Patents Represented by Attorney John F. Sieberth
  • Patent number: 5021176
    Abstract: A friction reducing additive composition comprising a long chain succinimide derivative and a long chain amide has superior friction reducing properties, especially in wet brake systems for tractors and other vehicles.
    Type: Grant
    Filed: March 5, 1990
    Date of Patent: June 4, 1991
    Assignee: Ethyl Petroleum Additives, Limited
    Inventors: John V. Bullen, David K. Walters
  • Patent number: 5017090
    Abstract: A propeller blade having (i) a planar configuration (ii) an inner end portion, (iii) an outer end portion, (iv) a relatively sharp, outwardly swept back leading edge portion, and (v) a cylindrical stub axially aligned with the plane of the blade and affixed to the inner end portion of the blade. Also described is a mechanism that enables the pitch of the blades to be adjusted by the operator through a continuum of positions ranging from fast forward to fast reverse so that the boat can be operated at a full range and variety of speeds, can be stopped rapidly, and can be maneuvered with precision. The mechanism can be used for operating flat-bottom boats ("mud boats") in swamps, shallow water, bayous, lakes, rivers and the like, and pass through wet mud and swampy marshes choked with mud or vegetation without excessively fouling the propellers. The mechanism can be serviced and repaired easily and quickly, and can be employed to operate small craft such as mud boats with a minimum loss of interior boat space.
    Type: Grant
    Filed: February 7, 1989
    Date of Patent: May 21, 1991
    Inventor: Douglas M. Morrison
  • Patent number: 5008425
    Abstract: A process which comprises reacting under substantially anhydrous conditions a perfluoroalkyltrihydrocarbylsilane and a carbonyl compound in the presence of a catalyst such that the carbonyl compound is perfluoroalkylated.
    Type: Grant
    Filed: April 12, 1989
    Date of Patent: April 16, 1991
    Assignee: Ethyl Corporation
    Inventor: G. Patrick Stahly
  • Patent number: 5006370
    Abstract: In humid atmospheres (e.g., 55% relative humidity or above) solutions of 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride/2,2-bis [4-(aminophenoxy)phenyl]hexafluoropropane polyamic acid polymers tend to be unstable in the sense that during spin coating operations undesirable precipitate formation may occur on the rotating surface of a semiconductor wafer. The result is the formation of unacceptable coatings due to their irregularity and lack of uniformity. Described are solutions of these polyamic acid polymers in a solvent containing at least 40% by weight of one or more liquid aromatic hydrocarbons having a boiling point of at least about 110.degree. C. and at least 5% by weight of one or more dipolar aprotic solvents having a boiling point of at least about 150.degree. C.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: April 9, 1991
    Assignee: Ethyl Corporation
    Inventors: Allan A. Eisenbraun, Wesley C. Blocker
  • Patent number: 4999447
    Abstract: Olefins and metal aluminum tetraalkyls react with alkylhalosilanes to yield mixtures of tetraalkyl silanes which may be employed as functional fluids. For example, decene-1 and sodium aluminum tetraoctyl, NaAl(C.sub.8 H.sub.17).sub.4, react with dialkyldichlorosilane. The mole ratio of sodium aluminum tetraalkyl to halosilane in from about 0.5:1.0 to about 1:1, and the ratio of olefin to the metal aluminate is selected to confer in the product mixture, the desired concentration of alkyl radicals derived from the olefin.
    Type: Grant
    Filed: May 1, 1989
    Date of Patent: March 12, 1991
    Assignee: Ethyl Corporation
    Inventor: Gunner E. Nelson
  • Patent number: 4999429
    Abstract: Aryl difluoromethyl sulfone adds to aldehydes under phase transfer conditions to give novel substituted alcohols of the general formulaRCH(OH)CF.sub.2 SO.sub.2 Ar (I)wherein R is an aryl, cycloaliphatic, sec- or tert-aliphatic, or heterocyclic group and Ar is an aryl group. The substituted alcohols of formula I are of particular utility as intermediates in the synthesis of a variety of useful end products. For example, the products of formula I may be utilized in desulfonylation reactions, oxidation reactions and fluorination reactions.
    Type: Grant
    Filed: November 13, 1989
    Date of Patent: March 12, 1991
    Assignee: Ethyl Corporation
    Inventor: G. Patrick Stahly
  • Patent number: 4999070
    Abstract: By compressing and heat curing a non-resilient, non-flexible recurable material formed by subjecting cured polyimide foam to the action of pressurized steam, a wide variety of useful articles may be produced. These include tough, flame-resistant plastic films, sheets, panels, boards, and shapes in general; composites (both reinforced and unreinforced); and laminates and other articles in which separate shapes or parts are bonded together by a new type of tough, flame-resistant adhesive. Additionally, heretofore worthless products such as the kerf cut away from buns of polyimide foam during the foam manufacturing process can be converted and vastly upgraded into any of such an array of new articles of manufacture such as those just mentioned.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: March 12, 1991
    Assignee: Imi-Tech Corporation
    Inventor: Gregory A. Ferro
  • Patent number: 4997456
    Abstract: Detergent additives for reducing or preventing deposits in the carburetor or in injectors are described. They are produced by reacting (a) at least one mono- or polycarboxylic acylating agent containing an average of from about 12 to about 50 carbon atoms in the molecule and having an acyclic aliphatic group containing an average of at least 12 but less than 30 carbon atoms, with (b) at least one alkanol polyamine containing an average of at least 4 carbon atoms. Succinimides made from 2-(2-aminoethylamino)ethanol have proved especially effective in reducing carburetor deposits.
    Type: Grant
    Filed: September 11, 1989
    Date of Patent: March 5, 1991
    Assignee: Ethyl Petroleum Additives, Inc.
    Inventor: Dennis J. Malfer
  • Patent number: 4997869
    Abstract: In humid atmospheres (e.g., 40% relative humidity or above) solutions of 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride/2,2-bis[4-(aminophenoxy)phenyl]hexafluoropropane polyimides tend to be unstable in the sense that during spin coating operations undesirable precipitate formation occurs on the rotating surface of the wafer. The result is the formation of unacceptable coatings due to their irregularity and lack of uniformity. Described are solutions of these polyimide polymers in a solvent containing one or more liquid aromatic hydrocarbons having a boiling point of at least about 110.degree. C. and one or more dipolar aprotic solvents having a boiling point of at least about 150.degree. C., such that the solution (a) contains on a weight basis from about 5% to about 50% of the polyimide, and (b) does not undergo precipitate formation during spin coating in an atmosphere of at least up to about 55% relative humidity.
    Type: Grant
    Filed: October 11, 1988
    Date of Patent: March 5, 1991
    Assignee: Ethyl Corporation
    Inventors: Allan A. Eisenbraun, Wesley C. Blocker
  • Patent number: 4996254
    Abstract: In human atmospheres (e.g., 55% relative humidity or above) solutions of 2,2-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride/2,2-bis[4-(aminophenoxy)phenyl]hexafluoropropane polyamic acid polymers tend to be unstable in the sense that during spin coating operations undesirable precipitate formation may occur on the rotating surface of a semiconductor wafer. The result is the formation of unacceptable coatings due to their irregularity and lack of uniformity. Described are solutions of these polyamic acid polymers in a solvent containing one or more cycloaliphatic ketones, such that the solution (a) contains on a weight basis from about 5% to about 40% of the polyamic acid and (b) does not undergo precipitate formation during spin coating in an atmosphere of up to at least about 55% relative humidity.
    Type: Grant
    Filed: October 11, 1988
    Date of Patent: February 26, 1991
    Assignee: Ethyl Corporation
    Inventors: Allan A. Eisenbraun, Wesley C. Blocker
  • Patent number: 4994580
    Abstract: 3,3'-Thiobis(2,5-dihydrothiophene-1,1-dioxides) on heating with a reactive Diels-Alder dienophile undergo a reaction producing thioethers having two six-membered alicyclic rings in the molecule, such as 4,4'-thiobis(3,6-dihydrophthalic acids) or the esters, anhydrides or imides thereof, and 4,4'-thiobis(1,2,3,6-tetrahydrophthalic acids) or the esters, anhydrides or imides thereof. Both rings of the dihydrothiophene dioxides participate in the reaction, apparently by forming a tetraene structure which co-reacts with two equivalents of the dienophile to form an adduct in which each six-membered ring has one or two olefinic double bonds. During the course of the reaction, the thioether bridge remains intact. Some of the bis(alicyclic) thioethers are readily converted to the corresponding bis(aromatic)thioethers by use of known aromatization methods and systems. Various utilities for the products of the foregoing reactions are described.
    Type: Grant
    Filed: October 26, 1989
    Date of Patent: February 19, 1991
    Assignee: Ethyl Corporation
    Inventor: G. Patrick Stahly
  • Patent number: 4994545
    Abstract: The polyetherimides have repeating groups which may be represented by the general formula: ##STR1## They are produced from novel monomers of the formula ##STR2## Synthesis procedures for forming such monomers are also described.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: February 19, 1991
    Assignee: Ethyl Corporation
    Inventors: Gene C. Robinson, G. Patrick Stahly
  • Patent number: 4990699
    Abstract: Despite the instabity of perfluoralkyl anions, it is possible to perfluoroalkylate aromatic compounds if appropriately substituted by suitable electronegative substituents (e.g., nitro, trifluoromethylsulfonyl, etc.). Thus a novel Meisenheimer complex is formed by thermally decomposing a salt of a perfluoroalkanoic acid in the presence of an aromatic compound such as 1,3,5-trinitrobenzene. Oxidation with organic hypochlorite yields the corresponding perfluoroalkylated aromatic compound.
    Type: Grant
    Filed: October 17, 1988
    Date of Patent: February 5, 1991
    Assignee: Ethyl Corporation
    Inventor: G. Patrick Stahly
  • Patent number: 4990627
    Abstract: The polyetherimides have repeating groups which may be represented by the general formula: ##STR1## They are produced from novel monomers of the formula ##STR2## Synthesis procedures for forming such monomers are also described.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: February 5, 1991
    Assignee: Ethyl Corporation
    Inventors: Gene C. Robinson, G. Patrick Stahly
  • Patent number: 4981890
    Abstract: Described are themoplastic condensation polymers containing a polyhaloaromatic aromatic flame retardant and an aromatic bis-sulfonamide having at least two aromatic rings and from 14 to 30 carbon atoms melt flow improver. These sulfonamides are of advantage in that they have relatively low volatilities at polymer processing temperatures.
    Type: Grant
    Filed: May 23, 1989
    Date of Patent: January 1, 1991
    Assignee: Ethyl Corporation
    Inventor: Robert A. Schleifstein
  • Patent number: 4979850
    Abstract: A sleeve is axially aligned with the bore which is to be cut by a cutting bar rotated in the sleeve. The sleeve is placed and held in proper position by radially projecting brackets having holes in them. These holes are aligned with holes in a member having its holes in preselected positions remote from the axis of the bore. The sleeve also serves as a stop to prevent excessive forward or rearward longitudinal travel of the cutting bar by abutment with collars detachably secured at suitable positions on the bar.
    Type: Grant
    Filed: March 28, 1990
    Date of Patent: December 25, 1990
    Inventor: Olman Dompe
  • Patent number: 4976971
    Abstract: Interior egg quality, usually expressed in Haugh Units, is prolonged by feeding the laying poultry a diet containing zeolite A. If the feed contains a reduced chloride content, egg shell quality, egg shell thickness or egg specific gravity may be also improved, and/or the number of shell-less eggs may be reduced.
    Type: Grant
    Filed: October 24, 1988
    Date of Patent: December 11, 1990
    Assignee: Ethyl Corporation
    Inventors: Sebastian M. Laurent, Robert N. Sanders
  • Patent number: 4975280
    Abstract: A device for controlled release of one or more pharmacologically active substances within an animal which comprises (i) a body of a bioerodable solid state poly(amino acid ester) phosphazene polymer, and (ii) at least one pharmacologically active substance physically incorporated within said body. The device may comprise an implantable body in which the poly(amino acid ester)phosphazene polymer is a matrix within which such pharmacologically active substance is dispersed. Alternatively, the polymer may constitute a coating or container within which such pharmacologically active substance is physically encased--i.e., the polymer surrounds the active agent as in a capsule or in a microencapsulated form. Results of in vivo experiments using implants of poly[bis((ethyl glycino)phosphazene] containing 25% ethidium are described.
    Type: Grant
    Filed: January 23, 1989
    Date of Patent: December 4, 1990
    Assignee: Ethyl Corporation
    Inventors: Etienne Schacht, Jan Crommen
  • Patent number: D316700
    Type: Grant
    Filed: May 19, 1989
    Date of Patent: May 7, 1991
    Inventor: Douglas M. Morrison
  • Patent number: D316992
    Type: Grant
    Filed: September 6, 1988
    Date of Patent: May 21, 1991
    Inventor: Joseph S. Geeck, III