Abstract: A process for preparing novel polymers having excellent physical properties by the polymerization of (A) a bicyclic amide acetal component and (B) a polyisocyanate component optionally with a small amount of water wherein the bicyclic amide acetal component is composed of two designated different types of bicyclic amide acetal is disclosed.
Abstract: A process for preparing novel interpolymers from mixtures of a bicyclic amide acetal, an oxazoline and a polyisocyanate and the novel polymers produced are described.
Abstract: A process for the preparation of novel polymeric products which involves the reaction of mixtures of bicyclic amide acetals and polyisocyanates with moisture is described.
Abstract: Novel polymers having excellent physical properties including heat distortion temperatures and izod impact strengths are prepared by the interaction of bicyclic amide acetals with epoxide resins and polyisocyanates.
Abstract: A process is described for the manufacture of diacyloxy aromatic hydrocarbons by the liquid phase reaction of an aromatic hydrocarbon or a monoacyloxy aromatic hydrocarbon with molecular oxygen in the presence of a carboxylic acid over a catalyst composed of a compound of palladium, a compound of antimony and a compound of at least one member selected from the group consisting of an alkali metal, chromium, zinc, antimony and tin wherein the water formed in the reaction is rapidly and continuously removed from the reaction as it forms.
Abstract: A process for the preparation of maleimide by the vapor phase oxydehydrogenation of succinimide over a heterogeneous catalyst composed of copper, phosphorous, vanadium, molybdenum and oxygen is described.
Abstract: A process for the preparation of maleimide by the vapor phase oxydehydrogenation of succinimide over an iron phosphate catalyst which may also contain one or more alkali metal and alkaline earth metal components is described.
Abstract: A process for the preparation of phenyl esters and phenol in which a feed mixture of benzene, molecular oxygen, a lower carboxylic acid and optionally water is passed over a catalyst composed of a palladium carboxylate, an antimony carboxylate and a chromium carboxylate is described.
Abstract: A process for the preparation of naphthyl or indene carboxylates by reaction of tetralin or indane with oxygen and a carboxylic acid in the presence of a catalyst comprising palladium is described.
Abstract: The oxidation process for the manufacture of acyloxy styrenes comprises contacting a compound such as styrene or ethyl benzene, a carboxylic acid and molecular oxygen in the liquid phase at an elevated temperature with a catalyst composed of palladium or a compound of palladium, and a compound of at least one member selected from the group consisting of antimony, lead, cobalt, nickel, iron, copper, zinc, chromium, tin and optionally also an alkali metal compound is described.
Abstract: The oxidation process for the manufacture of aryl esters comprising contacting the reaction mixture of an aromatic hydrocarbon, a carboxylic acid and molecular oxygen in the liquid phase at an elevated temperature with a catalyst composed of palladium or a compound of palladium, a chromium compound and a compound of at least one member selected from the group consisting of zinc, manganese, tin, cobalt and nickel is described.
Abstract: A process is described for preparing isobutyryl fluoride which involves reacting propylene, carbon monoxide and hydrogen fluoride under substantially anhydrous conditions in at least two continuous flow reaction zones, and the incremental addition of propylene and carbon monoxide to the reaction mixture at a point or points between the reaction zones.
Abstract: A process for preparing dibenzofuran by the oxidation of diphenyl ether in the presence of a carboxylic acid and a catalyst composed of a compound of palladium and at least one compound of a member selected from the group consisting of antimony, tin, cobalt, lead, zinc, chromium and potassium is described.
Abstract: The oxidation process for the manufacture of higher aryl esters comprising contacting the reaction mixture of a higher aromatic hydrocarbon, an organic solvent, a carboxylic acid and molecular oxygen in the liquid phase at an elevated temperature with a catalyst composed of palladium or a compound of palladium, an antimony compound and a compound of at least one member selected from the group consisting of alkali metals and alkaline earth metals is described.
Abstract: The conversion of a carboxylic acid having the formula RCOOH wherein R is a hydrocarbon group having from 1 to 20 carbon atoms to its corresponding anhydride by contacting said carboxylic acid with a salt of at least one metal selected from the group consisting of palladium, cobalt, manganese, chromium, nickel, copper, rhodium, iron and thorium at a temperature in the range of from about 120.degree. to 300.degree. C. is described.
Abstract: A process for converting antimony metal to an antimony (III) carboxylate by reaction with a carboxylic acid in the presence of at least one member selected from the group consisting of HNO.sub.3, NO.sub.2, NO plus O.sub.2, NOOCOR and HNO.sub.2 is described.
Abstract: A novel method for preparing soluble ##STR1## by reaction of palladium metal with a carboxylic acid of the formula RCOOH wherein R is a hydrocarbon or halogenated hydrocarbon group having from 1 to 10 carbon atoms in the presence of a member selected from the group consisting of A. HNO.sub.3 plus NO, B. HNO.sub.2, C. nitric oxide plus oxygen, D. nitric oxide plus nitrogen dioxide, E. nitrogen dioxide, and F. nitrosyl acetate, is described.
Abstract: A process is described for the manufacture of aryl esters such as phenyl esters by liquid phase reaction of an aromatic compound such as benzene with molecular oxygen in the presence of a carboxylic acid preferably having 6 or more carbon atoms over a catalyst composed essentially of a compound of palladium, a compound of antimony and a compound of at least one member selected from the group consisting of chromium, cobalt, nickel, manganese, iron, and tin wherein the aromatic compound is added continuously to the reaction and water formed in the reaction is rapidly and continuously removed from the reaction zone.