Patents Represented by Attorney Richard C. Willson, Jr.
  • Patent number: 4842903
    Abstract: Corrosion preventives, e.g. for automobiles, comprise sepiolite clays with waxes, sulfonates e.g. SACI, optional solvents, oils, soaps provide high viscosity, high solids, corrosion-preventatives. Application can be by hot spray or hot melt, hot dipping, and other standard techniques. The sepiolite clays provide excellent anti-sag capabilities to the dry films without excessively increasing the viscosity of the coating material. Conventional thixatropes such as bentonites and other common organo clays usually drastically increase product viscosity and complicate pumping at room temperature.
    Type: Grant
    Filed: April 12, 1988
    Date of Patent: June 27, 1989
    Assignee: Ashland Oil, Inc.
    Inventor: Roger E. Hayner
  • Patent number: 4831759
    Abstract: A wrap around valance system physically mounted to the top of a convenience store interior wall system, beneath the ceiling, is formed of end abutting, horizontally aligned, standard size interchangeable illuminated and non-illuminated modules of fabricated sheet metal formed with open front windows slidably mounting respectively, color display photo panels and color graphic decor panels. The non-illuminated modules have at least two sets of top and bottom facing open ended horizontal slots so that a color graphic display card may be superimposed over the color graphic decor panel to display temporary or seasonal information. A continuous wiring system is formed within the end to end coupled modules with electrical junction boxes mounted, respectively to opposite end walls of each illuminated module leading to a fluorescent lamp mounted internally of the illuminated module housings for backlighting of the photo panels.
    Type: Grant
    Filed: January 12, 1988
    Date of Patent: May 23, 1989
    Assignee: Ashland Oil, Inc.
    Inventor: Richard E. Hosey
  • Patent number: 4822761
    Abstract: A process for upgrading residual portions of crude oils comprising metal contaminants and Conradson Carbon contributing components by the combination of thermal visbreaking with fluid inert solids and catalytic upgrading of naphtha and higher boiling components of thermal visbreaking in separate systems of riser conversion and solids regeneration is discussed. Heat management of the regeneration systems is restricted in substantial measure by a novel external solids heat exchange apparatus arrangement utilized to partially cool hot regenerated solids utilized in the solids regeneration systems.
    Type: Grant
    Filed: December 21, 1987
    Date of Patent: April 18, 1989
    Assignee: Ashland Oil, Inc.
    Inventors: Paul W. Walters, Lloyd E. Busch, Oliver J. Zandona
  • Patent number: 4816195
    Abstract: A large number of melt blown carbon fibers from petroleum pitch through a multi-orifice die under continuous formation, are fed onto the periphery of a continuously moving endless conveyor surface whose surface speed is matched to the linear velocity of the melt blown carbon fibers to cause the fibers to be deposited in parallel alignment on the conveyor surface and to be maintained in fiber axial alignment to form a non-woven mat of aligned carbon fibers. The speed of the conveyor surface may be slightly less than the linear speed of the fibers to form a loose fiber mat to facilitate subsequent fiber oxidation and carbonization by permitting gas flow through the aligned fiber mat. The endless conveyor may comprise a cylindrical drum whose surface is perforated to facilitate gas flow and oxidation of the carbon fibers subsequent to non-woven mat formation.
    Type: Grant
    Filed: December 15, 1986
    Date of Patent: March 28, 1989
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., Larry D. Veneziano
  • Patent number: 4793827
    Abstract: A hydrocarbon cracking catalyst comprises rare earth exchanged "Y" zeolite which has been ion exchanged to enhance the yttrium content. The catalyst is employed in fluid catalytic cracking to maximize gasoline.
    Type: Grant
    Filed: February 24, 1987
    Date of Patent: December 27, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Charles F. Lochow, Daniel B. Kovacs
  • Patent number: 4792437
    Abstract: An apparatus for separating solids and vapors from a suspension of the two materials is disclosed. The solids are directed through a conoid element to enhance directional flow and to prevent return of solids to the separation apparatus.
    Type: Grant
    Filed: September 4, 1986
    Date of Patent: December 20, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., Steven W. Murray, Ricky L. Adkins, Billy T. Fritz, James R. Riggs, Paul W. Walters
  • Patent number: 4786400
    Abstract: A dual riser cracking operation in combination with sequential stages of catalyst regeneration in which the second regeneration stage is a riser regenerator is described in combination with deep solvent deasphalting a vacuum resid. The deasphalted resid is subjected to hydrogenation treatment prior to cracking thereof in a riser cracking zone in admixture with a heavy vacuum gas oil which may or may not be hydrogenated prior to cracking thereof. Lower boiling fractions of the crude oil are subjected to catalytic cracking in a separate riser cracking zone. Partially regenerated catalyst of dense fluid bed regeneration may be employed in the heavy oil feed riser cracking operation charged with deasphalted oil. The partially regenerated catalyst may be used alone or in combination with more completely regenerated catalyst of the riser regeneration operation.
    Type: Grant
    Filed: September 10, 1984
    Date of Patent: November 22, 1988
    Inventor: Carl D. Farnsworth
  • Patent number: 4786622
    Abstract: A method and arrangement of apparatus employed is described for regenerating solid particles comprising carbonaceous deposits. At least three sequential stages of separation of flue gases from entrained solids are provided in association with an upflow catalyst regeneration operation.
    Type: Grant
    Filed: January 9, 1984
    Date of Patent: November 22, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Paul W. Walters, William M. Rice
  • Patent number: 4782808
    Abstract: Plugging of fuel injectors for internal combustion engines is reduced by depressurizing the fuel pressure line which feeds the injectors, promptly after shutoff of ignition. Reduction of deposite assists in maintaining drivability and fuel economy.
    Type: Grant
    Filed: August 13, 1986
    Date of Patent: November 8, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Giles L. Bostick, Carlton H. Jewitt, Victor L. Kersey
  • Patent number: 4780109
    Abstract: Disclosed is a composition and method from making coal water slurries containing carbon black. A composition disclosed comprises: 65 to 85% by weight coal particulates; 0.2 to 2% by weight, based on the total weight of dry coal, of carbon black, and optionally 0.2 to 2% by weight, based on the total weight of the dry coal, of a dispersant.
    Type: Grant
    Filed: December 24, 1986
    Date of Patent: October 25, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Donald P. Malone, David G. Thompson
  • Patent number: 4780195
    Abstract: The invention is particularly concerned with controlling the two stage regeneration temperatures of the RCC residual oil cracking unit below 760.degree. C. (1400.degree. F.) by effecting a first stage regeneration with direct injection of water in an oxygen lean atmosphere to product CO rich flue gases under temperature conditions restricted not to substantially exceed 732.degree. C. (1350.degree. F.) preferably less than 732.degree. C. (1350.degree. F.) thereby partially regenerating the catalyst. The partially regenerated catalyst is withdrawn and directly cooled with boiler feed water to produce steam in an external catalyst cooler before passing the catalyst to a second stage catalyst regeneration for contact with an oxygen rich atmosphere restricted not to exceed 760.degree. C. (1400.degree. F.) and preferably maintain less than 760.degree. C. (1400.degree. F.). The catalyst regenerated by this technique comprising residual coke less than 0.
    Type: Grant
    Filed: July 25, 1983
    Date of Patent: October 25, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Charles B. Miller
  • Patent number: 4753907
    Abstract: Solids e.g. catalysts are separated from suspensions in gases e.g. products from catalytic cracking of crude oil fractions a discharging of suspensions against a surface positioned above the outlet of a riser conduit through which the suspensions are flowing and collecting the displaced gases for passage to cyclones.
    Type: Grant
    Filed: September 20, 1985
    Date of Patent: June 28, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Oliver J. Zandona, Paul W. Walters, Roger M. Benslay
  • Patent number: 4750987
    Abstract: A process is disclosed for the conversion of a hydrocarbon oil feed having a significant content of vanadium to lighter oil products by contacting the feed under conversion conditions in a conversion zone with a catalyst containing a metal additive to immobilize vanadium compounds. Conversion conditions are such that coke and vanadium are deposited on the catalyst in the conversion zone. Coked catalyst is regenerated in the presence of an oxygen containing gas at a temperature sufficient to remove the coke and regenerated catalyst is recycled to the conversion zone for contact with fresh feed. The metal additive is present on the catalyst in an amount sufficient to immobilize the vanadium compounds in the presence of oxygen containing gas at the catalyst regeneration temperature.
    Type: Grant
    Filed: November 7, 1986
    Date of Patent: June 14, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: H. Wayne Beck, James D. Carruthers, Edward B. Cornelius, William P. Hettinger, Jr., Stephen M. Kovach, James L. Palmer, Oliver J. Zandona
  • Patent number: 4750964
    Abstract: A large number of melt blown carbon fibers from petroleum pitch through a multi-orifice die under continuous formation, are fed onto the periphery of a continuously moving endless conveyor surface whose surface speed is matched to the linear velocity of the melt blown carbon fibers to cause the fibers to be deposited in parallel alignment on the conveyor surface and to be maintained in fiber axial alignment to form a non-woven mat of aligned carbon fibers. The speed of the conveyor surface may be slightly less than the linear speed of the fibers to form a loose fiber mat to facilitate subsequent fiber oxidation and carbonization by permitting gas flow through the aligned fiber mat. The endless conveyor may comprise a cylindrical drum whose surface is perforated to facilitate gas flow and oxidation of the carbon fibers subsequent to non-woven mat formation.
    Type: Grant
    Filed: March 13, 1986
    Date of Patent: June 14, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: William P. Hettinger, Jr., Larry D. Veneziano
  • Patent number: 4748055
    Abstract: Self-healing coatings are formed by first phosphating or nitriding ferrous parts, then coating with an emulsion of e.g. polysiloxane, oil, sorbitan derivative and sodium sulfonate, butyl cellosolve, oleic acid. Preferred phosphating is to a thickness of 2,000-3,000 mg Zn phosphate/square foot. This coating passes 240-plus hours in 5% salt spray (ASTM B-117) and resists wash off with car wash soap.
    Type: Grant
    Filed: October 22, 1986
    Date of Patent: May 31, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Perry E. Landers, George F. Felton, Richard L. Williams
  • Patent number: 4744883
    Abstract: In a reduced crude conversion the catalyst is regenerated with mixture of oxygen-enriched gas and H.sub.2 O either as steam or preferably as water to provide additional expansion and facilitate fluidization, while converting coke on catalyst to CO and H.sub.2 with minimum CO.sub.2 formation. The CO can be combined with hydrogen to produce methane, methanol or Fischer-Tropsch liquid hydrocarbons or can be passed through the reduced crude conversion operation as lift gas, or as cooling medium or subjected to water-gas shift to produce additional H.sub.2.
    Type: Grant
    Filed: June 16, 1986
    Date of Patent: May 17, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4728416
    Abstract: A process is disclosed for the catalytic cracking of gas oils with an additional nickel and vanadium metals-containing heavy feedstock. Included is regeneration of the catalyst by burning off coke.
    Type: Grant
    Filed: April 28, 1981
    Date of Patent: March 1, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: George D. Myers, deceased
  • Patent number: 4720477
    Abstract: An H-Coal Process hydrogenation operation and catalyst life is substantially improved when using colloidal particles of catalyst comprising a colloidal matrix of silica, alumina, titania and combinations thereof coated with hydrogenating components selected from cobalt, molybdenum, nickel, tungsten and combinations thereof. The colloidal catalyst activity may be altered by alkaline promoters, other metals and acidic promoters.
    Type: Grant
    Filed: July 23, 1986
    Date of Patent: January 19, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: William P. Hettinger, Jr.
  • Patent number: 4716958
    Abstract: An apparatus for upgrading residual portions of crude oils comprising metal contaminants and Conradson Carbon contributing components by the combination of thermal visbreaking with fluid inert solids and catalytic upgrading of naphtha and higher boiling components of thermal visbreaking in separate systems of riser conversion and solids regeneration includes an external solids heat exchange apparatus arrangement utilized to partially cool hot regenerated solids utilized in the solids regeneration systems.
    Type: Grant
    Filed: April 18, 1985
    Date of Patent: January 5, 1988
    Assignee: Ashland Oil, Inc.
    Inventors: Paul W. Walters, Lloyd E. Busch, Oliver J. Zandona
  • Patent number: D296667
    Type: Grant
    Filed: August 28, 1985
    Date of Patent: July 12, 1988
    Assignee: Ashland Oil, Inc.
    Inventor: Robert E. Salter