Abstract: A silver diffusion transfer film unit which comprises, in order, a support, a silver precipitating layer, a protective layer comprising chitosan having a copper salt and a polyol selected from the group consisting of glycerol, sorbitol, polyvinyl alcohol, inositol, ethylene glycol, propylene glycol and hydroxyethyl cellulose disposed therein, a release layer, and a photosensitive silver halide layer. In a particularly preferred embodiment, the film unit is an additive color diffusion transfer film unit.
Type:
Grant
Filed:
July 22, 1982
Date of Patent:
May 31, 1983
Assignee:
Polaroid Corporation
Inventors:
Michael Berger, Charles H. Byers, John J. Magenheimer
Abstract: A silver diffusion transfer film unit which comprises, in order, a support carrying a silver precipitating layer, a protective layer comprising chitosan having a copper salt and gelatin disposed therein, a release layer and a photosensitive silver halide layer. In a particularly preferred embodiment, the film unit is an additive color diffusion transfer film unit.
Abstract: A photosensitive element comprising a support carrying photosensitive silver halide grains in a substantially predetermined spaced array and methods for forming such photosensitive elements.
Abstract: A diffusion transfer film unit comprising a support, a photosensitive silver halide emulsion layer, an image-receiving layer and, intermediate said silver halide emulsion layer and said image-receiving layer, a release layer which comprises a water-soluble polymer and a styrenated acid functional acrylic resin. In a preferred embodiment, the film unit is a silver diffusion transfer film unit.
Abstract: A stripping sheet adapted for use with a diffusion transfer film unit to remove at least the photosensitive layer from said film unit subsequent to processing is disclosed, as well as methods for using said stripping sheet, wherein said stripping sheet comprises a support, carrying in order, a water-absorbing layer, and a layer capable of conversion from substantial liquid processing composition impermeability to a condition of substantial liquid processing composition permeability.
Type:
Grant
Filed:
June 26, 1981
Date of Patent:
November 16, 1982
Assignee:
Polaroid Corporation
Inventors:
Raymond B. Hanselman, Karl J. Schreiber
Abstract: A photosensitive silver halide element comprising a support carrying single effective silver halide grains in a predetermined spaced array is prepared by coalescing fine-grain silver halide in a plurality of spaced depressions in a surface by melting said fine-grain silver halide.
Abstract: A method for forming a photosensitive element comprising a plurality of single effective silver halide grains in a predetermined spaced array which comprises coalescing a fine-grain silver halide emulsion in a plurality of predetermined spaced depressions in a surface, wherein said coalescence is carried out by contacting said fine-grain emulsion with a silver halide solvent in the vapor phase.
Abstract: A method for forming a photosensitive element comprising a plurality of single effective siler halide grains in a predetermined spaced array which comprises coalescing fine-grain silver halide in a plurality of predetermined spaced depressions in a surface, thereby forming in situ a single effective silver halide grain in each of said depressions and a photosensitive element comprising coalesced single effective silver halide grains in a predetermined spaced array.
Abstract: A photosensitive silver halide element comprising a support carrying photosensitive silver halide grains in a predetermined spaced array is prepared by a method which comprises at least partially coalescing fine-grain silver halide in a plurality of spaced depressions in a hydrophobic layer, superposing said layer with a hydrophilic layer during or subsequent to said coalescence, and then separating said hydrophilic layer and said hydrophobic layer whereby said coalesced silver halide grains are retained on said hydrophilic layer in a pattern corresponding substantially to the pattern of said spaced depressions.
Type:
Grant
Filed:
September 2, 1981
Date of Patent:
October 12, 1982
Assignee:
Polaroid Corporation
Inventors:
Arthur M. Gerber, Warren D. Slafer, Vivian K. Walworth
Abstract: A fine-grain emulsion in a plurality of predetermined spaced depressions is coalesced to form, in situ, a plurality of single effective silver halide grains in a predetermined spaced array by the action of a solution of a silver halide solvent containing a dissolved silver salt.
Abstract: The present invention is directed to photosensitive elements and to diffusion transfer film units employing said elements wherein said photosensitive element includes a plurality of essential layers, including a first photosensitive silver halide layer and a second photosensitive silver halide layer, said first and second silver halide layers being sensitized to substantially the same spectral absorption range; a spacer layer intermediate and contiguous to said first and second silver halide layers, said spacer layer consisting essentially of inert particles which are substantially non-swelling in alkali, and substantially non-film forming; wherein said inert particles are equal to or less than the average diameter of the silver halide grains in said first and second silver halide layers and wherein said silver halide grains are 2.
Abstract: Photosensitive silver halide emulsion layers are formed by mixing a solution of a water-soluble complex of silver ion with a polymeric thickening agent, applying the thus formed mixture to a permeable substrate and crystallizing photosensitive silver halide grains therein by decomplexation of said silver halide complex within the layer.
Abstract: Monodisperse, negative working photosensitive silver halide emulsions comprising grains having a uniform habit and relatively high degree of crystal disorder are prepared by precipitating silver halide in the presence of a seed emulsion which is predominantly silver chloride under conditions whereby substantially none of the silver chloride of said seed emulsion is redissolved and substantially no additional grains are formed.
Abstract: Narrow grain size distribution silver halide emulsions are prepared by:1. Forming photosensitive silver halide grains in the presence of a water-soluble thiocyanate compound with a halide/silver molar ratio ranging from not more than about 5% molar excess of halide to not more than about a 25% molar excess of silver; and2. Growing said grains in the presence of said water-soluble thiocyanate compound for a time sufficient to grow said grains to a predetermined grain size distribution.
Abstract: Photosensitive silver halide emulsions are provided with enhanced stability by the following sequence of steps:(a) providing sufficient stabilizer to the emulsion to stop chemical ripening but insufficient to interfere with spectral sensitization;(b) spectrally sensitizing said emulsion; and(c) adding to said emulsion a water soluble bromide salt, 1-phenyl-5-mercaptotetrazole; and a stabilizer selected from the group consisting of an hydroxy triazaindene, an amino triazaindene, an hydroxy tetrazaindene, an amino tetrazaindene, an hydroxy pentazaindene and an amino pentazaindene.
Abstract: A processing composition adapted for use in a silver diffusion transfer process which includes a saturated polyol containing at least 3 hydroxyl groups wherein each hydroxyl group is no more than 3 carbon atoms away from another hydroxyl group.
Abstract: A receiving element for use in an additive color photographic diffusion transfer process which comprises a transparent support carrying an additive color screen and a layer comprising noble metal silver precipitating nuclei and a polymer; wherein said nuclei are present in a level of about 0.1-0.3 mgs/ft.sup.2, and said polymer is present at a level of from about 0.5 to 5 times the coverage of said nuclei. Preferably, the noble metal is obtained by reduction of a noble metal salt or complex, and more preferably, the noble metal is palladium.
Abstract: Photosensitive silver halide emulsions for use in diffusion transfer processes are stabilized without adversely affecting spectral sensitization by the following steps: (a) spectrally sensitizing the silver halide grains; (b) lowering the pH of the emulsion from a first pH of the emulsion subsequent to chemical ripening to a pH of about 5.5 to 4.0 and/or increasing the Br ion/Ag ratio to at least 5 mg Br ion/gAg and, subsequent to steps (a) and (b), (c) adding 5-80 mg/gAg to said emulsion of a stabilizer selected from the group consisting of an hydroxy triazaindene, an amino triazaindene, an hydroxy tetrazaindene, an amino tetrazaindene, an hydroxy pentazaindene and an amino pentazaindene.
Type:
Grant
Filed:
February 15, 1980
Date of Patent:
November 24, 1981
Assignee:
Polaroid Corporation
Inventors:
T. Nelson Baker, III, Bernard Zuckerman
Abstract: Silver-precipitating nuclei are prepared by partially oxidizing a stannous salt reducing agent with potassium, sodium or ammonium dichromate and then reducing a noble metal salt or complex with said reducing agent.
Abstract: Silver-precipitating nuclei are prepared by partially oxidizing a stannous salt reducing agent with a ferric oxidizing agent and then reducing a noble metal salt or complex with said reducing agent.