Toru Masatomi
  • Patent number: 6300383
    Abstract: A silicone rubber sponge composition, a silicone rubber sponge, and a process for making the silicone rubber sponge. The silicone rubber sponge composition comprises (A) 100 parts by weight organopolysiloxane gum described by average structural unit RaSiO(4−a)/2, where R is a monovalent hydrocarbon group or haloalkyl and a is 1.8 to 2.3 and having a viscosity of 1,000,000 mPa·s or above at 25° C., (B) 1 to 400 parts by weight inorganic filler, (C) 0.01 to 50 parts by weight hollow thermoplastic resin particles, (D) 0.1 to 10 parts by weight liquid compound with a boiling point above room temperature, and (E) a curing agent in an amount sufficient to cure the composition.
    Type: Grant
    Filed: March 29, 2001
    Date of Patent: October 9, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Katsuya Baba, Hiroshi Honma, Akito Nakamura
  • Patent number: 6300382
    Abstract: A silicone rubber sponge composition, a silicone rubber sponge, and a process for making a silicone rubber sponge. The silicone rubber sponge composition comprises (A) 100 parts by weight of an organopolysiloxane gum described by average structural unit RaSiO(4−a)/2, where R is a monovalent hydrocarbon radical or haloalkyl and a is 1.95 to 2.05, (B) 1 to 400 parts by weight of an inorganic filler, (C) 0.01 to 50 parts by weight hollow thermoplastic resin particles (D) a mixture of (a) water-soluble silicone and (b) water in an amount such that the water in the mixture is equivalent to 0.01 to 10 parts by weight per 100 parts by weight of component (A), and (E) a curing agent in an amount sufficient to cure the composition.
    Type: Grant
    Filed: March 6, 2001
    Date of Patent: October 9, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Katsuya Baba, Manabu Suto, Hiroshi Honma, Akito Nakamura
  • Patent number: 6300384
    Abstract: A silicone rubber sponge composition, a silicone rubber sponge, and a process for production thereof. The silicone rubber sponge composition, comprises (A) 100 parts by weight organopolysiloxane gum described by average structural unit RaSiO(4−a)/2, where R is a monovalent hydrocarbon group or haloalkyl and a is 1.8 to 2.3 and having a viscosity at 25° C. of 1,000,000 mPa·s or above, (B) 1 to 400 parts by weight inorganic filler, (C) 0.01 to 50 parts by weight hollow thermoplastic resin particles, (D) 0.1 to 10 parts by weight thermally decomposable blowing agent, and (E) a curing agent in an amount sufficient to cure the composition.
    Type: Grant
    Filed: April 4, 2001
    Date of Patent: October 9, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Katsuya Baba, Hiroshi Honma, Akito Nakamura
  • Patent number: 6300287
    Abstract: A parting agent for a copier toner is disclosed. The parting agent exhibits no loss of parting properties or generation of gel under high-temperature conditions near 200° C., and causes no problems with paper feed or the like. The parting agent is composed of a diorganopolysiloxane of the average unit formula: RaSiO4−a/2, where the R groups are the same or different and are substituted or unsubstituted monovalent hydrocarbon groups, with at least 50 mol % of the R groups being methyl groups, and 1.95 ≦a≦2.20. The diorganopolysiloxane has a viscosity of 10 to 100,000 centistokes at 25° C., and generates no more than 5 ppm (by weight) of formaldehyde per hour when kept at 200° C. in an air atmosphere.
    Type: Grant
    Filed: April 27, 2000
    Date of Patent: October 9, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Hiroki Ishikawa, Tsutomu Naganawa, Isao Ona
  • Patent number: 6297318
    Abstract: Emulsion polymerization techniques can be improved by using in the reaction, a precursor which is a cocyclic silicone which has a structure generally corresponding to the formula: where a and b have a value of 1-10; R3, R4, and R5 are alkyl groups containing 1-6 carbon atoms; and R6 is a C8 or higher alkyl group such as —(CH2)7CH3, —(CH2)11CH3, or —(CH2)15CH3. R3, R4, and R5 are preferably methyl groups.
    Type: Grant
    Filed: August 7, 2000
    Date of Patent: October 2, 2001
    Assignee: Dow Corning Corporation
    Inventors: Daniel Joseph Halloran, Judith Mervane Vincent
  • Patent number: 6297291
    Abstract: The present invention is a low-specific-gravity liquid silicone rubber composition comprising (A) 100 parts by weight of diorganopolysiloxane which is liquid at room temperature and contains at least two silicon-bonded alkenyl groups in each molecule, (B) an organohydrogenpolysiloxane which has at least two silicon-bonded hydrogen atoms in each molecule at a mole ratio of silicone-bonded hydrogen atoms contained in this component (B) to silicon-bonded alkenyl groups contained in component (A) within a range of 0.3:1 to 5:1, (C) a platinum catalyst providing metallic platinum atoms in an amount of 0.1 to 500 parts by weight per 1,000,000 parts by weight of component (A) (D) 0.5 to 30 parts by weight of gas-filled hollow particles having shells made of a non-silicone thermoplastic resin, and (E) 0.05 to 10 parts by weight of gas-filled hollow particles having shells made of a thermoplastic silicone resin.
    Type: Grant
    Filed: February 20, 2001
    Date of Patent: October 2, 2001
    Assignee: Dow Corning Toray Silicone Company, Ltd.
    Inventors: Yuichi Tsuji, Yutaka Oka
  • Patent number: 6294634
    Abstract: A method of preparing organosilicon compositions by heating various mixtures of (i) dimethylcyclosiloxanes or methylhydrogencyclosiloxanes, (ii) homopolymeric and copolymeric cyclosiloxanes containing a C5 or more carbon atom containing group, and (iii) homopolymeric and copolymeric cyclosiloxanes containing an oxyalkylene segment, in the presence of a catalyst, at a temperature and for a time sufficient to cause polymerization of cyclosiloxanes (i) to (iii) to the desired organosilicon composition.
    Type: Grant
    Filed: March 28, 2000
    Date of Patent: September 25, 2001
    Assignee: Dow Corning Corporation
    Inventors: Michael Salvatore Ferritto, William James Schulz, Jr.
  • Patent number: 6280748
    Abstract: A cosmetic raw material possesses excellent compounding stability in cosmetic products. The cosmetic raw material is produced from a vinyl-type polymer having a carbosiloxane dendrimer structure in its side molecular chain. The cosmetic raw material is composed of the vinyl-type polymer having a carbosiloxane dendrimer structure in its side molecular chain, and a solution or a dispersion of a liquid such as a silicone oil, organic oil, alcohol, or water.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: August 28, 2001
    Assignee: Dow Corning Toray Silicone, Ltd.
    Inventors: Yoshitsugu Morita, Haruhiko Furukawa, Takayuki Aso, Tadashi Hamachi